JP2003250417A - Thermal evaporation method and thermal evaporation container used therefor - Google Patents
Thermal evaporation method and thermal evaporation container used thereforInfo
- Publication number
- JP2003250417A JP2003250417A JP2002141087A JP2002141087A JP2003250417A JP 2003250417 A JP2003250417 A JP 2003250417A JP 2002141087 A JP2002141087 A JP 2002141087A JP 2002141087 A JP2002141087 A JP 2002141087A JP 2003250417 A JP2003250417 A JP 2003250417A
- Authority
- JP
- Japan
- Prior art keywords
- drug substance
- insecticidal
- container
- heating
- insecticidal drug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract description 16
- 238000002207 thermal evaporation Methods 0.000 title abstract 7
- 238000001704 evaporation Methods 0.000 claims abstract description 106
- 239000000654 additive Substances 0.000 claims abstract description 12
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 11
- 230000000996 additive effect Effects 0.000 claims abstract description 7
- 230000000749 insecticidal effect Effects 0.000 claims description 132
- 238000010438 heat treatment Methods 0.000 claims description 101
- 229940088679 drug related substance Drugs 0.000 claims description 92
- 239000008186 active pharmaceutical agent Substances 0.000 claims description 91
- 230000008020 evaporation Effects 0.000 claims description 77
- 239000007788 liquid Substances 0.000 claims description 37
- 239000002917 insecticide Substances 0.000 abstract description 30
- 239000000126 substance Substances 0.000 abstract description 24
- 239000002904 solvent Substances 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 abstract description 6
- 241000238631 Hexapoda Species 0.000 abstract description 4
- 239000003125 aqueous solvent Substances 0.000 abstract 1
- -1 d-T80-phthalthrin Chemical compound 0.000 description 23
- 238000012360 testing method Methods 0.000 description 12
- 239000004743 Polypropylene Substances 0.000 description 11
- 229920001155 polypropylene Polymers 0.000 description 11
- 229920000139 polyethylene terephthalate Polymers 0.000 description 10
- 239000005020 polyethylene terephthalate Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 229940079593 drug Drugs 0.000 description 9
- 239000003814 drug Substances 0.000 description 9
- 230000005068 transpiration Effects 0.000 description 8
- 230000001276 controlling effect Effects 0.000 description 7
- 238000002347 injection Methods 0.000 description 7
- 239000007924 injection Substances 0.000 description 7
- 239000000565 sealant Substances 0.000 description 7
- 241000255925 Diptera Species 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 235000006708 antioxidants Nutrition 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 238000010030 laminating Methods 0.000 description 5
- 229920000092 linear low density polyethylene Polymers 0.000 description 5
- 239000004707 linear low-density polyethylene Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 239000002781 deodorant agent Substances 0.000 description 4
- 239000003623 enhancer Substances 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 241000238876 Acari Species 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229920006015 heat resistant resin Polymers 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000005026 oriented polypropylene Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- MRBKEAMVRSLQPH-UHFFFAOYSA-N 3-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1 MRBKEAMVRSLQPH-UHFFFAOYSA-N 0.000 description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- UEKQGZQLUMSLNW-UHFFFAOYSA-N Propyl isome Chemical compound C1=C2C(C(=O)OCCC)C(C(=O)OCCC)C(C)CC2=CC2=C1OCO2 UEKQGZQLUMSLNW-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 2
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 2
- 229940043350 citral Drugs 0.000 description 2
- 229930003633 citronellal Natural products 0.000 description 2
- 235000000983 citronellal Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- HXTCWLNZDIPLCA-UHFFFAOYSA-N dodecanoic acid;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CCCCCCCCCCCC(O)=O HXTCWLNZDIPLCA-UHFFFAOYSA-N 0.000 description 2
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- WLLGXSLBOPFWQV-OTHKPKEBSA-N molport-035-783-878 Chemical compound C([C@H]1C=C2)[C@H]2C2C1C(=O)N(CC(CC)CCCC)C2=O WLLGXSLBOPFWQV-OTHKPKEBSA-N 0.000 description 2
- IZJDOKYDEWTZSO-UHFFFAOYSA-N phenethyl isothiocyanate Chemical compound S=C=NCCC1=CC=CC=C1 IZJDOKYDEWTZSO-UHFFFAOYSA-N 0.000 description 2
- 229960005235 piperonyl butoxide Drugs 0.000 description 2
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229960005199 tetramethrin Drugs 0.000 description 2
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 2
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- KSNRDYQOHXQKAB-UHFFFAOYSA-N 2,2,4-trimethyl-3,4-dihydro-1h-quinoline Chemical compound C1=CC=C2C(C)CC(C)(C)NC2=C1 KSNRDYQOHXQKAB-UHFFFAOYSA-N 0.000 description 1
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 1
- SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- ROHFBIREHKPELA-UHFFFAOYSA-N 2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]prop-2-enoic acid;methane Chemical compound C.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O ROHFBIREHKPELA-UHFFFAOYSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- IMOYOUMVYICGCA-UHFFFAOYSA-N 2-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C=C1C(C)(C)C IMOYOUMVYICGCA-UHFFFAOYSA-N 0.000 description 1
- GPNYZBKIGXGYNU-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol Chemical compound CC(C)(C)C1=CC(CC)=CC(CC=2C(=C(C=C(CC)C=2)C(C)(C)C)O)=C1O GPNYZBKIGXGYNU-UHFFFAOYSA-N 0.000 description 1
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 1
- FCDMUZZVRLCTLQ-UHFFFAOYSA-N 4-[1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C FCDMUZZVRLCTLQ-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- UXKQNCDDHDBAPD-UHFFFAOYSA-N 4-n,4-n-diphenylbenzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 UXKQNCDDHDBAPD-UHFFFAOYSA-N 0.000 description 1
- YLDDCEXDGNXCIO-UHFFFAOYSA-N 6-ethoxy-2,2,4-trimethyl-3,4-dihydro-1h-quinoline Chemical compound N1C(C)(C)CC(C)C2=CC(OCC)=CC=C21 YLDDCEXDGNXCIO-UHFFFAOYSA-N 0.000 description 1
- 206010004194 Bed bug infestation Diseases 0.000 description 1
- 239000005874 Bifenthrin Substances 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- 241000255930 Chironomidae Species 0.000 description 1
- 241001414835 Cimicidae Species 0.000 description 1
- 241000254171 Curculionidae Species 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- YUGWDVYLFSETPE-JLHYYAGUSA-N Empenthrin Chemical compound CC\C=C(/C)C(C#C)OC(=O)C1C(C=C(C)C)C1(C)C YUGWDVYLFSETPE-JLHYYAGUSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241000238711 Pyroglyphidae Species 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 description 1
- 229940087168 alpha tocopherol Drugs 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 210000000038 chest Anatomy 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 239000004318 erythorbic acid Substances 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 229940046533 house dust mites Drugs 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- KBHDSWIXRODKSZ-UHFFFAOYSA-N methyl 5-chloro-2-(trifluoromethylsulfonylamino)benzoate Chemical compound COC(=O)C1=CC(Cl)=CC=C1NS(=O)(=O)C(F)(F)F KBHDSWIXRODKSZ-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Landscapes
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、室内などで害虫防
除のために使用される加熱蒸散方法およびこれに使用す
る加熱蒸散容器に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat evaporation method used for controlling pests indoors and the like, and a heat evaporation container used for the method.
【０００２】[0002]
【従来の技術】従来、害虫防除のための加熱蒸散方法と
しては、吸液芯を用いて殺虫液剤を吸上げ加熱蒸散させ
る方法や、繊維板等の多孔質基材（固形マット）に吸着
させた殺虫剤を加熱して蒸散させる方法等が知られてい
る。2. Description of the Related Art Conventionally, as a heating evaporation method for controlling pests, a method of absorbing an insecticide liquid by using an absorbent core and heating it to evaporate, or adsorbing it on a porous base material (solid mat) such as a fiber board is used. It is known that the insecticide is heated and evaporated.
【０００３】前者の場合、殺虫剤を溶液形態で使用する
ため、水を加えた製剤では、揮散安定性が悪く、薬剤を
長時間蒸散させるのには向いていなかった。後者のマッ
ト方式の場合、無溶剤型ではあるが、薬剤の残存率が高
く安定した長期の揮散は望めなかった。In the former case, since the insecticide is used in the form of a solution, the formulation containing water has poor volatilization stability and is not suitable for evaporating the drug for a long time. In the case of the latter mat type, although it is a solvent-free type, the residual ratio of the drug is high and stable long-term volatilization cannot be expected.
【０００４】[0004]
【発明が解決しようとする課題】本発明の目的は、薬剤
を効率よく揮散できる加熱蒸散方法およびこれに使用す
る加熱蒸散容器を提供することである。SUMMARY OF THE INVENTION An object of the present invention is to provide a heating evaporation method capable of efficiently evaporating a drug and a heating evaporation container used for the method.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、上記課題
を解決すべく鋭意研究を重ねた結果、敢えて殺虫原体を
加熱すると、水を加えた殺虫液を使用するより、極めて
効率よく揮散させることができ、安定した長期の揮散が
可能になるという新たな事実を見出し、本発明を完成す
るに至った。また、本発明では、殺虫原体を加熱蒸散さ
せるため、加熱蒸散時に溶剤を使用せず、従って液剤の
ように水性・油性を区別する必要性もなくなり、容器や
器具もコンパクトになる。Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventors have found that when the insecticidal drug substance is intentionally heated, it is much more efficient than when an insecticidal solution containing water is used. The inventors have found the new fact that they can be volatilized and can be stably volatilized for a long period of time, and completed the present invention. Further, in the present invention, since the insecticidal drug substance is evaporated by heating, a solvent is not used at the time of evaporation by heating, so that it is not necessary to distinguish between aqueous and oily substances like a liquid agent, and the container and the device are compact.
【０００６】すなわち、本発明の加熱蒸散方法は、害虫
防除のための方法であって、殺虫原体またはこれに添加
剤を含有した添加殺虫原体を加熱して、蒸散させること
を特徴とする。That is, the heat evaporation method of the present invention is a method for controlling insect pests, and is characterized in that an insecticidal drug substance or an added insecticidal drug substance containing an additive is heated and evaporated. .
【０００７】本発明における殺虫原体とは、溶剤を含ま
ない殺虫剤成分自体をいい、２種以上の殺虫剤成分を混
合したものであってもよい。殺虫原体は、殺虫剤成分自
体であるから、無溶剤型の殺虫マットは本発明に含まれ
ない。また、本発明における添加殺虫原体とは、前記殺
虫原体に安定剤、酸化防止剤、紫外線防止剤、着色剤な
どを添加したものをいう。The insecticidal drug substance in the present invention means an insecticide component itself containing no solvent, and may be a mixture of two or more insecticide components. Since the insecticidal drug substance is the insecticide component itself, the solventless insecticidal mat is not included in the present invention. In addition, the term "added insecticidal drug substance" as used in the present invention refers to the above-mentioned insecticidal drug substance to which a stabilizer, an antioxidant, an anti-UV agent, a colorant and the like have been added.
【０００８】本発明の加熱蒸散方法では、前記殺虫原体
または添加殺虫原体を容器内に収容し、この容器を加熱
することによって、前記殺虫原体または添加殺虫原体を
蒸散させるのが好ましい。In the heat evaporation method of the present invention, it is preferable that the insecticidal drug substance or the added insecticidal drug substance is contained in a container and the container is heated to evaporate the insecticidal drug substance or the added insecticidal drug substance. .
【０００９】本発明の加熱蒸散方法では、ガス透過性フ
ィルムが前記殺虫原体または添加殺虫原体の液面に接触
した状態で、前記殺虫原体または添加殺虫原体を蒸散さ
せることもできる。これにより、殺虫成分の揮散量を高
めることができる。In the heat evaporation method of the present invention, the insecticidal drug substance or the added insecticidal drug substance may be evaporated while the gas permeable film is in contact with the liquid surface of the insecticidal drug substance or the added insecticidal drug substance. Thereby, the volatilization amount of the insecticidal component can be increased.
【００１０】本発明の加熱蒸散方法では、殺虫原体また
は添加殺虫原体の液面が蒸散空間中に開放されている状
態で、殺虫原体または添加殺虫原体を蒸散させることも
できる。これにより、殺虫成分の揮散量を高めることが
できる。ここで、「蒸散空間」とは、本発明の加熱蒸散
方法により害虫の防除を行う空間をいい、例えば家庭内
の居室、台所などの空気雰囲気中をいう。In the heat evaporation method of the present invention, the insecticidal drug substance or the added insecticidal drug substance can be evaporated while the liquid surface of the insecticidal drug substance or the added insecticidal drug substance is open in the evaporation space. Thereby, the volatilization amount of the insecticidal component can be increased. Here, the "transpiration space" means a space for controlling harmful insects by the heating evaporation method of the present invention, for example, in the air atmosphere of a living room in the home, a kitchen or the like.
【００１１】上記のような本発明の加熱蒸散方法に使用
する加熱蒸散容器としては、殺虫原体またはこれに添加
剤を含有した添加殺虫原体を収容した容器本体と、この
容器本体の蒸散口を塞ぐガス透過性フィルムとを備えた
ものや、殺虫原体またはこれに添加剤を含有した添加殺
虫原体を収容した容器本体と、少なくとも加熱蒸散時に
前記殺虫原体または添加殺虫原体の液面に接触するガス
透過性フィルムとを備えたもの等を使用することができ
る。As the heating evaporation container used in the above-described heating evaporation method of the present invention, a container body containing the insecticidal drug substance or the added insecticidal drug substance containing an additive therein, and the evaporation port of the container body. With a gas permeable film for closing the, insecticidal drug substance or a container body containing an added insecticidal drug substance containing an additive thereto, and a liquid of the insecticidal drug substance or the added insecticidal drug substance at least during heat evaporation. Those provided with a gas permeable film that contacts the surface can be used.
【００１２】[0012]
【発明の実施の形態】本発明において使用可能な殺虫原
体としては、加熱により蒸散し、害虫に対して防除効果
を示すものであればよい。このような殺虫原体として
は、例えばトランスフルスリン、「Ｓ−１２６４」（住
友化学工業（株））、ベーパースリン、フラメトリン、
d-T80-フラメトリン、エムペントリン、フェノトリン、
レスメトリン、フタルスリン、d-T80-フタルスリン、
（１Ｓ）−１−エチニル−２−メチル−２−ペンテニル
−（１Ｒ）−トランス−３−（２，２−ジクロロエテニ
ル）−２，２−ジメチルシクロプロパンカルボキシラー
ト（以下、化合物Ａという。）、１−エチニル−２−メ
チル−２−ペンテニル−３−（２，２−ジクロロエテニ
ル）−２，２−ジメチルシクロプロパンカルボキシラー
ト（以下、化合物Ｂという。）、およびこれらの異性
体、さらにビフェントリン、フェンフェノクスロン、ア
ミドフルメットなどが挙げられるが、これらに限定され
るものではない。また、殺虫原体の性状は液体、固体の
いずれでもよいが、液体であるのが好ましい。液体の場
合、殺虫原体の蒸気圧は４.８×１０-6（２５℃）ｍｍ
Ｈｇ以上、好ましくは４.８×１０-6〜６．０×１０-3
（２５℃）ｍｍＨｇであるのがよい。BEST MODE FOR CARRYING OUT THE INVENTION The insecticidal drug substance that can be used in the present invention may be any insecticidal drug substance that is evaporated by heating and exhibits a controlling effect against harmful insects. Examples of such insecticidal solids include transfluthrin, "S-1264" (Sumitomo Chemical Co., Ltd.), vaporthrin, flamethrin,
d-T80-flamethrin, empentrin, phenothrin,
Resmethrin, phthalthrin, d-T80-phthalthrin,
(1S) -1-Ethynyl-2-methyl-2-pentenyl- (1R) -trans-3- (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as compound A) , 1-ethynyl-2-methyl-2-pentenyl-3- (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as compound B), and isomers thereof, and further bifenthrin. , Fenfenoxuron, amidoflumet, and the like, but are not limited thereto. The insecticidal drug substance may be liquid or solid, but is preferably liquid. In the case of liquid, the vapor pressure of insecticide is 4.8 × 10 -6 (25 ° C) mm
Hg or more, preferably 4.8 × 10 −6 to 6.0 × 10 −3
(25 ° C.) mmHg is preferable.
【００１３】本発明における添加殺虫原体に添加される
添加剤としては、安定剤、酸化防止剤、紫外線防止剤、
着色剤などが挙げられ、必要に応じてそれらの１種また
は２種以上を添加する。The additives to be added to the added insecticidal drug substance in the present invention include stabilizers, antioxidants, anti-UV agents,
Colorants and the like can be mentioned, and one or more of them are added as necessary.
【００１４】酸化防止剤としては、例えば３,５−ジ−
ｔ−ブチル−４−ヒドロキシトルエン、３−ｔ−ブチル
−４−ヒドロキシアニソール、３,５−ジ−ｔ−ブチル
−４−ヒドロキシアニソール、メルカプトベンズイミダ
ゾール、ジラウリル−チオ−ジ−プロピオネート、２−
ｔ−ブチル−４−メトキシフェノール、３−ｔ−ブチル
−４−メトキシフェノール、２,６−ジ−ｔ−ブチル−
４−エチルフェノール、ステアリル−β−（３,５−ジ
−t−ブチル−４−ヒドロキシフェニル）プロピオネー
ト、α−トコフェロール、アスコルビン酸、エリソルビ
ン酸、２,２‘−メチレン−ビス(６−ｔ−ブチル−４−
メチルフェノール)、２,２‘−メチレン−ビス（６−ｔ
−ブチル−４−エチルフェノール)、４,４‘−メチレン
−ビス（２,６−ジ−ｔ−ブチルフェノール）、４,４
‘−ブチリデン−ビス(６−ｔ−ブチル−３−メチルフ
ェノール)、４,４‘−チオ−ビス（６−ｔ−ブチル−３
−メチルフェノール)、１,１−ビス（４−ヒドロキシフ
ェニル）シクロヘキサン、１,３,５−トリメチル−２，
４，６−トリス(３、５−ジ−ｔ−ブチル−４−ヒドロ
キシベンジル)ベンゼン、トリス(２−メチル−４−ヒド
ロキシ−５−ｔ−ブチルフェニル)ブタン、テトラキス
[メチレン(３,５−ジ−ｔ−ブチル−４−ヒドロキシヒ
ドロシンナメート)]メタン、オクタデシル−３,５−ジ
−ｔ−ブチル−４−ヒドロキシヒドロシンナメート、フ
ェニル−β−ナフチルアミン、Ｎ，Ｎ−ジフェニル−ｐ
−フェニレンジアミン、２，２，４−トリメチル−１,
３−ジヒドロキノリンポリマー、６−エトキシ−２,２,
４−トリメチル−１,３−ジヒドロキノリン、テトラキ
ス[メチレン３−(３,５−ジ−ｔ−ブチル−４−ヒドロ
キシフェニル)プロピオネート]メタンなどが挙げられ
る。着色剤としては、例えばアゾ系染料、アントラキノ
ン系染料、およびこれらの染料の２種以上の組み合わせ
から選ぶことができる。具体的には、例えば青色４０３
号、橙色４０３号、緑色２０２号、紫色２０１号、赤色
２２５号、黄色２０４号等が挙げられる。As the antioxidant, for example, 3,5-di-
t-butyl-4-hydroxytoluene, 3-t-butyl-4-hydroxyanisole, 3,5-di-t-butyl-4-hydroxyanisole, mercaptobenzimidazole, dilauryl-thio-di-propionate, 2-
t-butyl-4-methoxyphenol, 3-t-butyl-4-methoxyphenol, 2,6-di-t-butyl-
4-ethylphenol, stearyl-β- (3,5-di-t-butyl-4-hydroxyphenyl) propionate, α-tocopherol, ascorbic acid, erythorbic acid, 2,2'-methylene-bis (6-t- Butyl-4-
Methylphenol), 2,2'-methylene-bis (6-t
-Butyl-4-ethylphenol), 4,4'-methylene-bis (2,6-di-t-butylphenol), 4,4
'-Butylidene-bis (6-t-butyl-3-methylphenol), 4,4'-thio-bis (6-t-butyl-3)
-Methylphenol), 1,1-bis (4-hydroxyphenyl) cyclohexane, 1,3,5-trimethyl-2,
4,6-Tris (3,5-di-t-butyl-4-hydroxybenzyl) benzene, tris (2-methyl-4-hydroxy-5-t-butylphenyl) butane, tetrakis
[Methylene (3,5-di-t-butyl-4-hydroxyhydrocinnamate)] methane, octadecyl-3,5-di-t-butyl-4-hydroxyhydrocinnamate, phenyl-β-naphthylamine, N, N-diphenyl-p
-Phenylenediamine, 2,2,4-trimethyl-1,
3-dihydroquinoline polymer, 6-ethoxy-2,2,
4-trimethyl-1,3-dihydroquinoline, tetrakis [methylene 3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate] methane and the like can be mentioned. The colorant can be selected from, for example, azo dyes, anthraquinone dyes, and combinations of two or more of these dyes. Specifically, for example, blue 403
No. 403, orange No. 403, green No. 202, purple No. 201, red No. 225, yellow No. 204 and the like.
【００１５】これらの添加剤は必要最小限の添加量でよ
く、通常、添加殺虫原体の総量に対して安定剤が約５重
量％以下、酸化防止剤が約５重量％以下、紫外線防止剤
が約５重量％以下であればよい。前記着色剤の添加量
は、総量に対して０．００１〜０．１重量％、好ましく
は０．０１〜０．１重量％の濃度である。これにより、
殺虫原体の蒸散性に影響せず、遠距離からの視認性およ
び終点の視認性が向上する。These additives may be added in the minimum necessary amount, and usually, the stabilizer is not more than about 5% by weight, the antioxidant is not more than about 5% by weight, and the anti-UV agent is based on the total amount of the pesticidal substance added. Is about 5% by weight or less. The amount of the colorant added is 0.001 to 0.1% by weight, preferably 0.01 to 0.1% by weight, based on the total amount. This allows
The transpiration property of the insecticidal substance is not affected, and the visibility from a long distance and the visibility of the end point are improved.
【００１６】また、上記以外にも、通常用いられている
効力増強剤、揮散率向上剤、消臭剤、香料等の各種添加
剤も任意に添加することができる。効力増強剤として
は、ピペロニルブトキサイド、Ｎ−プロピルイゾーム、
ＭＧＫ−２６４、サイネピリン２２２、サイネピリン５
００、リーセン３８４、ＩＢＴＡ、Ｓ４２１等を、揮散
率向上剤としては、フエネチルイソチオシアネート、ハ
イミツクス酸ジメチル等を、消臭剤としてはラウリル酸
メタクリレート（ＬＭＡ）等を、香料としてはシトラー
ル、シトロネラール等を夫々例示できる。In addition to the above, various kinds of additives such as commonly used potency enhancers, volatilization rate improvers, deodorants and fragrances may be added. Examples of the efficacy enhancer include piperonyl butoxide, N-propylisome,
MGK-264, Cinepyrine 222, Cinepyrine 5
00, Reisen 384, IBTA, S421 and the like, volatilization rate improvers such as phenethyl isothiocyanate and dimethyl hymitixate, deodorants such as lauric acid methacrylate (LMA), and fragrances such as citral and citronellal. Etc. can be illustrated respectively.
【００１７】前記殺虫原体または添加殺虫原体（以下、
殺虫原体を代表させて説明する）は、これを容器内に収
容し、この容器を加熱することによって蒸散される。使
用する加熱蒸散容器は、該容器から殺虫剤成分を蒸散で
きる構造のものであれば、どのような容器も使用可能で
ある。The above insecticidal drug substance or the added insecticidal drug substance (hereinafter,
The insecticidal drug substance is described as a representative), and it is evaporated by placing it in a container and heating the container. As the heating evaporation container to be used, any container can be used as long as it has a structure capable of evaporating the insecticide component from the container.
【００１８】上記のような加熱蒸散容器の一例を図１に
示す。この加熱蒸散容器は、アルミニウムなどの金属シ
ート、耐熱性樹脂シートなどの耐熱性シート１の中央部
に凹部２を設け、この凹部２に殺虫原体を収容するよう
にしたものである。FIG. 1 shows an example of the heating evaporation container as described above. In this heating evaporation container, a concave portion 2 is provided in the center of a heat resistant sheet 1 such as a metal sheet of aluminum or the like, a heat resistant resin sheet or the like, and the insecticidal drug substance is accommodated in the concave portion 2.
【００１９】本発明においては、図２に示すように、殺
虫原体３を収容した凹部２上面の蒸散口をガス透過性フ
ィルム４で塞いだ構造の加熱蒸散容器５を使用してもよ
い。これにより、殺虫原体３が容器５からこぼれるのを
防止でき、運搬などの取り扱いが容易になる。In the present invention, as shown in FIG. 2, a heating evaporation container 5 having a structure in which the evaporation port on the upper surface of the recess 2 accommodating the insecticidal substance 3 is closed with a gas permeable film 4 may be used. As a result, the insecticidal drug substance 3 can be prevented from spilling from the container 5, and handling such as transportation becomes easy.
【００２０】加熱蒸散容器５は、使用に際して、図２に
示すように、下部に発熱体６を備えた放熱板７上に載置
され、放熱板７からの熱によって内部の殺虫原体３が加
熱される。殺虫原体３から蒸散した殺虫剤成分は、ガス
透過性フィルム４を通って拡散される（蒸散する殺虫剤
成分を矢印で示す）。In use, the heating evaporation container 5 is placed on a heat radiating plate 7 having a heating element 6 at its lower part, as shown in FIG. Be heated. The insecticide component evaporated from the insecticidal substance 3 is diffused through the gas-permeable film 4 (the evaporated insecticide component is indicated by an arrow).
【００２１】容器５に収容する殺虫原体３の量は、使用
する薬剤の蒸散性、単位時間当りの蒸散量、目標とする
蒸散持続時間等に応じて適宜決定されるため、特に限定
されるものではないが、通常約７５〜４５００ｍｇ、好
ましくは１５０〜１５００ｍｇ程度であればよい。例え
ば、殺虫剤トランスフルスリンの揮散量を１．６７ｍｇ
／２時間とすると、本発明における加熱蒸散方法により
１日当たり１２時間蒸散を行うと仮定すれば、３０日用
の殺虫原体３の量は約３００ｍｇとなり、６０日用、１
２０日用の量はそれぞれ約６００ｍｇ、１２００ｍｇと
なる。ちなみに、トランスフルスリンは、蚊の防除に
は、少なくとも０．１５ｍｇ／２時間の有効揮散量であ
るのがよい。The amount of the insecticidal drug substance 3 to be contained in the container 5 is appropriately determined in accordance with the transpiration property of the drug to be used, the transpiration amount per unit time, the target transpiration duration, etc., and therefore is not particularly limited. Although not limited, it is usually about 75 to 4500 mg, preferably about 150 to 1500 mg. For example, the volatilization amount of the insecticide transfluthrin is 1.67 mg.
/ 2 hours, the amount of insecticidal solid 3 for 30 days is about 300 mg, and for 60 days, 1
The amounts for 20 days are about 600 mg and 1200 mg, respectively. Incidentally, transfluthrin should have an effective volatilization amount of at least 0.15 mg / 2 hours for controlling mosquitoes.
【００２２】また、凹部２の深さや内容積は、これに収
容する殺虫原体３の量に応じて変化するため、特に限定
されるものではないが、例えば凹部２の深さは約０．３
〜５ｍｍ、好ましくは０．５〜４ｍｍの範囲から殺虫原
体３の量に応じて適宜決定することができる。The depth and the internal volume of the recess 2 are not particularly limited because they change depending on the amount of the insecticidal solid 3 contained therein. For example, the depth of the recess 2 is about 0. Three
It can be appropriately determined depending on the amount of the insecticidal drug substance 3 within a range of -5 mm, preferably 0.5-4 mm.
【００２３】ガス透過性フィルム４としては、殺虫原体
から揮散した薬剤成分の揮散を妨げずに該フィルム４を
通過させうるものであれば使用可能である。このような
ガス透過性フィルム４を例示すると、例えば延伸または
無延伸ポリプロピレン、ポリエチレン（例えば直鎖状低
密度ポリエチレン、低密度ポリエチレン等）、ポリエチ
レンテレフタレート、ポリメチルペンテンなどが挙げら
れる。これらのフィルムは単独で使用してもよく、２種
以上を貼り合わせたものであってもよい。Any gas permeable film 4 can be used as long as it can pass through the film 4 without hindering the volatilization of the drug component volatilized from the insecticidal substance. Examples of such a gas-permeable film 4 include stretched or unstretched polypropylene, polyethylene (for example, linear low-density polyethylene, low-density polyethylene, etc.), polyethylene terephthalate, polymethylpentene, and the like. These films may be used alone or in combination of two or more.
【００２４】また、フィルムにレーザー光などにより微
細な孔を多数あけた微多孔性フィルムもガス透過性フィ
ルムとして単独で、または他のガス透過性フィルムと貼
り合わせるなどして好適に使用可能である。さらに、針
などで孔をあけた多孔性フィルムも単独で、または他の
ガス透過性フィルムと貼り合わせるなどして使用するこ
とができる。ガス透過性フィルム４の厚さは約１０〜１
００μｍ、好ましくは３０〜７０μｍであるのがよい。Further, a microporous film having a large number of fine holes formed in the film by laser light or the like can also be suitably used alone as a gas permeable film or by laminating it with another gas permeable film. . Furthermore, a porous film having holes formed with a needle or the like can be used alone or by laminating it with another gas permeable film. The gas permeable film 4 has a thickness of about 10 to 1
The thickness is preferably 00 μm, preferably 30 to 70 μm.
【００２５】使用するガス透過性フィルム４の選定にあ
たっては、薬剤成分の蒸散に有効なフィルムであること
に加えて、加熱により外観上に著しい変化［例えば膨張
や破れ等の劣化、フィルム表面での有効成分の結晶化
（粉ふき）等］のないものを使用するのが望ましい。こ
のようなフィルムとしては、例えば２種以上のフィルム
を貼り合わせた複合フィルムを挙げることができる。具
体的には、例えば前記ポリエチレンまたは無延伸ポリプ
ロピレンをシーラント層とし、その外面に延伸ポリプロ
ピレン、ポリエチレンテレフタレート、穴あきフィルム
（例えば穴あきポリエチレンテレフタレートフィルム
等）を貼り合わせた複合フィルムが挙げられる。ここ
で、シーラント層とは加熱蒸散容器５に直接接着され、
該加熱蒸散容器５との間の密着性、液密性を高めるため
のフィルムをいう。前記複合フィルムの厚さは、前記し
たガス透過性フィルム４の厚さ約１０〜１００μｍの範
囲内でよい。なお、シーラント層は単独で容器５の上面
（フィルム４との接着面）に設けてもよい。In selecting the gas permeable film 4 to be used, in addition to being a film effective for evaporation of the drug component, a significant change in appearance due to heating [for example, deterioration such as expansion and tearing, deterioration of film surface It is desirable to use those which do not have crystallization of active ingredient (wiping etc.). As such a film, for example, a composite film obtained by laminating two or more kinds of films can be mentioned. Specific examples thereof include a composite film in which the polyethylene or unstretched polypropylene is used as a sealant layer and stretched polypropylene, polyethylene terephthalate, and a perforated film (for example, perforated polyethylene terephthalate film) are attached to the outer surface of the sealant layer. Here, the sealant layer is directly bonded to the heating evaporation container 5,
A film for enhancing the adhesion and liquid tightness with the heating evaporation container 5. The thickness of the composite film may be in the range of about 10 to 100 μm of the gas permeable film 4 described above. The sealant layer may be provided alone on the upper surface of the container 5 (adhesive surface to the film 4).
【００２６】薬剤の揮散に伴い凹部２内が経時的に陰圧
になって、ガス透過性フィルム４が凹部２の底面にくっ
つくのを防止するために、加熱蒸散容器５には、空気導
入口（図示せず）を設けて、ガス透過性フィルム４でシ
ールされた凹部２に空気を送るようにしてもよい。この
ような空気導入口は、例えばガス透過性フィルム４の一
部に設けることができる。In order to prevent the gas permeable film 4 from sticking to the bottom surface of the recess 2 due to the negative pressure in the recess 2 over time due to the volatilization of the drug, the heating evaporation container 5 has an air inlet port. (Not shown) may be provided to send air to the recess 2 sealed with the gas permeable film 4. Such an air inlet can be provided in a part of the gas permeable film 4, for example.
【００２７】殺虫原体の加熱方法としては、殺虫原体を
ヒーターなどの熱源に直接接触させて加熱蒸散させるこ
とも可能であるが、上記のように容器５を放熱板７等の
ヒーター上に載置したり、必要なら容器５とヒーターと
の間に空隙あるいはその他の介在物を設けて加熱するの
が好ましい。As a method for heating the insecticidal drug substance, it is possible to bring the insecticidal drug substance into direct contact with a heat source such as a heater to evaporate the heat, but as described above, the container 5 is placed on the heater such as the heat radiating plate 7. It is preferable to place it on the surface or heat it by providing a space or other inclusion between the container 5 and the heater if necessary.
【００２８】殺虫原体の加熱温度は、殺虫剤成分の有効
量を蒸散させるのに充分な温度であればよく、特に加熱
温度は限定されるものではないが、容器を使用する上記
加熱方式においてヒーター温度（例えば放熱板２の表面
温度）は通常、約５０〜１７０℃、好ましくは７０〜１
３０℃の範囲であるのがよい。The heating temperature of the insecticidal drug substance may be any temperature that is sufficient to evaporate an effective amount of the insecticide component, and the heating temperature is not particularly limited, but in the above heating method using a container. The heater temperature (for example, the surface temperature of the heat sink 2) is usually about 50 to 170 ° C, preferably 70 to 1 ° C.
It is preferably in the range of 30 ° C.
【００２９】このとき、ガス透過性フィルム４の表面温
度は約４０〜１６０℃、好ましくは約６０〜１２０℃で
あるのがよい。また、容器５内の加熱時における殺虫原
体の温度は約４５〜１６５℃、好ましくは約６５〜１２
５℃であるのがよい。具体的には、蚊等の害虫駆除に必
要とされる個々の殺虫剤の有効揮散量を目安にして、加
熱温度を決定することができる。At this time, the surface temperature of the gas permeable film 4 is about 40 to 160 ° C, preferably about 60 to 120 ° C. The temperature of the insecticidal drug substance during heating in the container 5 is about 45 to 165 ° C, preferably about 65 to 12 ° C.
It should be 5 ° C. Specifically, the heating temperature can be determined based on the effective volatilization amount of each insecticide required for controlling pests such as mosquitoes.
【００３０】このように、本発明では、殺虫剤成分の有
効量を蒸散させる温度で殺虫原体を１日当り１２時間程
度加熱蒸散することにより、３０日あるいはそれ以上の
長時間にわたり殺虫剤成分を持続的に蒸散させることが
できる。As described above, according to the present invention, the insecticidal ingredient is heated and evaporated for about 12 hours per day at a temperature at which an effective amount of the insecticide ingredient is evaporated, so that the insecticide ingredient can be removed over a long period of 30 days or more. It can be transpired continuously.
【００３１】なお、薬剤を加熱蒸散させるにあたって
は、容器５を放熱板７と共に、殺虫原体３とガス透過性
フィルム４とが、予めもしくは使用開始時に接するよう
な角度となるように傾斜させた状態で保持するのが好ま
しく、これにより容器５内の殺虫原体の蒸散による減少
量が当該殺虫原体の液面の推移から判別しやすくなり、
殺虫原体の残量を示すインジケータ機構を果たすことが
でき、また蒸散量を長期にわたって安定させることがで
きる。容器５の水平面に対する傾斜角度は１０〜９０
°、好ましくは４０〜６０°程度が適当である。In heating and evaporating the drug, the container 5 together with the heat radiating plate 7 were tilted so that the insecticidal substance 3 and the gas permeable film 4 were in contact with each other in advance or at the start of use. It is preferable to maintain the state in which the amount of reduction of the insecticidal drug substance in the container 5 due to transpiration is easy to distinguish from the transition of the liquid level of the insecticidal drug substance.
It can serve as an indicator mechanism showing the residual amount of the insecticidal substance, and can stabilize the transpiration amount for a long period of time. The inclination angle of the container 5 with respect to the horizontal plane is 10 to 90.
The suitable angle is 40 °, preferably 40 to 60 °.
【００３２】また、本発明の加熱蒸散方法においては、
図３(a)に示すように殺虫原体３を収容した凹部２を有
する耐熱シート１（容器本体）と、前記殺虫原体３の液
面に接触するガス透過性フィルム４とを備えた加熱蒸散
容器を用いてガス透過性フィルム４が殺虫原体３の液面
に接触した状態で殺虫原体３を加熱して蒸散させたり、
あるいは図３(b)に示すように殺虫原体３の液面が蒸散
空間中に開放されている状態、すなわちガス透過性フィ
ルム４なしで殺虫原体３を加熱するのが好ましく、これ
により殺虫成分の揮散量をさらに高めることができる。Further, in the heat evaporation method of the present invention,
As shown in FIG. 3 (a), heating including a heat-resistant sheet 1 (container body) having a recess 2 accommodating an insecticidal substance 3 and a gas-permeable film 4 in contact with the liquid surface of the insecticidal substance 3 Using the evaporation container, the gas permeable film 4 is in contact with the liquid surface of the insecticidal drug substance 3 to heat and evaporate the insecticidal drug substance 3,
Alternatively, as shown in FIG. 3 (b), it is preferable to heat the insecticidal drug substance 3 in a state where the liquid surface of the insecticidal drug substance 3 is opened in the evaporation space, that is, without heating the gas permeable film 4. The volatilization amount of the component can be further increased.
【００３３】図３(a)に示す形態の場合、殺虫成分の蒸
散に伴って殺虫原体３の残量が減少したときにでもガス
透過性フィルム４と殺虫原体３とを接触させるために
は、例えば、予めガス透過性フィルム４にたるみを持た
せたり、液面を一定に保つための殺虫原体供給手段（図
示せず）を別に設けたり、容器本体を水平面に対して傾
斜させた状態で保持（傾斜角度１０〜９０°、好ましく
は４０〜６０°程度）したりすればよい。また、図２に
示す加熱蒸散容器５のように、水平に保持した状態では
ガス透過性フィルム４と殺虫原体３の液面とが接触して
いない場合であっても、少なくとも加熱蒸散時に、容器
５を水平面に対して傾斜させることにより、ガス透過性
フィルム４を殺虫原体３の液面に接触させることができ
る。図３(a)に示す形態の場合、ガス透過性フィルム４
は、上記で例示したものを使用することができ、特に殺
虫原体３が浸透しフィルム表面から蒸散しやすいものを
使用すると、殺虫成分の揮散量を高めることができる。
このような殺虫原体３が浸透しやすい液浸透性フィルム
を例示すると、ポリプロピレン、ポリエチレン、エチレ
ンとプロピレンの共重合体などが挙げられる。これらの
フィルムは単独で使用してもよく、あるいは２種以上を
貼り合わせたものであってもよい。このガス透過性フィ
ルム４の厚さは、殺虫成分の浸透しやすさおよび揮散量
と関係するため重要であり、好ましくは約１０〜１００
μｍ、より好ましくは約２５〜７５μｍであるのがよ
い。In the case of the form shown in FIG. 3 (a), in order to bring the gas permeable film 4 and the insecticidal drug substance 3 into contact with each other even when the residual amount of the insecticidal drug substance 3 decreases as the insecticidal component evaporates. For example, the gas permeable film 4 may be preliminarily provided with slack, an insecticidal substance supplying means (not shown) for keeping the liquid level constant may be separately provided, or the container body may be inclined with respect to the horizontal plane. It may be held in a state (inclination angle 10 to 90 °, preferably about 40 to 60 °). Further, even when the gas permeable film 4 and the liquid surface of the insecticidal solid 3 are not in contact with each other in a horizontally held state like the heating evaporation container 5 shown in FIG. 2, at least during heating evaporation, The gas permeable film 4 can be brought into contact with the liquid surface of the insecticidal solid 3 by inclining the container 5 with respect to the horizontal plane. In the case of the form shown in FIG. 3 (a), the gas permeable film 4
The above-exemplified ones can be used. Particularly, when the one which permeates the insecticidal drug substance 3 and easily evaporates from the film surface, the amount of the insecticidal component vaporized can be increased.
Examples of such a liquid-permeable film through which the insecticidal drug substance 3 easily penetrates include polypropylene, polyethylene, and a copolymer of ethylene and propylene. These films may be used alone, or may be a laminate of two or more kinds. The thickness of the gas permeable film 4 is important because it is related to the ease of penetration of the insecticidal component and the amount of volatilization, and is preferably about 10 to 100.
The thickness is preferably about 25 to 75 μm.
【００３４】一方、図３(b)に示す形態、すなわちガス
透過性フィルム４を使用しない形態の場合、同図に示す
ように凹部２の上面は開口している（殺虫原体３の液面
が蒸散空間中に開放されている）ため、例えば以下の図
４(a)および(b)に示すような加熱蒸散容器１１を用いる
のが好ましい。On the other hand, in the case of the configuration shown in FIG. 3B, that is, the configuration in which the gas permeable film 4 is not used, the upper surface of the recess 2 is open as shown in the figure (the liquid surface of the insecticidal solid 3). Is opened in the evaporation space), it is preferable to use a heating evaporation container 11 as shown in FIGS. 4 (a) and 4 (b) below, for example.
【００３５】図４(a)および(b)は、それぞれ殺虫原体３
がこぼれにくい構造を有した加熱蒸散容器１１の断面図
およびフィルム１４を取り外した状態での加熱蒸散容器
１１の平面図である。図４(a)および(b)に示すように、
加熱蒸散容器１１は、アルミニウムなどの金属、耐熱性
樹脂などにより形成された箱形の容器本体１２と、その
蓋１３とからなり、容器本体１２に殺虫原体３を収容す
るようにしたものである。蓋１３は、容器本体１２の周
壁上端から内向き下方に傾斜する傾斜部１３ａを備え、
さらにこの傾斜部１３ａの中央部に蒸散口１３ｂを備え
ている。この蓋１３の上面にはガス不透過性フィルム１
４が貼り付けられており、使用時にこのフィルム１４を
剥がすことで殺虫剤成分が蒸散可能となる。蓋１３は容
器本体１２に被せるだけでもよいが、両者を接着などで
一体に固定するか、あるいは蓋１３と容器本体１２とを
一体成形して作製するのが好ましい。FIGS. 4 (a) and 4 (b) show insecticidal solids 3 respectively.
FIG. 3 is a cross-sectional view of the heating evaporation container 11 having a structure that prevents spillage and a plan view of the heating evaporation container 11 with the film 14 removed. As shown in FIGS. 4 (a) and 4 (b),
The heating evaporation container 11 is composed of a box-shaped container body 12 formed of a metal such as aluminum or a heat-resistant resin and a lid 13 thereof, and the insecticidal substance 3 is housed in the container body 12. is there. The lid 13 includes an inclined portion 13a inclined inward and downward from the upper end of the peripheral wall of the container body 12,
Further, a transpiration port 13b is provided at the center of the inclined portion 13a. The gas impermeable film 1 is provided on the upper surface of the lid 13.
4 is attached, and the insecticide component can be evaporated by peeling off the film 14 at the time of use. The lid 13 may be simply covered on the container body 12, but it is preferable that both are integrally fixed by adhesion or the lid 13 and the container body 12 are integrally molded.
【００３６】前記加熱蒸散容器１１を使用するに当たっ
ては、図５および図６に示すような殺虫原体３を加熱す
るための加熱器具２１を使用することができる。この加
熱器具２１は、加熱蒸散容器１１を着脱自在に収容する
ための凹部２５と、この凹部２５の底面に設けられた加
熱蒸散容器１１を加熱するためのヒーター２２と、この
ヒーター２２に電力を供給するための差込プラグ２３と
を備えた箱体である。加熱器具２１は、差込プラグ２３
が取り付けられている面の反対面に殺虫原体３の液量確
認用の窓２４を備えている。このため殺虫原体３の残量
を窓２４を通して容易に確認することができる。したが
って、加熱器具２１を使用する場合には、加熱蒸散容器
１１は透明ないし半透明の耐熱性樹脂などにより形成さ
れているのがよい。In using the heating evaporation container 11, a heating device 21 for heating the insecticidal drug substance 3 as shown in FIGS. 5 and 6 can be used. The heating device 21 includes a recess 25 for removably accommodating the heating evaporation container 11, a heater 22 provided on the bottom surface of the recess 25 for heating the heating evaporation container 11, and an electric power supplied to the heater 22. It is a box provided with a plug 23 for supplying. The heating device 21 has an insertion plug 23.
A window 24 for confirming the liquid volume of the insecticidal drug substance 3 is provided on the surface opposite to the surface on which is attached. Therefore, the remaining amount of the insecticidal solid 3 can be easily confirmed through the window 24. Therefore, when the heating device 21 is used, the heating evaporation container 11 is preferably formed of a transparent or translucent heat resistant resin or the like.
【００３７】加熱蒸散時には、加熱器具２１に加熱蒸散
容器１１を収容した状態でヒーター２２からの熱によっ
て殺虫原体３が加熱され、殺虫剤成分は蒸散口１３ｂを
通って蒸散する。使用により加熱蒸散容器１１内の全て
の殺虫原体３が蒸散した際には、加熱器具２１から加熱
蒸散容器１１を取り出して、殺虫原体３が注入された新
しい加熱蒸散容器１１と交換することができる。また、
全ての殺虫原体３が蒸散した加熱蒸散容器１１内へ殺虫
原体３を新たに注入するようにしてもよい。At the time of heat evaporation, the insecticidal ingredient 3 is heated by the heat from the heater 22 with the heating evaporation container 11 housed in the heating device 21, and the insecticide component evaporates through the evaporation port 13b. When all the insecticidal drug substance 3 in the heating evaporation container 11 has evaporated, the heating evaporation container 11 should be taken out of the heating device 21 and replaced with a new heating evaporation container 11 into which the insecticidal drug substance 3 has been injected. You can Also,
The insecticidal drug substance 3 may be newly injected into the heating evaporation container 11 in which all the insecticidal drug substance 3 has evaporated.
【００３８】前記加熱器具２１には、未使用時に加熱蒸
散容器１１の上面を閉塞する開閉式あるいは着脱式の蓋
（図示せず）を取り付けることもできる。また、加熱蒸
散容器１１および加熱器具２１は、これらの平面形状が
方形以外の多角形や円形であってもよい。The heating device 21 may be provided with an openable or detachable lid (not shown) that closes the upper surface of the heating evaporation container 11 when not in use. The planar shape of the heating evaporation container 11 and the heating device 21 may be polygonal or circular other than square.
【００３９】加熱蒸散容器としては、図４(a)および(b)
に示したような箱形の容器本体１２と蓋１３とからなる
形態の他、例えば図７(a)および(b)に示す容器３１、３
２のように容器の上部に蒸散口３３、３４を備え、殺虫
原体の液面を蒸散空間中に開放することができるもので
あれば使用することができる。これらの容器３１、３２
の平面形状は、方形、方形以外の多角形、円形などにす
ることができ、特に限定されない。The heating evaporation container is shown in FIGS. 4 (a) and 4 (b).
In addition to the box-shaped container body 12 and the lid 13 as shown in FIG. 7, for example, the containers 31 and 3 shown in FIGS.
2 can be used as long as it has evaporation ports 33, 34 on the upper part of the container and can open the liquid surface of the insecticidal substance into the evaporation space. These containers 31, 32
The planar shape of can be a square, a polygon other than a square, a circle, and the like, and is not particularly limited.
【００４０】本発明の加熱蒸散方法は、防除が要求され
る様々な害虫、例えばゴキブリ、ハエ、蚊、ヌカカ、ア
ブ、ノミ、ナンキンムシなどの衛生害虫ないし吸血害
虫、イガ、コイガなどの衣類害虫、コクヌストモドキ、
コクゾウムシなどの貯穀害虫、イエダニ、ツメダニ、コ
ナダニなどのダニ類、アリ、シロアリ、ナメクジなどの
防除に適用可能である。従って、本発明の加熱蒸散方法
は、様々な場所で使用可能であり、例えば家庭内の居
室、台所、食堂；畜舎、犬小屋、農園芸ハウス；押入
れ、タンス等の衣類等収納庫、食物収納庫などで好適に
使用することができる。The heat evaporation method of the present invention comprises various pests required to be controlled, for example, sanitary pests such as cockroaches, flies, mosquitoes, midges, flies, fleas, bed bugs, blood-sucking pests, clothing pests such as squid and carp. Konosutomodoki,
It can be applied to the control of stored grain pests such as weevil, mites such as house dust mites, ticks, and mites, ants, termites and slugs. Therefore, the heat evaporation method of the present invention can be used in various places, for example, a living room, kitchen, dining room in a home; a livestock barn, a kennel, an agricultural and horticultural house; a storage room for clothes such as closets and chests, and food storage. It can be suitably used in a warehouse or the like.
【００４１】なお、以上の説明では、殺虫原体または添
加殺虫原体を加熱して蒸散させる場合について記載した
が、殺虫原体または添加殺虫原体が常温で揮散性を有す
る場合には、殺虫原体または添加殺虫原体（例えば、前
記化合物Ａ、化合物Ｂなど）を加熱せず、必要に応じて
風を当て、常温で蒸散させるようにしてもよい。In the above description, the case where the insecticidal drug substance or the added insecticidal drug substance is heated and evaporated is described. However, when the insecticidal drug substance or the added insecticidal drug substance is volatile at room temperature, the insecticidal drug substance is added. The drug substance or the added insecticidal drug substance (for example, the compound A, the compound B, etc.) may be heated at room temperature without being heated, and may be evaporated at room temperature.
【００４２】[0042]
【実施例】以下、実施例を挙げて本発明の加熱蒸散方法
を説明するが、本発明は以下の実施例のみに限定される
ものではない。EXAMPLES The heating evaporation method of the present invention will be described below with reference to examples, but the present invention is not limited to the following examples.
【００４３】実施例１
１．殺虫原体
表１に示す組成の添加殺虫原体を使用した。この添加殺
虫原体は、殺虫原体トランスフルスリンに以下に示す添
加剤を添加して調製したものである。
色素：プラストブルー８５４０（有本化学工業（株）
製）
酸化防止剤Ｍ：イルガノックス１０１０（チバ社製のテ
トラキス[メチレン３−(３,５−ジ−ｔ−ブチル−４−
ヒドロキシフェニル)プロピオネート]メタンの商品名）
酸化防止剤Ｎ：３,５−ジ−ｔ−ブチル−４−ヒドロキ
シトルエン（ＢＨＴ）Example 1 1. Insecticidal substance An added insecticidal substance having the composition shown in Table 1 was used. This added insecticidal drug substance is prepared by adding the following additives to the insecticidal drug substance transfluthrin. Dye: Plast Blue 8540 (Arimoto Chemical Co., Ltd.)
Antioxidant M: Irganox 1010 (tetrakis [methylene 3- (3,5-di-t-butyl-4-, manufactured by Ciba)
Trade name of hydroxyphenyl) propionate] methane) Antioxidant N: 3,5-di-t-butyl-4-hydroxytoluene (BHT)
【表１】 [Table 1]
【００４４】２.加熱蒸散容器
図２に示すような加熱蒸散容器５を使用した。耐熱性シ
ート１（容器本体）として、凹部２を有する縦３５ｍｍ
×横３０ｍｍ×厚さ０．１５ｍｍのアルミニウム板（凹
部２の寸法：縦３０ｍｍ×横１８ｍｍ、凹部２の深さは
表２に示す）を用い、その上面をガス透過性フィルム４
でシールした後、注射器を用いて殺虫原体（以下、内容
液という）を容器内に注入し、注入部を接着剤で閉じ
た。注入量は、表２に示す試料Ｎｏ.５および９で３０
０ｍｇとし、それ以外は１２００ｍｇとした。使用した
アルミニウム板は、厚さ１００μｍのＡｌシートの表面
にガス透過性フィルム４との間の密着性、液密性を高め
るためのシーラント層として、厚さ５０μｍの（無延
伸）ポリプロピレンフィルム (CPP)をコーティングし、
裏面にニ軸延伸ポリプロピレンのニスを薄く塗布したも
のである。2. Heating evaporation container A heating evaporation container 5 as shown in FIG. 2 was used. The heat-resistant sheet 1 (container body) has a concave portion 2 and a length of 35 mm
An aluminum plate having a width of 30 mm and a thickness of 0.15 mm (the size of the recess 2 is 30 mm in length, a width of 18 mm, and the depth of the recess 2 is shown in Table 2) is used.
After sealing with, the insecticidal drug substance (hereinafter referred to as the content liquid) was injected into the container using a syringe, and the injection portion was closed with an adhesive. The injection amount was 30 for sample Nos. 5 and 9 shown in Table 2.
The amount was 0 mg, and the other values were 1200 mg. The aluminum plate used was a 50 μm-thick (unstretched) polypropylene film (CPP) as a sealant layer for improving the adhesion and liquid-tightness with the gas permeable film 4 on the surface of an Al sheet having a thickness of 100 μm. ) Coating,
The back surface is thinly coated with a biaxially oriented polypropylene varnish.
【表２】
なお、使用したガス透過性フィルムは以下の通りであ
る。
(i)ＯＰＰ２０／ＰＥ３０：厚さ２０μｍのニ軸延伸ポ
リプロピレンフィルム(OPP)と厚さ３０μｍのポリエチ
レンフィルム(PE)とを貼り合わせたガス透過性フィルム
(ii)ペレカ：厚さ３０μｍの（無延伸）ポリプロピレン
フィルム (CPP)と厚さ１２μｍの微多孔性ポリエチレン
テレフタレートフィルム(PET)とを貼り合わせたガス透
過性フィルム
(iii)レトルトＣＰＰ３０：厚さ３０μｍの（無延伸）
耐熱性ポリプロピレンフィルム (CPP)[Table 2] The gas permeable film used is as follows. (i) OPP20 / PE30: a gas permeable film obtained by laminating a 20 μm thick biaxially stretched polypropylene film (OPP) and a 30 μm thick polyethylene film (PE). (ii) Peleca: a 30 μm thick (non-stretched). ) A gas permeable film obtained by bonding a polypropylene film (CPP) and a microporous polyethylene terephthalate film (PET) having a thickness of 12 μm (iii) retort CPP30: a thickness of 30 μm (unstretched)
Heat resistant polypropylene film (CPP)
【００４５】３.試験方法
ヒーター温度（放熱板７の表面温度）を９５℃に設定し
たマット式電気蚊取器を用いて、水平面に対して５０°
傾斜させた状態で加熱蒸散容器５の底部を全面加熱して
薬剤を蒸散させた。加熱蒸散容器５から揮散した殺虫剤
成分はシリカゲルカラムに吸引捕集し、このシリカゲル
をクロロホルムで抽出し、濃縮後、ガスクロマトグラフ
にて定量し、所定時間ごとの揮散量を求めた。3. Test method Using a mat-type electric mosquito trap with the heater temperature (surface temperature of the heat sink 7) set at 95 ° C., 50 ° with respect to the horizontal plane.
The bottom of the heating evaporation container 5 was entirely heated in the inclined state to evaporate the drug. The insecticide component volatilized from the heating evaporation container 5 was collected by suction on a silica gel column, this silica gel was extracted with chloroform, concentrated and then quantified by a gas chromatograph to obtain the volatilization amount at predetermined time intervals.
【００４６】４．試験結果
ヒーターへの通電開始から６８〜７２時間目および１９
２〜１９８時間目の揮散量を表３に示す。4. Test results 68 to 72 hours after the start of energization of the heater and 19
Table 3 shows the amount of volatilization from 2 to 198 hours.
【表３】
また、試料５および９の１２〜１８時間目の揮散量を表
４に示す。[Table 3] Table 4 shows the volatilization amount of Samples 5 and 9 at 12 to 18 hours.
【表４】
表３および表４から、殺虫原体を用いる本発明の加熱蒸
散方法は、殺虫剤成分が安定して揮散していることがわ
かる。[Table 4] From Tables 3 and 4, it can be seen that in the heat evaporation method of the present invention using the insecticidal drug substance, the insecticide component is stably vaporized.
【００４７】実施例２
（通電時間と揮散性との関係）以下に示す条件にて殺虫
原体の揮散を行い、実施例１と同様にして揮散量を求め
た。なお、以下の説明で、例えば「断続１２時間通電」
とは、１２時間通電、１２時間非通電を交互に繰り返す
ことをいう。Example 2 (Relationship between energization time and volatility) The insecticidal substance was volatilized under the following conditions, and the volatilization amount was determined in the same manner as in Example 1. In the following description, for example, "intermittent 12-hour energization"
Means that the energization for 12 hours and the non-energization for 12 hours are alternately repeated.
【００４８】〔Ｉ〕 使用期間３０日用
(1) 試験条件
ａ． 内容液 ： 表１のＡ
ｂ． 加熱蒸散容器 ： 表２の試料Ｎｏ．１と同じ容
器を使用
ｃ． ガス透過性フィルム ： ＯＰＰ２０／ＰＥ３０
（前出）
ｄ． 注入量 ： ３００ｍｇ
ｅ． ヒータ設定温度 ： ８５℃
ｆ． 試料数 ： ３
ｇ． 揮散量測定時間 ： 次の(2)の各表に示す通り[I] Use period 30 days (1) Test conditions a. Content liquid: Ab of Table 1 b. Heating evaporation container: Sample No. of Table 2 Use same container as 1 c. Gas permeable film: OPP20 / PE30
(Above) d. Injection volume: 300 mg e. Heater set temperature: 85 ° C f. Number of samples: 3 g. Volatilization amount measurement time: As shown in each table in (2) below
【００４９】(2) 試験結果(2) Test result
【表５】 [Table 5]
【表６】 [Table 6]
【表７】 [Table 7]
【表８】 [Table 8]
【００５０】〔II〕 使用期間６０日用
(1) 試験条件
ａ． 内容液 ： 表１のＡ
ｂ． 加熱蒸散容器 ： 表２の試料Ｎｏ．１と同じ容
器を使用
ｃ． ガス透過性フィルム ： ＯＰＰ２０／ＰＥ３０
（前出）
ｄ． 注入量 ： ６００ｍｇ
ｅ． ヒータ設定温度 ： ８５℃
ｆ． 試料数 ： ３
ｇ． 揮散量測定時間 ： 次の(2)の各表に示す通り[II] Use period 60 days (1) Test conditions a. Content liquid: Ab of Table 1 b. Heating evaporation container: Sample No. of Table 2 Use same container as 1 c. Gas permeable film: OPP20 / PE30
(Above) d. Injection volume: 600 mg e. Heater set temperature: 85 ° C f. Number of samples: 3 g. Volatilization amount measurement time: As shown in each table in (2) below
【００５１】(2) 試験結果(2) Test result
【表９】 [Table 9]
【表１０】 [Table 10]
【表１１】 [Table 11]
【表１２】 [Table 12]
【００５２】〔III〕 使用期間１２０日用
(1) 試験条件
ａ． 内容液 ： 表１のＡ
ｂ． 加熱蒸散容器 ： 表２の試料Ｎｏ．１と同じ容
器を使用
ｃ． ガス透過性フィルム ： ＯＰＰ２０／ＰＥ３０
（前出）
ｄ． 注入量 ： １２００ｍｇ
ｅ． ヒータ設定温度 ： ８５℃
ｆ． 試料数 ： ３
ｇ． 揮散量測定時間 ： 次の(2)の表に示す通り[III] Use period for 120 days (1) Test conditions a. Content liquid: Ab of Table 1 b. Heating evaporation container: Sample No. of Table 2 Use same container as 1 c. Gas permeable film: OPP20 / PE30
(Above) d. Injection volume: 1200 mg e. Heater set temperature: 85 ° C f. Number of samples: 3 g. Volatilization amount measurement time: As shown in the table in (2) below
【００５３】(2) 試験結果(2) Test result
【表１３】 [Table 13]
【００５４】表５〜表１３より、殺虫原体を用いる本発
明の加熱蒸散方法は、断続揮散、連続揮散を問わず殺虫
剤成分が安定して揮散していることがわかる。また、表
９〜表１３より、本発明方法は、３６０時間以上の長時
間の揮散であっても殺虫剤成分が安定して揮散している
ことがわかる。From Tables 5 to 13, it can be seen that in the heat evaporation method of the present invention using the insecticidal substance, the insecticide component is stably evaporated regardless of intermittent volatilization or continuous volatilization. Further, from Tables 9 to 13, it can be seen that the method of the present invention stably vaporizes the insecticide component even when it is vaporized for a long time of 360 hours or more.
【００５５】実施例３
（ガス透過性フィルムの揮散性への影響）図８に示す加
熱蒸散容器３５にガス透過性フィルム４を貼り付けた場
合と貼り付けない場合との揮散性を比較し、かつガス透
過性フィルム４と内容液３とが接触している場合と接触
していない場合との揮散性を比較するために、以下に示
す条件で殺虫原体の揮散を行わせ、実施例１と同様にし
て揮散量を求めた。Example 3 (Influence on Volatility of Gas Permeable Film) The volatility of the case where the gas permeable film 4 was attached to the heating evaporation container 35 shown in FIG. In order to compare the volatility of the gas permeable film 4 and the content liquid 3 in contact with each other, volatilization of the insecticidal substance was performed under the following conditions, and Example 1 was performed. The amount of volatilization was obtained in the same manner as in.
【００５６】(1) 試験条件
ａ． 内容液 ： 表１のＡ
ｂ． 加熱蒸散容器 ： 図８(a)および(b)に示す加熱
蒸散容器３５を使用した。このものは同図(a)および(b)
に示すような形状で、サイズが縦３３ｍｍ×横２５ｍ
ｍ、凹部３６は縦２６ｍｍ×横１７ｍｍ×深さ３ｍｍで
ある。その他は、実施例１で使用した容器と同じであ
る。
ｃ． ガス透過性フィルム
ガス透過性フィルムの厚さおよび材質 ： 厚さ５０μ
ｍの（無延伸）ポリプロピレンフィルム
ｄ． 注入量 ： 表１４に示す通り
ｅ． ヒータ設定温度 ： １０４℃
このときガス透過性フィルムの表面温度および内容液の
温度は表１４に示す通りである。ここで、ガス透過性フ
ィルムの表面温度は該フィルムの上面かつ中央付近にお
いて測定し、内容液の温度は内容液の中央付近において
測定した。
ｆ． 試料数 ： 各試料とも３
ｇ． 揮散量測定時間 ： ヒーターへの通電開始から
６〜１２時間目
ｈ． 加熱蒸散容器の加熱時の置き方 ： 水平に置い
て加熱(1) Test conditions a. Content liquid: Ab of Table 1 b. Heating evaporation container: The heating evaporation container 35 shown in FIGS. 8 (a) and 8 (b) was used. This is shown in (a) and (b) of the same figure.
The shape is as shown in, and the size is 33 mm long × 25 m wide.
m, the recess 36 is 26 mm in length × 17 mm in width × 3 mm in depth. Others are the same as the container used in Example 1. c. Gas permeable film Thickness and material of gas permeable film: Thickness 50μ
m (unstretched) polypropylene film d. Injection Volume: As shown in Table 14, e. Heater set temperature: 104 ° C. At this time, the surface temperature of the gas permeable film and the temperature of the content liquid are as shown in Table 14. Here, the surface temperature of the gas permeable film was measured near the center of the upper surface of the film, and the temperature of the content liquid was measured near the center of the content liquid. f. Number of samples: 3 g for each sample. Volatilization amount measurement time: 6 to 12 hours after the start of energization of the heater h. How to place the heating evaporation container when heating: Place horizontally and heat
【００５７】(2) 試験結果(2) Test result
【表１４】 [Table 14]
【００５８】表１４から、フィルム４と内容液３とが接
触していない試料No.１４と比較して、フィルム４と内
容液３とが接触している試料No.１３およびフィルム４
を貼り付けていない試料No.１５は、揮散量が多いこと
がわかる。From Table 14, as compared with the sample No. 14 in which the film 4 and the content liquid 3 are not in contact, the sample No. 13 and the film 4 in which the film 4 and the content liquid 3 are in contact with each other.
It can be seen that Sample No. 15 to which is not attached has a large amount of volatilization.
【００５９】実施例４
（各種殺虫原体の揮散性）３種類の殺虫原体の揮散性を
比較するために、以下に示す条件にて殺虫原体の揮散を
行い、実施例１と同様にして揮散量を求めた。Example 4 (Volatility of Various Insecticides) In order to compare the volatility of three types of insecticidal substances, the insecticidal substances were volatilized under the following conditions, and the same procedure as in Example 1 was performed. The amount of volatilization was calculated.
【００６０】(1) 試験条件
ａ． 内容液 ： 表１５に示す通り
ｂ． 加熱蒸散容器 ： 実施例３と同じ容器を使用
ｃ． ガス透過性フィルム ： 各試料とも厚さ５０μ
ｍの（無延伸）ポリプロピレンフィルムを使用。図３
(a)に示すように、ガス透過性フィルム４と内容液３と
が接触している状態で試験を行った。
ｄ． 注入量 ： １７００ｍｇ
ｅ． ヒータ設定温度 ： １０４℃
ｆ． 試料数 ： 各試料とも３
ｇ． 揮散量測定時間 ： ヒーターへの通電開始から
１２〜２４時間目
ｈ． 加熱蒸散容器の加熱時の置き方 ： 水平に置い
て加熱(1) Test conditions a. Content liquid: As shown in Table 15, b. Heat evaporation container: Use the same container as in Example 3 c. Gas permeable film: Each sample has a thickness of 50μ
m (unstretched) polypropylene film is used. Figure 3
As shown in (a), the test was conducted with the gas permeable film 4 and the content liquid 3 in contact with each other. d. Injection volume: 1700 mg e. Heater set temperature: 104 ° C f. Number of samples: 3 g for each sample. Volatilization amount measurement time: 12 to 24 hours after the start of energization of the heater h. How to place the heating evaporation container when heating: Place horizontally and heat
【００６１】(2) 試験結果(2) Test result
【表１５】 [Table 15]
【００６２】表１５から、試料No.１６〜１８における
各殺虫原体はいずれも殺虫剤成分が安定して揮散されて
いることがわかる。From Table 15, it can be seen that the insecticidal ingredient is stable and volatilized in each of the insecticidal drug substances in Sample Nos. 16-18.
【００６３】実施例５
（ガス透過性フィルムの検討）
１.ガス透過性フィルム
表１６に示すように、２種または３種のフィルムを貼り
合わせた複合フィルムを準備した。ここで、ＬＬＤＰ
Ｅ、ＬＤＰＥまたはＣＰＰは、シーラント層として加熱
蒸散容器に直接貼り合わせる。なお、試料Ｎｏ．２２の
「ＬＬＤＰＥ／穴あきＰＥＴ／ＬＬＤＰＥ」はこの順で
積層接着したことを示しており、試料Ｎｏ．２３も同様
である。表１６中の開孔率とは、ＰＥＴフィルムにレー
ザー光であけた微細な孔の総面積がフィルムの全面積に
占める割合を示している。Example 5 (Study of gas permeable film) 1. Gas permeable film As shown in Table 16, a composite film prepared by laminating two or three kinds of films was prepared. Where LLDP
E, LDPE or CPP is directly attached as a sealant layer to a heating evaporation container. Sample No. No. 22 “LLDPE / Perforated PET / LLDPE” indicates that they were laminated and adhered in this order. The same applies to 23. The porosity in Table 16 indicates the ratio of the total area of fine holes formed by laser light to the PET film to the total area of the film.
【表１６】 (i) ＬＬＤＰＥ：直鎖状低密度ポリエチレン (ii)ＣＰＰ：無延伸ポリプロピレン (iii)ＯＰＰ：ニ軸延伸ポリプロピレン (iｖ)ＰＥＴ：ポリエチレンテレフタレート[Table 16] (i) LLDPE: linear low-density polyethylene (ii) CPP: unstretched polypropylene (iii) OPP: biaxially oriented polypropylene (iv) PET: polyethylene terephthalate
【００６４】２.加熱蒸散容器
図８に示すような加熱蒸散容器３５を使用した。耐熱性
シート１（容器本体）として、凹部２を有する縦４２ｍ
ｍ×横３８ｍｍ×厚さ０．１ｍｍのアルミニウム板（内
厚２．９ｍｍ、凹部２の寸法：縦２６ｍｍ×横１７ｍｍ
×深さ３ｍｍ）を用いた。この容器の凹部２に、０．０
１重量％の濃度で色素（緑色２０２号）を添加したトラ
ンスフルスリンを充填し、その上面を表１６に示すガス
透過性フィルム４で塞いだ。2. Heating evaporation container A heating evaporation container 35 as shown in FIG. 8 was used. Heat-resistant sheet 1 (container body) has a concave portion 2 and a length of 42 m
Aluminum plate of m × 38 mm × thickness 0.1 mm (internal thickness 2.9 mm, dimensions of recessed portion: 26 mm length × 17 mm width)
X depth 3 mm) was used. In the recess 2 of this container, 0.0
Transfluthrin added with a dye (Green No. 202) at a concentration of 1% by weight was filled, and the upper surface thereof was covered with the gas permeable film 4 shown in Table 16.
【００６５】３.試験方法
ヒーター温度（放熱板７の表面温度）を１００℃に設定
した加熱蒸散容器を用いて、水平面に対して５０°傾斜
させた状態で加熱蒸散容器３５の底部を全面加熱して添
加殺虫原体を１２時間加熱し、実施例１と同様にして有
効成分の揮散量を測定した。また、加熱蒸散前後の外観
上の変化を、目視にて評価した。その結果を表１７に示
す。なお、表１７の「○」および「△」はガス透過性フ
ィルムとして使用できること示す。3. Test method Using a heating evaporation container in which the heater temperature (surface temperature of the heat dissipation plate 7) is set to 100 ° C., the entire bottom of the heating evaporation container 35 is heated while being inclined at 50 ° with respect to the horizontal plane. Then, the added insecticidal drug substance was heated for 12 hours, and the volatilization amount of the active ingredient was measured in the same manner as in Example 1. In addition, the change in appearance before and after heat evaporation was visually evaluated. The results are shown in Table 17. In Table 17, “◯” and “Δ” indicate that the film can be used as a gas permeable film.
【表１７】
表１７から、ガス透過性フィルムの材質としては、ＬＬ
ＤＰＥやＣＰＰをシーラント層とし、これにＯＰＰ、穴
あきＰＥＴおよびＰＥＴ等のフィルムを貼り合わせて、
２層もしくは３層の複合フィルムにすることにより、加
熱による膨潤や破れ等の劣化や、フィルム表面での殺虫
剤成分の結晶化が起こりにくく、加熱蒸散に使用するの
に適していることがわかる。[Table 17] From Table 17, the material of the gas permeable film is LL.
DPE or CPP is used as a sealant layer, and a film such as OPP, perforated PET or PET is attached to this,
It can be seen that the use of a two-layer or three-layer composite film is less likely to cause swelling or tearing due to heating and crystallization of the insecticide component on the film surface, and is suitable for use in heat evaporation. .
【００６６】[0066]
【発明の効果】以上詳述したように、殺虫原体または添
加殺虫原体を加熱蒸散させる本発明方法およびこれに使
用する加熱蒸散容器によれば、水を加えた殺虫液を、吸
液芯を用いた加熱蒸散方式で加熱蒸散させるよりも、殺
虫剤成分を効率よく揮散させることができるため、水を
加えた殺虫液の問題点を一掃でき、かつ加熱蒸散時に溶
剤の必要性がなく、従って溶剤を使用する場合に生じる
水性・油性を区別する必要性もなくなり、しかも加熱蒸
散させる容器や加熱器具もコンパクトになるという効果
がある。INDUSTRIAL APPLICABILITY As described above in detail, according to the method of the present invention for heating and evaporating the insecticidal drug substance or the added insecticidal drug substance, and the heating evaporation container used for this method, the insecticidal liquid to which water is added is used as a liquid absorbent core. Rather than heat evaporation using a heating evaporation method using, it is possible to efficiently volatilize the insecticide component, it is possible to eliminate the problem of the insecticidal solution added water, and there is no need for a solvent at the time of heat evaporation, Therefore, there is no need to distinguish between water-based properties and oil-based properties that occur when a solvent is used, and moreover, there is an effect that a container for heating and evaporating and a heating tool are also compact.
【図１】(a)は本発明における加熱蒸散容器の一例を示
す平面図、(b)はそのＸ−Ｘ線断面図である。FIG. 1 (a) is a plan view showing an example of a heating evaporation container according to the present invention, and FIG. 1 (b) is a sectional view taken along line XX.
【図２】ガス透過性フィルムでシールした加熱蒸散容器
の使用状態を示す断面図である。FIG. 2 is a cross-sectional view showing a usage state of a heating evaporation container sealed with a gas permeable film.
【図３】(a)はガス透過性フィルムと殺虫原体とを接触
させた状態を示す断面図で、(b)はガス透過性フィルム
を凹部の上面に貼り付けていない状態を示す断面図であ
る。FIG. 3 (a) is a cross-sectional view showing a state in which a gas-permeable film and an insecticidal substance are in contact with each other, and (b) is a cross-sectional view showing a state in which the gas-permeable film is not attached to the upper surface of the recess. Is.
【図４】(a)は殺虫原体がこぼれにくい構造を有した加
熱蒸散容器を示す断面図であり、(b)は上面からガス不
透過性フィルムを除外した状態での当該容器の平面図で
ある。FIG. 4 (a) is a cross-sectional view showing a heating evaporation container having a structure in which an insecticidal substance does not easily spill, and FIG. 4 (b) is a plan view of the container with the gas impermeable film removed from the upper surface. Is.
【図５】殺虫原体を加熱するための加熱器具と、この加
熱器具に収容された加熱蒸散容器とを示す断面図であ
る。FIG. 5 is a cross-sectional view showing a heating device for heating an insecticidal drug substance and a heating evaporation container housed in the heating device.
【図６】殺虫原体を加熱するための加熱器具を示す斜視
図である。FIG. 6 is a perspective view showing a heating device for heating an insecticidal drug substance.
【図７】(a)および(b)は加熱蒸散容器の他の形態を示し
た断面図である。7 (a) and 7 (b) are cross-sectional views showing another form of the heating evaporation container.
【図８】(a)は実施例３および４において使用する加熱
蒸散容器を示す平面図、(b)はそのＺ−Ｚ線断面図であ
る。8A is a plan view showing a heating evaporation container used in Examples 3 and 4, and FIG. 8B is a sectional view taken along line ZZ.
１…耐熱性シート、２…凹部、３…殺虫原体、４…ガス
透過性フィルム、５…加熱蒸散容器、６…発熱体、７…
放熱板DESCRIPTION OF SYMBOLS 1 ... Heat-resistant sheet, 2 ... Recessed part, 3 ... Insecticidal substance, 4 ... Gas permeable film, 5 ... Heating evaporation container, 6 ... Heating element, 7 ...
Heat sink
【手続補正書】[Procedure amendment]
【提出日】平成１５年１月２２日（２００３．１．２
２）[Submission date] January 22, 2003 (2003.1.2
2)
【手続補正１】[Procedure Amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１６[Correction target item name] 0016
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００１６】また、上記以外にも、通常用いられている
効力増強剤、揮散率向上剤、消臭剤、香料等の各種添加
剤も任意に添加することができる。効力増強剤として
は、ピペロニルブトキサイド、Ｎ−プロピルイゾーム、
ＭＧＫ−２６４、サイネピリン２２２、サイネピリン５
００、リーセン３８４、ＩＢＴＡ、Ｓ−４２１等を、揮
散率向上剤としては、フエネチルイソチオシアネート、
ハイミツクス酸ジメチル等を、消臭剤としてはラウリル
酸メタクリレート（ＬＭＡ）等を、香料としてはシトラ
ール、シトロネラール等を夫々例示できる。In addition to the above, various kinds of additives such as commonly used potency enhancers, volatilization rate improvers, deodorants and fragrances may be added. Examples of the efficacy enhancer include piperonyl butoxide, N-propylisome,
MGK-264, Cinepyrine 222, Cinepyrine 5
00, Reisen 384, IBTA, S-421 and the like, as a volatilization rate improver, phenethyl isothiocyanate,
Examples include dimethyl hymituxate and the like, examples of the deodorant include lauric acid methacrylate (LMA), and examples of the fragrance include citral and citronellal.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 田々美 健治 兵庫県赤穂市坂越3150 Ｆターム(参考） 2B121 AA12 AA16 CA04 CA16 CA31 CA36 CA81 CC02 CC31 EA01 EA02 EA03 EA12 EA13 FA06 FA08 4H011 AC02 AC03 AC05 BA01 BB15 BC08 DA13 DB03 DB04 DD05 DD06 DE06 ─────────────────────────────────────────────────── ─── Continued front page (72) Inventor Kenji Tasami 3150 Sakakoshi, Ako City, Hyogo Prefecture F term (reference) 2B121 AA12 AA16 CA04 CA16 CA31 CA36 CA81 CC02 CC31 EA01 EA02 EA03 EA12 EA13 FA06 FA08 4H011 AC02 AC03 AC05 BA01 BB15 BC08 DA13 DB03 DB04 DD05 DD06 DE06
Claims (6)
加殺虫原体を加熱して、蒸散させることを特徴とする、
害虫防除のための加熱蒸散方法。1. An insecticidal drug substance or an added insecticidal drug substance containing an additive thereto is heated to evaporate.
Heat evaporation method for pest control.
に収容し、この容器を加熱することによって、前記殺虫
原体または添加殺虫原体を蒸散させる請求項１記載の加
熱蒸散方法。2. The heat evaporation method according to claim 1, wherein the insecticidal drug substance or the added insecticidal drug substance is contained in a container, and the container is heated to evaporate the insecticidal drug substance or the added insecticidal drug substance.
添加殺虫原体の液面に接触した状態で、前記殺虫原体ま
たは添加殺虫原体を蒸散させる請求項１または２記載の
加熱蒸散方法。3. The heat evaporation method according to claim 1, wherein the insecticidal drug substance or the added insecticidal drug substance is evaporated while the gas permeable film is in contact with the liquid surface of the insecticidal drug substance or the added insecticidal drug substance. .
空間中に開放されている請求項１または２記載の加熱蒸
散方法。4. The heat evaporation method according to claim 1, wherein the liquid surface of the insecticidal drug substance or the added insecticidal drug substance is opened in the evaporation space.
加殺虫原体を収容した容器本体と、この容器本体の蒸散
口を塞ぐガス透過性フィルムとを備えたことを特徴とす
る、請求項１〜３のいずれかに記載の加熱蒸散方法に使
用するための加熱蒸散容器。5. A container main body containing an insecticidal drug substance or an added insecticidal drug substance containing an additive therein, and a gas permeable film for closing the evaporation port of the container body. A heating evaporation container for use in the heating evaporation method according to any one of Items 1 to 3.
加殺虫原体を収容した容器本体と、少なくとも加熱蒸散
時に前記殺虫原体または添加殺虫原体の液面に接触する
ガス透過性フィルムとを備えたことを特徴とする、請求
項１〜３のいずれかに記載の加熱蒸散方法に使用するた
めの加熱蒸散容器。6. A container body containing an insecticidal drug substance or an added insecticidal drug substance containing an additive therein, and a gas-permeable film which comes into contact with the liquid surface of the insecticidal drug substance or the added insecticidal drug substance at least during heat evaporation. A heating evaporation container for use in the heating evaporation method according to any one of claims 1 to 3, further comprising:
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002141087A JP4317349B2 (en) | 2001-07-11 | 2002-05-16 | Heating transpiration method and heating transpiration container used therefor |
| EP03730503A EP1547464A4 (en) | 2002-05-16 | 2003-05-16 | Method of thermal transpiration, thermal transpiration container for use therein and thermal transpiration device |
| KR10-2004-7018436A KR20050010806A (en) | 2002-05-16 | 2003-05-16 | Method of thermal transpiration, thermal transpiration container for use therein and thermal transpiration device |
| PCT/JP2003/006160 WO2003105579A1 (en) | 2002-05-16 | 2003-05-16 | Method of thermal transpiration, thermal transpiration container for use therein and thermal transpiration device |
| BRPI0310056A BRPI0310056A2 (en) | 2002-05-16 | 2003-05-16 | thermal perspiration method, thermal perspiration vessel and thermal perspiration apparatus used for the same |
| AU2003242312A AU2003242312A1 (en) | 2002-05-16 | 2003-05-16 | Method of thermal transpiration, thermal transpiration container for use therein and thermal transpiration device |
| CNB038111624A CN100482072C (en) | 2002-05-16 | 2003-05-16 | Method of thermal transpiration, thermal transpiration container for use therein and thermal transpiration device |
| APAP/P/2004/003173A AP2004003173A0 (en) | 2002-05-16 | 2003-05-16 | Heat transpiration method, heat transpiration container and heat transpiration apparatus used in the same. |
| OA1200400306A OA12818A (en) | 2002-05-16 | 2003-05-16 | Method of thermal transpiration, thermal transpiration container for use therein and thermal transpiration device. |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001-210564 | 2001-07-11 | ||
| JP2001210564 | 2001-07-11 | ||
| JP2001-401023 | 2001-12-28 | ||
| JP2001401023 | 2001-12-28 | ||
| JP2002141087A JP4317349B2 (en) | 2001-07-11 | 2002-05-16 | Heating transpiration method and heating transpiration container used therefor |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007133290A Division JP4199815B2 (en) | 2001-07-11 | 2007-05-18 | Heating transpiration method and heating transpiration container used therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003250417A true JP2003250417A (en) | 2003-09-09 |
| JP4317349B2 JP4317349B2 (en) | 2009-08-19 |
Family
ID=28678678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002141087A Expired - Fee Related JP4317349B2 (en) | 2001-07-11 | 2002-05-16 | Heating transpiration method and heating transpiration container used therefor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4317349B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003095822A (en) * | 2001-09-25 | 2003-04-03 | Sumitomo Chem Co Ltd | Mite inhibitory resin composition |
| JP2013014524A (en) * | 2011-07-01 | 2013-01-24 | Dainippon Jochugiku Co Ltd | Aromatic mothproofing agent |
-
2002
- 2002-05-16 JP JP2002141087A patent/JP4317349B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003095822A (en) * | 2001-09-25 | 2003-04-03 | Sumitomo Chem Co Ltd | Mite inhibitory resin composition |
| JP2013014524A (en) * | 2011-07-01 | 2013-01-24 | Dainippon Jochugiku Co Ltd | Aromatic mothproofing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4317349B2 (en) | 2009-08-19 |
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