JP2003002733A - Ceramics for removing slime or the like around kitchen sink cabinet - Google Patents
Ceramics for removing slime or the like around kitchen sink cabinetInfo
- Publication number
- JP2003002733A JP2003002733A JP2001215999A JP2001215999A JP2003002733A JP 2003002733 A JP2003002733 A JP 2003002733A JP 2001215999 A JP2001215999 A JP 2001215999A JP 2001215999 A JP2001215999 A JP 2001215999A JP 2003002733 A JP2003002733 A JP 2003002733A
- Authority
- JP
- Japan
- Prior art keywords
- ceramics
- kitchen sink
- shape
- slime
- sink cabinet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims description 12
- 239000000463 material Substances 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 3
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000011941 photocatalyst Substances 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 5
- 230000009931 harmful effect Effects 0.000 abstract description 4
- 230000001699 photocatalysis Effects 0.000 abstract description 4
- 239000004408 titanium dioxide Substances 0.000 abstract description 3
- 206010035148 Plague Diseases 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 239000011343 solid material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000010304 firing Methods 0.000 description 5
- 235000019645 odor Nutrition 0.000 description 4
- 229910052845 zircon Inorganic materials 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 102100033040 Carbonic anhydrase 12 Human genes 0.000 description 1
- 102100033029 Carbonic anhydrase-related protein 11 Human genes 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 101000867855 Homo sapiens Carbonic anhydrase 12 Proteins 0.000 description 1
- 101000867841 Homo sapiens Carbonic anhydrase-related protein 11 Proteins 0.000 description 1
- 101001075218 Homo sapiens Gastrokine-1 Proteins 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003669 anti-smudge Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
- Sink And Installation For Waste Water (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Ceramic Products (AREA)
- Catalysts (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】この発明は厨房用流し台近辺
における残滓受け篭や排水パイプ等のヌメリ及び悪臭等
を防止ないし除去するセラミックスに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a ceramic for preventing or removing slime and bad odor of a residue receiving basket, a drainage pipe, etc. near a kitchen sink.
【０００２】[0002]
【従来の技術】厨房用流し台近辺、とりわけ残滓受け篭
や排水管等には微生物の働きによりヌメリや悪臭を生じ
やすいため、これを防止ないし除去する目的で、既に塩
素系や過炭酸ソーダ系のヌメリ防止剤が市販されてい
る。それらの中には固形物に成形したものもあるが、何
れも水分によって水和膨張するとともに２〜３週間で溶
解し、その際に塩素ガスを発生したり、残滓や排水中に
有害物が流出するので、環境汚染の原因ともなり、また
消費者は溶解し消失した製品を補うために、その都度取
り替え・補充を要しているのが現状である。2. Description of the Related Art In the vicinity of a kitchen sink, especially slag receiving baskets and drain pipes, slimes and offensive odors are easily generated by the action of microorganisms. Anti-smudge agents are commercially available. Some of them are molded into solids, but they both hydrate and expand with water and dissolve in a few weeks, generating chlorine gas at that time, and toxic substances in the residue and wastewater. Since it is spilled, it also causes environmental pollution, and the current situation is that consumers need to replace and replenish the dissolved and lost products each time.
【０００３】[0003]
【発明が解決しようとする課題】厨房付近の衛生環境を
良好に保つために、二次的に有害物を生じたり頻繁な取
り替えを要するようでは、真にこの問題を解決すること
にはならない。そこで常に水分に接触していても全く溶
解・流出することがなく、しかもヌメリ等の弊害を長期
にわたって安定的に防止できる扱い易い製品の提供が要
望されていた。本発明はかかる課題を解決しようとする
ものである。In order to maintain a good hygienic environment near the kitchen, it is not possible to truly solve this problem if secondary harmful substances are generated or frequent replacement is required. Therefore, it has been demanded to provide a product which is not dissolved or leaked out at all even if it is constantly in contact with water, and which can easily prevent harmful effects such as slime over a long period of time and which is easy to handle. The present invention is intended to solve such problems.
【０００４】[0004]
【課題を解決するための手段】本発明者らはヌメリ等の
原因となる微生物の働きを抑える化学物質の付与という
手段によることなく、また電気等の物理的エネルギーを
使うことなく、所期の目的を達成できる手段を種々試み
てきたが、意外にも次のような手段でこれを解決できる
ことが判明し、本発明に至った。[Means for Solving the Problems] The inventors of the present invention have not expected to use a chemical substance that suppresses the action of microorganisms that cause slime or the like, or to use a physical energy such as electricity, for a desired purpose. Although various means have been tried to achieve the object, it was surprisingly found that this can be solved by the following means, resulting in the present invention.
【０００５】すなわち、アルミニウム酸化物とジルコニ
ウム系金属酸化物とカーボンのうち少なくとも１つを主
成分として含む遠赤外線放射材料と、チタン酸化物を少
なくとも主成分として含む光触媒材料を、３〜３０：１
の比率で混合して所定形状に成形し、これを７００〜１
３５０℃で焼結して、セラミックス製品とする。That is, the far-infrared emitting material containing at least one of aluminum oxide, zirconium-based metal oxide and carbon as a main component and the photocatalytic material containing titanium oxide as at least a main component are contained in an amount of 3 to 30: 1.
Mixed in a ratio of 1 to form into a predetermined shape, which is 700 to 1
Sinter at 350 ° C. to obtain a ceramic product.
【０００６】上記において、実際に成形・焼結してセラ
ミックス製品とするためには、粘土等の結合材料の配合
を要することは、通常の窯業製品の場合と同様である。
従って上記における配合は、粘土中にもこれらの成分が
含まれていることも想定した上で、全体としての比率を
述べたものであり、また「主成分」とは、具体的には５
０重量％以上含むものとして扱い、その上で全体に換算
するものとする。In the above, it is necessary to mix a binder material such as clay in order to actually form and sinter into a ceramic product, as in the case of a normal ceramic product.
Therefore, the above-mentioned composition describes the ratio as a whole on the assumption that these components are also contained in clay, and the “main component” is specifically 5
It shall be treated as containing 0% by weight or more, and then converted as a whole.
【０００７】様々な実験によれば、光触媒材料に対する
遠赤外線放射材料の比率が３倍未満もしくは３０倍を超
えると、所期の目的を達成するためには適さないことが
判明した。Various experiments have revealed that a ratio of far-infrared emitting material to photocatalytic material of less than 3 times or more than 30 times is not suitable for achieving the intended purpose.
【０００８】また焼成温度が７００℃に満たないものは
十分な耐水性が得られないか或いは鉛等の害を伴いがち
であり、１３５０℃を超えたものは著しくコスト高にな
るばかりか、かえって製品の性能を害なうことが判っ
た。なお好ましい焼成温度は、通常１０００〜１１００
℃である。If the firing temperature is lower than 700 ° C., sufficient water resistance cannot be obtained or lead is liable to be harmed. If the firing temperature is higher than 1350 ° C., not only the cost is significantly high, but rather It was found to impair the performance of the product. The preferable firing temperature is usually 1000 to 1100.
℃.
【０００９】この際、遠赤外線放射性材料として、アル
ミナやジルコン系素材を用いる場合は酸化焼成を原則と
するが、カーボンを用いる場合にはそれが燃焼・消失し
ないように、非酸化ないし還元焼成するものとする。At this time, when alumina or zircon-based material is used as the far-infrared radiation material, oxidative firing is in principle, but when carbon is used, non-oxidative or reduction firing is performed so that it does not burn or disappear. I shall.
【００１０】なお具体的な成形品の形状としては、図１
に掲げたような（略円板状の）板片状体１であって、こ
れに複数の貫通孔２を穿ったものが特に好ましい。この
貫通孔２のうちの一つは紐を通して板片状の当該セラミ
ックスを括り付けながら残滓受け篭内に収めるのに使わ
れ、他のそれらは水の通路をつくる働きをする。The concrete shape of the molded product is shown in FIG.
It is particularly preferable that the plate piece 1 (substantially disk-shaped) as described in (1) above is provided with a plurality of through holes 2. One of the through holes 2 is used to hold the plate-shaped ceramics in a slag receiving basket while bundling the ceramics through a string, and the other ones serve to form a passage for water.
【００１１】[0011]
【作用】本発明のセラミックスを例えば厨房用流し台の
残滓受け篭内に収めると、水分によって膨潤・崩壊した
り、成分が溶出することは全くないが、にもかかわらず
ヌメリの発生が抑えられ、悪臭も減少した。そのメカニ
ズムを学術的に解明することは本願の役目ではないが、
およそ次のような理由によるものと考えられる。When the ceramic of the present invention is stored in, for example, a residue receiving basket of a kitchen sink, it does not swell or disintegrate with water or elute components, but it nevertheless suppresses slime formation. The stench also decreased. Although it is not the role of the present application to elucidate the mechanism academically,
It is considered that the reason is as follows.
【００１２】すなわち、完全にセラミック化されたアル
ミナやジルコン系の鉱物やカーボン等は、常温において
波長５〜３０μの遠赤外線を優先的に放射ないし反射す
る。一方、酸化チタンは光触媒機能を有しており、これ
らの相互作用は、ヌメリや悪臭の原因となる嫌気性微生
物に対しその代謝を阻害すると考えられ、またその発生
や増殖を抑えるなどの抗菌性を発揮することにより、結
果として所期の目的を達成することができたと推定され
る。That is, completely ceramicized alumina, zircon-based minerals, carbon and the like preferentially emit or reflect far infrared rays having a wavelength of 5 to 30 μm at room temperature. On the other hand, titanium oxide has a photocatalytic function, and these interactions are considered to inhibit the metabolism of anaerobic microorganisms that cause slime and malodor, and antibacterial properties such as suppressing its generation and proliferation. It is highly probable that the intended purpose was achieved as a result by exerting the above.
【００１３】[0013]
【発明の実施の形態】重量において、二酸化珪素３１
％、酸化アルミニウム３８％、酸化ジルコン２２％、二
酸化チタン７％、酸化カリウム１．３％、酸化マグネシ
ウム０．７％の各粉末を適当なバインダー及び水分とと
もに撹拌・混合して、これをフレキションプレスで図１
のような形状に成形する。DETAILED DESCRIPTION OF THE INVENTION By weight, silicon dioxide 31
%, Aluminum oxide 38%, Zircon oxide 22%, Titanium dioxide 7%, Potassium oxide 1.3%, Magnesium oxide 0.7% powder with stirring and mixing with a suitable binder and water, and flexing this. Figure 1 on the press
Mold into a shape like.
【００１４】或いは又、アルミナＡｌ２Ｏ３３重量部、
酸化ジルコンＺｒＯ２３重量部、二酸化チタンＴｉＯ２
１重量部、及び蛙目粘土３重量部を適当な水分ととも
に混練し、同様に成形する。Alternatively, 3 parts by weight of Al 2 O 3 alumina,
Zircon oxide ZrO 2 3 parts by weight, titanium dioxide TiO 2
1 part by weight and 3 parts by weight of frog clay are kneaded together with an appropriate water content and similarly shaped.
【００１５】その具体的寸法は、例えば円板の直径６５
ｍｍ、暑さ１０ｍｍであって、これに直径７〜８ｍｍの
貫通孔を４個、図示したように設けるものとする。The specific dimensions are, for example, the diameter 65 of the disk.
mm, the heat is 10 mm, and four through holes having a diameter of 7 to 8 mm are provided in the hole as illustrated.
【００１６】上記成形物を１０００〜１１００℃で酸化
焼成し焼結して、本発明のセラミックスを得る。これを
厨房用流し台の残滓受け篭に紐で括り着け、そのまま使
用したところ、３ケ月を経ても全く膨潤、溶出、崩壊等
の兆しが見られず、しかも篭や排水管等におけるヌメリ
が著しく減少し、悪臭も減って掃除が容易となった。The above molded product is oxidized and baked at 1000 to 1100 ° C. and sintered to obtain the ceramic of the present invention. When this was tied up with a string on the residue receiving basket of the kitchen sink with a string and used as it was, no signs of swelling, elution, collapse, etc. were seen even after 3 months, and the slime in the basket and drainage pipe was significantly reduced. However, the odor was reduced and cleaning became easier.
【００１７】[0017]
【発明の効果】このように本発明によれば、流出するよ
うな薬剤を用いたり電源等を要することなく、安定的な
セラミックスを取り付けるのみで長期にわたり厨房用流
し台付近のヌメリや悪臭を防止することができ、有害物
の二次放出もなく、メンテナンスや掃除が容易になるな
どの多大な効果がある。As described above, according to the present invention, it is possible to prevent slime and a bad odor in the vicinity of the kitchen sink for a long period of time by simply attaching stable ceramics without using a chemical that may flow out or requiring a power source. Therefore, there is no secondary emission of harmful substances, and there are great effects such as easy maintenance and cleaning.
【図１】本発明一例の外観を示す見取図FIG. 1 is a sketch drawing showing the appearance of an example of the present invention.
１……板片状体 ２……貫通孔 1 ... Plate piece 2 ... Through hole
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０２Ｆ 1/50 ５２０ Ｃ０２Ｆ 1/50 ５３１Ｈ ４Ｇ０３２ ５３１ ５４０Ｅ ４Ｇ０６９ ５４０ ５６０Ｃ ５６０ 1/72 １０１ 1/72 １０１ Ｃ０４Ｂ 35/48 Ｚ Ｃ０４Ｂ 35/48 Ｅ０３Ｃ 1/30 35/52 Ｃ０４Ｂ 35/10 Ｚ Ｅ０３Ｃ 1/30 35/52 Ｂ (72)発明者 西川 艶子 大阪市東成区中本３−９−20−1011 Ｆターム(参考） 2D061 AA00 AB06 AE10 4D037 AA11 AB03 AB04 BA17 BA18 CA12 4D050 AA15 AB04 AB06 BB01 BC06 CA07 4G030 AA04 AA07 AA16 AA17 AA36 AA37 AA60 BA32 GA14 GA22 GA27 HA05 4G031 AA01 AA03 AA11 AA12 AA29 AA30 AA40 BA26 GA04 GA11 4G032 AA06 AA23 AA24 AA26 AA27 BA02 4G069 AA02 AA08 BA01A BA01B BA04A BA04B BA05A BA05B BA08A BA08B BA10B BA48A CA01 CA11 CA17 DA06 EA02X EA02Y EA11 FB70 FB76─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C02F 1/50 520 C02F 1/50 531H 4G032 531 540E 4G069 540 560C 560 1/72 101 1/72 101 C04B 35 / 48 Z C04B 35/48 E03C 1/30 35/52 C04B 35/10 Z E03C 1/30 35/52 B (72) Inventor Tsutoko Nishikawa 3-9-20-1011 F-term of Nakamoto, Higashisei-ku, Osaka ( (Reference) 2D061 AA00 AB06 AE10 4D037 AA11 AB03 AB04 BA17 BA18 CA12 4D050 AA15 AB04 AB06 BB01 BC06 CA07 4G030 AA04 AA07 AA16 AA17 AA36 AA37 AA60 BA32 GA14 GA22 GA27 GA27 GA27 GA27 HA27 A05 A4 A03 BA02 4G069 AA02 AA08 BA01A BA01B BA04A BA04B BA05A BA05B BA08A BA08B BA10B BA48A CA01 CA11 CA17 DA06 EA02X EA02Y EA11 FB70 FB76
Claims (2)
酸化物とカーボンのうち少なくとも１つを主成分として
含む遠赤外線放射材料と、チタン酸化物を少なくとも主
成分として含む光触媒材料を、３〜３０：１の比率で混
合して所定形状に成形し、これを７００〜１３５０℃で
焼結したことを特徴とする厨房用流し台近辺におけるヌ
メリ等除去用セラミックス。1. A far-infrared emitting material containing at least one of aluminum oxide, zirconium-based metal oxide and carbon as a main component, and a photocatalyst material containing at least titanium oxide as a main component in an amount of 3 to 30: 1. The ceramics for removing slime and the like near the sink for a kitchen, which are obtained by mixing at a ratio of 1 to form a predetermined shape and sintering the mixture at 700 to 1350 ° C.
である請求項１記載の厨房用流し台近辺におけるヌメリ
等除去用セラミックス。2. The ceramics for removing slime and the like near a kitchen sink according to claim 1, wherein the predetermined shape is a plate piece provided with a plurality of through holes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001215999A JP2003002733A (en) | 2001-06-12 | 2001-06-12 | Ceramics for removing slime or the like around kitchen sink cabinet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001215999A JP2003002733A (en) | 2001-06-12 | 2001-06-12 | Ceramics for removing slime or the like around kitchen sink cabinet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003002733A true JP2003002733A (en) | 2003-01-08 |
Family
ID=19050534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001215999A Pending JP2003002733A (en) | 2001-06-12 | 2001-06-12 | Ceramics for removing slime or the like around kitchen sink cabinet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003002733A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007148054A1 (en) | 2006-06-23 | 2007-12-27 | Reckitt Benckiser Inc. | Improvements in dispensing devices and compositions therefor |
| US8197739B2 (en) | 2006-06-23 | 2012-06-12 | Reckitt Benckiser Llc | Method for manufacturing cageless lavatory dispensing devices |
| US8277715B2 (en) | 2006-03-22 | 2012-10-02 | Reckitt Benckiser Llc | Process for manufacturing improved dispensing devices |
| US8615820B2 (en) | 2006-03-22 | 2013-12-31 | Reckitt Benckiser Llc | Dispensing devices |
| CN103805948A (en) * | 2014-01-20 | 2014-05-21 | 福州阿石创光电子材料有限公司 | Titanium crystal sintering die |
| US8858879B2 (en) | 2008-07-03 | 2014-10-14 | Reckitt Benckiser Llc | Method for production of dispensing devices |
| US8966674B2 (en) | 2008-07-03 | 2015-03-03 | Reckitt Benckiser Llc | Dispensing device for toilet bowl |
| KR20150095305A (en) * | 2014-02-13 | 2015-08-21 | 보 현 이 | The method of preparing frypan of double coating layers using ceramics composition of high hardness |
| US9334640B2 (en) | 2007-09-21 | 2016-05-10 | Reckitt Benckiser Llc. | Cageless dispensing device |
-
2001
- 2001-06-12 JP JP2001215999A patent/JP2003002733A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8277715B2 (en) | 2006-03-22 | 2012-10-02 | Reckitt Benckiser Llc | Process for manufacturing improved dispensing devices |
| US8615820B2 (en) | 2006-03-22 | 2013-12-31 | Reckitt Benckiser Llc | Dispensing devices |
| US8685304B2 (en) | 2006-03-22 | 2014-04-01 | Reckitt Benckiser Llc | Process for manufacturing improved dispensing devices |
| US8197739B2 (en) | 2006-06-23 | 2012-06-12 | Reckitt Benckiser Llc | Method for manufacturing cageless lavatory dispensing devices |
| AU2007262851B2 (en) * | 2006-06-23 | 2013-01-31 | Reckitt Benckiser Llc | Improvements in dispensing devices and compositions therefor |
| WO2007148054A1 (en) | 2006-06-23 | 2007-12-27 | Reckitt Benckiser Inc. | Improvements in dispensing devices and compositions therefor |
| US9334640B2 (en) | 2007-09-21 | 2016-05-10 | Reckitt Benckiser Llc. | Cageless dispensing device |
| US8858879B2 (en) | 2008-07-03 | 2014-10-14 | Reckitt Benckiser Llc | Method for production of dispensing devices |
| US8966674B2 (en) | 2008-07-03 | 2015-03-03 | Reckitt Benckiser Llc | Dispensing device for toilet bowl |
| CN103805948A (en) * | 2014-01-20 | 2014-05-21 | 福州阿石创光电子材料有限公司 | Titanium crystal sintering die |
| CN103805948B (en) * | 2014-01-20 | 2015-12-02 | 福建阿石创新材料股份有限公司 | A kind of titanium crystal sintering mold |
| KR101600166B1 (en) | 2014-02-13 | 2016-03-14 | 보 현 이 | The method of preparing frypan of double coating layers using ceramics composition of high hardness |
| KR20150095305A (en) * | 2014-02-13 | 2015-08-21 | 보 현 이 | The method of preparing frypan of double coating layers using ceramics composition of high hardness |
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