JP2002362921A - Method for preventing caking of strontium compound or barium compound and composition therefor - Google Patents
Method for preventing caking of strontium compound or barium compound and composition thereforInfo
- Publication number
- JP2002362921A JP2002362921A JP2001170673A JP2001170673A JP2002362921A JP 2002362921 A JP2002362921 A JP 2002362921A JP 2001170673 A JP2001170673 A JP 2001170673A JP 2001170673 A JP2001170673 A JP 2001170673A JP 2002362921 A JP2002362921 A JP 2002362921A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- strontium
- average particle
- barium
- surface area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明はストロンチウム化合
物又はバリウム化合物の固結防止に関し、詳しくは、微
粒子珪酸を添加混合する固結防止方法に関する。The present invention relates to the prevention of caking of a strontium compound or a barium compound, and more particularly, to a caking prevention method of adding and mixing particulate silica.
【０００２】[0002]
【従来の技術】ストロンチウム化合物又はバリウム化合
物の結晶は従来では製造後の保管の経時的な変化を受け
徐徐に固結が起こり、更に塊状にまで成長し、取扱いが
困難な状態であった。2. Description of the Related Art Conventionally, crystals of a strontium compound or a barium compound are gradually solidified due to a change over time in storage after production, and further grow to a mass, which is difficult to handle.
【０００３】この原因となる固結及び凝集現象は粒子の
接触点で溶解・析出を繰返し液橋を作り、この液橋が温
湿度作用によって固橋となり、結合するためと考えられ
ている。固結防止法としてはフラッシングのような粒子
の表面改質及び環境のコントロールがあるがそれに応じ
た設備増強等の費用がかかる問題を抱えていた。It is thought that the caking and cohesion phenomena causing this are caused by repeatedly dissolving and precipitating at the contact points of the particles to form a liquid bridge, and the liquid bridge becomes a solid bridge due to the action of temperature and humidity and is bonded. As a method for preventing caking, there is a problem such as flushing, which involves surface modification of particles and control of the environment, but it requires a cost for equipment enhancement and the like.
【０００４】[0004]
【発明が解決しようとする課題】本発明は上述したよう
な問題を解決するためになされたものであって、ストロ
ンチウ化合物又はバリウム化合物に固結防止剤を少量添
加混合し、容易に効果的に固結を防止し、長期保管を可
能にする方法を提供することにある。SUMMARY OF THE INVENTION The present invention has been made in order to solve the above-mentioned problems, and is intended to easily and effectively add a small amount of an anti-caking agent to a strontium compound or a barium compound and mix them. An object of the present invention is to provide a method for preventing caking and enabling long-term storage.
【０００５】[0005]
【課題を解決するための手段】本発明は微粒子珪酸を
０．１〜１５．０重量％添加混合することによりその目
的を達し、篩分法による平均粒子径が１５０μｍ以上の
場合は０．５〜３．０重量％が望ましい。またその際の
微粒子珪酸の比表面積は１００〜４００ｍ2／ｇ、さら
に望ましくは２００〜４００m2／ｇが望ましいことを特
徴とする固結防止方法である。The object of the present invention is attained by adding and mixing 0.1 to 15.0% by weight of fine-particle silicic acid. ~ 3.0% by weight is desirable. In this case, the specific surface area of the fine silica particles is preferably 100 to 400 m2 / g, more preferably 200 to 400 m2 / g.
【０００６】以下本発明の構成要件について詳述する。
本発明における微粒子珪酸は特に制限が無く、湿式法、
乾式法によるものいずれでも良く、適宜選択し使用でき
るが比表面積が非常に大きな１００〜４００m2/gの微粉
末状の微粒子珪酸が好ましい。Hereinafter, the constituent elements of the present invention will be described in detail.
The particulate silica in the present invention is not particularly limited, a wet method,
Any of the dry methods may be used, and it can be appropriately selected and used, but finely divided silica in the form of fine powder having a very large specific surface area of 100 to 400 m2 / g is preferable.
【０００７】本発明における微粒子珪酸の含有率はスト
ロンチウム化合物又はバリウム化合物の篩分法による平
均粒子径が１５０μｍ以上であれば０．１重量％以上
で、また１５０μｍ以下であっても１５重量％以上であ
れば固結防止効果が発揮されるがあまり多量ではストロ
ンチウム化合物又はバリウム化合物の純度の低下という
問題が発生するためストロンチウム化合物又はバリウム
化合物の篩分法による平均粒子径が１５０μｍ以上で微
粒子珪酸の含有率が０．１〜５．０重量％が好ましく、
０．５〜３．０重量％であればさらに好ましい。In the present invention, the content of the fine particle silicic acid is 0.1% by weight or more if the average particle diameter of the strontium compound or the barium compound is 150 μm or more by sieving. If it is, the anti-caking effect is exerted, but if the amount is too large, the problem of reduced purity of the strontium compound or barium compound occurs, so that the average particle diameter of the strontium compound or barium compound by the sieving method is 150 μm or more and the fine silica The content is preferably 0.1 to 5.0% by weight,
More preferably, the amount is 0.5 to 3.0% by weight.
【０００８】本発明のストロンチウム化合物又はバリウ
ム化合物の篩分法による平均粒子経は１５〜４００μｍ
が望ましく、さらに望ましくは１５０〜４００μｍが望
ましい結果を与える。本発明におけるストロンチウム化
合物又はバリウム化合物と微粒子珪酸の添加混合方法は
それぞれ所要量加えて常温で混合すれば良いのであり、
公知の混合手段を適宜選択して行なえば良い。The average particle size of the strontium compound or barium compound of the present invention by a sieving method is 15 to 400 μm.
Is more preferable, and more preferably 150 to 400 μm gives a desired result. The addition and mixing method of the strontium compound or the barium compound and the fine particle silicic acid in the present invention may be added at required amounts and mixed at room temperature,
What is necessary is just to select a well-known mixing means suitably and carry out.
【０００９】[0009]
【実施例】以下に実施例として硝酸ストロンチウム、塩
化ストロンチウム、水酸化ストロンチウム、硝酸バリウ
ム、酢酸バリウムを挙げて本発明を説明するが、本発明
はこの実施例により何ら限定されるものではない。EXAMPLES The present invention will be described below with reference to examples of strontium nitrate, strontium chloride, strontium hydroxide, barium nitrate, and barium acetate, but the present invention is not limited to these examples.
【００１０】実施例−１ 硝酸ストロンチウム８０kg（平均粒子径１７μｍ）に微
粒子珪酸（比表面積４０２m2/g）を１０．０重量％の比
率である８．８９kgをリボンブレンダーで混合し、 紙
袋３袋にそれぞれ２５kgを詰めた。それら紙袋１袋につ
き１４３gf／cm2の荷重を加え、常温常湿で放置し、４
週間、８週間、１２週間後にそれぞれ１袋づつ開封し、
固結防止効果の確認を行なった。Example-1 A strontium nitrate (80 kg, average particle diameter: 17 μm) was mixed with fine particles of silicic acid (specific surface area: 402 m 2 / g) at a ratio of 10.0% by weight by 8.89 kg by a ribbon blender to form three paper bags. Each packed 25 kg. A load of 143 gf / cm2 was applied to each of the paper bags, and the bag was allowed to stand at room temperature and humidity.
After one week, eight weeks, and 12 weeks, open one bag at a time,
The effect of preventing caking was confirmed.
【００１１】実施例−２ 硝酸ストロンチウム８０kg（平均粒子径１７μｍ）に微
粒子珪酸（比表面積１０７m2/g）を１５．０重量％の混
合比率である１４．１２kg混合した以外は実施例−１と
同様な試験を行なった。Example 2 Same as Example 1 except that 80 kg of strontium nitrate (average particle diameter: 17 μm) was mixed with 14.12 kg of a 15.0 wt% fine silica powder (specific surface area: 107 m 2 / g). Tests were performed.
【００１２】実施例−３ 硝酸ストロンチウム８０kg（平均粒子径１４７μｍ）に
微粒子珪酸（比表面積１０７m2/g）を０．１重量％の混
合比率である０．０８kgを混合した以外は実施例−１と
同様な試験を行なった。Example 3 Example 1 was repeated except that 80 kg of strontium nitrate (average particle diameter: 147 μm) and 0.08 kg of a mixing ratio of 0.1% by weight of fine particle silica (specific surface area: 107 m 2 / g) were mixed. A similar test was performed.
【００１３】実施例−４ 硝酸ストロンチウム８０kg（平均粒子径１４７μｍ）に
微粒子珪酸（比表面積１０７m2/g）を０．５重量％の混
合比率である０．４０kgを混合した以外は実施例−１と
同様な試験を行なった。Example 4 Example 1 was the same as Example 1 except that 80 kg of strontium nitrate (average particle diameter: 147 μm) was mixed with 0.40 kg of a 0.5% by weight fine particle silica (specific surface area: 107 m 2 / g). A similar test was performed.
【００１４】実施例−５ 硝酸ストロンチウム８０kg（平均粒子径１４７μｍ）に
微粒子珪酸（比表面積２０６m2/g）を５．０重量％の混
合比率である４．２１kgを混合した以外は実施例−１と
同様な試験を行なった。Example 5 Example 1 was repeated except that 80 kg of strontium nitrate (average particle diameter: 147 μm) was mixed with 4.21 kg of a 5.0 wt% fine silica powder (specific surface area: 206 m 2 / g). A similar test was performed.
【００１５】実施例−６ 硝酸ストロンチウム８０kg（平均粒子径２８４μｍ）に
微粒子珪酸（比表面積１０７m2/g）を０．１重量％の混
合比率である０．０８kgを混合した以外は実施例−１と
同様な試験を行なった。Example-6 Example 1 was repeated except that 80 kg of strontium nitrate (average particle diameter: 284 μm) was mixed with 0.08 kg of a 0.1% by weight fine particle silica (specific surface area: 107 m2 / g). A similar test was performed.
【００１６】実施例−７ 硝酸ストロンチウム８０kg（平均粒子径２８４μｍ）に
微粒子珪酸（比表面積２０６m2/g）を３．０重量％の混
合比率である２．４７kgを混合した以外は実施例−１と
同様な試験を行なった。Example -7 Example 1 was repeated except that 80 kg of strontium nitrate (average particle diameter: 284 μm) was mixed with 2.47 kg of a 3.0 wt% fine silica powder (specific surface area: 206 m 2 / g). A similar test was performed.
【００１７】実施例−８ 硝酸ストロンチウム８０kg（平均粒子径３８３μｍ）に
微粒子珪酸（比表面積１０７m2/g）を０．１重量％の混
合比率である０．０８kgを混合した以外は実施例−１と
同様な試験を行なった。Example -8 Example 8 was repeated except that 80 kg of strontium nitrate (average particle diameter: 383 μm) was mixed with 0.08 kg of a 0.1% by weight fine particle silica (specific surface area: 107 m 2 / g). A similar test was performed.
【００１８】実施例−９ 硝酸ストロンチウム８０kg（平均粒子径３８３μｍ）に
微粒子珪酸（比表面積２０６m2/g）を１．０重量％の混
合比率である０．８１kgを混合した以外は実施例−１と
同様な試験を行なった。Example-9 Example 1 was repeated except that 80 kg of strontium nitrate (average particle diameter: 383 μm) was mixed with 0.81 kg of a 1.0% by weight fine particle silica (specific surface area: 206 m2 / g). A similar test was performed.
【００１９】実施例−１０ 塩化ストロンチウム８０kg（平均粒子径３９５μｍ）に
微粒子珪酸（比表面積２０６m2/g）を０．５重量％の比
率である０．４０kgをリボンブレンダーで混合し、 紙
袋３袋にそれぞれ２５kgを詰めた。それら紙袋１袋につ
き１４３gf／cm2の荷重を加え、常温常湿で放置し、４
週間、８週間、１２週間後にそれぞれ１袋づつ開封し、
固結防止効果の確認を行なう試験を行なった。Example-10 80 kg of strontium chloride (average particle size: 395 μm) and 0.40 kg of a 0.5% by weight fine particle silica (specific surface area: 206 m 2 / g) were mixed by a ribbon blender into a three paper bag. Each packed 25 kg. A load of 143 gf / cm2 was applied to each of the paper bags, and the bag was allowed to stand at room temperature and humidity.
After one week, eight weeks, and 12 weeks, open one bag at a time,
A test was conducted to confirm the anti-caking effect.
【００２０】実施例−１１ 塩化ストロンチウム８０kg（平均粒子径３９５μｍ）に
微粒子珪酸（比表面積２０６m2/g）を１．０重量％の混
合比率である０．８１kgを混合した以外は実施例−１０
と同様な試験を行なった。Example-11 Example-10 was repeated except that 80 kg of strontium chloride (average particle diameter: 395 μm) was mixed with 0.81 kg of a 1.0% by weight fine particle silica (specific surface area: 206 m2 / g).
The same test was performed.
【００２１】実施例−１２ 水酸化ストロンチウム８０kg（平均粒子径３８１μｍ）
に微粒子珪酸（比表面積２０６m2/g）を０．５重量％の
比率である０．４０kgをリボンブレンダーで混合し、
紙袋３袋にそれぞれ２５kgを詰めた。それら紙袋１袋に
つき１４３gf／cm2の荷重を加え、常温常湿で放置し、
４週間、８週間、１２週間後にそれぞれ１袋づつ開封
し、固結防止効果の確認を行なう試験を行なった。Example-12 80 kg of strontium hydroxide (average particle size: 381 μm)
Then, 0.40 kg, which is a ratio of 0.5% by weight, of fine particle silicic acid (specific surface area 206 m2 / g) is mixed with a ribbon blender,
Each of the three paper bags was filled with 25 kg. A load of 143 gf / cm2 is applied to each of these paper bags, and the bags are allowed to stand at room temperature and humidity.
After 4 weeks, 8 weeks, and 12 weeks, the bags were opened one by one, and a test was performed to confirm the effect of preventing caking.
【００２２】実施例−１３ 水酸化ストロンチウム８０kg（平均粒子径３８１μｍ）
に微粒子珪酸（比表面積１０７m2/g）を１．０重量％の
混合比率である０．８１kg混合した以外は実施例−１２
と同様な試験を行なった。Example-13 80 kg of strontium hydroxide (average particle size: 381 μm)
Example -12, except that 0.81 kg of a 1.0% by weight mixing ratio of fine-particle silicic acid (specific surface area: 107 m2 / g) was added to the mixture.
The same test was performed.
【００２３】実施例−１４ 硝酸バリウム８０kg（平均粒子径１５μｍ）に微粒子珪
酸（比表面積４０２m2/g）を１０．０重量％の比率であ
る８．８９kgをリボンブレンダーで混合し、 紙袋３袋
にそれぞれ２５kgを詰めた。それら紙袋１袋につき１４
３gf／cm2の荷重を加え、常温常湿で放置し、４週間、
８週間、１２週間後にそれぞれ１袋づつ開封し、固結防
止効果の確認を行なう試験を行なった。Example -14 A mixture of 80 kg of barium nitrate (average particle size: 15 μm) and 8.89 kg of fine silica particles (specific surface area: 402 m 2 / g) at a ratio of 10.0% by weight was mixed with a ribbon blender into three paper bags. Each packed 25 kg. 14 per paper bag
Apply a load of 3 gf / cm2 and leave it at room temperature and humidity for 4 weeks.
After 8 weeks and 12 weeks, the bags were opened one by one, and a test was conducted to confirm the effect of preventing caking.
【００２４】実施例−１５ 硝酸バリウム８０kg（平均粒子径１５μｍ）に微粒子珪
酸（比表面積１０７m2/g）を１５．０重量％の混合比率
である１４．１２kgを混合した以外は実施例−１４と同
様な試験を行なった。Example -15 Example 14 was repeated except that 80 kg of barium nitrate (average particle diameter 15 μm) was mixed with 14.12 kg of a 15.0% by weight fine particle silica (specific surface area 107 m 2 / g). A similar test was performed.
【００２５】実施例−１６ 硝酸バリウム８０kg（平均粒子径１５８μｍ）に微粒子
珪酸（比表面積１０７m2/g）を０．１重量％の混合比率
である０．０８kgを混合した以外は実施例−１４と同様
な試験を行なった。Example -16 The procedure of Example -14 was repeated except that 80 kg of barium nitrate (average particle diameter: 158 μm) was mixed with 0.08 kg of a 0.1 wt% fine silica powder (specific surface area: 107 m 2 / g). A similar test was performed.
【００２６】実施例−１７ 硝酸バリウム８０kg（平均粒子径１５８μｍ）に微粒子
珪酸（比表面積１０７m2/g）を０．５重量％の混合比率
である０．４０kgを混合した以外は実施例−１４と同様
な試験を行なった。Example 17 Example 14 was the same as Example 14 except that 80 kg of barium nitrate (average particle size: 158 μm) was mixed with 0.40 kg of a 0.5% by weight fine silica powder (specific surface area: 107 m 2 / g). A similar test was performed.
【００２７】実施例−１８ 硝酸バリウム８０kg（平均粒子径１５８μｍ）に微粒子
珪酸（比表面積２０６m2/g）を５．０重量％の混合比率
である４．２１kgを混合した以外は実施例−１４と同様
な試験を行なった。Example -18 The same procedure as in Example 14 was carried out except that 4.21 kg of a mixing ratio of 5.0% by weight of particulate silica (specific surface area: 206 m2 / g) was mixed with 80 kg of barium nitrate (average particle diameter: 158 μm). A similar test was performed.
【００２８】実施例−１９ 硝酸バリウム８０kg（平均粒子径３１２μｍ）に微粒子
珪酸（比表面積１０７m2/g）を０．１重量％の混合比率
である０．０８kgを混合した以外は実施例−１４と同様
な試験を行なった。Example -19 Example 14 was repeated except that 80 kg of barium nitrate (average particle size: 312 μm) was mixed with 0.08 kg of a 0.1 wt% fine silica powder (specific surface area: 107 m 2 / g). A similar test was performed.
【００２９】実施例−２０ 硝酸バリウム８０kg（平均粒子径３１２μｍ）に微粒子
珪酸（比表面積２０６m2/g）を３．０重量％の混合比率
である２．４７kgを混合した以外は実施例−１０と同様
な試験を行なった。Example -20 The same procedure as in Example -10 was carried out except that 80 kg of barium nitrate (average particle diameter: 312 μm) and 2.47 kg of a mixing ratio of 3.0% by weight of particulate silica (specific surface area: 206 m 2 / g) were mixed. A similar test was performed.
【００３０】実施例−２１ 硝酸バリウム８０kg（平均粒子径３９６μｍ）に微粒子
珪酸（比表面積１０７m2/g）を０．１重量％の混合比率
である０．０８kgを混合した以外は実施例−１４と同様
な試験を行なった。Example -21 Example 14 was repeated except that 80 kg of barium nitrate (average particle diameter: 396 μm) and 0.08 kg of a mixing ratio of 0.1% by weight of fine silica particles (specific surface area: 107 m 2 / g) were mixed. A similar test was performed.
【００３１】実施例−２２ 硝酸バリウム８０kg（平均粒子径３９６μｍ）に微粒子
珪酸（比表面積２０６m2/g）を１．０重量％の混合比率
である０．８１kgを混合した以外は実施例−１４と同様
な試験を行なった。Example -22 Example 14 was repeated except that 80 kg of barium nitrate (average particle diameter: 396 μm) was mixed with 0.81 kg of a 1.0% by weight fine particle silica (specific surface area: 206 m 2 / g). A similar test was performed.
【００３２】実施例−２３ 酢酸バリウム８０kg（平均粒子径３７３μｍ）に微粒子
珪酸（比表面積２０６m2/g）を０．５０重量％の比率で
ある０．４０kgをリボンブレンダーで混合し、紙袋３袋
にそれぞれ２５kgを詰めた。それら紙袋１袋につき１４
３gf／cm2の荷重を加え、常温常湿で放置し、４週間、
８週間、１２週間後にそれぞれ１袋づつ開封し、固結防
止効果の確認を行なう試験を行なった。Example -23 80 kg of barium acetate (average particle diameter: 373 μm) and 0.40 kg of a 0.50 wt% fine silica powder (specific surface area: 206 m 2 / g) were mixed with a ribbon blender, and mixed in three paper bags. Each packed 25 kg. 14 per paper bag
Apply a load of 3 gf / cm2 and leave it at room temperature and humidity for 4 weeks.
After 8 weeks and 12 weeks, one bag was opened, and a test was conducted to confirm the effect of preventing caking.
【００３３】実施例−２４ 酢酸バリウム８０kg（平均粒子径３７３μｍ）に微粒子
珪酸（比表面積２０６m2/g）を１．０重量％の混合比率
である０．８１kgを混合した以外は実施例−２３と同様
な試験を行なった。Example -24 The procedure of Example 23 was repeated except that 80 kg of barium acetate (average particle diameter: 373 μm) was mixed with 0.81 kg of a 1.0% by weight fine silica particle (specific surface area: 206 m 2 / g). A similar test was performed.
【００３４】比較例−１ 硝酸ストロンチウム（平均粒子径３８３μｍ）のみ２５
kgを紙袋詰めにする以外は実施例−１と同様な試験を行
なった。Comparative Example 1 Strontium nitrate (average particle size: 383 μm) only 25
The same test as in Example 1 was performed except that the kg was packed in a paper bag.
【００３５】比較例−２ 塩化ストロンチウム（平均粒子径３９５μｍ）のみ２５
kgを紙袋詰めにする以外は実施例−１０と同様な試験を
行なった。Comparative Example 2 Strontium chloride (average particle diameter: 395 μm) only 25
The same test as in Example 10 was performed except that the kg was packed in a paper bag.
【００３６】比較例−３ 水酸化ストロンチウム（平均粒子径３８１μｍ）のみ２
５kgを紙袋詰めにする以外は実施例−１２と同様な試験
を行なった。Comparative Example 3 Strontium hydroxide (average particle size: 381 μm) only 2
The same test as in Example -12 was conducted except that 5 kg was packed in a paper bag.
【００３７】比較例−４ 硝酸バリウム（平均粒子径３９６μｍ）のみ２５kgを紙
袋詰めにする以外は実施例−１４と同様な試験を行なっ
た。Comparative Example 4 The same test as in Example 14 was conducted except that only 25 kg of barium nitrate (average particle size: 396 μm) was packed in a paper bag.
【００３８】比較例−５ 酢酸バリウム（平均粒子径３７３μｍ）のみ２５kgを紙
袋詰めにする以外は実施例−２３と同様な試験を行なっ
た。Comparative Example-5 The same test as in Example 23 was conducted except that only 25 kg of barium acetate (average particle diameter: 373 μm) was packed in a paper bag.
【００３９】実施試験結果を表１にまとめた。The test results are shown in Table 1.
【００４０】[0040]
【表１】 ※平均粒子径は篩分法による。なお、固結状態を示す符
号は下記の如くとする。 ◎：優 さらさらした状態であり、塊が認められな
い。 ○：良 塊が僅かに認められるが手で掴めない状態。 △：普通 塊が認められ、手で掴めるが容易に崩す事が
できる状態。 ×：劣る 塊の数が多く、しかも固い。[Table 1] * The average particle size is determined by the sieving method. The symbols indicating the consolidated state are as follows. ：: Excellent The condition was smooth and no lump was observed. ：: Good lump is slightly recognized but cannot be grasped by hand. △: Normally, a lump is recognized and can be easily broken by hand. ×: Inferior Lump number is large and hard.
【００４１】[0041]
【発明の効果】以上のように本発明の固結防止方法はス
トロンチウム化合物又はバリウム化合物の固結を防止
し、長期の保管を可能にするものである。As described above, the caking preventing method of the present invention prevents caking of a strontium compound or a barium compound and enables long-term storage.
Claims (4)
に、微粒子珪酸を０．１〜１５．０重量％含有させるこ
とを特徴とする固結防止方法。1. A method for preventing caking, comprising adding 0.1 to 15.0% by weight of particulate silica to a strontium compound or a barium compound.
/gであることを特徴とする請求項１の固結防止方法。2. The fine silica particles have a specific surface area of 100 to 400 m @ 2.
2. The method according to claim 1, wherein the ratio is / g.
０μmであることを特徴とする請求項１及び２のストロ
ンチウム化合物又はバリウム化合物よりなる組成物。3. An average particle size of 15 to 40 as determined by sieving the particles.
3. A composition comprising the strontium compound or the barium compound according to claim 1, wherein the composition is 0 μm.
合物又はバリウム化合物が硝酸塩、水酸化物、塩化物、
酢酸塩であることを特徴とする固結防止法及び組成物。4. The strontium compound or barium compound according to claim 1, wherein the strontium compound or the barium compound is nitrate, hydroxide, chloride,
An anti-caking method and composition comprising an acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001170673A JP5017752B2 (en) | 2001-06-06 | 2001-06-06 | Composition of strontium compound or barium compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001170673A JP5017752B2 (en) | 2001-06-06 | 2001-06-06 | Composition of strontium compound or barium compound |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002362921A true JP2002362921A (en) | 2002-12-18 |
| JP5017752B2 JP5017752B2 (en) | 2012-09-05 |
Family
ID=19012555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001170673A Expired - Lifetime JP5017752B2 (en) | 2001-06-06 | 2001-06-06 | Composition of strontium compound or barium compound |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5017752B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006027966A (en) * | 2004-07-16 | 2006-02-02 | Sakai Chem Ind Co Ltd | Solidification prevention of magnesium nitrate hexahydrate |
| JP2014009122A (en) * | 2012-06-29 | 2014-01-20 | Nippon Electric Glass Co Ltd | Glass material and process of producing glass |
| WO2014027617A1 (en) * | 2012-08-16 | 2014-02-20 | 堺化学工業株式会社 | Particulate composition containing nitrate salt, method for producing same, glass, and method for storing nitrate salt |
| WO2015182466A1 (en) * | 2014-05-30 | 2015-12-03 | 日本化学工業株式会社 | Powdered composition containing barium compound |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6321535A (en) * | 1986-07-15 | 1988-01-29 | Shimadzu Corp | Sample apparatus |
| JPH0393605A (en) * | 1989-09-01 | 1991-04-18 | Asahi Glass Co Ltd | Improvement of flowability of metal oxide film powder |
| JPH03265667A (en) * | 1989-12-19 | 1991-11-26 | Buckman Lab Internatl Inc | Calcium pyroborate pigment covered with silica |
| JPH05279009A (en) * | 1992-03-31 | 1993-10-26 | Mitsui Toatsu Chem Inc | Sodium silicofluoride composition |
| JPH05310409A (en) * | 1992-05-13 | 1993-11-22 | Mitsui Toatsu Chem Inc | Ammonium phosphate composition |
| JPH07506081A (en) * | 1992-04-28 | 1995-07-06 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | Improved method for producing silica-coated inorganic particles |
| JP2000095587A (en) * | 1998-09-24 | 2000-04-04 | Onoda Chemical Industry Co Ltd | Granular magnesium sulfate fertilizer and its production |
| JP2001010888A (en) * | 1999-06-23 | 2001-01-16 | Nippon Kayaku Co Ltd | Gas generator composition |
-
2001
- 2001-06-06 JP JP2001170673A patent/JP5017752B2/en not_active Expired - Lifetime
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6321535A (en) * | 1986-07-15 | 1988-01-29 | Shimadzu Corp | Sample apparatus |
| JPH0393605A (en) * | 1989-09-01 | 1991-04-18 | Asahi Glass Co Ltd | Improvement of flowability of metal oxide film powder |
| JPH03265667A (en) * | 1989-12-19 | 1991-11-26 | Buckman Lab Internatl Inc | Calcium pyroborate pigment covered with silica |
| JPH05279009A (en) * | 1992-03-31 | 1993-10-26 | Mitsui Toatsu Chem Inc | Sodium silicofluoride composition |
| JPH07506081A (en) * | 1992-04-28 | 1995-07-06 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | Improved method for producing silica-coated inorganic particles |
| JPH05310409A (en) * | 1992-05-13 | 1993-11-22 | Mitsui Toatsu Chem Inc | Ammonium phosphate composition |
| JP2000095587A (en) * | 1998-09-24 | 2000-04-04 | Onoda Chemical Industry Co Ltd | Granular magnesium sulfate fertilizer and its production |
| JP2001010888A (en) * | 1999-06-23 | 2001-01-16 | Nippon Kayaku Co Ltd | Gas generator composition |
Non-Patent Citations (1)
| Title |
|---|
| 永井彰一郎編, 新しい工業材料の科学 Ｂ−８ シリカとアルミナ（コロイド製品）, JPN6012001629, 1967, pages 31 - 42, ISSN: 0002122464 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006027966A (en) * | 2004-07-16 | 2006-02-02 | Sakai Chem Ind Co Ltd | Solidification prevention of magnesium nitrate hexahydrate |
| JP4572613B2 (en) * | 2004-07-16 | 2010-11-04 | 堺化学工業株式会社 | Prevention of caking of magnesium nitrate |
| JP2014009122A (en) * | 2012-06-29 | 2014-01-20 | Nippon Electric Glass Co Ltd | Glass material and process of producing glass |
| WO2014027617A1 (en) * | 2012-08-16 | 2014-02-20 | 堺化学工業株式会社 | Particulate composition containing nitrate salt, method for producing same, glass, and method for storing nitrate salt |
| JP2014055098A (en) * | 2012-08-16 | 2014-03-27 | Sakai Chem Ind Co Ltd | Particulate composition including nitrate, production method of the same, glass, and preservation method of nitrate |
| JP2014177397A (en) * | 2012-08-16 | 2014-09-25 | Sakai Chem Ind Co Ltd | Particulate composition including nitrate, production method of the same, glass, and preservation method of nitrate |
| JP2014185076A (en) * | 2012-08-16 | 2014-10-02 | Sakai Chem Ind Co Ltd | Particulate composition including nitrate, production method of the same, glass, and preservation method of nitrate |
| KR101522151B1 (en) * | 2012-08-16 | 2015-05-20 | 사카이 가가쿠 고교 가부시키가이샤 | Particulate composition containing nitrate salt, method for producing same, and method for producing glass |
| KR101822704B1 (en) | 2012-08-16 | 2018-01-26 | 사카이 가가쿠 고교 가부시키가이샤 | Particulate composition containing nitrate salt, method for producing same, glass, and method for storing nitrate salt |
| WO2015182466A1 (en) * | 2014-05-30 | 2015-12-03 | 日本化学工業株式会社 | Powdered composition containing barium compound |
| JP2015224178A (en) * | 2014-05-30 | 2015-12-14 | 日本化学工業株式会社 | Powdery composition comprising barium compound |
| KR20170013242A (en) | 2014-05-30 | 2017-02-06 | 니폰 가가쿠 고교 가부시키가이샤 | Powdered composition containing barium compound |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5017752B2 (en) | 2012-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2010514660A5 (en) | ||
| JPS62868B2 (en) | ||
| CA2493176A1 (en) | Viscous compositions containing hydrophobic liquids | |
| JPS5896634A (en) | Composition based on water-soluble rubber, manufacture and use | |
| US4260420A (en) | Aqueous liquid adhesive composition and method | |
| JP2002362921A (en) | Method for preventing caking of strontium compound or barium compound and composition therefor | |
| US4245054A (en) | Process for the manufacture of a dry mixture for insulating stucco or plaster | |
| WO2018087318A1 (en) | Calcium silicate powders | |
| JP2005350636A (en) | Solidification material of soil | |
| US5193941A (en) | Grout and method of distributing aluminum therein | |
| US3829320A (en) | Hardening of refractory/sodium silicate mixtures | |
| JP2003013064A (en) | Dusting-preventing type solidification material, and method for producing dusting-preventing type solidification material | |
| JPH042644A (en) | Compound binder for concrete | |
| US20220127551A1 (en) | Suspension Medium for Improved Grit Delivery in Vapor Blast Operations | |
| US2520206A (en) | Silver brazing flux | |
| JP4572613B2 (en) | Prevention of caking of magnesium nitrate | |
| JPS6214524B2 (en) | ||
| JP2002173379A (en) | Ceramic adhesive | |
| JPS61166879A (en) | Heat storage material composition | |
| JPH03221238A (en) | Method for coating foamed resin pattern | |
| JPH0711234A (en) | Modification of chemical foaming agent | |
| US3704149A (en) | Liquid binding agent for bonded arc welding flux | |
| RU2185864C1 (en) | Fire-extinguishing composition and method of preparation thereof | |
| JP2001253741A (en) | Additive for concrete | |
| JPH01321095A (en) | Welding auxiliary |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080213 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20091130 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110329 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110530 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20110530 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20110531 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20120117 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120411 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20120418 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120515 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120528 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5017752 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150622 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150622 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |