JP2002256360A - White gold alloy - Google Patents

White gold alloy

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Publication number
JP2002256360A
JP2002256360A JP2001107806A JP2001107806A JP2002256360A JP 2002256360 A JP2002256360 A JP 2002256360A JP 2001107806 A JP2001107806 A JP 2001107806A JP 2001107806 A JP2001107806 A JP 2001107806A JP 2002256360 A JP2002256360 A JP 2002256360A
Authority
JP
Japan
Prior art keywords
weight
gold alloy
white
white gold
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001107806A
Other languages
Japanese (ja)
Inventor
Tetsuyoshi Suzuki
鉄良 鈴木
Yoshiaki Tanaka
吉秋 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IJIMA KINGIN KOGYO KK
Original Assignee
IJIMA KINGIN KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IJIMA KINGIN KOGYO KK filed Critical IJIMA KINGIN KOGYO KK
Priority to JP2001107806A priority Critical patent/JP2002256360A/en
Publication of JP2002256360A publication Critical patent/JP2002256360A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To obtain an inexpensive white gold alloy which does not contain Ni and Pd, or does not contain Ni and contains Pd of <=5%, has whiteness which has not been attained heretofore, and does not cause metal allergies by Ni. SOLUTION: The white gold alloy has a composition containing, by weight, 70 to 92% Au, and to which one or two kinds selected from 8 to 30% Fe and 8 to 30% Cr are added. Alternatively, the whity gold alloy is obtained by adding one or more kinds selected from 0.05 to 5% Pd, 0.05 to 20% Pt, 0.05 to 3% Ru, 0.05 to 3% Rh, 0.05 to 3% Ir, 0.05 to 5% Co, 0.05 to 5% Mn, 0.05 to 15% Ag, 0.05 to 15% Cu, 0.05 to 10% Zn, 0.05 to 10% In and 0.05 to 10% Ga to an alloy having a composition containing 70 to 92% Au, and to which one or two kinds selected from 0.05 to 25% Fe and 0.05 to 25% Cr are added.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】 本発明は、白色を有する金合金
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gold alloy having a white color.

【0002】[0002]

【従来の技術】 これまで、指輪、イヤリング、ペンダ
ント、ネックレスなどの装飾品用材料として用いられて
きた白色金合金(ホワイトゴールドと同意)は、周知の
ように、Niを含むNi系白色金合金と、Pdを含むP
d系白色金合金のいずれかであった。
2. Description of the Related Art As is well known, a white gold alloy containing Ni has been used as a material for decorative articles such as rings, earrings, pendants, necklaces, etc., as is well known. And P including Pd
d-type white gold alloy.

【0003】 このうちNi系白色金合金は、Niが金
属アレルギーを引き起こすことが知られており、他の金
属と比較して症例も多いことから、Niを含まない白色
金合金が求められていた。
[0003] Of these, Ni-based white gold alloys are known to cause metal allergy to Ni, and in many cases compared to other metals, there has been a demand for Ni-free white gold alloys. .

【0004】 一方、Pd系白色金合金では、Auの黄
金色を消して白色にするためには、Pdを10%以上加
える必要がある。ところが、昨今のPd高騰により、P
d含有率を従来のものより低くするか、或いはPdを含
まない白色金合金が求められていた。
On the other hand, in a Pd-based white gold alloy, it is necessary to add 10% or more of Pd in order to erase Au's golden color and make it white. However, due to the recent rise in Pd,
There has been a demand for a white gold alloy having a lower d content than conventional ones or containing no Pd.

【0005】 さらに、Pd系白色金合金は、黒味がか
った白色であるため、より白色に近い色の合金が要望さ
れていた。
Further, since the Pd-based white gold alloy is blackish white, an alloy having a color closer to white has been demanded.

【0006】[0006]

【発明が解決しようとする課題】 そこで本発明は、N
iとPdを含まない白色金合金、及びNiを含まず、P
d含有率が5%以下の白色金合金を開発したものであ
る。
Therefore, the present invention provides an
i and Pd-free white gold alloy, and Ni-free, P
A white gold alloy having a d content of 5% or less has been developed.

【0007】[0007]

【問題を解決するための手段】 上記課題を解決するた
め、本発明による白色金合金は、Auが70〜92重量
%で、これにFeを8〜30重量%、Crを8〜30重
量%の1種類もしくは2種類加えたもの、また、Auが
70〜92重量%で、これにFeを0.05〜25重量
%、Crを0.05〜25重量%の1種類もしくは2種
類加えた合金に、Pdを0.05〜5重量%、Ptを
0.05〜20重量%、Ruを0.05〜3重量%、R
hを0.05〜3重量%、Irを0.05〜3重量%、
Coを0.05〜5重量%、Mnを0.05〜5重量
%、Agを0.05〜15重量%、Cuを0.05〜1
5重量%、Znを0.05〜10重量%、Inを0.0
5〜10重量%、Gaを0.05〜10重量%、の1種
類もしくは2種類以上加えたものである。
Means for Solving the Problems In order to solve the above problems, the white gold alloy according to the present invention comprises 70 to 92% by weight of Au, 8 to 30% by weight of Fe, and 8 to 30% by weight of Cr. And 70 to 92% by weight of Au, and 0.05 to 25% by weight of Fe and 0.05 to 25% by weight of Cr. In the alloy, 0.05-5% by weight of Pd, 0.05-20% by weight of Pt, 0.05-3% by weight of Ru, R
h is 0.05-3% by weight, Ir is 0.05-3% by weight,
0.05-5% by weight of Co, 0.05-5% by weight of Mn, 0.05-15% by weight of Ag, 0.05-1% of Cu
5% by weight, 0.05 to 10% by weight of Zn, 0.0% of In
One or two or more of 5 to 10% by weight and 0.05 to 10% by weight of Ga are added.

【0008】[0008]

【作用】 上記組成の白色金合金は、NiとPdを含ま
ない、及びNiを含まず、Pd含有率が5%以下の、こ
れまでにない成分組成の白色金合金で、色も従来品より
白色であり、さらに安価でNiによる金属アレルギーを
起こさない、商品価値の高い白色金合金となる。
The white gold alloy having the above composition does not contain Ni and Pd, and does not contain Ni, and has a Pd content of 5% or less. It is a white gold alloy which is white, less expensive, does not cause metal allergy due to Ni, and has high commercial value.

【0009】 ここで、FeとCrは、Auの黄金色を
消して白色にするため用い、さらにCrは、Feの酸化
を防ぐために用いている。
Here, Fe and Cr are used to erase the golden color of Au to make it white, and Cr is used to prevent oxidation of Fe.

【0010】また、鋳造性、加工性、硬さ改善のため、
Pd、Pt、Ru、Rh、Ir、Co、Mn、Ag、C
u、Zn、In、Gaを加えている
In order to improve castability, workability and hardness,
Pd, Pt, Ru, Rh, Ir, Co, Mn, Ag, C
u, Zn, In, and Ga are added

【0011】[0011]

【実施例 1】 Au:83.5重量%、Fe:14.
5重量%、Cr:2.0重量%を真空溶解炉で溶解、鋳
造してインゴットとした。これを板材に加工してプレス
抜きし、指輪に加工後表面を切削して、カットリングと
した。合金は鋳造性、加工性、切削性共に良好であっ
た。製品の色合いは白色であり、NiとPdを含まな
い、これまでにない色調のK20ホワイトゴールド(白
色金合金)リングが得られた。
Example 1 Au: 83.5% by weight, Fe: 14.
5% by weight and Cr: 2.0% by weight were melted and cast in a vacuum melting furnace to form an ingot. This was processed into a plate material, punched out, processed into a ring, and the surface was cut to form a cut ring. The alloy had good castability, workability, and machinability. The color of the product was white, and a K20 white gold (white gold alloy) ring with an unprecedented color tone without Ni and Pd was obtained.

【0012】[0012]

【実施例 2】 実施例1と同様の方法で、Au:8
3.5重量%、Fe:13.0重量%、Cr:2.0重
量%、Pd:1.5重量%を溶解、鋳造、加工して製品
を得た。製品の色合いは白色であり、Niを含まず、P
d含有率の低い、これまでにない色調のK20ホワイト
ゴールド(白色金合金)リングが得られた。
Second Embodiment Au: 8 in the same manner as in the first embodiment.
3.5% by weight, 13.0% by weight of Fe, 2.0% by weight of Cr and 1.5% by weight of Pd were melted, cast and processed to obtain a product. The color of the product is white, not containing Ni, P
An unprecedented K20 white gold (white gold alloy) ring with a low d content was obtained.

【0013】[0013]

【実施例 3】 実施例1と同様の方法で、Au:8
3.5重量%、Fe:16.0重量%、Ga:0.5重
量%、を溶解、鋳造、加工して製品を得た。製品の色合
いは白色であり、Ni及びPdを含まない、これまでに
ない色調のK20ホワイトゴールド(白色金合金)リン
グが得られた。
Embodiment 3 Au: 8 in the same manner as in Embodiment 1.
3.5% by weight, Fe: 16.0% by weight, and Ga: 0.5% by weight were melted, cast and processed to obtain a product. The color of the product is white, and an unprecedented K20 white gold (white gold alloy) ring containing no Ni and Pd is obtained.

【0014】[0014]

【実施例 4】 実施例1と同様の方法で、Au:7
5.0重量%、Fe:20.0重量%、Cr:3.0重
量%、Pd:2.0重量%を溶解、鋳造、加工して製品
を得た。製品の色合いは白色であり、Niを含まず、P
d含有率の低い、これまでにない色調のK18ホワイト
ゴールド(白色金合金)リングが得られた。
Embodiment 4 In the same manner as in Embodiment 1, Au: 7
5.0% by weight, 20.0% by weight of Fe, 3.0% by weight of Cr, and 2.0% by weight of Pd were melted, cast and processed to obtain a product. The color of the product is white, not containing Ni, P
An unprecedented K18 white gold (white gold alloy) ring with a low d content was obtained.

【0015】[0015]

【実施例 5】 実施例1と同様の方法で、Au:7
5.0重量%、Fe:15.0重量%、Ag:5.0重
量%、Cu:5.0重量%を溶解、鋳造、加工して製品
を得た。製品の色合いは白色であり、Ni及びPd含ま
ない、これまでにない色調のK18ホワイトゴールド
(白色金合金)リングが得られた。
Embodiment 5 In the same manner as in Embodiment 1, Au: 7
5.0 wt%, Fe: 15.0 wt%, Ag: 5.0 wt%, and Cu: 5.0 wt% were melted, cast and processed to obtain a product. The color of the product is white, and an unprecedented K18 white gold (white gold alloy) ring without Ni and Pd is obtained.

【0016】[0016]

【発明の効果】 以上のような本発明により、装飾品用
材料としてNiとPdを含まない、及びNiを含まずP
d含有率5%以下の、これまでにない成分組成と色調
の、白色を有する金合金が得られた。さらに、従来品に
比べて安価で、Niによる金属アレルギーの心配がない
ため、色調と合わせて商品価値の高い白色金合金となっ
た。
According to the present invention described above, Ni and Pd are not contained as a decorative material, and P is contained without Ni.
A white gold alloy having an unprecedented component composition and color tone having a d content of 5% or less was obtained. Furthermore, since it is cheaper than conventional products and there is no concern about metal allergy due to Ni, a white gold alloy having a high commercial value is obtained together with the color tone.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 Auが70〜92重量%で、これにFe
を8〜30重量%、Crを8〜30重量%の1種類もし
くは2種類加えたことを特徴とする、白色を有する金合
金。
1. Au is 70 to 92% by weight, which contains Fe
And 8 to 30% by weight of Cr and 8 to 30% by weight of Cr.
【請求項2】 Auが70〜92重量%で、これにFe
を0.05〜25重量%、Crを0.05〜25重量%
の1種類もしくは2種類加えた合金に、Pdを0.05
〜5重量%、Ptを0.05〜20重量%、Ruを0.
05〜3重量%、Rhを0.05〜3重量%、Irを
0.05〜3重量%、Coを0.05〜5重量%、Mn
を0.05〜5重量%、Agを0.05〜15重量%、
Cuを0.05〜15重量%、Znを0.05〜10重
量%、Inを0.05〜10重量%、Gaを0.05〜
10重量%の1種類もしくは2種類以上加えたことを特
徴とする、白色を有する金合金。
2. Au is 70 to 92% by weight, which contains Fe.
0.05 to 25% by weight, Cr 0.05 to 25% by weight
Pd is added to one or two alloys of
-5% by weight, 0.05-20% by weight of Pt, and 0.
0.05 to 3% by weight, 0.05 to 3% by weight of Rh, 0.05 to 3% by weight of Ir, 0.05 to 5% by weight of Co, Mn
Is 0.05 to 5% by weight, Ag is 0.05 to 15% by weight,
0.05 to 15% by weight of Cu, 0.05 to 10% by weight of Zn, 0.05 to 10% by weight of In, and 0.05 to 5% of Ga
A gold alloy having a white color, characterized in that one or more of 10% by weight is added.
JP2001107806A 2001-03-01 2001-03-01 White gold alloy Pending JP2002256360A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001107806A JP2002256360A (en) 2001-03-01 2001-03-01 White gold alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001107806A JP2002256360A (en) 2001-03-01 2001-03-01 White gold alloy

Publications (1)

Publication Number Publication Date
JP2002256360A true JP2002256360A (en) 2002-09-11

Family

ID=18960063

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2002256360A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4879729B2 (en) * 2003-02-11 2012-02-22 メタロール・テクノロジーズ・インターナショナル・ソシエテ・アノニム Gold alloy
EP2546371A1 (en) * 2011-07-12 2013-01-16 Cendres + Métaux SA 18-carat grey gold
US20130259736A1 (en) * 2012-03-14 2013-10-03 Victor Dyment Thermoregulatory Interactive Gold Alloys for Therapeutic Jewelry Items
RU2500825C1 (en) * 2012-12-18 2013-12-10 Юлия Алексеевна Щепочкина Gold-base alloy
ITPD20130002A1 (en) * 2013-01-11 2014-07-12 Legor Group S P A COMPOSITION OF LEGA MADRE FOR THE PRODUCTION OF WHITE GOLD AND ALLOY WHITE GOLD ALLOYS.
CN104884650A (en) * 2012-11-08 2015-09-02 贺利氏有限公司 Nickel containing gold alloys having low nickel releasing rate, master alloys for obtaining them and use of metal elements therein
CN107419130A (en) * 2017-07-27 2017-12-01 深圳市福麒珠宝首饰有限公司 A kind of preparation method of 18K gold and 18K gold ornaments
CN112251625A (en) * 2020-10-15 2021-01-22 深圳市宝瑞莱珠宝首饰有限公司 Fading-resistant 18K black gold for jewelry and processing technology thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4879729B2 (en) * 2003-02-11 2012-02-22 メタロール・テクノロジーズ・インターナショナル・ソシエテ・アノニム Gold alloy
EP2546371A1 (en) * 2011-07-12 2013-01-16 Cendres + Métaux SA 18-carat grey gold
US20130259736A1 (en) * 2012-03-14 2013-10-03 Victor Dyment Thermoregulatory Interactive Gold Alloys for Therapeutic Jewelry Items
CN104884650A (en) * 2012-11-08 2015-09-02 贺利氏有限公司 Nickel containing gold alloys having low nickel releasing rate, master alloys for obtaining them and use of metal elements therein
RU2500825C1 (en) * 2012-12-18 2013-12-10 Юлия Алексеевна Щепочкина Gold-base alloy
ITPD20130002A1 (en) * 2013-01-11 2014-07-12 Legor Group S P A COMPOSITION OF LEGA MADRE FOR THE PRODUCTION OF WHITE GOLD AND ALLOY WHITE GOLD ALLOYS.
WO2014108848A1 (en) * 2013-01-11 2014-07-17 Legor Group S.P.A. Master alloy composition for producing white gold alloys and white gold alloy thus obtained
CN107419130A (en) * 2017-07-27 2017-12-01 深圳市福麒珠宝首饰有限公司 A kind of preparation method of 18K gold and 18K gold ornaments
CN112251625A (en) * 2020-10-15 2021-01-22 深圳市宝瑞莱珠宝首饰有限公司 Fading-resistant 18K black gold for jewelry and processing technology thereof
CN112251625B (en) * 2020-10-15 2022-04-15 深圳市宝瑞莱珠宝首饰有限公司 Fading-resistant 18K black gold processing technology for jewelry

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