JP2002075102A - Electrical contact-point material - Google Patents

Electrical contact-point material

Info

Publication number
JP2002075102A
JP2002075102A JP2000254859A JP2000254859A JP2002075102A JP 2002075102 A JP2002075102 A JP 2002075102A JP 2000254859 A JP2000254859 A JP 2000254859A JP 2000254859 A JP2000254859 A JP 2000254859A JP 2002075102 A JP2002075102 A JP 2002075102A
Authority
JP
Japan
Prior art keywords
contact
electrical contact
contact material
oxide film
point material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2000254859A
Other languages
Japanese (ja)
Inventor
Shigeki Ono
成樹 尾野
Nobutoshi Horiuchi
宣利 堀内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimadzu Corp
Research Institute of Innovative Technology for the Earth RITE
Original Assignee
Shimadzu Corp
Research Institute of Innovative Technology for the Earth RITE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shimadzu Corp, Research Institute of Innovative Technology for the Earth RITE filed Critical Shimadzu Corp
Priority to JP2000254859A priority Critical patent/JP2002075102A/en
Publication of JP2002075102A publication Critical patent/JP2002075102A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/027Composite material containing carbon particles or fibres
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H2300/00Orthogonal indexing scheme relating to electric switches, relays, selectors or emergency protective devices covered by H01H
    • H01H2300/036Application nanoparticles, e.g. nanotubes, integrated in switch components, e.g. contacts, the switch itself being clearly of a different scale, e.g. greater than nanoscale

Abstract

PROBLEM TO BE SOLVED: To provide an electrical contact point material, where no oxide film is formed, and which has stable contact resistance. SOLUTION: A carbon nanotube, as a conductive particle, a binder polymer (for example, vinyl chloride-vinyl acetate resin), and a solvent (mixture of toluene, methyl ethyl ketone, and ethyl acetate) are mixed at a weight ratio of 25:25:50 to generate a paste-like electrical contact-point material. Since the contact point uses a carbon nano tube as a conductive particle, no oxide film is formed for making stable contact resistance.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、スイッチやリレー
などの接点部分に用いられる電気接点材料、特に微小電
流を切り換える接点材料に適した電気接点材料に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electric contact material used for a contact portion such as a switch or a relay, and more particularly to an electric contact material suitable for a contact material for switching a minute current.

【0002】[0002]

【従来の技術】従来、スイッチやリレーなどの接点部分
に用いられる電気接点材料として、導電性にすぐれた金
属あるいは金や銀などの貴金属が多く用いられている。
これらの金属は、スイッチやリレーの接点部分にメッキ
したり貼り付けるなどの方法により固着され、接点を保
護し電流の導通性をよくするために使用されている。こ
のような電気接点材料を接点として長く使用している
と、動作電流がミリアンペア以上の比較的大きな電流で
ある場合は、接点がオン時の接触抵抗(オン抵抗)の値
は小さくて安定しているのに対し、動作電流がマイクロ
アンペアレンジの電流である場合は、接触抵抗値が大き
く不安定になり、接点の信頼性が極端に低下する傾向が
ある。
2. Description of the Related Art Conventionally, as an electrical contact material used for a contact portion such as a switch or a relay, a metal having excellent conductivity or a noble metal such as gold or silver is often used.
These metals are fixed to a contact portion of a switch or a relay by plating or affixing, and are used for protecting the contact and improving current conductivity. If such an electrical contact material is used for a long time as a contact, if the operating current is a relatively large current of milliamperes or more, the value of the contact resistance (on resistance) when the contact is on is small and stable. On the other hand, when the operating current is a current in the microamp range, the contact resistance value becomes largely unstable, and the reliability of the contact tends to be extremely reduced.

【0003】この現象の主な原因は、接点に使用されて
いる金属表面に酸化膜が形成されるためであるが、比較
的酸化膜が形成されにくい金接点のスイッチやリレーで
も、例えば亜硫酸ガスが存在する雰囲気中で使用してい
ると接点表面に硫化物が付着し、接触抵抗が大きくなり
やがて接触不良や腐食破損が進行することがよく知られ
ている。この接点における接触抵抗の増大や接触不良
は、動作電流が小さいほどのその影響が大きいこともま
たよく知られている。
[0003] The main cause of this phenomenon is that an oxide film is formed on the metal surface used for the contact. Even a switch or relay having a gold contact where an oxide film is relatively difficult to form, for example, sulfur dioxide gas It is well known that sulfides adhere to the contact surface when used in an atmosphere in which contact is present, increasing the contact resistance and eventually causing poor contact and corrosion damage. It is also well known that the increase in the contact resistance and the poor contact at the contact have a greater effect as the operating current is smaller.

【0004】[0004]

【発明が解決しようとする課題】このような金属材料を
使用した接点では、使用環境の雰囲気状態によっても進
行度が異なるが、使用期間に比例して接点表面に酸化膜
や雰囲気ガスの化合物膜が徐々に形成され、接点の接触
状態を劣化させるという問題がある。従来は、接点にお
ける接触不良を防止するためにスイッチやリレーを密閉
構造にして酸素や腐食性ガスとの接触を遮断したり、一
定期間毎に取り替えたり、あるいは定期点検毎に劣化度
をチェックして、交換の必要があると認めた場合に取り
替えるなどの方法が採られている。
In a contact using such a metal material, the degree of progress varies depending on the atmospheric conditions of the use environment, but an oxide film or a compound film of an atmospheric gas is formed on the contact surface in proportion to the use period. Are gradually formed, and there is a problem that the contact state of the contact is deteriorated. Conventionally, in order to prevent contact failure at the contacts, switches and relays are sealed to prevent contact with oxygen and corrosive gas, replaced at regular intervals, or checked for deterioration at regular inspections. In such a case, if it is deemed necessary to replace it, it is replaced.

【0005】しかしながら、スイッチやリレーを密閉構
造にした場合、部品そのものが非常に高価になることや
形状が大きくなると装置内に収容仕切れない場合もでて
くるという問題がある。また、取り替える場合にはその
作業のためにプラント運転を一定期間停止しなければな
らないことや交換費用が高価になるという問題がある。
本発明は、このような事情に鑑みてなされたものであっ
て、特に微小電流に対しても長期間接触抵抗が安定して
使用できる電気接点材料を提供することを目的とする。
[0005] However, when the switches and relays have a sealed structure, there is a problem that the parts themselves become very expensive, and if the parts are large in size, they may not be able to be housed in the apparatus. In addition, when replacing, there is a problem that the plant operation must be stopped for a certain period of time for the work, and replacement cost becomes high.
The present invention has been made in view of such circumstances, and an object of the present invention is to provide an electrical contact material that can be used with a stable contact resistance for a long period of time, even for a very small current.

【0006】[0006]

【課題を解決するための手段】上記の目的を達成するた
め、本発明の電気接点材料は、導電性粒子とバインダ用
ポリマーを混合処理して生成される電気接点材料におい
て、導電性粒子がカーボンナノチューブであることを特
徴とするものである。本発明の電気接点材料は上記の構
成を用いることにより、酸化膜や腐食膜を形成せず、微
小電流に対しても安定な接触状態を保持することができ
る。
In order to achieve the above object, an electric contact material according to the present invention is an electric contact material produced by mixing conductive particles and a binder polymer, wherein the conductive particles are made of carbon. It is characterized by being a nanotube. By using the above structure, the electrical contact material of the present invention does not form an oxide film or a corrosion film, and can maintain a stable contact state even with a minute current.

【0007】[0007]

【発明の実施の形態】本発明による電気接点材料の実施
例を以下に説明する。本発明の電気接点材料は下記に説
明するようなバインダー用ポリマーと、カーボンナノチ
ューブと、トルエン、キシレン、メチルエチルケトンか
らなる混合溶剤とを混合し、下記に示す条件によって混
練、加熱、加圧することにより導電性ペースト状態で生
成される。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the electric contact material according to the present invention will be described below. The electric contact material of the present invention is obtained by mixing a polymer for a binder as described below, a carbon nanotube, and a mixed solvent composed of toluene, xylene, and methyl ethyl ketone, and kneading under the following conditions. It is produced in a paste state.

【0008】前記バインダー用ポリマーとしては、アク
リル系樹脂、ポリエステル系樹脂、ポリウレタン系樹脂
または塩酢ビ系樹脂が用いられる。また、前記カーボン
ナノチューブは、図1に示す流通式固定床反応器を用い
て生成される。本流通式固定床反応器は、内径8cm、
長さ30cmなる石英製の反応管1と、これを囲んで加
熱するための電気炉4と、反応管1内の反応ガスを排出
するためのバルブ5から構成されると共に、前記反応管
1の中央付近には触媒2とその上下にグラスウール3が
それぞれ充填されている。
As the binder polymer, an acrylic resin, a polyester resin, a polyurethane resin or a polyvinyl chloride resin is used. Further, the carbon nanotubes are produced using the flow-type fixed bed reactor shown in FIG. This flow-type fixed bed reactor has an inner diameter of 8 cm,
The reactor comprises a quartz reaction tube 1 having a length of 30 cm, an electric furnace 4 surrounding the reaction tube 1 for heating, and a valve 5 for discharging a reaction gas in the reaction tube 1. Near the center, a catalyst 2 and glass wool 3 above and below it are filled.

【0009】前記反応管1にwt%で各50%づつのN
iとSiOからなる触媒を充填し、流量1L/min
の水素ガスを供給し、500℃で1hr還元した後、体
積比で2:1のHガスとCOガスからなる混合ガス
を流量7.5L/minで導入し、500℃で6hr反
応させた後、同反応管内を窒素で置換して室温まで冷却
することにより、カーボンナノチューブが生成される。
なお、アーク放電法、レーザー蒸発法、化学気相成長
法、熱分解法などの公知のカーボンナノチューブ生成法
によって生成されたカーボンナノチューブも本電気接点
材料の導電性粒子として用いることができる。
In the reaction tube 1, 50% by weight of N
i and a catalyst composed of SiO 2 were filled, and the flow rate was 1 L / min.
Is supplied at a temperature of 500 ° C. for 1 hour, a mixed gas consisting of H 2 gas and CO 2 gas at a volume ratio of 2: 1 is introduced at a flow rate of 7.5 L / min, and the mixture is reacted at 500 ° C. for 6 hours. After that, the inside of the reaction tube is replaced with nitrogen and cooled to room temperature, thereby generating carbon nanotubes.
Note that carbon nanotubes generated by a known carbon nanotube generation method such as an arc discharge method, a laser evaporation method, a chemical vapor deposition method, and a thermal decomposition method can also be used as the conductive particles of the electric contact material.

【0010】上記の方法で得られたカーボンナノチュー
ブと、バインダー用ポリマーとして塩酢ビ樹脂と、前記
混合溶剤とを重量比で25:25:50の割合で混合
し、さらに分割剤、可塑剤および酸化防止剤を適宜加え
た後、ボールミルで40分間混合すると、体積固有抵抗
値がほぼ0.1Ω・cmのペースト状態の電気接点材料
が生成される。この電気接点材料は非常に微小なカーボ
ンナノチューブを導電材として使用しているので、接点
同士の接触性がよく、また空気中に放置されていても酸
化膜が形成されず、微小電流に対しても安定した接触抵
抗を維持することができる。
[0010] The carbon nanotubes obtained by the above method, the polyvinyl chloride resin as a binder polymer, and the mixed solvent are mixed at a weight ratio of 25:25:50. After the antioxidant is appropriately added, the mixture is mixed in a ball mill for 40 minutes to produce a paste-form electrical contact material having a volume resistivity of approximately 0.1 Ω · cm. Since this electrical contact material uses very small carbon nanotubes as the conductive material, the contact between the contacts is good, and an oxide film is not formed even when left in the air. Also, stable contact resistance can be maintained.

【0011】この電気接点材料は次に示すような方法で
リレーやスイッチの接点部分に固着され接点として用い
られる。図2は矢印方向に移動してオンオフ動作をする
リレーの可動片6に、本電気接点材料を使用した接点7
が固着されている状態を示したもので、図3は接点7を
可動片6上に形成するための枠体を備えた治具8の斜視
図を示したものである。この治具8を図に示すように可
動片6の上に置き、ペースト状の電気接点材料を治具8
の深さ0.3〜0.5mm程度の枠体内に埋め込み、余
分の電気接点材料を除去した後、加熱して混合溶媒中の
揮発分を除去する。これにより電気接点材料は可動片6
上に接点として固着されるので、治具8を取り除く。
The electric contact material is fixed to the contact portion of a relay or a switch in the following manner and used as a contact. FIG. 2 shows a contact 7 using the present electric contact material for a movable piece 6 of a relay which moves on and off by moving in the direction of the arrow.
FIG. 3 is a perspective view of a jig 8 provided with a frame for forming the contact 7 on the movable piece 6. The jig 8 is placed on the movable piece 6 as shown in FIG.
Embedded in a frame having a depth of about 0.3 to 0.5 mm to remove excess electrical contact material, and then heat to remove volatile components in the mixed solvent. As a result, the electric contact material becomes the movable piece 6.
The jig 8 is removed because it is fixed as a contact on the top.

【0012】なお、予め可動片6の接点側表面を表面処
理により荒らしておくことにより、接点7をより強固に
可動片6に固着させることができる。また、枠体を複数
個繋がった形状の治具を用いることにより、一度に複数
個の可動片6に電気接点材料を埋め込み、上記と同様の
方法で接点の固着作業を行うことができ、それによって
作業効率を上げることができる。
By previously roughening the contact-side surface of the movable piece 6 by surface treatment, the contact 7 can be more firmly fixed to the movable piece 6. Further, by using a jig having a shape in which a plurality of frames are connected, the electric contact material can be embedded in the plurality of movable pieces 6 at a time, and the operation of fixing the contacts can be performed in the same manner as described above. Work efficiency can be improved.

【0013】図4はロータリスイッチの接点にこの電気
接点材料が使用された状態を示したものである。図4
(a)は複数個の接点10が固着されているセラミック
ス等の絶縁性の基盤9の上面図であり、図4(b)はそ
のA−A断面図を示したものである。前記基盤9には予
め導電性端子11が埋め込まれており、電気接点材料を
埋め込んで形成された接点10と電気的に接続されてい
る。
FIG. 4 shows a state in which this electrical contact material is used for a contact of a rotary switch. FIG.
4A is a top view of an insulating base 9 made of ceramic or the like to which a plurality of contacts 10 are fixed, and FIG. 4B is a cross-sectional view taken along line AA. A conductive terminal 11 is embedded in the base 9 in advance, and is electrically connected to a contact 10 formed by embedding an electric contact material.

【0014】以上は、ペースト状の電気接点材料を直接
スイッチやリレーに埋め込み、接点として使用した例を
示したものであるが、このペースト状の電気接点材料を
予め成形型に注入してシート状あるいは円形状などの目
的とする接点に適した形に成形し、熱処理により接点用
部品として作成しておき、スイッチやリレーなどの可動
片に導電性接着材を用いて接点を接着することもでき
る。
The above is an example in which a paste-like electric contact material is directly embedded in a switch or a relay and used as a contact. Alternatively, it can be molded into a shape suitable for the intended contact, such as a circle, and made as a contact part by heat treatment, and the contact can be bonded to a movable piece such as a switch or relay using a conductive adhesive. .

【0015】本発明は導電性粒子にカーボンナノチュー
ブを使用することにより、酸化膜の形成を防止し、微小
電流に対しても接触抵抗を安定に保持することを特徴と
するしており、カーボンナノチューブ、バインダー用ポ
リマー、混合溶剤の混合比率については本実施例に限定
されるものではない。
The present invention is characterized in that the use of carbon nanotubes as conductive particles prevents the formation of an oxide film and stably maintains the contact resistance even with a small current. The mixing ratio of the binder polymer and the mixed solvent is not limited to this embodiment.

【0016】[0016]

【発明の効果】本発明の電気接点材料は導電性粒子とし
てカーボンナノチューブを使用しているので、接触面に
酸化膜が生成されず、接触抵抗の変化が少なく、耐環境
性に優れ、長時間安定して使用することができる。この
電気接点材料は酸化されないので、過酷な環境中に曝し
て使用することができ、キーボードを始めとして従来の
金属接点では使用できない分野にも用いることができ
る。
According to the electric contact material of the present invention, since carbon nanotubes are used as the conductive particles, no oxide film is formed on the contact surface, the contact resistance does not change much, the environment resistance is excellent, and the electric contact material has a long life. Can be used stably. Since this electrical contact material is not oxidized, it can be used by exposing it to a harsh environment, and can be used in keyboards and other fields where conventional metal contacts cannot be used.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に係わるカーボンナノチューブを製造す
る流通式固定床反応器の構成図である。
FIG. 1 is a configuration diagram of a flow-type fixed-bed reactor for producing carbon nanotubes according to the present invention.

【図2】本発明に係わるリレーの構成図である。FIG. 2 is a configuration diagram of a relay according to the present invention.

【図3】本発明に係わる治具の斜視図である。FIG. 3 is a perspective view of a jig according to the present invention.

【図4】本発明に係わるロータリスイッチの基盤の上面
図(a)とそのA−A断面図(b)である。
FIG. 4 is a top view (a) of a base of the rotary switch according to the present invention and a sectional view (A) of FIG.

【符号の説明】[Explanation of symbols]

1…反応管 2…触媒 3…グラスウール 4…電気炉 5…バルブ 6…可動片 7、10…接点 8…治具 9…基盤 11…導電性端子 DESCRIPTION OF SYMBOLS 1 ... Reaction tube 2 ... Catalyst 3 ... Glass wool 4 ... Electric furnace 5 ... Valve 6 ... Movable piece 7, 10 ... Contact 8 ... Jig 9 ... Base 11 ... Conductive terminal

───────────────────────────────────────────────────── フロントページの続き (72)発明者 堀内 宣利 京都市中京区西ノ京桑原町1番地 株式会 社島津製作所内 Fターム(参考) 5G050 AA07 AA60 BA04 BA08 CA14 CA16 DA01 DA02 EA06 EA09 EA20 5G301 DA18 DA42 DA53 DA59 DD01 ────────────────────────────────────────────────── ─── Continuing from the front page (72) Inventor Norito Horiuchi 1 Fukui term in Shimadzu Corporation, Nishinokyo Kuwaharacho, Nakagyo-ku, Kyoto 5G050 AA07 AA60 BA04 BA08 CA14 CA16 DA01 DA02 EA06 EA09 EA20 5G301 DA18 DA42 DA53 DA59 DD01

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】導電性粒子とバインダ用ポリマーを混合処
理して生成される電気接点材料において、導電性粒子が
カーボンナノチューブであることを特徴とする電気接点
材料。
1. An electric contact material produced by mixing a conductive particle and a binder polymer, wherein the conductive particles are carbon nanotubes.
JP2000254859A 2000-08-25 2000-08-25 Electrical contact-point material Withdrawn JP2002075102A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000254859A JP2002075102A (en) 2000-08-25 2000-08-25 Electrical contact-point material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000254859A JP2002075102A (en) 2000-08-25 2000-08-25 Electrical contact-point material

Publications (1)

Publication Number Publication Date
JP2002075102A true JP2002075102A (en) 2002-03-15

Family

ID=18743736

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000254859A Withdrawn JP2002075102A (en) 2000-08-25 2000-08-25 Electrical contact-point material

Country Status (1)

Country Link
JP (1) JP2002075102A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1256856A2 (en) * 2001-05-11 2002-11-13 Seiko Instruments Inc. Composite main plate structure and electronic timepiece using the same
WO2003079375A1 (en) * 2002-03-18 2003-09-25 Atofina Research Conductive polyolefins with good mechanical properties
JP2004040844A (en) * 2002-06-28 2004-02-05 Shinano Kenshi Co Ltd Commutator and rotary electric machine using it
WO2004053893A1 (en) * 2002-11-28 2004-06-24 Shinano Kenshi Kabushiki Kaisha Electric contact member
JP2005006479A (en) * 2003-06-16 2005-01-06 Matsushita Electric Ind Co Ltd Sliding contact material
EP1538643A2 (en) * 2003-12-01 2005-06-08 Fuji Xerox Co., Ltd. Electrical member, electrical device, and method of manufacturing the electrical member and electrical device
KR20200029131A (en) * 2018-09-10 2020-03-18 김상경 Power window switch contact structure using nano carbon fabric

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1256856A3 (en) * 2001-05-11 2004-04-21 Seiko Instruments Inc. Composite main plate structure and electronic timepiece using the same
EP1256856A2 (en) * 2001-05-11 2002-11-13 Seiko Instruments Inc. Composite main plate structure and electronic timepiece using the same
WO2003079375A1 (en) * 2002-03-18 2003-09-25 Atofina Research Conductive polyolefins with good mechanical properties
EP1349179A1 (en) * 2002-03-18 2003-10-01 ATOFINA Research Conductive polyolefins with good mechanical properties
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