JP2001192311A - Volatile slime inhibitor - Google Patents
Volatile slime inhibitorInfo
- Publication number
- JP2001192311A JP2001192311A JP2000089947A JP2000089947A JP2001192311A JP 2001192311 A JP2001192311 A JP 2001192311A JP 2000089947 A JP2000089947 A JP 2000089947A JP 2000089947 A JP2000089947 A JP 2000089947A JP 2001192311 A JP2001192311 A JP 2001192311A
- Authority
- JP
- Japan
- Prior art keywords
- water
- parts
- slime
- oil
- essential oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、台所流し、浴室の排水
口などに置いて除菌とぬめり防止効果を有する揮発性ぬ
めり防止剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a volatile anti-slime agent having a disinfecting effect and an anti-slimming effect when placed in a kitchen sink or a drain of a bathroom.
【０００２】[0002]
【従来の技術】従来、台所流し台のくずかごや浴室の排
水口などに設置して、ぬめりを除去する目的でトリクロ
ロイソシアヌール酸、ジクロロイソシアヌール酸ナトリ
ウムあるいは安定化二酸化塩素を成形した錠剤が用いら
れてきた。2. Description of the Related Art Conventionally, tablets formed of trichloroisocyanuric acid, sodium dichloroisocyanurate, or stabilized chlorine dioxide have been used in kitchen waste sinks or bathroom drains to remove slime. Have been.
【０００３】ところが、これらのぬめり取り剤は漂白剤
などのアルカリ性物質または食酢などの酸性物質とまざ
ると塩素ガスを発生して危険であること、水を流さない
日が続く時は取り除く必要があるなど安全性と取扱性の
点で欠点があった。However, these removers are dangerous because they generate chlorine gas when mixed with an alkaline substance such as a bleach or an acidic substance such as vinegar, and must be removed when water is not poured continuously. There were drawbacks in terms of safety and handling.
【０００４】最近になって、まざっても塩素ガスを発生
しない商品として、過炭酸ソーダを主成分とした錠剤、
銅や亜鉛を抗菌成分とした抗菌セラミック錠剤、あるい
はクロロメチルイソチアゾリン包接化合物を殺菌成分と
した商品などが上市されてきた。[0004] Recently, as a product which does not generate chlorine gas at all, tablets containing sodium percarbonate as a main component,
Antibacterial ceramic tablets containing copper or zinc as an antibacterial component or products containing a chloromethylisothiazoline inclusion compound as a bactericidal component have been marketed.
【０００５】[0005]
【発明が解決しようとする課題】上記した改良品は、い
ずれも他の薬剤とまざっても塩素ガスを発生せず安全性
は向上したものゝ、くずかごの底部で錠剤と接触した部
分においてはぬめり防止効果を発揮するが、錠剤が接触
しないくずかごの周辺部とくに側壁部のぬめりを防止す
る効果は前記のイソシアヌール酸系の従来品にくらべて
著しく劣っていた。The above-mentioned improved products do not generate chlorine gas even if they are mixed with other chemicals and have improved safety. However, slimming occurs at the bottom of the waste basket in contact with the tablet. Although it exhibits an effect of prevention, the effect of preventing slimming of the peripheral portion of the waste basket in which the tablet does not come into contact, particularly the side wall portion, is remarkably inferior to that of the above-mentioned isocyanuric acid-based conventional products.
【０００６】本発明は上述の現状に鑑みなされたもの
で、他の薬剤とまざっても塩素ガスを発生しない安全性
を保ちながら、錠剤が接触するくずかごの底部のみなら
ずその周辺部に対してもぬめり防止効果を発揮できるぬ
めり防止剤を提供するのを目的としている。The present invention has been made in view of the above-mentioned situation, and maintains not only the bottom of the scrap basket in contact with the tablets but also the periphery thereof while maintaining safety such that chlorine gas is not generated even if it is mixed with other drugs. An object of the present invention is to provide an anti-slime agent capable of exhibiting an anti-slime effect.
【０００７】[0007]
【課題を解決するための手段】前記目的を達成するため
に、本発明者らは揮発して抗菌作用、殺菌作用を呈し、
しかも安全性にすぐれる素材として天然植物抽出精油に
着目して、これをぬめり防止用製剤が接触する部分のぬ
めり防止に効果を有する銅化合物と組合せて成形物とす
ることを鋭意研究した結果、 （１）揮発性植物精油が一時に揮発して効果が短期間に
失効するのを防ぐためには、該精油を吸着担持してこれ
を徐放する性質、いわゆるリリースコントロール性をも
たせる必要があること。 （２）この吸着担体としては微細孔構造をもったけい藻
土、ゼオライト、活性アルミナなどの無機化合物粉末ま
たはか粒が適すること。 （３）銅化合物としては、水溶性塩が効果が大きく好適
であること。 （４）流水によって徐々に流失する性質をもった固形物
とする際に、植物精油と銅化合物とを分散保持させるキ
ャリアー物質としては水不溶性の無機化合物と水溶性セ
ルロース化合物の混合物が適していること。を見出して
本発明を完成したものである。In order to achieve the above object, the present inventors volatilize to exhibit an antibacterial action and a bactericidal action,
In addition, focusing on natural plant extracted essential oils as a material with excellent safety, as a result of earnest research on forming a molded product by combining this with a copper compound having an effect on preventing slimming of the part where the slime preventing formulation comes into contact, (1) In order to prevent volatile plant essential oil from volatilizing at one time and losing its effect in a short period of time, it is necessary that the essential oil has a property of adsorbing and carrying the essential oil and releasing it gradually, so-called release control property. . (2) Powders or granules of inorganic compounds such as diatomaceous earth, zeolite and activated alumina having a microporous structure are suitable as the adsorption carrier. (3) As the copper compound, a water-soluble salt has a large effect and is suitable. (4) A mixture of a water-insoluble inorganic compound and a water-soluble cellulose compound is suitable as a carrier substance for dispersing and holding a vegetable essential oil and a copper compound when the solid substance has a property of being gradually washed away by running water. thing. To complete the present invention.
【０００８】すなわち、本発明は、銅化合物の０．１〜
１０重量％と、揮発して殺菌または抗菌効果を有する植
物抽出精油の１〜４８重量％とを必須成分として含有
し、これらを担持してリリースコントロール性を発揮で
きる吸着担体と共に流水によって徐々に流失する性質を
もった固形物に成形したことを特長とする揮発性ぬめり
防止剤を要旨としている。[0008] That is, the present invention relates to a method for preparing a copper compound of 0.1 to 0.1%.
It contains 10% by weight and 1 to 48% by weight of a plant extract essential oil having a bactericidal or antibacterial effect which is volatilized as an essential component. SUMMARY OF THE INVENTION The gist of the present invention is a volatile slime preventive characterized by being formed into a solid having the following properties.
【０００９】[0009]
【作 用】本発明の構成と作用とを説明する。まず、本
発明で用いる銅化合物としては硫酸銅、酢酸銅などの水
溶性塩、酸化銅、亜酸化銅などの水不溶性化合物のいず
れも用いうるが、ヌメリ防止効果が大きい点で水溶性塩
がより好適に用いられる。[Operation] The configuration and operation of the present invention will be described. First, as the copper compound used in the present invention, any of water-soluble salts such as copper sulfate and copper acetate, and water-insoluble compounds such as copper oxide and cuprous oxide can be used. More preferably used.
【００１０】本発明で用いる揮発して抗菌効果を呈する
植物抽出精油（以下、植物精油と略称する。）として
は、とくに制限はないが、一般的には、ユーカリ油、レ
モングラス油、レモン油、しそ油、ラベンダー油、はっ
か油、ペーパミント油、ヒバ油、ヒノキ油、針葉油、ガ
ーリック油、しょう脳油、木酢油あるいはわさび抽出油
などが用いられ、これらは単独あるいは併用して用いる
ことができる。[0010] The plant extract essential oil (hereinafter abbreviated as plant essential oil) which evaporates and exhibits an antibacterial effect used in the present invention is not particularly limited, but is generally eucalyptus oil, lemongrass oil, lemon oil. Sesame oil, lavender oil, peppermint oil, paper mint oil, hiba oil, hinoki oil, needle oil, garlic oil, camphor oil, wood vinegar oil or wasabi extracted oil, etc., used alone or in combination Can be.
【００１１】本発明ぬめり防止剤でぬめり防止作用を呈
する銅化合物および植物精油は、これらが一度に流失ま
たは揮発すればぬめり防止剤としての効果の持続性が劣
ることになり、これを徐々にリリース（放出）させるに
はリリースコントロール作用をもたせることが必要なこ
とを見出したのは前述のとおりであるが、この目的に用
いられる担体としては微細孔構造をもったけい藻土、天
然または合成ゼオライトあるいは活性アルミナなどが好
適である。これらは単独あるいは併用して用いられる
が、より好適には微細孔の数、孔径の異なる二種以上を
併用した方がリリースコントロール性にすぐれる。The copper compound and the vegetable essential oil exhibiting the anti-slimming action of the anti-slime agent of the present invention, if they are washed away or volatilized at one time, the durability of the effect as the anti-slime agent is inferior, and the release is gradually released. As described above, it has been found that it is necessary to have a release control effect in order to release (release), but diatomaceous earth having a microporous structure, natural or synthetic zeolite is used as a carrier for this purpose. Alternatively, activated alumina and the like are suitable. These may be used alone or in combination. More preferably, two or more kinds having different numbers of pores and different pore diameters are more excellent in release controllability.
【００１２】本発明では、銅化合物、植物精油およびリ
リースコントロール性担体の三成分を成形するのでな
く、適度の水流失性を付与できる他の成分をキャリアー
物質として混合する必要がある。こゝで、キャリアー物
質として水溶性化合物単独を用いれば、当然のことなが
ら流失が早すぎ、また、水不溶性化合物のみを用いれば
逆に水流失性が劣りぬめり防止効果を十分に発揮できな
い。In the present invention, it is necessary to mix, as a carrier substance, other components capable of imparting a proper water-spill property, instead of molding the three components of the copper compound, the vegetable essential oil and the release control carrier. Here, if the water-soluble compound alone is used as the carrier substance, the spillage is naturally too fast, and if only the water-insoluble compound is used, the water spillability is inferior and the slimming prevention effect cannot be sufficiently exhibited.
【００１３】本発明では、このキャリアー物質として水
不溶性の無機化合物と水溶性化合物とを併用して用いれ
ばよいことを見出したのは前述したとおりであるが、具
体的には、水不溶性化合物としてはけい酸カルシウム、
炭酸カルシウムまたは硫酸カルシウムなどのカルシウム
塩、二酸化けい素、けい藻土などのシリカーアルミニウ
ム化合物、水溶性化合物としてはでんぷん、メチルセル
ローズまたはセルロースエーテル化合物などのセルロー
ズ化合物があげられる。その混合比率は、要求される水
流失性の程度によって無機化合物の１００重量部に対し
て水溶性セルロース化合物の０．５〜５０重量部が好適
であった。In the present invention, as described above, it has been found that a water-insoluble inorganic compound and a water-soluble compound may be used in combination as the carrier substance. Calcium silicate,
Calcium salts such as calcium carbonate and calcium sulfate; silica-aluminum compounds such as silicon dioxide and diatomaceous earth; and water-soluble compounds include starch, methylcellulose and cellulose ether compounds such as cellulose ether compounds. The mixing ratio was preferably 0.5 to 50 parts by weight of the water-soluble cellulose compound to 100 parts by weight of the inorganic compound depending on the required degree of water loss.
【００１４】本発明で用いる各成分の量比について述べ
ると、銅化合物は０．１〜１０重量％、揮発して殺菌ま
たは抗菌効果を有する植物精油を１〜４８重量％、これ
らを担持してリリースコントロール性を発揮できる担体
は担持させる上記成分量に応じて約２〜４０重量％を用
い、残りを前述のキャリアー物質とするものである。The amount ratio of each component used in the present invention is described as follows: 0.1 to 10% by weight of a copper compound, and 1 to 48% by weight of a plant essential oil which volatilizes and has a bactericidal or antibacterial effect. A carrier capable of exhibiting release control is used in an amount of about 2 to 40% by weight according to the amount of the component to be supported, and the rest is used as the above-mentioned carrier substance.
【００１５】銅化合物の０．１重量％未満は抗菌効果が
不十分なため、また、１０重量％を超える使用は下水道
への銅化合物の流入濃度規制値を超える危険性があるた
め避けた方が望ましい。It is recommended to avoid using less than 0.1% by weight of the copper compound because the antibacterial effect is insufficient, and using more than 10% by weight is likely to exceed the regulated value of the concentration of the copper compound flowing into the sewer. Is desirable.
【００１６】植物精油の１重量％未満は抗菌効果が劣る
ため、また４８重量％を超えると成形物としての造形性
が劣るため本発明から除かれる。If the amount is less than 1% by weight, the antibacterial effect is inferior, and if it exceeds 48% by weight, the formability of a molded article is inferior, so that it is excluded from the present invention.
【００１７】リリースコントロール性を発揮できる担体
は、担持させるおもに植物精油の量に応じて約２〜４０
重量％とするものであるが、この範囲外では精油のにじ
み出しなどで成形上不利であった。The carrier capable of exhibiting the release controllability is about 2 to 40 depending on the amount of the plant essential oil to be carried.
However, if it is out of this range, it is disadvantageous in molding due to oozing of essential oil.
【００１８】本発明ぬめり防止剤を調製するには、各成
分を定められた量比に従って混合した後製剤とすればよ
いが、製剤方法としては、通常の圧縮打錠成形または湿
式成形など配合と用途に応じて選択すればよい。In order to prepare the anti-seize agent of the present invention, the respective components may be mixed according to a predetermined ratio, and then the resulting formulation may be prepared. What is necessary is just to select according to a use.
【００１９】各成分を配合するに際して、銅化合物と植
物精油はあらかじめリリースコントロール性をもつ担体
粉末に吸着または均一に混合した後キャリアー粉末と混
合する順序を採用した方が製品の均一性の面から有利で
あるのでこの順序が好適に用いられる。When compounding each component, the order of adsorbing or uniformly mixing the copper compound and the plant essential oil with a carrier powder having release control properties in advance and then mixing with the carrier powder is preferred from the viewpoint of product uniformity. This order is preferably used because it is advantageous.
【００２０】本発明ぬめり防止剤の調製に際して、着色
剤を添加して着色すること、および洗浄効果を付与する
ために界面活性剤を添加することは任意に行ってよい。In preparing the anti-seizing agent of the present invention, coloring may be carried out by adding a coloring agent, and a surfactant may be added to impart a cleaning effect.
【００２１】本発明ぬめり防止剤は、たとえばネットや
孔あきのプラスチック容器に収納して台所流し台のくず
かご、浴室の排水口、あるいはトイレットの水洗タンク
などに用いれば破損することなく徐々に流失していき、
成形物との接触面のみならずその周辺にも抗菌とぬめり
防止効果を発揮でき、また、酸性やアルカリ性物質とま
ざっても有害ガスの発生がなく安全性にすぐれている。
しかも、流失した成分は再固結することもないのでパイ
プなどの流水路を詰らすこともない。The anti-slime agent of the present invention, for example, is stored in a net or a perforated plastic container and is gradually washed away without being damaged when used in a kitchen wastebasket, a bathroom drain, or a toilet flush tank. ,
The antibacterial and anti-slimming effects can be exerted not only on the contact surface with the molded product but also on the periphery thereof, and even when mixed with acidic or alkaline substances, no harmful gas is generated and the safety is excellent.
In addition, the lost components do not solidify again, and thus do not clog the flowing water channels such as pipes.
【００２２】本発明を実施例によって具体的に説明す
る。部および％はとくに明示しない限りそれぞれ重量
部、重量％で示した。The present invention will be described specifically with reference to examples. Parts and% are indicated by parts by weight and% by weight, respectively, unless otherwise specified.
【００２３】[0023]
【実施例１】硫酸銅五水和物の１５％水溶液１００部を
微細孔を有する活性アルミナ粉末（和光純薬工業株式会
社品）２００部に吸着させた。他にヒノキチオール含有
ひば油（大阪有機化学工業株式会社品）３０部、ユーカ
リ油（寿香料株式会社品）３０部を上記活性アルミナ粉
末１１５部に吸着させた。キャリアー物質として硫酸カ
ルシウム粉末１７５部とメチルセルローズ粉末（和光純
薬工業株式会社品）１０部との混合物を用意する。Example 1 100 parts of a 15% aqueous solution of copper sulfate pentahydrate was adsorbed on 200 parts of activated alumina powder having fine pores (manufactured by Wako Pure Chemical Industries, Ltd.). In addition, 30 parts of hinokitiol-containing hiba oil (manufactured by Osaka Organic Chemical Industry Co., Ltd.) and 30 parts of eucalyptus oil (manufactured by Kotobuki Co., Ltd.) were adsorbed to 115 parts of the activated alumina powder. A mixture of 175 parts of calcium sulfate powder and 10 parts of methylcellulose powder (manufactured by Wako Pure Chemical Industries, Ltd.) is prepared as a carrier substance.
【００２４】こうしてえられた硫酸銅吸着粉末、植物精
油吸着粉末およびキャリアー混合物を均一に混合した
後、賦型剤としてヒドロキシプロピルメチルセルローズ
（信越化学工業株式会社、商品名メトローズ）１００
部、滑沢剤としてステアリン酸アルミニウム粉末（和光
純薬工業株式会社品）２０部を加えて混合し常法に従っ
て３０ｍｍφ、厚み１５ｍｍの錠剤に打錠成形して本発
明ぬめり防止剤とした。After the thus obtained copper sulfate-adsorbed powder, vegetable essential oil-adsorbed powder and carrier mixture are uniformly mixed, hydroxypropyl methyl cellulose (Shin-Etsu Chemical Co., Ltd., trade name Metrolose) 100 is used as a shaping agent.
Parts and 20 parts of aluminum stearate powder (manufactured by Wako Pure Chemical Industries, Ltd.) as a lubricant were added and mixed, and the mixture was tablet-formed into tablets having a diameter of 30 mm and a thickness of 15 mm according to a conventional method to obtain the anti-slip agent of the present invention.
【００２５】本錠剤は、銅化合物１．９％、植物精油
７．７％リリースコントロール性担体４０．４％、水溶
性成分１．２８％を含んだ組成となっており、台所流し
台くずかご内に置いて錠剤接触面のみならず周辺部分の
ぬめりの付着防止に効果を発揮し約３０日間で流失し
た。This tablet has a composition containing 1.9% of a copper compound, 7.7% of a vegetable essential oil, 40.4% of a release control carrier, and 1.28% of a water-soluble component. It was effective in preventing the adhesion of slimy not only on the tablet contact surface but also on the peripheral portion, and was washed away in about 30 days.
【００２６】[0026]
【実施例２】銅化合物として酢酸銅一水塩（和光純薬工
業株式会社品）０．１部、植物精油として市販木酢液
（ヨーキ産業株式会社品）４８部、リリースコントロー
ル性担体として活性アルミナ粉末５部およびけい藻土
（昭和化学工業株式会社品）３．５部、キャリアー物質
として硫酸カルシウムの半水塩４０部とヒドロキシプロ
ピルメチルセルローズ１．４部の混合物、および市販界
面活性剤（日本油脂株式会社、商品名アノンＬＧ）２部
を混合してクリーム状とした後、３５ｍｍφ、深さ１６
ｍｍのプラスチック型を使用して常法により成形して本
発明品とした。Example 2 0.1 part of copper acetate monohydrate (product of Wako Pure Chemical Industries, Ltd.) as a copper compound, 48 parts of commercially available wood vinegar (product of Yoki Sangyo Co., Ltd.) as a plant essential oil, and activated alumina as a release control carrier A mixture of 5 parts of powder and 3.5 parts of diatomaceous earth (manufactured by Showa Chemical Industry Co., Ltd.), 40 parts of calcium sulfate hemihydrate and 1.4 parts of hydroxypropylmethylcellulose as carrier substances, and a commercially available surfactant (Japan Yushi Co., Ltd., product name Anon LG) 2 parts were mixed to make a cream, and then 35 mmφ, depth 16
The product of the present invention was molded by a conventional method using a plastic mold of mm.
【００２７】こうしてえられた本発明ぬめり防止剤（２
１部）を市販のクロルメチルイソチアゾリン包接化合物
を成分とするぬめり取り剤（株式会社白元、１４．９
部）と台所流し台くずかごで比較したところ下記の結果
をえた。The antislime agent of the present invention thus obtained (2
1 part) as a component of a commercially available chloromethylisothiazoline inclusion compound as a component (Shiramoto Co., Ltd., 14.9)
Part) and the kitchen sink wastebasket gave the following results.
【００２８】まず、本発明ぬめり防止剤は、くずかごの
錠剤接触面のみならず底面全面および側壁約４〜５ｃｍ
の高さまでぬめりの付着防止効果が認められたのに対し
て、市販比較品は、底面の錠剤接触面とそのまわりのみ
に効果がみられるにとゞまった。First, the anti-slip agent of the present invention is used not only for the tablet contact surface of the wastebasket but also for the entire bottom surface and side walls of about 4 to 5 cm.
In contrast, the effect of preventing the adhesion of the slimming was observed up to the height, whereas the effect of the commercially available comparative product was observed only on and around the tablet contact surface on the bottom surface.
【００２９】[0029]
【実施例３】硫酸銅五水和物２．５部、酸化銅粉末９
部、ヒノキチオール（大阪有機化学工業株式会社品、天
然品）５部を８０％エチルアルコール水溶液４５部に分
散溶解した溶液の４７部、レモングラス油３部、実施例
２で用いたけい藻土９部、市販けい酸カルシウム粉末
（和光純薬工業株式会社品）３０部、およびメチルセル
ローズ１５部を混練りした後押出し成型機で１０ｍｍ
φ、長さ４０ｍｍに成形しこれを自然乾燥して本発明ぬ
めり防止剤をうる。これを、孔あきのプラスチックケー
スに入れて浴室で用いたところ、排水口のぬめり防止お
よび吹上げてくる臭気の防止に約２５日間有効であっ
た。Example 3 2.5 parts of copper sulfate pentahydrate, copper oxide powder 9
Part, a solution obtained by dispersing 5 parts of hinokitiol (product of Osaka Organic Chemical Industry Co., Ltd., natural product) in 45 parts of an 80% aqueous ethyl alcohol solution, 47 parts of lemongrass oil, 9 parts of diatomaceous earth used in Example 2 , 30 parts of commercially available calcium silicate powder (manufactured by Wako Pure Chemical Industries, Ltd.) and 15 parts of methylcellulose, and then kneaded with an extruder.
It is formed into a φ, length of 40 mm, and naturally dried to obtain the anti-slime agent of the present invention. When this was put into a perforated plastic case and used in a bathroom, it was effective for about 25 days in preventing slimming of the drain port and preventing odor from blowing up.
【００３０】[0030]
【発明の効果】本発明は以上説明したように構成されて
いるから、各種流水路に置くだけで流水によって徐々に
流失していき抗菌作用を発揮でき、しかも本剤が接触し
ない周辺部にも植物精油の揮発によって抗菌作用を発揮
できることから、流水路におけるぬめり付着防止に従来
市販品にない効果をもつものである。Since the present invention is constructed as described above, it can be gradually washed away by running water and exerted an antibacterial effect only by being placed in various flowing water channels, and it can also be used in peripheral parts where the agent does not come into contact. Since the essential oil can exhibit an antibacterial action by volatilization of the essential oil, it has an effect which is not presently available on commercial products in preventing slimy adhesion in running water channels.
【００３１】さらに、酸性洗剤や漂白剤などのアルカリ
性物質とまざっても有害ガスを発生することもないので
安全性にすぐれている。これらの効果はこの種従来品で
は到底達成できないものであり、安全性と取扱性とにす
ぐれたぬめり防止剤として有益である。Further, even when mixed with an alkaline substance such as an acidic detergent or a bleaching agent, no harmful gas is generated, so that the safety is excellent. These effects cannot be achieved with conventional products of this type at all, and are useful as anti-slimming agents having excellent safety and handleability.
Claims (1)
て殺菌または抗菌効果を有する植物抽出精油の１〜４８
重量％を必須成分として含有し、これらを担持してリリ
ースコントロール性を発揮できる吸着担体と共に流水に
よって徐々に流失する性質をもった固形物に成形したこ
とを特長とする揮発性ぬめり防止剤。1. An essential oil of a plant extract having a bactericidal or antibacterial effect by volatilization with 0.1 to 10% by weight of a copper compound.
A volatile anti-seizure agent characterized in that it is formed into a solid having a weight% as an essential component, and an adsorbent capable of carrying these and exhibiting release controllability, and having a property of being gradually washed away by running water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000089947A JP2001192311A (en) | 2000-01-06 | 2000-01-06 | Volatile slime inhibitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000089947A JP2001192311A (en) | 2000-01-06 | 2000-01-06 | Volatile slime inhibitor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001192311A true JP2001192311A (en) | 2001-07-17 |
Family
ID=18605628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000089947A Pending JP2001192311A (en) | 2000-01-06 | 2000-01-06 | Volatile slime inhibitor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001192311A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002154907A (en) * | 2000-11-16 | 2002-05-28 | Fumakilla Ltd | Mothproof microbial removing agent for drainage hole |
| JP2002154902A (en) * | 2000-11-16 | 2002-05-28 | Fumakilla Ltd | Microbe removing agent for drainage hole |
| JP2003105384A (en) * | 2001-09-28 | 2003-04-09 | Keiji Tsuchiya | Cleaning composition containing wood vinegar of bincho charcoal |
| JP2006502225A (en) * | 2002-10-08 | 2006-01-19 | エルドレッド・ブラッドレー・ジェイ | Disinfecting and purifying composition by synergistic effect of organic compound and metal ion and method for producing the same |
| JP2006518339A (en) * | 2003-02-21 | 2006-08-10 | パー・ウォーター・ピュリフィケイション・プロダクツ・インコーポレイテッド | Water treatment composition having masking agent |
| JP2015218162A (en) * | 2014-05-14 | 2015-12-07 | 株式会社ピカソ美化学研究所 | Antibacterial/preservative agent and composition for external application |
-
2000
- 2000-01-06 JP JP2000089947A patent/JP2001192311A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002154907A (en) * | 2000-11-16 | 2002-05-28 | Fumakilla Ltd | Mothproof microbial removing agent for drainage hole |
| JP2002154902A (en) * | 2000-11-16 | 2002-05-28 | Fumakilla Ltd | Microbe removing agent for drainage hole |
| JP2003105384A (en) * | 2001-09-28 | 2003-04-09 | Keiji Tsuchiya | Cleaning composition containing wood vinegar of bincho charcoal |
| JP2006502225A (en) * | 2002-10-08 | 2006-01-19 | エルドレッド・ブラッドレー・ジェイ | Disinfecting and purifying composition by synergistic effect of organic compound and metal ion and method for producing the same |
| JP4634801B2 (en) * | 2002-10-08 | 2011-02-16 | エルドレッド・ブラッドレー・ジェイ | Disinfecting and purifying composition by synergistic effect of organic compound and metal ion and method for producing the same |
| JP2006518339A (en) * | 2003-02-21 | 2006-08-10 | パー・ウォーター・ピュリフィケイション・プロダクツ・インコーポレイテッド | Water treatment composition having masking agent |
| JP2015218162A (en) * | 2014-05-14 | 2015-12-07 | 株式会社ピカソ美化学研究所 | Antibacterial/preservative agent and composition for external application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2001049818A1 (en) | Effervescent toilet bowl sanitizer tablet | |
| JP2002154907A (en) | Mothproof microbial removing agent for drainage hole | |
| JP2001192311A (en) | Volatile slime inhibitor | |
| JPH09202706A (en) | Sterilizing and cleaning agent for drainage | |
| JPS62176453A (en) | Aroma or sterilizing agent and solid for releasing the same | |
| JP3421282B2 (en) | Drainage remover for drain | |
| JP2010202564A (en) | Dichloroisocyanuric acid tablet | |
| JP4925300B2 (en) | Chlorinated isocyanuric acid tablets | |
| JP2003246998A (en) | Foaming detergent | |
| JP4963334B2 (en) | Drainage removal agent and drainage removal tool for drain outlet | |
| JP2000327509A (en) | Slime-controlling agent | |
| JP5940047B2 (en) | Waste water purification material | |
| JP2004043422A (en) | Volatile agent for preventing sliminess | |
| JP4669604B2 (en) | Disinfectant for drain outlet | |
| JP2003013095A (en) | Water-washed out sterilizing cleanser | |
| JP2008007494A (en) | Slime control agent | |
| JP2001065020A (en) | Slime removing tool | |
| JP2002154902A (en) | Microbe removing agent for drainage hole | |
| JPH1143404A (en) | Degerming and cleaning agent | |
| JPH11158016A (en) | Sodium percarbonate-containing composition | |
| JPH1087415A (en) | Agent for sterilizing and cleansing for drain outlet | |
| JPH1129797A (en) | Peroxide-containing composition | |
| JP2920360B2 (en) | Purifier for sink basket and method for producing the same | |
| KR20030096491A (en) | Foaming cleaner for a drain-outlet | |
| ITPI20000026A1 (en) | SCENTED DISINFECTANT TABLET |