JP2000351719A5 - - Google Patents
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- JP2000351719A5 JP2000351719A5 JP1999161831A JP16183199A JP2000351719A5 JP 2000351719 A5 JP2000351719 A5 JP 2000351719A5 JP 1999161831 A JP1999161831 A JP 1999161831A JP 16183199 A JP16183199 A JP 16183199A JP 2000351719 A5 JP2000351719 A5 JP 2000351719A5
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- Prior art keywords
- hair
- acid
- salts
- hair dye
- present
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- 239000000118 hair dye Substances 0.000 claims description 22
- 239000011780 sodium chloride Substances 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 9
- 150000001277 beta hydroxy acids Chemical class 0.000 claims description 7
- 239000004166 Lanolin Substances 0.000 claims description 5
- 229940039717 Lanolin Drugs 0.000 claims description 5
- 235000019388 lanolin Nutrition 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 235000018936 Vitellaria paradoxa Nutrition 0.000 claims 1
- 241001135917 Vitellaria paradoxa Species 0.000 claims 1
- 150000001280 alpha hydroxy acids Chemical class 0.000 description 10
- 229940061720 Alpha Hydroxy Acids Drugs 0.000 description 7
- -1 alkali metal salts Chemical class 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000002537 cosmetic Substances 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N Squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229960005188 collagen Drugs 0.000 description 2
- 229920001436 collagen Polymers 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000001024 permanent hair color Substances 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-Aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-Hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 description 1
- 229940093740 Amino acids and derivatives Drugs 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N Cetyl alcohol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N Hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 1
- 229940117969 NEOPENTYL GLYCOL Drugs 0.000 description 1
- 229960002969 Oleic Acid Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Natural products CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N Oleyl alcohol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229960004274 Stearic acid Drugs 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Tris Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000111 anti-oxidant Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N butylene glycol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 230000000295 complement Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N ethanolamine Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003051 hair bleaching agent Substances 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000001771 impaired Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 230000003020 moisturizing Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003287 optical Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001888 polyacrylic acid Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001737 promoting Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000001026 semi permanent hair color Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229960001367 tartaric acid Drugs 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Description
【0004】
一方、α−ヒドロキシ酸及び/又はその塩は皮膚化粧料の分野に於いては、そのシワ改善効果が認められて既にシワ改善化粧料に含有されているが、このものは染毛料中に含有されたことはなかったし、このものが存在することにより、染毛料の均一な染毛性とその堅牢性が著しく向上しうることも全く知られていなかった。又、β−ヒドロキシ酸及び/又はその塩については、化粧料分野での作用は、酸としての作用のみしか知られていなかった。更に、ラノリン誘導体について、このものとヒドロキシカルボン酸とともに使用することは知られておらず、従って、染毛料の分野に於いてヒドロキシカルボン酸とラノリン誘導体を組み合わせて使用することは全く知られておらず、この様な組合せにより、堅牢性に優れ、髪に優しい染毛料が得られることも全く知られていなかった。[0004]
On the other hand, in the field of skin cosmetics, α - hydroxy acids and / or salts thereof are already contained in wrinkle improving cosmetics because of their effect of improving wrinkles, but these are contained in hair dyes. It was never known that the presence of this product could significantly improve the uniform hair dyeing properties and the fastness of the hair dye. Further, regarding the β-hydroxy acid and / or its salt, the action in the cosmetic field was known only as an acid. Further, it is not known that the lanolin derivative is used together with the hydroxycarboxylic acid. Therefore, it is completely known that the combination of the hydroxycarboxylic acid and the lanolin derivative is used in the field of hair dyes. In addition, it has not been known at all that such a combination provides a hair coloring material having excellent fastness and being gentle to hair.
【0006】
【課題の解決手段】
この様な状況に鑑みて、本発明者らは、均一な染毛性と優れた堅牢性を有する染毛料を求めて鋭意研究努力を重ねた結果、ラノリン及びその誘導体から選ばれる1種乃至は2種以上とヒドロキシカルボン酸及び/又はその塩から選ばれる1種乃至は2種以上を含有することを特徴とする、染毛料にその様な特性を見出し、発明を完成させるに至った。以下、本発明について、その実施の形態を中心に詳細に説明を加える。[0006]
[Means for solving the problem]
In view of such a situation, the present inventors have conducted intensive research efforts in search of a hair dye having uniform hair dyeing properties and excellent fastness, and as a result, one or more selected from lanolin and its derivatives. one to be selected from two or more and hydrate ii Kishikarubon acid and / or salts thereof is characterized by containing two or more, found such characteristics hair dye, and have completed the invention. Hereinafter, the present invention will be described in detail focusing on its embodiments.
【0008】
(2)本発明の必須成分であるヒドロキシカルボン酸及び/又はその塩
本発明の染毛料は、α−ヒドロキシ酸、β−ヒドロキシ酸及びそれらの塩等のヒドロキシカルボン酸及び/又はその塩から選ばれる1種乃至は2種以上を必須成分として含有することを特徴とする。これらヒドロキシカルボン酸としては、水酸基を有するカルボン酸であれば特段の限定なく使用できるが、α−ヒドロキシ酸とβ−ヒドロキシ酸が特に好ましい。このうち、α−ヒドロキシ酸としては、化粧料などの分野で使用されているα位に水酸基を有するカルボン酸であれば特段の限定を受けずに、本発明で用いることが出来、この様なα−ヒドロキシ酸としては、例えば、グリコール酸、乳酸、酒石酸等が好ましく例示できる。これらα−ヒドロキシ酸の多くはα位が不整炭素であり、光学異性体やジアステレオマー等の立体異性体が存在する場合が多いが、本発明の染毛料に於いては、α−ヒドロキシ酸の作用は立体特異性が大きくはないので、何れの立体配座のものでも使用できる。これらの中では、グリコール酸がその効果の面から特に好ましい。β−ヒドロキシ酸としては、β位に水酸基を有するカルボン酸であれば、特段の限定はされず、例えば、β−乳酸等が好ましく例示できる。α−ヒドロキシ酸とβ−ヒドロキシ酸ではα−ヒドロキシ酸がより好ましい。又、それらの塩としては、生理的に許容されるものであれば特段の限定を受けず使用でき、例えば、ナトリウムやカリウムなどのアルカリ金属塩、カルシウムやマグネシウムなどのアルカリ土類金属塩、アンモニウム塩、トリエタノールアミン、トリエチルアミン、モノエタノールアミン等の有機アミン塩、リジンやアルギニンなどの塩基性アミノ酸塩等が例示できる。本発明の染毛料では、これらのα−ヒドロキシ酸、β−ヒドロキシ酸及びその塩等のヒドロキシカルボン酸及び/又はその塩から選ばれる1種乃至は2種以上を含有する。これらは、染毛成分が毛髪内部に浸透するのを促進するため、染毛の深度が深くなり、染毛の均一性と堅牢性が向上する。更に加えて、この様な浸透促進作用に優れることから、染毛に要する時間が短縮されると言う、画期的な効果、それに伴う染毛後の毛髪のダメージの抑制効果も有する。本発明の染毛料に於ける、ヒドロキシカルボン酸及び/又はその塩の好ましい含有量は、0.01〜10重量%であり、更に好ましくは0.1〜5重量%である。これは、少なすぎると効果を発現できない場合があり、多すぎると他の成分の配合自由度を損なうことがあるからである。[0008]
(2) Hydroxycarboxylic acid and / or salt thereof as an essential component of the present invention The hair dye of the present invention is selected from hydroxycarboxylic acids and / or salts thereof such as α-hydroxy acids, β-hydroxy acids and salts thereof. It is characterized by containing one or two or more of the above as essential components. As these hydroxycarboxylic acids, any carboxylic acid having a hydroxyl group can be used without any particular limitation, and α-hydroxy acids and β-hydroxy acids are particularly preferred. Among them, as the α-hydroxy acid, any carboxylic acid having a hydroxyl group at the α-position used in the field of cosmetics and the like can be used in the present invention without any particular limitation. Preferred examples of the α-hydroxy acid include glycolic acid, lactic acid, tartaric acid and the like. Many of these α-hydroxy acids have an asymmetric carbon at the α-position and often have stereoisomers such as optical isomers and diastereomers, but in the hair dye of the present invention, the α-hydroxy acid Does not have a large stereospecificity, so that any conformation can be used. Among these, glycolic acid is particularly preferred from the viewpoint of its effect. The β - hydroxy acid is not particularly limited as long as it is a carboxylic acid having a hydroxyl group at the β-position. For example, β-lactic acid can be preferably exemplified. Among the α-hydroxy acids and β-hydroxy acids, α-hydroxy acids are more preferred. Further, as their salts, any physiologically acceptable salts can be used without any particular limitation. Examples thereof include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as calcium and magnesium, and ammonium. Examples thereof include salts, organic amine salts such as triethanolamine, triethylamine and monoethanolamine, and basic amino acid salts such as lysine and arginine. The hair dye of the present invention contains one or two or more selected from hydroxycarboxylic acids and / or salts thereof such as α-hydroxy acids, β-hydroxy acids and salts thereof. These promote the penetration of the hair dye component into the interior of the hair, thereby increasing the depth of the hair dye and improving the uniformity and the fastness of the hair dye. In addition, such excellent penetration promoting effect has an epoch-making effect that the time required for hair dyeing is shortened, and also has an effect of suppressing damage to hair after hair dyeing. The preferred content of hydroxycarboxylic acid and / or a salt thereof in the hair dye of the present invention is 0.01 to 10% by weight, and more preferably 0.1 to 5% by weight. This is because if the amount is too small, the effect may not be exhibited, and if the amount is too large, the flexibility of mixing other components may be impaired.
【0009】
(3)本発明の染毛料
本発明の染毛料は、上記ラノリン及びその誘導体から選ばれる1種乃至は2種以上とヒドロキシカルボン酸及びそれらの塩から選ばれる1種乃至2種以上とをことを特徴とする。本発明の染毛料は、上記必須成分以外に、通常染毛料で使用される任意成分を含有することができる。ここで、本発明で言う染毛料とは、毛髪の色調を変化させるために使用される外用剤の総称であって、半永久染毛料、永久染毛料、毛髪脱色剤、これらの前処理剤や後処理剤などの概念を包括するものである。本発明の染毛料として特に好ましいものは、酸化染料などを含有する、永久染毛料である。本発明の染毛料で使用できる任意成分としては例えば、反応性染料、レゾルシン、アミノフェノールとその誘導体等の酸化染料、コラーゲン、ケラチンやその誘導体、植物抽出エキスなどの保湿剤、アミノ酸やその誘導体などの毛髪保護成分、スクワランやマイクロクリスタリンワックス等のような炭化水素類、ホホバ油やゲイロウ等のエステル類、牛脂、オリーブ油等のトリグリセライド類、セタノール、オレイルアルコール等の高級アルコール類、ステアリン酸、オレイン酸等の脂肪酸、グリセリンや1,3−ブタンジオール等の多価アルコール類、非イオン界面活性剤、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、エタノール、カーボポール等の増粘剤、防腐剤、紫外線吸収剤、抗酸化剤、色素、粉体類等が好ましく例示できる。これらの内で、特に好ましい任意成分は、コラーゲン等の蛋白とその誘導体であり、更に好ましくは、この様な成分の内、分子量の大きいものと小さいものとを組み合わせて使用することである。この様な組合せとしては成和化成工業株式会社製のプロモイスW−32RとプロモイスW−52Qの組合せがあり、これらを40:60〜60:40の割合で0.001〜0.1重量%含有するのが、染毛後毛髪のダメージ補完ができることから好ましい。更に、又、保湿性を有する油脂や櫛通り改善などの作用を有する油脂類を含有させることは染毛に於けるダメージを軽減できるので非常に有利である。この様な油脂として例示できるものは、スクワランなどの炭化水素類、ホホバ油やネオペンチルグリコールジイソオクタネート等のエステル類、ジメチコン、メチルフェニルポリシロキサン、シリコーンエラストマー、ポリオキシエチレン変性シリコーン、アモジメチコン、アクリル酸変性シリコーンなどのシリコーン類(エマルジョン形態を含む。)等が挙げられる。このうち特に好ましいものは、シリコーン類である。これらの原料を常法に従って処理することにより、本発明の染毛料は製造することが出来る。[0009]
(3) Hair dye of the present invention The hair dye of the present invention comprises one or more selected from the above lanolin and derivatives thereof and one or two or more selected from hydroxycarboxylic acids and salts thereof. It is characterized by. The hair dye of the present invention can contain optional components usually used in hair dyes in addition to the above essential components. Here, the hair dye referred to in the present invention is a generic name of external preparations used for changing the color tone of hair, and includes semi-permanent hair dyes, permanent hair dyes, hair bleaching agents, these pretreatment agents and It encompasses concepts such as treatment agents. Particularly preferred as the hair dye of the present invention is a permanent hair dye containing an oxidation dye or the like. Optional components that can be used in the hair dye of the present invention include, for example, reactive dyes, resorcinol, oxidation dyes such as aminophenol and derivatives thereof, collagen, keratin and derivatives thereof, humectants such as plant extract extracts, amino acids and derivatives thereof and the like. Hair protection ingredients, hydrocarbons such as squalane and microcrystalline wax, esters such as jojoba oil and gay wax, triglycerides such as tallow, olive oil, higher alcohols such as cetanol and oleyl alcohol, stearic acid, oleic acid Fatty acids such as, polyhydric alcohols such as glycerin and 1,3-butanediol, nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, thickeners such as ethanol and carbopol, Preservatives, UV absorbers, antioxidants, pigments, powders, etc. are preferred It can be shown. Among these, particularly preferred optional components are proteins such as collagen and derivatives thereof, and more preferably, of these components, those having a large molecular weight and those having a small molecular weight are used in combination. As such a combination, there is a combination of Promois W-32R and Promois W-52Q manufactured by Seiwa Kasei Kogyo Co., Ltd., and these are contained in a ratio of 40:60 to 60:40 by 0.001 to 0.1% by weight. This is preferable because it can complement the damage of the hair after hair dyeing. Furthermore, it is very advantageous to include oils and fats having a moisturizing property and oils and fats having an action of improving combing, because damage in hair dyeing can be reduced. What can be exemplified as such fats, hydrocarbons such as squalane, esters such as jojoba oil or neopentyl glycol di isooctanoate sulfonates, dimethicone, methylphenyl polysiloxane, silicone elastomer, polyoxyethylene-modified silicones, Amojimechi con And silicones (including emulsions) such as acrylic acid-modified silicone. Of these, silicones are particularly preferred. The hair dye of the present invention can be produced by treating these raw materials according to a conventional method.
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP16183199A JP2000351719A (en) | 1999-06-09 | 1999-06-09 | Hair dyeing agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP16183199A JP2000351719A (en) | 1999-06-09 | 1999-06-09 | Hair dyeing agent |
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JP2000351719A JP2000351719A (en) | 2000-12-19 |
JP2000351719A5 true JP2000351719A5 (en) | 2004-12-02 |
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JP16183199A Pending JP2000351719A (en) | 1999-06-09 | 1999-06-09 | Hair dyeing agent |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2002226338A (en) * | 2001-02-05 | 2002-08-14 | Hoyu Co Ltd | Oxidative hair dye composition |
DE10132915A1 (en) * | 2001-07-06 | 2003-01-30 | Wella Ag | Aqueous emulsion carrier for oxidation hair dye contains fatty alcohols or glycerol esters of saturated fatty acids, surfactants and lanolin or glyceryl monooleate |
JP2004026770A (en) * | 2002-06-28 | 2004-01-29 | Milbon Co Ltd | First agent for correcting curly hair and method for correcting treatment of curly hair using the same |
JP2010037315A (en) * | 2008-08-08 | 2010-02-18 | Kao Corp | Hairdye composition |
JP5547906B2 (en) * | 2009-04-27 | 2014-07-16 | 中野製薬株式会社 | First agent for two-component oxidative hair dye and depigmenting agent |
-
1999
- 1999-06-09 JP JP16183199A patent/JP2000351719A/en active Pending
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