JP2000262605A - Air cleaning device - Google Patents

Air cleaning device

Info

Publication number
JP2000262605A
JP2000262605A JP11071802A JP7180299A JP2000262605A JP 2000262605 A JP2000262605 A JP 2000262605A JP 11071802 A JP11071802 A JP 11071802A JP 7180299 A JP7180299 A JP 7180299A JP 2000262605 A JP2000262605 A JP 2000262605A
Authority
JP
Japan
Prior art keywords
photocatalyst
honeycomb
light
air
photocatalyst member
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11071802A
Other languages
Japanese (ja)
Inventor
Shinya Hioki
信也 火置
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Paper Mills Ltd
Original Assignee
Mitsubishi Paper Mills Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Paper Mills Ltd filed Critical Mitsubishi Paper Mills Ltd
Priority to JP11071802A priority Critical patent/JP2000262605A/en
Publication of JP2000262605A publication Critical patent/JP2000262605A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide an air cleaning device which efficiently converts the light energy generated by a light source to deodorant, antimicrobial and other functions. SOLUTION: Honeycomb-shaped photocatalyst members 5 are arranged at an angle with a flowing direction of air in the air cleaning device having a fan 8, the photocatalyst members 5, 6, 7 and the light source 4 for emitting the light to excite these photocatalyst members within a casing 3 having an air suction port 1 and an air exit 2. Further, the photocatalyst members 7 are arranged on the inside surface of the easing to which the light leaking from the honeycomb-shaped photocatalyst members 5 falls.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、冷蔵庫・冷蔵コン
テナ、家庭、事業所、車室内などの各種容器内および建
造物内の悪臭を脱臭するために用いられる脱臭抗菌機能
を有する空気清浄装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an air purifying apparatus having a deodorizing and antibacterial function, which is used for deodorizing odors in various containers such as refrigerators and refrigerated containers, homes, business offices, vehicle interiors, and buildings. .

【0002】[0002]

【従来の技術】食品臭、たばこ臭、ペット臭、便所臭な
どの悪臭の成分は、多種多様であり、代表的なものとし
て、アンモニア、アミン類、インドール、スカトールな
どの窒素化合物、硫化水素、メチルメルカプタン、硫化
メチル、二硫化メチル、二硫化ジメチルなどの硫黄化合
物、ホルムアルデヒド、アセトアルデヒドなどのアルデ
ヒド類、アセトンなどのケトン類、メタノール、エタノ
ールなどのアルコール類がある。
2. Description of the Related Art The components of malodor such as food odor, tobacco odor, pet odor, and toilet odor are various, and typical ones are ammonia, amines, nitrogen compounds such as indole and skatole, hydrogen sulfide, There are sulfur compounds such as methyl mercaptan, methyl sulfide, methyl disulfide and dimethyl disulfide, aldehydes such as formaldehyde and acetaldehyde, ketones such as acetone, and alcohols such as methanol and ethanol.

【0003】従来、このような悪臭を脱臭する方法とし
て、悪臭物質と薬剤とを化学反応させる方法、芳香剤で
悪臭物質をマスキングする方法、活性炭、ゼオライトな
どの吸着剤にて悪臭物質を吸着する方法、または、これ
らの方法を組み合わせて行う方法があった。このような
各種の脱臭方法が使用されているが、薬剤及び芳香剤
は、共に悪臭物質と反応した後での再生はほとんど不可
能である。また、吸着剤の場合も、吸着容量が飽和する
と脱臭性能は著しく低下する。従って、どのような方法
においても、新しいものと定期的に交換しなければなら
ない。
Heretofore, as a method of deodorizing such malodor, a method of chemically reacting a malodorous substance with a medicine, a method of masking a malodorous substance with an aromatic agent, and adsorption of a malodorous substance by an adsorbent such as activated carbon and zeolite are known. There has been a method or a method of combining these methods. Although various such deodorizing methods have been used, it is almost impossible to regenerate both the drug and the fragrance after reacting with the malodorous substance. Also, in the case of an adsorbent, when the adsorption capacity is saturated, the deodorizing performance is significantly reduced. Therefore, any replacement must be periodically replaced with a new one.

【0004】そこで、光触媒とランプとを用いて、脱臭
機能を果たすようにした脱臭装置が開発されている。光
触媒は光エネルギーを化学エネルギーに変える物質であ
り、具体的には、酸化タングステン、酸化チタン、酸化
イットリウム、酸化亜鉛などの金属酸化物またはこれら
の混合物からなる半導体である。
Therefore, a deodorizing apparatus has been developed which uses a photocatalyst and a lamp to perform a deodorizing function. The photocatalyst is a substance that converts light energy into chemical energy, and is specifically a semiconductor made of a metal oxide such as tungsten oxide, titanium oxide, yttrium oxide, zinc oxide, or a mixture thereof.

【0005】この脱臭装置では、ランプから紫外線を光
触媒に照射してその光エネルギーにて光触媒を活性化さ
せ、酸化反応を促進させて悪臭物質を無臭物質に変換す
る。紫外線照射によって光触媒が励起されると、光触媒
から電子が飛び出し表面に吸着した酸素を攻撃してO2 -
を生成し、また、正孔が空気中の水分を攻撃して、OH
ラジカルを生成し、これらの活性種により悪臭物質の酸
化反応が促進され、種々の悪臭物質が、具体的には水、
二酸化炭素などの無臭物質まで最終的に分解される。
In this deodorizing apparatus, a photocatalyst is irradiated with ultraviolet rays from a lamp to activate the photocatalyst with the light energy, thereby promoting an oxidation reaction and converting a malodorous substance into an odorless substance. When the photocatalyst is excited by the ultraviolet radiation, attacking the oxygen electrons from the photocatalyst is adsorbed on the surface popping O 2 -
And the holes attack the moisture in the air to form OH
Radicals are generated, and the oxidation reaction of malodorous substances is promoted by these active species, and various malodorous substances, specifically, water,
It is finally decomposed to odorless substances such as carbon dioxide.

【0006】光触媒を用いた脱臭装置においては、通気
性を有するハニカム状の光触媒部材に通気しながら励起
光を照射することが有効であるが、ハニカムのセル孔か
ら励起光がもれ、エネルギー効率が低いという問題があ
った。
In a deodorizing apparatus using a photocatalyst, it is effective to irradiate excitation light while ventilating a honeycomb-shaped photocatalyst member having air permeability. However, the excitation light leaks from cell holes of the honeycomb, and energy efficiency is reduced. Was low.

【0007】これに対して特開平9−66096号公報
にはハニカム状光触媒部材を空気の流れる方向に対して
角度を持たせて配置させる装置が開示されているが、光
は斜め方向にもれるため根本的な解決には至っていな
い。
On the other hand, Japanese Patent Application Laid-Open No. 9-66096 discloses an apparatus for disposing a honeycomb-shaped photocatalyst member at an angle with respect to the direction of air flow. As a result, no fundamental solution has been reached.

【0008】[0008]

【発明が解決しようとする課題】本発明の課題は、光源
が発する光エネルギーを効率よく脱臭・抗菌などの機能
に転換する空気清浄装置の提供である。
SUMMARY OF THE INVENTION An object of the present invention is to provide an air purifying apparatus for efficiently converting light energy emitted from a light source into functions such as deodorization and antibacterial.

【0009】[0009]

【課題を解決するための手段】本発明者らは、上記課題
を解決するため鋭意検討を重ねた結果、本発明に到達し
たものである。
Means for Solving the Problems The present inventors have made intensive studies to solve the above problems, and as a result, have reached the present invention.

【0010】すなわち、本発明は吸気口および排気口を
有する筐体内に送風機、光触媒部材および該光触媒を励
起させる光を発する光源を有する空気清浄装置におい
て、ハニカム状光触媒部材が空気の流れる方向に対して
角度を持って配置され、更に該ハニカム状光触媒部材か
らもれる光の当たる筐体内面に光触媒部材を配置するこ
とを特徴とする空気清浄装置である。
That is, the present invention relates to an air cleaning apparatus having a blower, a photocatalyst member, and a light source for emitting light for exciting the photocatalyst in a housing having an intake port and an exhaust port. The air purifying device is characterized in that the photocatalyst member is disposed on the inner surface of the housing where light leaks from the honeycomb-shaped photocatalyst member.

【0011】[0011]

【発明の実施の形態】本発明は、光源が発する光エネル
ギーを効率よく脱臭・抗菌などの機能に転換する空気清
浄装置を提供する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention provides an air purifying apparatus for efficiently converting light energy emitted from a light source to functions such as deodorization and antibacterial.

【0012】本発明の空気清浄装置は、吸気口および排
気口を有する筐体内に送風機、光触媒部材および該光触
媒を励起させる光を発する光源を有し、ハニカム状光触
媒部材が空気の流れる方向に対して角度を持って配置さ
れ、更に該ハニカム状光触媒部材からもれる光の当たる
筐体内面に光触媒部材を配置してなる。
[0012] The air purifying apparatus of the present invention has a blower, a photocatalyst member and a light source for emitting light for exciting the photocatalyst in a housing having an intake port and an exhaust port. The photocatalyst member is disposed on the inner surface of the housing where light leaking from the honeycomb-shaped photocatalyst member is applied.

【0013】本発明に係わる光触媒とは、0.5〜5e
V、好ましくは1〜4eVの禁止帯幅を有する、光触媒
反応をもたらす光反応性半導体である。本発明に係わる
このような光触媒としては、酸化亜鉛、酸化タングステ
ン、酸化チタン、及び酸化セリウム等の金属酸化物粒子
が挙げられるが、殊に酸化チタンはその構造安定性、光
反応性有害物除去能、更には取扱い上の安全性等から生
活空間において使用するには最も適しており、本発明に
係わる光触媒として有利に用いられる。
The photocatalyst according to the present invention is 0.5 to 5 e
V, preferably a photoreactive semiconductor that provides a photocatalytic reaction with a band gap of 1-4 eV. Examples of such a photocatalyst according to the present invention include metal oxide particles such as zinc oxide, tungsten oxide, titanium oxide, and cerium oxide. In particular, titanium oxide has structural stability and photoreactive harmful substances removal. The photocatalyst according to the present invention is most suitable for use in a living space because of its performance and safety in handling.

【0014】本発明に係わる光触媒部材は、光触媒を担
持した部材または光触媒からなる部材であって、光触媒
の他に活性炭、ゼオライトなどの吸着剤を含むものが好
ましく、特に、光触媒を担持した繊維状シートからなる
部材であることが好ましい。
The photocatalyst member according to the present invention is preferably a member carrying a photocatalyst or a member comprising a photocatalyst, which contains an adsorbent such as activated carbon or zeolite in addition to the photocatalyst. It is preferably a member made of a sheet.

【0015】本発明に係わるハニカム状とは、開孔を有
するセル壁からなる構造体の形状であり、ハニカムの具
体例として、JIS−Z−1516に記載の「外装用段
ボール」に準拠して作製される片段ボールを積層してな
るコルゲートハニカム、六角形セルからなるヘキサゴン
ハニカム、正方形セルからなるハニカム、三角形セルか
らなるハニカム、および中空円筒状セルを集合してなる
ハニカムなどが挙げられる。
The honeycomb shape according to the present invention is a shape of a structure composed of cell walls having openings. As a specific example of the honeycomb, the honeycomb shape conforms to “corrugated cardboard for exterior” described in JIS-Z-1516. A corrugated honeycomb formed by laminating single-walled cardboards, a hexagon honeycomb formed by hexagonal cells, a honeycomb formed by square cells, a honeycomb formed by triangular cells, and a honeycomb formed by assembling hollow cylindrical cells are exemplified.

【0016】ハニカム状光触媒部材を設置する際の空気
の流れる方向に対する角度は、30°〜60°であるこ
とが好ましい。30°未満では、空気の流れが阻害さ
れ、十分な風量が得られ難いという問題がある。一方、
60°を超えると、ハニカム状光触媒部材での受光面積
が減少し、セル孔からの光のもれが多くなる問題があ
る。
The angle of the honeycomb-shaped photocatalyst member with respect to the direction in which the air flows when the honeycomb-shaped photocatalyst member is installed is preferably 30 ° to 60 °. If the angle is less than 30 °, the flow of air is hindered, and there is a problem that it is difficult to obtain a sufficient air volume. on the other hand,
If it exceeds 60 °, there is a problem that the light receiving area in the honeycomb-shaped photocatalyst member is reduced and light leakage from the cell holes is increased.

【0017】ハニカム状光触媒部材は光源の風上と風下
に設置することが好ましく、更に光源の周囲の非通気方
向に光触媒部材を設置することが好ましい。
The honeycomb-shaped photocatalyst member is preferably installed on the windward and leeward side of the light source, and more preferably the photocatalyst member is installed in the non-ventilating direction around the light source.

【0018】ハニカム状光触媒部材からもれる光の当た
る筐体内面に設置される光触媒部材および光源の周囲の
非通気方向、特に筐体内面に設置される光触媒部材の形
状は、特に限定されるものではないが、光のもれがない
ようなシート状または板状であることが好ましい。
The shape of the photocatalyst member provided on the inner surface of the housing to be exposed to light leaking from the honeycomb-shaped photocatalyst member and the direction of non-ventilation around the light source, particularly the shape of the photocatalyst member provided on the inner surface of the housing, are particularly limited. However, it is preferable that the sheet has a sheet shape or a plate shape which does not leak light.

【0019】本発明に係わる光源は、光触媒を励起させ
る波長の光を効率よく放射するものが好ましく、例え
ば、ブラックライト、捕虫灯、健康ランプ、殺菌灯、一
般照明用蛍光灯、高圧水銀ランプ、メタルハライドラン
プ、高圧ナトリウムランプなどが挙げられる。
The light source according to the present invention preferably emits light having a wavelength that excites the photocatalyst efficiently. Examples of the light source include a black light, an insect lamp, a health lamp, a germicidal lamp, a fluorescent lamp for general lighting, a high-pressure mercury lamp, and the like. Examples include a metal halide lamp and a high-pressure sodium lamp.

【0020】本発明に係わる送風機としては、シロッコ
ファン、クロスフローファン、ターボファン、ラジアル
ファン、プロペラファン、軸流ファンなどが挙げられ
る。
The blower according to the present invention includes a sirocco fan, a cross flow fan, a turbo fan, a radial fan, a propeller fan, an axial fan and the like.

【0021】本発明の空気清浄装置は、活性炭などの吸
着剤を用いた脱臭部材または除塵フィルターや集塵電極
ユニットなどの除塵部品を内臓しても良く、特に光触媒
や励起光源よりも風上に設置されることが好ましい。
The air purifying apparatus of the present invention may incorporate a deodorizing member using an adsorbent such as activated carbon or a dust removing component such as a dust removing filter and a dust collecting electrode unit. Preferably, it is installed.

【0022】[0022]

【実施例】以下、本発明の一実施例を図面に基づき説明
するが、本発明の趣旨を逸脱しない限り、実施例に限定
されるものではない。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to the drawings. However, the present invention is not limited to the embodiment without departing from the spirit of the present invention.

【0023】図1に示すように、本発明の一実施例を示
す空気清浄装置は、吸気口1および排気口2を有する筐
体3と、この筐体3に内蔵した直管型の紫外線ランプ4
と、空気の流れる方向に対して角度を持って配置された
ハニカム状光触媒部材5と、光源の周囲の非通気方向の
筐体内面に設置された光触媒部材6と、該ハニカム状光
触媒部材5からもれる光の当たる筐体内面に配置された
光触媒部材7と、光触媒部材の風下に設けたクロスフロ
ーファンよりなる送風機8より構成される。
As shown in FIG. 1, an air purifying apparatus according to an embodiment of the present invention comprises a housing 3 having an inlet 1 and an outlet 2, and a straight tube type ultraviolet lamp incorporated in the housing 3. 4
And a honeycomb-shaped photocatalyst member 5 disposed at an angle with respect to the direction of air flow, a photocatalyst member 6 disposed on the inner surface of the housing in a non-ventilating direction around a light source, and a honeycomb-shaped photocatalyst member 5. It is composed of a photocatalyst member 7 arranged on the inner surface of the housing to which light leaks, and a blower 8 composed of a cross flow fan provided downstream of the photocatalyst member.

【0024】ハニカム状光触媒部材5は光触媒として酸
化チタンおよび担体として無機吸着剤を含有する繊維状
シートのコルゲート成形品(商品名ラジット光触媒コル
ゲート、三菱製紙製)であり、光触媒部材6および7は
上記の繊維状シート(商品名ラジット光触媒シート、三
菱製紙製)を波板状に成型したものである。また、紫外
線ランプ4は市販のブラックライトである。
The honeycomb-shaped photocatalyst member 5 is a corrugated molded product of a fibrous sheet containing titanium oxide as a photocatalyst and an inorganic adsorbent as a carrier (trade name: Ragit photocatalyst corrugate, manufactured by Mitsubishi Paper Mills). (Radit photocatalyst sheet, trade name, manufactured by Mitsubishi Paper Mills) is molded into a corrugated sheet. The ultraviolet lamp 4 is a commercially available black light.

【0025】本発明の空気清浄装置は、紫外線ランプ4
から放出される光は周囲に配置されたハニカム状光触媒
部材5と光触媒部材6が受光し、更にハニカム状光触媒
部材5が受光せずにもれた光は光触媒部材7が受光する
ため、紫外線ランプ4から放出される光はほぼ完全に光
触媒反応に利用されて脱臭作用および抗菌作用に転換さ
れ、効率の高い空気清浄効果が得られる。
The air purifying apparatus of the present invention comprises an ultraviolet lamp 4
Is emitted from the honeycomb-shaped photocatalyst member 5 and the photocatalyst member 6 disposed in the periphery, and furthermore, the light that is not received by the honeycomb-shaped photocatalyst member 5 is received by the photocatalyst member 7. The light emitted from 4 is almost completely utilized for the photocatalytic reaction and converted into a deodorizing action and an antibacterial action, so that a highly efficient air purifying effect can be obtained.

【0026】[0026]

【発明の効果】本発明によれば、吸気口および排気口を
有する筐体内に送風機、光触媒部材および該光触媒を励
起させる光を発する光源を有する空気清浄装置であっ
て、ハニカム状光触媒部材が空気の流れる方向に対して
角度を持って配置され、更に該ハニカム状光触媒部材か
らもれる光の当たる筐体内面に光触媒部材を配置するこ
とを特徴とする空気清浄装置は、空気の流れる方向に対
して角度を持って配置されたハニカム状光触媒部材が励
起光を受光し、更にハニカム状光触媒部材からもれた励
起光は筐体内面に配置された光触媒部材が受光するた
め、光源から放出される光はほぼ完全に光触媒反応に利
用され、空気清浄効果の効率を著しく高めることが可能
である。
According to the present invention, there is provided an air purifying apparatus having a blower, a photocatalyst member, and a light source for emitting light for exciting the photocatalyst in a housing having an intake port and an exhaust port. The air purifier is disposed at an angle with respect to the flowing direction of the honeycomb-shaped photocatalyst member. The honeycomb-shaped photocatalyst member arranged at an angle receives the excitation light, and the excitation light leaked from the honeycomb-shaped photocatalyst member is emitted from the light source because the photocatalyst member arranged on the inner surface of the housing receives the excitation light. Light is almost completely utilized for the photocatalytic reaction, which can significantly increase the efficiency of the air purifying effect.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の空気清浄化装置の一実施例を示す側面
の断面図である。
FIG. 1 is a side sectional view showing one embodiment of an air cleaning device of the present invention.

【符号の説明】[Explanation of symbols]

1 吸気口 2 排気口 3 筐体 4 直管型の紫外線ランプ 5 ハニカム状光触媒部材 6 光源の周囲の非通気方向の筐体内面に設置された光
触媒部材 7 ハニカム状光触媒部材からもれる光を受光する光触
媒部材 8 送風機
DESCRIPTION OF SYMBOLS 1 Inlet port 2 Exhaust port 3 Housing 4 Straight-tube ultraviolet lamp 5 Honeycomb-shaped photocatalyst member 6 Photocatalyst member installed on the inner surface of the housing around the light source in the non-ventilating direction 7 Receiving light leaking from the honeycomb-shaped photocatalyst member Photocatalyst member 8 blower

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4C080 AA07 AA10 BB02 BB05 CC02 CC03 CC04 CC05 CC07 CC08 CC09 HH05 JJ03 MM02 QQ17 QQ20 4D048 AA21 AA22 BA07X BA13X BA16Y BA19Y BA37Y BA41X BB02 BB04 BB08 CC32 CC35 CC40 CC45 EA01 EA04 4G069 AA03 BA04A BA04B BA48A BB04A BC35A BC43A BC60A CA01 CA11 CA17 EA13 EA18 EB02 EE08  ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4C080 AA07 AA10 BB02 BB05 CC02 CC03 CC04 CC05 CC07 CC08 CC09 HH05 JJ03 MM02 QQ17 QQ20 4D048 AA21 AA22 BA07X BA13X BA16Y BA19Y BA37Y BA41X BB02 BB04 CC04 ACC04A BA04B BA48A BB04A BC35A BC43A BC60A CA01 CA11 CA17 EA13 EA18 EB02 EE08

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 吸気口および排気口を有する筐体内に送
風機、光触媒部材および該光触媒を励起させる光を発す
る光源を有する空気清浄装置において、ハニカム状光触
媒部材が空気の流れる方向に対して角度を持って配置さ
れ、更に該ハニカム状光触媒部材からもれる光の当たる
筐体内面に光触媒部材を配置することを特徴とする空気
清浄装置。
In an air purifying apparatus having a blower, a photocatalyst member, and a light source that emits light for exciting the photocatalyst in a housing having an intake port and an exhaust port, the honeycomb-shaped photocatalyst member has an angle with respect to a direction in which air flows. An air cleaning device, wherein the photocatalyst member is disposed on an inner surface of a housing to which light leaking from the honeycomb-shaped photocatalyst member is applied.
JP11071802A 1999-03-17 1999-03-17 Air cleaning device Pending JP2000262605A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11071802A JP2000262605A (en) 1999-03-17 1999-03-17 Air cleaning device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11071802A JP2000262605A (en) 1999-03-17 1999-03-17 Air cleaning device

Publications (1)

Publication Number Publication Date
JP2000262605A true JP2000262605A (en) 2000-09-26

Family

ID=13471070

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11071802A Pending JP2000262605A (en) 1999-03-17 1999-03-17 Air cleaning device

Country Status (1)

Country Link
JP (1) JP2000262605A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007130042A (en) * 2005-11-08 2007-05-31 Seki:Kk Air cleaner using photocatalyst
JP2008246405A (en) * 2007-03-30 2008-10-16 Nippon Muki Co Ltd Photocatalytic unit
US7758821B2 (en) 2001-07-30 2010-07-20 Carrier Corporation Modular photocatalytic air purifier
US10391194B2 (en) 2012-09-01 2019-08-27 Dbg Group Investments, Llc Active photocatalytic oxidation

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7758821B2 (en) 2001-07-30 2010-07-20 Carrier Corporation Modular photocatalytic air purifier
US7951327B2 (en) 2001-07-30 2011-05-31 Carrier Corporation Photocatalytic air purifier for a fan coil unit
JP2007130042A (en) * 2005-11-08 2007-05-31 Seki:Kk Air cleaner using photocatalyst
JP2008246405A (en) * 2007-03-30 2008-10-16 Nippon Muki Co Ltd Photocatalytic unit
US10391194B2 (en) 2012-09-01 2019-08-27 Dbg Group Investments, Llc Active photocatalytic oxidation
US10434209B2 (en) 2012-09-01 2019-10-08 Dbg Group Investments, Llc Active photocatalytic oxidation

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