JP2000200515A - Pvc tape - Google Patents

Pvc tape

Info

Publication number
JP2000200515A
JP2000200515A JP11000263A JP26399A JP2000200515A JP 2000200515 A JP2000200515 A JP 2000200515A JP 11000263 A JP11000263 A JP 11000263A JP 26399 A JP26399 A JP 26399A JP 2000200515 A JP2000200515 A JP 2000200515A
Authority
JP
Japan
Prior art keywords
pts
weight
parts
pvc
nbr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11000263A
Other languages
Japanese (ja)
Inventor
Kishio Niwayama
喜司雄 庭山
Ichiro Ito
一郎 伊藤
Akira Goto
朗 五藤
Tadashi Ogushi
忠 大串
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Kagaku Co Ltd
Original Assignee
Toyo Kagaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Kagaku Co Ltd filed Critical Toyo Kagaku Co Ltd
Priority to JP11000263A priority Critical patent/JP2000200515A/en
Publication of JP2000200515A publication Critical patent/JP2000200515A/en
Pending legal-status Critical Current

Links

Landscapes

  • Adhesive Tapes (AREA)
  • Organic Insulating Materials (AREA)

Abstract

PROBLEM TO BE SOLVED: To reduce the generation of dioxin while lowering the quantity of chlorine included in the base material to 20 wt.% or less by composing the film base material of PVC resin at 100 pts.wt., plasticizer at 30-70 pts.wt., NBR at 2-30 pts.wt. weight, polyethylene chlorination at 5-40 pts.wt., and fire-resistant filler at 70-200 pts.wt. SOLUTION: Content percentage of chloride is restricted to 20 wt.% or less, and required mechanical strength and desirable breaking drawing are totally evaluated. As a plasticizer, DOP or the like is used, and included at 30-70 pts.wt., desirably at 40-60 pts.wt., in relation to the PVC(polyvinyl ethylene) at 100 pts.wt. NBR is included at 2-30 pts.wt., desirably at 5-15 pts.wt., in relation to the PVC resin at 100 pts.wt. Polyethylene chlorination is included at 5-40 pts.wt., desirably at 10-30 pts.wt., in relation to the PVC resin at 100 pts.wt. The fire-resistant filler such as antimony trioxide and/or aluminum hydroxide is included at 70-200 pts.wt., desirably at 100-10 pts.wt., in relation to the PVC resin at 100 pts.wt.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、電気機器や自動車
などの電線に電気絶縁材とし使用されるPVC系テープ
に係り、従来の軟質PVC(ポリ塩化ビニル)テープに
比べ、フィルム基材中の塩素量を大幅に低減した環境を
考慮したPVC系テープに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a PVC tape used as an electrical insulating material in electric wires of electric equipment and automobiles, and more particularly to a tape material in a film base material than a conventional flexible PVC (polyvinyl chloride) tape. The present invention relates to an environment-friendly PVC tape in which the amount of chlorine is significantly reduced.

【0002】[0002]

【従来の技術】従来,PVC系樹脂組成物を基材とした
電気絶縁用軟質PVCテープとしては、基材組成物とし
てPVC樹脂100重量部に対し、可塑剤25〜60重
量部、その他の配合剤(安定剤、滑剤、着色剤、充填材
等)2〜30重量部添加したものが一般に使用されてい
る。また、電気絶縁用として要求されるためには、体積
固有抵抗値で1×1012Ω・cm以上の抵抗値が必要と
されている。
2. Description of the Related Art Conventionally, as a soft PVC tape for electrical insulation using a PVC resin composition as a base material, 25 to 60 parts by weight of a plasticizer and 100 parts by weight of a PVC resin as a base material composition, Additives (stabilizers, lubricants, coloring agents, fillers, etc.) in an amount of 2 to 30 parts by weight are generally used. Further, in order to be required for electrical insulation, a resistance value of 1 × 10 12 Ω · cm or more in volume specific resistance value is required.

【0003】このようなPVC系テープの基材中に含有
される塩素量は30〜45重量%の範囲にあり、通常3
5重量%に近いものが多い。
[0003] The amount of chlorine contained in the base material of such a PVC tape is in the range of 30 to 45% by weight, usually 3 to 45% by weight.
Many are close to 5% by weight.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、近年塩
素含有物質を燃焼させると、ダイオキシン発生の報告が
ある。燃焼条件によっては、発生に至らない報告もある
が、焼却炉の燃焼条件により発生の可能性があり、且
つ、塩化水素の発生により酸性雨の原因ともなりうる課
題がある。
However, in recent years, there has been a report that dioxin is generated when a chlorine-containing substance is burned. Some reports do not lead to generation depending on the combustion conditions, but there is a problem that generation may occur depending on the combustion conditions of the incinerator, and generation of hydrogen chloride may cause acid rain.

【0005】したがって、本発明者等は、上記課題につ
いて鋭意研究を重ねた結果、従来のテープの物理的特性
(電気絶縁性、柔軟性、手切れ性、難燃性等)を有しな
がら、基材中の塩素量を20重量%以下に低減して上記
課題発生を減少させることを見いだした。
Accordingly, the present inventors have conducted intensive studies on the above-mentioned problems, and as a result, while having the physical properties (electrical insulation, flexibility, hand-cutting properties, flame retardancy, etc.) of conventional tapes, It has been found that the amount of chlorine in the substrate is reduced to 20% by weight or less to reduce the occurrence of the above-mentioned problems.

【0006】[0006]

【課題を解決するための手段】すなわち、本発明は、P
VC(ポリ塩化ビニル)を主材とするフィルム基材をテ
ープ状に形成したPVC系テープにおいて、該フィルム
基材の配合を、PVC樹脂100重量部、可塑剤30〜
70重量部、NBR(ニトリルゴム)2〜30重量部、
塩素化ポリエチレン5〜40重量部、難燃性充填剤70
〜200重量部とし、これによりPVC系テープ全体の
塩素量を20重量%以下にしたPVC系テープである。
That is, the present invention provides a P
In a PVC-based tape in which a film base mainly composed of VC (polyvinyl chloride) is formed in a tape shape, the film base is mixed with 100 parts by weight of a PVC resin, a plasticizer 30 to
70 parts by weight, 2-30 parts by weight of NBR (nitrile rubber),
5 to 40 parts by weight of chlorinated polyethylene, flame-retardant filler 70
This is a PVC tape in which the amount of chlorine in the entire PVC tape is reduced to 20% by weight or less.

【0007】本発明において可塑剤を配合するのは、フ
ィルム基材に柔軟性を持たせるためである。該可塑剤の
配合量にあっては、あまりにも多く配合すると難燃テー
プ自身の機械的強度が低下し、あまりにも少なく配合す
ると柔軟性が無くなるため、PVC樹脂100重量部に
対し30〜70重量部(DOP換算)、さらに好ましく
は40〜60重量部(DOP換算)が良い。
In the present invention, the plasticizer is blended in order to impart flexibility to the film substrate. When the amount of the plasticizer is too large, the mechanical strength of the flame-retardant tape itself is reduced if the amount is too large, and the flexibility is lost if the amount is too small. Therefore, 30 to 70 parts by weight with respect to 100 parts by weight of the PVC resin. Parts (in terms of DOP), more preferably 40 to 60 parts by weight (in terms of DOP).

【0008】前記可塑剤としては、従来公知の可塑剤を
適宜選択して採用でき、DOP(ジ―2−エチルヘキシ
ルフタレート)、DIDP(ジイソデシルフタレー
ト)、エポキシ化大豆油、ポリエステル系可塑剤、トリ
メリット酸エステル、リン酸エステル、塩素化パラフィ
ン等がある。
As the plasticizer, conventionally known plasticizers can be appropriately selected and employed, and DOP (di-2-ethylhexyl phthalate), DIDP (diisodecyl phthalate), epoxidized soybean oil, polyester plasticizer, trimellit Acid esters, phosphate esters, chlorinated paraffins and the like.

【0009】本発明においてNBR(ニトリルゴム)を
配合するのはNBRがPVC樹脂と相容性が良いこと、
多量の充填剤の添加による機械的特性の低下防止及び耐
油性向上のためである。該NBRの配合比は、あまりに
も多いと引張強度が低下し、あまりにも少ないと破断伸
度が低下するため、PVC樹脂100重量部に対し2〜
30重量部が好ましく、さらに好ましくは5〜15重量
部が良い。
In the present invention, NBR (nitrile rubber) is compounded because NBR has good compatibility with PVC resin.
This is because the addition of a large amount of filler prevents the mechanical properties from being lowered and improves the oil resistance. If the compounding ratio of the NBR is too large, the tensile strength decreases, and if it is too small, the elongation at break decreases.
It is preferably 30 parts by weight, more preferably 5 to 15 parts by weight.

【0010】前記NBRとしては、従来公知のNBRを
適宜選択して採用でき、NBR中の結合アクリロニトリ
ル量が15〜55重量%のもの、ブタジエンとアクリロ
ニトリルの他に少量のアクリル酸、またはメタアクリル
酸を含むトリマー等がある。
As the NBR, a conventionally known NBR can be appropriately selected and employed. The NBR has an amount of bound acrylonitrile of 15 to 55% by weight, and a small amount of acrylic acid or methacrylic acid in addition to butadiene and acrylonitrile. And the like.

【0011】本発明において塩素化ポリエチレンを配合
するのは、多量の充填剤の添加による機械的特性の低下
防止及び難燃性向上のためであると共に該塩素化ポリエ
チレンがPVC樹脂と相容性がよいためである。該塩素
化ポリエチレンの配合比は、あまりにも多いと引張強度
が低下し、あまりにも少ないと破断伸度が低下するた
め、PVC樹脂100重量部に対し5〜40重量部、さ
らに好ましくは10〜30重量部が良い。
In the present invention, the chlorinated polyethylene is blended to prevent a decrease in mechanical properties by adding a large amount of filler and to improve the flame retardancy, and that the chlorinated polyethylene is compatible with the PVC resin. It is for good. If the compounding ratio of the chlorinated polyethylene is too large, the tensile strength is reduced, and if it is too small, the elongation at break is reduced. Therefore, 5 to 40 parts by weight, more preferably 10 to 30 parts by weight, per 100 parts by weight of the PVC resin. Good by weight.

【0012】該塩素化ポリエチレンとしては、従来公知
の塩素化ポリエチレンを適宜採択でき、非結晶タイプ、
結晶タイプ等の何れのタイプでも採択でき、30〜40
重量%の塩素含有量のものだけでなく、30重量%以下
のものも採択できる。
As the chlorinated polyethylene, a conventionally known chlorinated polyethylene can be appropriately adopted, and a non-crystalline type,
Any type such as crystal type can be adopted, and 30-40
Not only those having a chlorine content of 30% by weight but also those having a chlorine content of 30% by weight or less can be adopted.

【0013】本発明において、難燃性充填剤を配合する
のは、PVC系テープ自体の難燃性(自己消火性)を向
上させること、および、基材中の塩素量を低減させるた
めである。該難燃性充填剤の配合比は、あまりにも多い
と伸びが低下し、あまりにも少ないと基材中の塩素量が
低減されないため、PVC樹脂100重量部に対して7
0〜200重量部が良く、さらに好ましくは100〜1
50重量部がよい。
In the present invention, the reason why the flame-retardant filler is blended is to improve the flame retardancy (self-extinguishing property) of the PVC tape itself and to reduce the amount of chlorine in the base material. . If the compounding ratio of the flame-retardant filler is too large, the elongation is reduced. If the compounding ratio is too small, the amount of chlorine in the base material is not reduced.
The amount is preferably 0 to 200 parts by weight, more preferably 100 to 1 part by weight.
50 parts by weight is good.

【0014】前記難燃性充填剤としては、従来公知の難
燃性充填剤を適宜採択でき、塩素化パラフィン、塩素系
難燃剤、反応型塩素系難燃剤、臭素系難燃剤、臭素化エ
ポキシ樹脂系難燃剤,臭素化エポキシ・フェノキシ樹脂
難燃剤、臭素系添加型難燃剤、臭素系反応型難燃剤、臭
素系ポリマー型難燃剤、リン酸エステル系難燃剤、赤リ
ン系難燃剤、水酸化アルミニウム系難燃剤、水酸化マグ
ネシウム系難燃剤、三酸化アンチモン系難燃剤、四酸化
アンチモン系難燃剤、五酸化アンチモン系難燃剤、シリ
コーン系難燃剤、ホウ素系難燃剤、錫系難燃剤、ホウ酸
亜鉛系難燃剤、錫・亜鉛系難燃剤、ポリリン酸アンモニ
ウム系難燃剤、ポリリン酸アミド系難燃剤、ジルコニウ
ム系難燃剤、窒素化合物系難燃剤、カルシウム・アルミ
ネート系難燃剤、モリブデン酸アンモン系難燃剤、グア
ニジン系難燃剤、メラミン系難燃剤炭酸カルシウム系難
燃剤、炭酸マグネスウム系難燃剤等がある。
As the flame-retardant filler, conventionally known flame-retardant fillers can be appropriately selected. Chlorinated paraffin, chlorine-based flame retardant, reactive chlorine-based flame retardant, brominated flame-retardant, brominated epoxy resin Flame retardant, brominated epoxy / phenoxy resin flame retardant, bromine-based flame retardant, bromine-based reactive flame retardant, bromine-based polymer flame retardant, phosphate ester flame retardant, red phosphorus flame retardant, aluminum hydroxide Flame retardant, magnesium hydroxide flame retardant, antimony trioxide flame retardant, antimony tetroxide flame retardant, antimony pentoxide flame retardant, silicone flame retardant, boron flame retardant, tin flame retardant, zinc borate -Based flame retardants, tin / zinc-based flame retardants, ammonium polyphosphate-based flame retardants, polyphosphoramide-based flame retardants, zirconium-based flame retardants, nitrogen compound-based flame retardants, calcium / aluminate-based flame retardants, Ribuden of ammonium-based flame retardant, a guanidine based flame retardant, melamine-based flame retardant calcium carbonate-based flame retardant, there is carbonate Magunesuumu flame retardants.

【0015】上記フィルム基材の厚さは50〜400μ
mが適当である。
The thickness of the film substrate is 50 to 400 μm.
m is appropriate.

【0016】本発明にかかるPVC系テープでは、上記
のようなフィルム基材の片面又は両面に粘着剤層が形成
してもよい。粘着剤層を構成するための粘着剤として
は、一般的に用いられている粘着剤を適宜使用すること
ができ、例えばゴム系粘着剤、アクリル系粘着剤等を用
いることができる。
In the PVC tape according to the present invention, an adhesive layer may be formed on one side or both sides of the above-mentioned film substrate. As the pressure-sensitive adhesive for forming the pressure-sensitive adhesive layer, a generally used pressure-sensitive adhesive can be appropriately used, and for example, a rubber-based pressure-sensitive adhesive, an acrylic pressure-sensitive adhesive, or the like can be used.

【0017】前記粘着剤の上記フィルム基材ヘの塗工
は、溶剤型及びエマルジョン型の場合は粘着剤溶液をフ
ィルム基材の片面に塗布し、乾燥する方法が一般的であ
る。粘着剤層の厚みは5〜40μmが適当である。
In the case of the solvent type or the emulsion type, the method of applying the pressure-sensitive adhesive to the film substrate is generally performed by applying a pressure-sensitive adhesive solution to one surface of the film substrate and drying. The thickness of the pressure-sensitive adhesive layer is suitably from 5 to 40 μm.

【0018】[0018]

【実施例】以下、本発明にかかる実施例について、表1
を用いて比較例を参照しつつ、より詳細に説明する。
EXAMPLES Examples of the present invention will be described below with reference to Table 1.
This will be described in more detail with reference to Comparative Examples.

【0019】[0019]

【表1】 [Table 1]

【0020】表1中、配合の欄にある素材の値は全て重
量部であり、可塑剤としてはDOP(ジ―2−エチルヘ
キシルフタレート)を採用し、難燃充填剤として三酸化
アンチモン及び/又は水酸化アルミニウムを採用した。
特性値における「含有塩素量」は配合した素材全体にお
ける含有塩素量であり、PVC樹脂内の塩素含有量を5
6.8重量%、塩素化ポリエチレン内の塩素含有量を3
0.0重量%として算出したものである。実施例1の1
9.6重量%を例に取れば、全体(305重量部)中の
59.8重量部(PVC樹脂100重量部中の56.8
%、塩素化ポリエチレン10重量部中の30%)であ
り、(56.8+3)/305から算出されている。こ
の値は低減目的から20重量%以下が望ましい。
In Table 1, the values of the raw materials in the column of formulation are all parts by weight, DOP (di-2-ethylhexyl phthalate) is used as a plasticizer, and antimony trioxide and / or Aluminum hydroxide was employed.
The “chlorine content” in the characteristic value is the chlorine content in the whole compounded material, and the chlorine content in the PVC resin is 5%.
6.8 wt%, chlorine content in chlorinated polyethylene is 3
It was calculated as 0.0% by weight. Example 1-1
Taking 9.6% by weight as an example, 59.8 parts by weight in the whole (305 parts by weight) (56.8 parts in 100 parts by weight of PVC resin)
%, 30% in 10 parts by weight of chlorinated polyethylene), and is calculated from (56.8 + 3) / 305. This value is desirably 20% by weight or less for the purpose of reduction.

【0021】表中、引張強度はJIS K 6732に
準じて測定したもので、10N/mm2以上が必要であ
り、破断伸びはJIS K 6732に準じて測定した
ものである。該破断伸びにあっては、あまりに低い値で
あると必要とされるテープの伸びが生じずあまりに高い
値であると手切れ性が悪くなるため、150%以上35
0%未満が好ましい。上記総合評価は、全ての特性値が
○だったものを○とし、いずれかの特性値に×が付いた
ものを×とした。
In the table, the tensile strength was measured in accordance with JIS K 6732, and required 10 N / mm 2 or more, and the elongation at break was measured in accordance with JIS K 6732. If the elongation at break is too low, the required elongation of the tape does not occur, and if the value is too high, the hand-cutting property deteriorates.
Less than 0% is preferred. In the above overall evaluation, the case where all the characteristic values were ○ was evaluated as ○, and the case where any of the characteristic values was marked with と し た was evaluated as ×.

【0022】次に、実施例1について説明する。本実施
例におけるPVC系テープに使用する基材フィルムはP
VC樹脂100重量部に対し、可塑剤としてのDOP5
0重量部、塩素化ポリエチレン10重量部、NBR(ニ
トリルゴム)15重量部、三酸化アンチモン10重量
部、水酸化アルミニウム120部配合されたもので、そ
の他少量の安定剤、滑剤、着色剤を含有する。この配合
剤をバンバリーミキサーで混練し、カレンダー加工にて
約120μmの厚さに形成したものである。なお、以下
に説明する他の実施例及び比較例は、配合比以外、本実
施例と同様の方法にて形成したものである。
Next, a first embodiment will be described. The base film used for the PVC tape in this example is P
DOP5 as a plasticizer per 100 parts by weight of VC resin
0 parts by weight, 10 parts by weight of chlorinated polyethylene, 15 parts by weight of NBR (nitrile rubber), 10 parts by weight of antimony trioxide, and 120 parts of aluminum hydroxide. Also contains a small amount of other stabilizers, lubricants and coloring agents. I do. This compounding agent was kneaded with a Banbury mixer and formed into a thickness of about 120 μm by calendering. The other examples and comparative examples described below were formed by the same method as the present example except for the mixing ratio.

【0023】フィルム基材のDOP(可塑剤)の配合比
を変化させた比較例2、実施例1、比較例3(DOP配
合比20、50及び80)を比べてみると、DOPの量
が少な過ぎると破断伸びが小さくなり、柔軟性も劣り、
DOPの量が多すぎると引張強度が小さくなった。
When comparing Comparative Example 2, Example 1, and Comparative Example 3 (DOP compounding ratios 20, 50 and 80) in which the compounding ratio of DOP (plasticizer) of the film substrate was changed, the amount of DOP was If the amount is too small, the elongation at break becomes small, and the flexibility is poor.
When the amount of DOP was too large, the tensile strength was reduced.

【0024】フィルム基材の塩素化ポリエチレンの配合
比を変化させた比較例4、実施例1、2、3及び比較例
5(塩素化ポリエチレンの配合比0、10、20、3
0、及び50)を比べてみると、塩素化ポリエチレンが
配合されない場合は引張強度と破断伸びが小さく、塩素
化ポリエチレンの量が多過ぎると伸びが大きくなり手切
れ性が悪くなった。
Comparative Example 4, Example 1, 2, 3 and Comparative Example 5 in which the blending ratio of chlorinated polyethylene of the film substrate was changed (blending ratio of chlorinated polyethylene 0, 10, 20, 3)
When 0 and 50) were compared, when chlorinated polyethylene was not blended, the tensile strength and the elongation at break were small, and when the amount of chlorinated polyethylene was too large, the elongation was large and the hand-cutting property was poor.

【0025】フィルム基材のNBR(ニトリルゴム)の
配合比を変化させた比較例6、実施例3、2、1及び比
較例7(NBRの配合比0、5、10、15及び40)
を比べてみると、NBRが配合されない場合は破断伸び
が小さく、NBRの量が多過ぎると伸びが大きくなり手
切れ性が悪くなった。
Comparative Example 6, Examples 3, 2, 1 and Comparative Example 7 in which the blending ratio of NBR (nitrile rubber) of the film base was changed (NBR blending ratios 0, 5, 10, 15 and 40)
When NBR was not added, the elongation at break was small, and when the amount of NBR was too large, the elongation was large and the hand-cutting property was poor.

【0026】フィルム基材の難燃性充填剤としての三酸
化アンチモン(Sb23)、水酸化アルミニウムの配合
比を変化させた比較例1、8及び実施例1、2、3及び
比較例9(難燃性充填剤の配合比10、60、130、
140、150及び260)を比べてみると、難燃性充
填剤の量が少な過ぎると含有塩素量が20重量%を超え
塩素量低減とならず、量が多過ぎると破断伸びが小さく
なり柔軟性が劣った。
Comparative Examples 1, 8 and Examples 1, 2, 3, and Comparative Examples in which the compounding ratio of antimony trioxide (Sb 2 O 3 ) and aluminum hydroxide as the flame retardant filler for the film substrate was changed. 9 (mixing ratio of flame-retardant filler: 10, 60, 130,
Comparing 140, 150 and 260), when the amount of the flame-retardant filler is too small, the chlorine content exceeds 20% by weight and the chlorine amount does not decrease, and when the amount is too large, the elongation at break becomes small, resulting in flexibility. Sex was poor.

【0027】なお、表には示さなかったが、各実施例、
各比較例共、従来と同様の電気絶縁性(体積固有抵抗値
で1×1012Ω・cm以上)を備えていた。
Although not shown in the table, each of the examples,
Each of the comparative examples had the same electrical insulation properties as those of the related art (1 × 10 12 Ω · cm or more in volume resistivity).

【0028】[0028]

【発明の効果】本発明は、フィルム基材よりなるPVC
系テープにおいて、フィルム基材をPVC樹脂100重
量部、可塑剤30〜70重量部,NBRが2〜30重量
部、塩素化ポリエチレン5〜40重量部、難燃性充填剤
70〜200重量部とし、これにより、電気機器や自動
車等の電線に電気絶縁材及び結束用として使用必要とさ
れる物理的特性(電気絶縁性、柔軟性、手切れ性、難燃
性等)を持たせつつ、フィルム基材の含有塩素量を大幅
に低減(20重量%以下)させ、これにより、焼却され
てもダイオキシン発生を低減させることができた。
Industrial Applicability The present invention relates to a PVC comprising a film substrate
In the system tape, the film base material is 100 parts by weight of a PVC resin, 30 to 70 parts by weight of a plasticizer, 2 to 30 parts by weight of NBR, 5 to 40 parts by weight of chlorinated polyethylene, and 70 to 200 parts by weight of a flame-retardant filler. This allows films for electrical equipment and automobiles to have the necessary electrical properties (electrical insulation, flexibility, hand-cutting properties, flame retardancy, etc.) for electrical insulation and binding. The chlorine content of the base material was significantly reduced (20% by weight or less), thereby reducing the generation of dioxin even when incinerated.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 大串 忠 神奈川県鎌倉市台2丁目13番1号 東洋化 学株式会社内 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Tadashi Ogushi 2-13-1, Dai, Kamakura-shi, Kanagawa Prefecture Toyo Chemical Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 PVC(ポリ塩化ビニル)を主材とする
フィルム基材をテープ状に形成したPVC系テープにお
いて、該フィルム基材の配合が、PVC樹脂100重量
部、可塑剤30〜70重量部、NBR(ニトリルゴム)
2〜30重量部、塩素化ポリエチレン5〜40重量部、
難燃性充填剤70〜200重量部であることを特徴とす
るPVC系テープ。
1. A PVC-based tape in which a film base material mainly composed of PVC (polyvinyl chloride) is formed in a tape shape, wherein the film base material is blended with 100 parts by weight of a PVC resin and 30 to 70 parts by weight of a plasticizer. Part, NBR (nitrile rubber)
2 to 30 parts by weight, chlorinated polyethylene 5 to 40 parts by weight,
A PVC tape, comprising 70 to 200 parts by weight of a flame-retardant filler.
【請求項2】上記フィルム基材の片面又は両面に粘着剤
層を形成したことを特徴とする請求項1記載のPVC系
テープ。
2. The PVC tape according to claim 1, wherein an adhesive layer is formed on one or both sides of the film substrate.
JP11000263A 1999-01-05 1999-01-05 Pvc tape Pending JP2000200515A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11000263A JP2000200515A (en) 1999-01-05 1999-01-05 Pvc tape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11000263A JP2000200515A (en) 1999-01-05 1999-01-05 Pvc tape

Publications (1)

Publication Number Publication Date
JP2000200515A true JP2000200515A (en) 2000-07-18

Family

ID=11469036

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11000263A Pending JP2000200515A (en) 1999-01-05 1999-01-05 Pvc tape

Country Status (1)

Country Link
JP (1) JP2000200515A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007027851A1 (en) 2007-06-13 2008-12-18 Tesa Ag Compound and wrapping tape made of TPU
DE102007027842A1 (en) 2007-06-13 2008-12-18 Tesa Ag Compound and wrapping tape made of TPU
DE102007027852A1 (en) 2007-06-13 2008-12-24 Tesa Ag Wrap tape with a foil made of TPU
DE102007028593A1 (en) 2007-06-19 2008-12-24 Tesa Ag Halogen free fire-retardant compound from thermoplastic polyurethane, useful e.g. as wire isolation material, comprises 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and nitrogen based fire-retardant
DE102007027855A1 (en) 2007-06-13 2008-12-24 Tesa Ag Wrap tape with a foil made of TPU
DE102007027853A1 (en) 2007-06-13 2008-12-24 Tesa Ag Wrap tape with a foil made of TPU
DE102008037223A1 (en) 2008-08-11 2010-02-18 Tesa Se Wrap tape made of a TPU film with coextruded release
CN103820044A (en) * 2014-03-06 2014-05-28 江苏大海塑料股份有限公司 Light-fast auto membrane
CN104409141A (en) * 2014-11-17 2015-03-11 成都华尔森环保科技有限公司 High-elastic molding flexible wire cable and production method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007027851A1 (en) 2007-06-13 2008-12-18 Tesa Ag Compound and wrapping tape made of TPU
DE102007027842A1 (en) 2007-06-13 2008-12-18 Tesa Ag Compound and wrapping tape made of TPU
DE102007027852A1 (en) 2007-06-13 2008-12-24 Tesa Ag Wrap tape with a foil made of TPU
DE102007027855A1 (en) 2007-06-13 2008-12-24 Tesa Ag Wrap tape with a foil made of TPU
DE102007027853A1 (en) 2007-06-13 2008-12-24 Tesa Ag Wrap tape with a foil made of TPU
DE102007028593A1 (en) 2007-06-19 2008-12-24 Tesa Ag Halogen free fire-retardant compound from thermoplastic polyurethane, useful e.g. as wire isolation material, comprises 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and nitrogen based fire-retardant
DE102008037223A1 (en) 2008-08-11 2010-02-18 Tesa Se Wrap tape made of a TPU film with coextruded release
CN103820044A (en) * 2014-03-06 2014-05-28 江苏大海塑料股份有限公司 Light-fast auto membrane
CN104409141A (en) * 2014-11-17 2015-03-11 成都华尔森环保科技有限公司 High-elastic molding flexible wire cable and production method thereof

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