JP2000175628A - Additive contributing to successive diminishing of environmental pollution and formula feed containing the same - Google Patents
Additive contributing to successive diminishing of environmental pollution and formula feed containing the sameInfo
- Publication number
- JP2000175628A JP2000175628A JP10377957A JP37795798A JP2000175628A JP 2000175628 A JP2000175628 A JP 2000175628A JP 10377957 A JP10377957 A JP 10377957A JP 37795798 A JP37795798 A JP 37795798A JP 2000175628 A JP2000175628 A JP 2000175628A
- Authority
- JP
- Japan
- Prior art keywords
- additive
- feed
- environmental pollution
- excrement
- fossil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Feed For Specific Animals (AREA)
- Fodder In General (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、動物の***物及び
飼料がもたらす有機物負荷を専ら逓減するものである環
境汚染負荷の逓減につながる添加物及びその配合飼料に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an additive for reducing the load on the environment, which is to reduce the load of organic matter caused by animal excrement and feed, and to a compound feed thereof.
【０００２】[0002]
【従来の技術】水産業の中で重要な位置を占める魚類養
殖は、風波を避けるため、内湾や入江のように閉鎖性の
強い水域で行われることが多い。このような水域では海
水の交換が悪いため、魚類の***物や残餌などによる直
接的な水質汚染と共に、これら多くの養殖漁場におい
て、自家汚染による漁場老化が進行しており、このよう
な養殖漁場では赤潮の発生や種々の疾病による養殖魚の
大量へい死を引き起こし、生産性の低下をきたしてい
る。したがって、すでに悪化した養殖漁場の環境回復の
ために、浚渫や海水交換のための施策など土木工学的技
法や、底質改良剤の散布など多くの施策がとられてい
る。2. Description of the Related Art Fish farming, which is an important part of the fishing industry, is often performed in highly enclosed water areas such as inner bays and coves in order to avoid wind waves. In such waters, the exchange of seawater is poor, and the aging of fishing grounds due to self-contamination is progressing in many of these farms, along with direct water pollution by fish excrement and remaining food. In fishing grounds, red tides occur and large numbers of cultured fish die due to various diseases, resulting in reduced productivity. Therefore, in order to recover the environment of the aquaculture, which has already deteriorated, many measures have been taken, such as civil engineering techniques such as dredging and seawater exchange, and the application of sediment improvers.
【０００３】また、専業の漁業者との関係で釣りが出来
る領域は限られているから、その釣り場においても、最
近の釣り人口の急増、スポーツフィッシングの流行など
と共に大量の撒き餌などによる水質や底質の汚染も進行
しており、上記養殖漁場と同じような状況となってい
る。釣り場については現状では特に対策はなされていな
い。[0003] In addition, since the area where fishing can be performed in relation to a dedicated fisherman is limited, the water quality and the bottom of the fishing ground due to a large amount of bait and the like due to the recent increase in the fishing population and the spread of sport fishing have been increasing. Quality pollution is also progressing, and the situation is similar to that of the above farms. No measures have been taken for the fishing grounds at present.
【０００４】一方、畜産業においても、牛、豚、鶏など
で代表される飼育動物の***物に由来する臭い対策や排
泄物自体の処理が必要となる。動物の腸内は嫌気的な環
境にあり、有機態窒素や有機態硫黄は腸内の微生物群に
より、アンモニアやチオール化合物まで分解されて、糞
と共に***される。また、動物の細胞内でも種々の窒素
化合物が尿酸、尿素などの化合物に分解されて、尿中に
***される。これら体外に***された糞尿は、さらに嫌
気性微生物により嫌気的分解を受け、アンモニア、硫化
水素などとなって、大気中に揮散して、悪臭の原因とな
る。これら悪臭の原因となるアンモニア、硫化水素など
は、飼育者は無論のこと飼育動物に対して毒性と共にス
トレスがあるから、その発生を抑制しかつ除去すること
が必要となる。On the other hand, also in the livestock industry, it is necessary to take measures against odors derived from excrement of domestic animals such as cattle, pigs and chickens and to treat excrement itself. The intestine of animals is in an anaerobic environment, and organic nitrogen and organic sulfur are decomposed into ammonia and thiol compounds by microorganisms in the intestine and excreted together with feces. Also, various nitrogen compounds are decomposed into compounds such as uric acid and urea in animal cells and excreted in urine. The excrement excreted outside the body is further anaerobically decomposed by anaerobic microorganisms, becomes ammonia, hydrogen sulfide, etc., and evaporates into the air, causing odor. Since such odor-causing ammonia, hydrogen sulfide, and the like are toxic to and stressful on the bred animals, it is necessary for the breeders to suppress the generation and remove them.
【０００５】したがって、悪臭対策として、飼育場にオ
ガクズを撒き、***された糞尿を混ぜ込み臭気を封じる
方法があるが、不充分である。また、消臭剤を使用した
りする方法もあるが、悪臭の原因となるアンモニア、硫
化水素などは、同時に有害物質でもあるから、その除去
を伴わない方法は意味がない。このような状況に対し
て、飼料成分に対してゼオライト、シリカゲル、アルミ
ナおよび活性炭からなる群から選ばれる１種類以上を配
合した飼料組成物（特開平４−２７３５０号公報参照）
が知られている。この飼料組成物によれば、飼育動物の
体内でアンモニア、硫化水素などをゼオライト、シリカ
ゲル、アルミナおよび活性炭により吸着するから、***
される糞尿中の含有量が減り、かつ***後に発生するア
ンモニア、硫化水素などに対しても糞尿中のゼオライ
ト、シリカゲル、アルミナおよび活性炭により吸着し
て、充分な悪臭対策となって飼育場を好ましい環境とす
るとが出来る。[0005] Therefore, as a countermeasure against odor, there is a method of sowing sawdust on a breeding ground and mixing excreted manure to prevent odor, but it is insufficient. There is also a method of using a deodorant, but ammonia, hydrogen sulfide, and the like, which cause malodor, are also harmful substances, and therefore, a method that does not involve the removal thereof is meaningless. Under such circumstances, a feed composition in which at least one member selected from the group consisting of zeolite, silica gel, alumina and activated carbon is blended with feed components (see JP-A-4-27350)
It has been known. According to this feed composition, ammonia, hydrogen sulfide and the like are adsorbed by zeolite, silica gel, alumina and activated carbon in the breeding animal, so that the content in excreted manure is reduced, and the ammonia and sulfide generated after excretion are reduced. Adsorption to hydrogen and the like by the zeolite, silica gel, alumina and activated carbon in the manure can provide sufficient odor countermeasures and make the breeding ground a favorable environment.
【０００６】[0006]
【発明が解決しようとする課題】しかしながら、上記の
養殖漁場の環境回復のための土木工学的技法は、大がか
りな工事となることが多く莫大な費用を必要とし、反面
かかった費用に対する反対給付が低く、その費用を回収
することが不可能に近く、経済効率が極めて低い。ま
た、底質改良剤の散布は、選択した底質改良剤の種類に
よっては簡便でその効果も高く、かつ費用もかからない
が、１〜２年に１度、底質改良剤を散布する必要があ
り、加えて環境汚染源となる魚類の***物及び餌料がも
たらす有機物負荷を逓減する作用をするものでないた
め、限界がある。However, the above-mentioned civil engineering techniques for restoring the environment of the aquaculture and fishing grounds are often large-scale works and require enormous costs. Low, almost impossible to recover the cost, and economic efficiency is extremely low. In addition, the application of the sediment improving agent is simple, highly effective, and inexpensive depending on the type of the selected sediment improving agent, but it is necessary to spray the sediment improving agent once every one to two years. In addition, it is limited because it does not act to reduce the organic load caused by fish excreta and food, which is a source of environmental pollution.
【０００７】また、飼料組成物は、ゼオライト、シリカ
ゲル、アルミナおよび活性炭により、体内において及び
糞尿の***後において環境汚染物質を吸収して、好まし
い環境を保持できるものの、ゼオライト、シリカゲル、
アルミナおよび活性炭のかなりの量を飼料に添加しなけ
ればならず、しかもこれらは消化されないからそのまま
***物として***され、糞尿の量が相対的に多くなり、
その処分に困り新たな公害発生源となりかねない。[0007] Further, the feed composition can absorb environmental pollutants in the body and after excretion of manure by zeolite, silica gel, alumina and activated carbon, and can maintain a favorable environment.
A considerable amount of alumina and activated carbon must be added to the feed, and since they are not digested, they are excreted directly as excrement, and the amount of manure is relatively large,
It could be a source of new pollution due to its disposal.
【０００８】そこで、本発明は、上記事情に鑑みてなさ
れたもので、莫大な費用をかけること無く、動物の***
物に含有する有機物負荷自体を逓減し、***された***
物自体による分解能を高め、更に残餌からの環境汚染物
質の発生を防いで、水域に於ける養殖漁場や釣り場、陸
上における飼育場の環境汚染を減らすことが出来る環境
汚染負荷の逓減につながる添加物及びその配合飼料を提
供することを課題とする。Accordingly, the present invention has been made in view of the above circumstances, and reduces the organic load itself contained in animal excrement without increasing enormous cost, thereby improving the resolution by excreted excrement itself. Additives and compound feeds that reduce the environmental pollution load that can increase and further reduce the environmental pollution of aquaculture and fishing grounds in water areas and breeding grounds on land by preventing the generation of environmental pollutants from residual feed The task is to provide
【０００９】[0009]
【課題を解決するための手段】本発明者は、長年貝化石
の組成、性質について調査研究を続け、同時に、魚類の
養殖、養殖漁場の水質及び底質の環境保全、畜産におけ
る家畜の飼育、飼育場の環境保全ついても調査研究を続
けてきた。その結果、これら飼育現場の環境保全を図る
ことが魚類や家畜の飼育にとり不可欠であり、それには
魚類や家畜から***される***物中の有機物負荷自体を
逓減するのが理にかなうことから、如何にして***物中
の有機物負荷自体を逓減するかについて、鋭意研究をし
た。その成果として、餌料中に貝化石を添加し、魚類に
与え、***された***物について分析すると、有機炭素
量、有機窒素量、Ｃ（炭素）／Ｎ（窒素）比が劇的に低
下し、しかも***物中の細菌数が増え、***後の***物
の分解性が高まっている、という貝化石の有する新たな
側面を見い出し、本発明に到達したのである。SUMMARY OF THE INVENTION The present inventor has been conducting research and research on the composition and properties of shell fossils for many years, and at the same time, cultivating fish, preserving the water and sediment quality of fish farms, raising livestock in livestock, We have been conducting research on the conservation of breeding grounds. As a result, it is indispensable for the breeding of fish and livestock to protect the environment of these breeding sites, because it makes sense to reduce the organic load itself in the excrement excreted from fish and livestock. We studied diligently on how to reduce the organic matter load itself in the excrement. As a result, when the fossils were added to the feed and fed to fish, and the excreted matter was analyzed, the amount of organic carbon, the amount of organic nitrogen, and the ratio of C (carbon) / N (nitrogen) decreased dramatically. In addition, the present inventors have found a new aspect of shell fossils in which the number of bacteria in the excrement has increased and the excretion of the excreta has increased after excretion, and have reached the present invention.
【００１０】すなわち、請求項１の発明は、石灰質や珪
酸等からなる各種ネクトン、プランクトン、藻類、海藻
等が埋没して堆積し、腐植溶性を帯びた結晶体である貝
化石を有効成分としてなり、動物の***物及び飼料がも
たらす有機物負荷を専ら逓減するものであることを特徴
とする環境汚染負荷の逓減につながる添加物である。[0010] That is, the invention of claim 1 comprises, as an active ingredient, shell fossils, which are humic-soluble crystals, in which various nekton, plankton, algae, seaweeds and the like made of calcareous or silicic acid are buried and deposited. , Which is an additive that leads to a gradual reduction of the environmental pollution load, characterized in that it reduces the organic matter load caused by animal excrement and feed.
【００１１】この環境汚染負荷の逓減につながる添加物
（以下単に逓減添加物と言う）は、貝化石を有効成分と
するから、貝化石単独あるいは貝化石に後の詳述する他
の物を添加したものにより、構成される。本発明に使用
される貝化石は、考古学名では有孔虫化石、地質学名で
は石灰質砂岩であり、日本では富山県、石川県能登半
島、岐阜県高山市、北海道、山口県、徳島県、福島県、
鹿児島県に産するが、産地による限定がない。以下に順
次説明する特性を有する貝化石であれば、いかなる産地
の貝化石であっても良い。その主な産地における貝化石
の分析値は、表１のとおりである。[0011] Since the additive which leads to the reduction of the environmental pollution load (hereinafter simply referred to as the diminishing additive) contains shell fossil as an active ingredient, shell fossil alone or other substances described later in detail are added to shell fossil. It is constituted by what was done. The shell fossils used in the present invention are foraminiferal fossils in the archaeological name and calcareous sandstone in the geological name.In Japan, Toyama, Ishikawa, Noto Peninsula, Takayama, Gifu, Hokkaido, Yamaguchi, Tokushima, Fukushima Prefecture,
It is produced in Kagoshima Prefecture, but it is not limited by the place of production. Shell fossils from any locality may be used as long as the shell fossils have the following characteristics. Table 1 shows the analytical values of shell fossils in the main production areas.
【００１２】本発明の貝化石は、より具体的には、富山
県内の数カ所の採掘場において採掘された試料について
の下記定量分析表（表２）によるものと、これらの採掘
場から採掘された表２に示す成分の貝化石の類似品と、
である。More specifically, the shell fossils of the present invention are based on the following quantitative analysis table (Table 2) of samples mined at several mines in Toyama Prefecture, and mined from these mines. An analog of the fossil shell of the ingredients shown in Table 2,
It is.
【００１３】[0013]
【表１】 [Table 1]
【００１４】[0014]
【表２】 [Table 2]
【００１５】なお、上記富山県において採掘されている
貝化石は、日本の他の地域で採掘される貝化石の成分構
成と、分子集合形態が大きく異なり、特に珪素もある程
度含有するが、炭酸カルシウムの含有率が非常に高いこ
とが特徴となっている。また、この貝化石は、生体より
分泌されたアラゴライト形の結晶構造をとり、一定の有
効径を持つ小孔が無数に有り、これら無数の小孔には結
晶水を含むものも、含まないものもあり、様々である。
これら結晶水を含まない小孔は、活性炭と同様に吸着性
能を有し、被吸着物質の種類によっては活性炭の数十倍
の能力を示す場合がある。The shell fossils mined in Toyama Prefecture differ greatly in the molecular composition from those of shell fossils mined in other parts of Japan. Is characterized by a very high content of. In addition, this fossil shell has an aragolite-type crystal structure secreted from living organisms, and has a myriad of small holes having a certain effective diameter, and these numerous small holes do not include those containing crystal water. There are things, too.
These pores that do not contain water of crystallization have adsorption performance similar to activated carbon, and may exhibit tens of times the capacity of activated carbon depending on the type of the substance to be adsorbed.
【００１６】そして、逓減添加物の有効成分であり、主
成分である貝化石と他のもの、例えば、酵素、ビタミン
剤、有効微生物・発酵生成物などとを併用して一定の効
果を上げようとすることは、本発明の範囲内である。更
に、逓減添加物としての効果、すなわち、貝化石を有効
成分としてなり、動物の***物及び飼料がもたらす有機
物負荷を専ら逓減する性質を、害しない範囲内で他の物
を添加しても良く、この場合も無論本発明の範囲内であ
る。[0016] The fossil shellfish, which is the active ingredient of the diminishing additive and the main component, and other substances, such as enzymes, vitamins, effective microorganisms and fermentation products, are used in combination to achieve a certain effect. Is within the scope of the present invention. Furthermore, other substances may be added within a range that does not impair the effect as a diminishing additive, i.e., the property of using shell fossils as an active ingredient and exclusively diminishing the organic matter load caused by animal excrement and feed. Of course, this case is also within the scope of the present invention.
【００１７】前記動物は、人以外の動物はすべて含み限
定がないが、養殖の水産動物を例示すると、海水生息動
物では、マダイ、クロダイ、イシダイ、イシガキダイ、
カンパチ、シマアジ、マアジ、ヒラメ、カレイ、スズ
キ、トラフグ、カワハギ、ウマズラハギ、イサキ、ハ
タ、オニオコゼ、クロソイ、アナゴ、ハモ、イセエビ、
クルマエビ、ガザミ、ケガニ、マダコ、イカ、アワビ、
サザエ、ホタテガイ、ホッキガイなどであり、淡水生息
動物では、ウナギ、マス類、コイ、アユ、ヘラブナ、ド
ジョウ、カジカ、ペヘレイ、スッポンなどである。更
に、錦ゴイ、金魚、熱帯魚などの鑑賞魚も含む。陸上動
物で家畜を例示すると、肉牛、乳牛、豚、羊、馬、山
羊、猪、鹿、ウサギ、ニワトリ、鴨、雉、七面鳥などで
ある。更に、犬、猫、小鳥などのペット類も含む。The above-mentioned animals include, but are not limited to, all animals other than humans. Examples of cultured aquatic animals include, for example, red sea bream, black porgy, porcupine, porpoise,
Amberjack, horse mackerel, horse mackerel, flounder, flounder, perch, sea bass, tiger pufferfish, kawahagi, quailfish, isaki, grouper, oniokoze, kurosoi, anago, harmo, lobster,
Kuruma shrimp, thistle, crab, octopus, squid, abalone,
It is a squirrel, a scallop, a scallop, etc., and in freshwater inhabitants, it is an eel, a trout, a carp, an ayu, a herbna, a loach, a sculpin, a peheley, a turtle. Also includes appreciation fish such as Nishiki goi, goldfish and tropical fish. Domestic animals such as beef cattle, dairy cows, pigs, sheep, horses, goats, boars, deer, rabbits, chickens, duck, pheasant, and turkey are examples of land animals. Further, pets such as dogs, cats, and birds are also included.
【００１８】前記有機物負荷は、動物の***物及び飼料
がもたらすすべての負荷を含む。この有機負荷の発生形
態は、水産動物では***物自体及び***物から二次的に
発生するもの並びに残餌自体及び残餌から二次的に発生
するものである。陸上動物では***物自体及び***物か
ら二次的に発生するものであって、残餌自体及び残餌か
ら二次的に発生するものは事実上ほとんどない。[0018] The organic load includes all loads produced by animal waste and feed. In the case of marine animals, the form of generation of this organic load is excretion itself and secondary generation from excrement, and residual food itself and secondary generation from residual food. In terrestrial animals, excrement itself and secondary production from excrement, and practically very few residual food itself and secondary production from residual food.
【００１９】この貝化石を有効成分とする逓減添加物の
使用形態は、水産動物の場合、飼料に逓減添加物として
の貝化石を添加し、混合して飼料中に貝化石を均一に分
散させることが重要である。貝化石を均一に分散させる
ために、粉砕され粉末状になっているのが望ましいが、
塊状態となっていることを拒むものではない。陸上動物
の場合、飼料に貝化石を添加し、混合して飼料中に貝化
石を均一に分散させる必要があり、水産動物の場合と同
じように、貝化石を均一に分散させるために、粉末状に
なっているのが望ましいが、塊状態となっていることを
拒むものではない。更に、陸上動物の場合に貝化石を直
接与えても良く、この場合は粉末状でも、塊状でも差が
なくどちらでも良い。In the case of marine animals, the decreasing form of the additive containing the shell fossil as an active ingredient is added to the feed, and the mixture is mixed to uniformly disperse the shell fossil in the feed. This is very important. In order to disperse the shell fossils uniformly, it is desirable to be crushed and powdered,
We do not refuse to be in a lump state. In the case of terrestrial animals, it is necessary to add shell fossils to the feed, mix and disperse the shell fossils evenly in the feed, and, as in the case of marine animals, to disperse shell fossils evenly, powder It is desirable to be in a shape, but it does not refuse to be in a lump state. Further, in the case of a land animal, shell fossils may be directly provided, and in this case, the powder may be in a powder form, a lump form, or any form without any difference.
【００２０】なお、貝化石の粒径は、一般的に小さい方
が良いが、環境汚染物質を吸着する小孔より小さい粒径
では意味がなく、粉砕コストも上昇する。逆に粒径があ
まり大きいと、上記のように飼料中に貝化石を均一に分
散させることがむずかしくなる。したがって、貝化石の
粒径は０．５μｍ〜６２５μｍの範囲、好ましくは２μ
ｍ〜１００μｍの範囲、より好ましくは５μｍ〜７４μ
ｍの範囲であり、少なくとも上記０．５μｍ〜６２５μ
ｍの粒度分布内であれば、飼料に添加し易く、かつ均一
分散と吸着効果とを同時にバランス良く満足し、その性
能を維持することが容易となる。In general, the smaller the particle diameter of the shell fossil is, the smaller the particle diameter is. Conversely, if the particle size is too large, it becomes difficult to uniformly disperse the shell fossils in the feed as described above. Therefore, the particle size of the shell fossils ranges from 0.5 μm to 625 μm, preferably 2 μm.
m to 100 μm, more preferably 5 μm to 74 μm
m, at least 0.5 μm to 625 μm
If the particle size distribution is within the range of m, it is easy to add to the feed, and the uniform dispersion and the adsorption effect are simultaneously satisfied in a well-balanced manner, and its performance is easily maintained.
【００２１】なお、前記飼料は、特に限定がなく、通常
動物の種類によりそれ専用の飼料があるから、その専用
飼料に対して逓減添加物を添加することになる。添加率
は飼料に対して逓減添加物０．２〜１０重量％であり、
好ましくは０．５〜７重量％であり、より好ましくは２
〜５重量％である。０．２重量％未満では効果を確認す
ることが出来ず、１０重量％を越えて添加すると、所謂
飼料としての栄養価が低下し、かつ効果の上積みが無い
のに逓減添加物の費用がそれだけかさむことになり、無
駄となる。The feed is not particularly limited, and there is usually a dedicated feed depending on the kind of animal. Therefore, a decreasing additive is added to the dedicated feed. The addition rate is 0.2 to 10% by weight of the feed additive,
Preferably it is 0.5 to 7% by weight, more preferably 2 to 7% by weight.
~ 5% by weight. If the content is less than 0.2% by weight, the effect cannot be confirmed. If the content exceeds 10% by weight, the nutritional value as a so-called feed decreases, and the cost of the additive gradually decreases without the additional effect. It becomes bulky and wasteful.
【００２２】飼料中に均一に分散した逓減添加物として
の貝化石は、まず、その有する吸着性能により飼料の劣
化を緩和すると共に飼料から発生する臭気などの環境汚
染物質を吸着すると、想定され、次いで、動物の体内で
は必要なミネラルとして吸収され、更に体内の有害物質
が吸着されて、動物の生理活性が高まり、良好な健康状
態が保持される。動物が良好な健康状態になると、飼料
中の栄養素、特に血や肉となる成分（有機物）が充分に
消化吸収され、したがって、***物自体に残存する有機
物が減少するものとなる（飼料転換効率が上昇している
とを示す）。これは、***物の強熱減量、有機物量の指
標として見た有機態炭素量及び有機態窒素量、Ｃ／Ｎ比
に明確に現れている。そして、***後の***物中には未
吸収の貝化石が残り直接的に臭気などを吸着し、かつ排
泄物中に残存する有機物を分解する細菌類、例えば、好
気性及び嫌気性従属栄養細菌数、蛋白分解細菌数、でん
ぷん分解細菌数が多く含まれているから、速やかな分解
無機化が予測される。これは***物の残存有機物の分解
進行度をＣＯＤ値で見ると、速やかな分解無機化の事実
が明確に出ている。It is assumed that shell fossils as a reducing additive uniformly dispersed in a feed first alleviate the deterioration of the feed by its adsorption performance and adsorb environmental pollutants such as odors generated from the feed. Then, it is absorbed as a necessary mineral in the body of the animal, and furthermore, harmful substances in the body are adsorbed, the physiological activity of the animal is increased, and a good health condition is maintained. When the animal is in good health, nutrients in the feed, especially blood and meat components (organic matter) are sufficiently digested and absorbed, and the amount of organic matter remaining in the excrement itself is reduced (feed conversion efficiency). Is rising). This clearly appears in the amount of organic carbon and the amount of organic nitrogen and the C / N ratio, which are regarded as indices of the amount of ignition loss of excrement and the amount of organic matter. In the excrement after excretion, unabsorbed shell fossils remain to directly absorb odors and the like, and bacteria that decompose organic substances remaining in the excretion, for example, aerobic and anaerobic heterotrophic bacteria As the number, the number of proteolytic bacteria, and the number of starch-degrading bacteria are large, rapid decomposition and mineralization are expected. When the degree of progress of decomposition of the residual organic matter in the excrement is viewed in terms of the COD value, the fact of rapid decomposition and mineralization is clearly shown.
【００２３】請求項２の発明は、前記貝化石が、石灰質
や珪酸等からなる各種ネクトン、プランクトン、藻類、
海藻等が埋没して堆積し、腐植溶性を帯びた結晶体を１
５０°Ｃ〜３００°Ｃの範囲内で加熱処理して結晶水を
除去し賦活化させたものである環境汚染負荷の逓減につ
ながる添加物である。According to a second aspect of the present invention, the shell fossils include various nektons, planktons, algae, and the like made of calcareous or silicic acid.
A humus-soluble crystal is deposited when seaweeds are buried and deposited.
This is an additive which is obtained by heat treatment within a range of 50 ° C. to 300 ° C. to remove and activate water of crystallization, which leads to a gradual reduction of the environmental pollution load.
【００２４】前記貝化石を１５０°Ｃ〜３００°Ｃの範
囲内で加熱処理する意味は、小孔に含まれている結晶水
を除去し、吸着性能を高めると共に、加熱処理により貝
化石に付着している雑菌を死滅させるためである。した
がって、この熱処理貝化石を主成分とすることは、小孔
に含まれている結晶水を除去した分、吸着性能が高ま
り、逓減添加物としての性能が高まって、雑菌を死滅さ
せていることから動物投与の際の安全性が高いことにな
る。The heat treatment of the shell fossil in the range of 150 ° C. to 300 ° C. means that the water of crystallization contained in the pores is removed, the adsorption performance is enhanced, and the shell fossil adheres to the shell fossil by the heat treatment. This is for killing various bacteria. Therefore, using the heat-treated shell fossil as the main component means that the removal of the water of crystallization contained in the pores enhances the adsorption performance, the performance as a gradually decreasing additive increases, and kills various bacteria. Therefore, the safety at the time of animal administration is high.
【００２５】請求項３の発明は、飼料に請求項１又は２
記載の環境汚染負荷の逓減につながる添加物を添加して
なることを特徴とする配合飼料である。[0025] The invention of claim 3 provides the feed according to claim 1 or 2.
It is a compound feed characterized by adding an additive that leads to a gradual reduction of the environmental pollution load described above.
【００２６】前記配合飼料は、水産動物並びに陸上動物
に付与でき、ここでは、釣り餌について詳述する。釣り
餌の場合には、前記飼料として、特に限定がないが生餌
では上記逓減添加物を添加することができず使用が困難
である。したがって、飼料は、例えば粉末や生餌をミン
チにして練り合わせたネリ餌やゲル物質で餌成分を被覆
したものなどが使用できる。ネリ餌ではミンチに逓減添
加物である貝化石を添加して均一に混合して使用し、ゲ
ル物質被覆餌では餌成分に貝化石を添加して均一に混合
して使用する。貝化石は粉末状のものが使いやすく、未
熱処理のものでも、熱処理したものでも、どちらでも良
い。貝化石が粉末であると、釣り針に本発明による釣り
餌を付けて、釣り場に投げ込むと貝化石の一部が分散し
て、釣り餌の周辺がわずかに白濁した状態となり、魚の
食いつきが増し、釣りやすくなる。また、本発明による
釣り餌を撒き餌とした場合も白濁効果を期待でき、そし
て、撒き餌が魚に食べられず底に沈んでも、貝化石の有
する吸着性能により、環境汚染物質が吸着される。撒き
餌が魚に食べられれば、魚の体内では必要なミネラルと
して吸収され、魚の生理活性が高まるから、上記と同様
に魚の消化吸収が良くなり、***物自体の有機物が減少
するものとなる。***後の***物中には、未吸収の貝化
石が残り直接的に臭気などを吸着し、かつ***物中には
残存する有機物の上記分解菌が豊富に含まれているか
ら、速やかな分解無機化がなされる。The above-mentioned compound feed can be given to marine animals and land animals. Here, fishing baits will be described in detail. In the case of fishing bait, the feed is not particularly limited, but in the case of raw bait, the above-mentioned decreasing additive cannot be added and it is difficult to use. Therefore, the feed can be, for example, a powdered or raw bait that is kneaded with mince and kneaded, or a feed coated with a gel substance. In the case of Neri bait, the fossil shellfish, which is a decreasing additive, is added to the mince and uniformly mixed and used, and in the case of the gel substance-coated bait, the fossil shellfish is added to the bait ingredient and uniformly mixed. Shell fossils are easy to use in powder form, and may be either unheated or heat-treated. When the shell fossil is powder, the fishing hook according to the present invention is attached to the fishing hook, and when thrown into the fishing ground, a part of the shell fossil is dispersed, the periphery of the fishing bait becomes slightly cloudy, the bite of the fish increases, It becomes easier to fish. Also, when the fishing bait according to the present invention is used as a sow bait, a cloudy effect can be expected, and even if the sow bait cannot be eaten by fish and sinks to the bottom, environmental pollutants are adsorbed by the adsorption performance of the shell fossils. If sowed bait is eaten by fish, it will be absorbed as necessary minerals in the body of the fish, and the physiological activity of the fish will be enhanced. Therefore, the digestion and absorption of the fish will be improved and the organic matter of the excreta itself will be reduced as described above. The excrement after excretion contains unabsorbed shell fossils and directly adsorbs odors, etc., and the excretion is rich in the above-mentioned decomposing bacteria of the remaining organic substances, so it is rapidly decomposed. Mineralization is performed.
【００２７】なお、貝化石の粒径は、白濁効果と吸着効
果とを同時に満足するには、２μｍ〜１００μｍの範
囲、好ましくは５μｍ〜７４μｍの範囲であるのが良
く、上記粒度分布であれば、飼料に添加し易く、かつ白
濁効果と吸着効果とを同時にバランス良く満足し、その
性能を維持することが容易となる。The particle size of the shell fossil is preferably in the range of 2 μm to 100 μm, and more preferably in the range of 5 μm to 74 μm, in order to simultaneously satisfy the clouding effect and the adsorption effect. It is easy to add to feed, and it is easy to satisfy the white turbidity effect and the adsorption effect at the same time in a well-balanced manner and to maintain its performance.
【００２８】請求項４の発明は、前記飼料に対して前記
環境汚染負荷の逓減につながる添加物０．５〜２０重量
％を添加する請求項３記載の配合飼料である。The invention according to claim 4 is the compound feed according to claim 3, wherein 0.5 to 20% by weight of an additive which leads to a gradual reduction of the environmental pollution load is added to the feed.
【００２９】前記逓減添加物の添加率は、飼料に対して
逓減添加物０．５〜２０重量％であり、好ましくは１〜
１０重量％であり、より好ましくは２〜７重量％であ
る。０．５重量％未満では上記効果を確認出来ず、２０
重量％を越えて添加すると、所謂配合飼料としての摂餌
性及び栄養価が低下し、例えば、釣り餌では集魚性が低
下し、かつ逓減添加物の費用がかさむことになる。[0029] The rate of addition of the decreasing additive is 0.5 to 20% by weight based on the feed, preferably 1 to 20% by weight.
It is 10% by weight, more preferably 2 to 7% by weight. If the amount is less than 0.5% by weight, the above effect cannot be confirmed.
If added in excess of weight percent, the feeding and nutritional value of so-called compound feeds will be reduced, for example, the fishing lure will be reduced in fishing baits, and the cost of diminishing additives will increase.
【００３０】[0030]
１．試験期間 ６５日間 ２．試験魚 マダイ稚魚 ３．マダイの飼育状況 ２００ｌのパンライト水槽に海水を入れ、１水槽あたり
６尾のマダイ稚魚（平均体長１３５ｍｍ×平均体重６１
ｇ）を入れ、８０ｌの砂濾過槽で循環濾過方式とした。
試験水温は試験期間中平均して約２２°Ｃであった。 ４．飼料供給 丸紅飼料（株）製の「稚魚期間シングルモイスト」に肝
油と水を加え、これに貝化石製品のフィッシュグリーン
（（株）グリーン・カルチャア製の商品名）を有効成分
とする逓減添加物を１．５重量％、３．０重量％、５．
０重量％添加したものをペレット状に調整した餌料を、
上記マダイ稚魚に与えた。この餌料は午前９時に給餌
し、残餌がある場合は給餌後回収する。 ５．***物の採取 ***物は給餌後、４時間後〜６時間後内に***された直
後のものをサイフォンにて採取し、直ちに試験をした。
当日に試験出来ないものは冷凍保存した。 ６．試験項目及び試験内容の概要 （１）***物中の強熱減量 電気炉を用いて８００°Ｃ強熱減量を求めた。 （２）***物中の有機炭素量と有機窒素量 ***物中の無機炭酸を除去した後、柳本社製ＣＨＮコー
ダーを用いて有機炭素量と有機窒素量とを定量測定し、
更にそれに基づきＣ／Ｎ比を算出した。 （３）***物中の細菌数 ***物中における好気性従属栄養細菌及び嫌気性従属栄
養細菌、蛋白分解細菌、でんぷん分解細菌について、下
記の構成により常法に基づき作製した培地を用いて計数
した。 従属栄養細菌培地（ＺｏＢｅ１１２２１６Ｅ 培地） ペプトン（ディフィコ）〔Ｐｅｐｔｏｎ（Ｄｉｆｉｃｏ）〕 ５．０ｇ イースト抽出物〔Ｙｅａｓｔ ｅｘｔｒａｃｔ（Ｄｉｆｉｃｏ）〕１．０ｇ 濾過天然海水（ｐＨ７．６〜７．８） １ｌ ＦｅＳＯ４・７Ｈ２Ｏを４．９８ｇ蒸留水に溶かしたもの ３．７ｍｌ ＮａＨ２ＰＯ４を１．２６４５ｇ蒸留水に溶かしたもの ６．３ｍｌ 蛋白分解細菌培地 バクト−カシトン（Ｂａｃｔｏ−Ｃａｓｉｔｏｎ） ５ｌ ビーフ抽出物（Ｂｅｅｆ ｅｘｔｒａｃｔ） ３ｌ ゼラチン １２０ｇ ８０％天然海水 １ｌ でんぷん分解細菌培地 ポリ−ペプトン（Ｐｏｌｙ−Ｐｅｐｔｏｎ） ０．２５ｇ イースト抽出物〔Ｙｅａｓｔ ｅｘｔｒａｃｔ（Ｄｉｆｉｃｏ）〕０．２５ｇ 可溶性でんぷん ２．０ｇ ＦｅＳＯ４・７Ｈ２Ｏ ０．０１ｇ ＮａＨ２ＰＯ４ ０．０１ｇ 天然海水 ７５０ｍｌ 水道水 ２５０ｍｌ （４）***物の分解 ***物の分解の進行を見る試験では、逓減添加物を１．
５重量％、３．０重量％、５．０重量％添加した上記餌
料について試験をした。この測定は、２００ｍｌのフラ
スコに人工海水１００ｍｌ、マダイ***物０．５ｇを入
れ攪拌したのち、直ぐにメンブレンフィルターで濾過し
た濾液と、２５°Ｃで３日間静置したのち、メンブレン
フィルターで濾過した濾液との化学的酸素要求量（ＣＯ
Ｄ）をアルカリ性過マンガン酸カリウム法を用いて測定
し、ＣＯＤ値の変動状態を***物中の未分解の固形有機
物の分解の指標とした。 （５）飼育期間中の水槽水の水質変動 ・水槽水の水質につき、アンモニア態窒素、亜硝酸態窒
素、リン酸態リン、ＣＯＤ、溶存有機炭素（ＤＯＣ）、
ｐＨを測定する。 ・アンモニア態窒素はインドフェノール法の二村の変法
を用いて測定する。 ・亜硝酸態窒素はナフチル−エチレンジアミン法を用い
て測定する。 ・リン酸態リンはモリブデンブルー法を用いて測定す
る。 ・ＣＯＤはアルカリ性過マンガン酸カリウム法を用いて
測定する。 ・溶存有機炭素（ＤＯＣ）はＴＯＣアナライザー（島津
製作所製のＴＯＣ−５００型）を用いて測定する。 ・ｐＨは一般市販のｐＨメーターを用いて測定する。 （６）飼育マダイの成長 逓減添加物を１．５重量％、３．０重量％、５．０重量
％添加調整した餌料によるマダイ稚魚のそれぞれの成長
具合を測定する。試験開始前と試験終了後のマダイ稚魚
の体重及び体長を測定し、日間投餌率、日間成長率、餌
料転換効率、増肉係数を常法により計算する。1. Testing period 65 days 2. Test fish Red sea bream fry 3. Breeding conditions of red sea bream Seawater is placed in a 200-liter panlight aquarium, and six red sea bream juveniles per aquarium (average length 135 mm x average body weight 61)
g) was put in, and the system was circulated and filtered in an 80 l sand filter tank.
The test water temperature averaged about 22 ° C during the test. 4. Feed supply Add liver oil and water to Marubeni Feed Co., Ltd.'s “Fry Single Period Moist”, and gradually add a fish fossil shellfish product (trade name of Green Culturea Co., Ltd.) as an active ingredient. 1.5% by weight, 3.0% by weight, 5.
0% by weight of the feed is adjusted to a pellet,
The red sea bream was given to the fry. This feed is fed at 9 am and any remaining feed is collected after feeding. 5. Collection of excretion The excretion was collected immediately after excretion within 4 to 6 hours after feeding by siphon and immediately tested.
Those that could not be tested on the day were stored frozen. 6. Outline of test items and test contents (1) Ignition loss in excrement 800 ° C ignition loss was obtained using an electric furnace. (2) The amount of organic carbon and the amount of organic nitrogen in the excrement After removing the inorganic carbonic acid in the excrement, the amount of organic carbon and the amount of organic nitrogen were quantitatively measured using a CHN coder manufactured by Yanagi Head Office.
Further, the C / N ratio was calculated based thereon. (3) Bacterial count in excreta Aerobic heterotrophic and anaerobic heterotrophic bacteria, proteolytic bacteria, and starch-degrading bacteria in the excrement were counted using a medium prepared according to a conventional method with the following configuration. . Heterotrophic bacterial medium (ZoBe112216E medium) Peptone (Difco) [Pepton (Difico)] 5.0 g Yeast extract [Yeast extract (Difico)] 1.0 g Filtered natural seawater (pH 7.6 to 7.8) 1 1 FeSO 4. 6.3ml those were dissolved 3.7 ml NaH 2 PO 4 that dissolved 7H 2 O in 4.98g of distilled water 1.2645g distilled water proteolytic bacterial medium Bacto - Casitone (Bacto-Casiton) 5l beef extract ( Beef extract 3 l Gelatin 120 g 80% natural seawater 1 l Starch-degrading bacterial culture medium Poly-Peptone 0.25 g Yeast extract [Yeast extract (Difico)] 0.25 g Soluble starch 2.0 g FeS 4 · 7H 2 O 0.01g NaH 2 PO 4 0.01g natural seawater 750ml tap water 250 ml (4) In a study to see the progress of decomposition of the decomposition waste excrement, the decreasing additive 1.
A test was conducted on the above-mentioned feed to which 5% by weight, 3.0% by weight and 5.0% by weight were added. In this measurement, 100 ml of artificial seawater and 0.5 g of red sea bream excrement were placed in a 200 ml flask, stirred, and then immediately filtered with a membrane filter, and left at 25 ° C. for 3 days, and then filtered with a membrane filter. Chemical oxygen demand (CO
D) was measured using the alkaline potassium permanganate method, and the fluctuation state of the COD value was used as an index of the decomposition of undecomposed solid organic matter in the excrement. (5) Fluctuations in aquarium water quality during the breeding period ・ Ammonia nitrogen, nitrite nitrogen, phosphate phosphorus, COD, dissolved organic carbon (DOC),
Measure the pH.・ Ammonia nitrogen is measured using the modified two village method of the indophenol method. -Nitrite nitrogen is measured using the naphthyl-ethylenediamine method. -Phosphoric acid phosphorus is measured using the molybdenum blue method. COD is measured using the alkaline potassium permanganate method. -Dissolved organic carbon (DOC) is measured using a TOC analyzer (TOC-500, manufactured by Shimadzu Corporation). -The pH is measured using a commercially available pH meter. (6) Growth of breeding red sea bream The growth condition of each red sea bream based on the diet to which the decreasing additive was added at 1.5% by weight, 3.0% by weight and 5.0% by weight was measured. The body weight and body length of the red sea bream before and after the test are measured, and the daily feeding rate, daily growth rate, feed conversion efficiency, and meat increase coefficient are calculated by ordinary methods.
【００３１】なお、比較のために逓減添加物を無添加と
した対照区について、上記測定項目を測定する。得られ
た結果を下記の表３〜１０に示す。 （１）***物中の強熱減量の測定結果は表３に示す。 （２）***物中の有機炭素量の測定結果は表４に、有機
窒素量の測定結果は表５に、Ｃ／Ｎ比は表６に、それぞ
れ示す。 （３）***物中の細菌数の測定結果は表７に示す。 （４）***物の分解の測定結果は表８に示す。 （５）飼育期間中の水槽水の水質変動のアンモニア態窒
素、亜硝酸態窒素、リン酸態リン、ＣＯＤ、溶存有機炭
素（ＤＯＣ）、ｐＨの測定結果は表９に示す。 （６）飼育マダイの成長の測定結果は表１０に示す。For the purpose of comparison, the above-mentioned measurement items were measured for a control group in which no decreasing additive was added. The obtained results are shown in Tables 3 to 10 below. (1) Table 3 shows the measurement results of the ignition loss in the excrement. (2) Table 4 shows the measurement results of the amount of organic carbon in the excrement, Table 5 shows the measurement results of the amount of organic nitrogen, and Table 6 shows the C / N ratio. (3) Table 7 shows the measurement results of the number of bacteria in the excrement. (4) Table 8 shows the measurement results of the decomposition of excrement. (5) Table 9 shows the measurement results of ammonia nitrogen, nitrite nitrogen, phosphate phosphorus, COD, dissolved organic carbon (DOC), and pH of the water quality fluctuation of the tank water during the breeding period. (6) Table 10 shows the measurement results of the growth of reared red sea bream.
【００３２】[0032]
【表３】 [Table 3]
【００３３】[0033]
【表４】 [Table 4]
【００３４】[0034]
【表５】 [Table 5]
【００３５】[0035]
【表６】 [Table 6]
【００３６】[0036]
【表７】 [Table 7]
【００３７】[0037]
【表８】 [Table 8]
【００３８】[0038]
【表９】 [Table 9]
【００３９】[0039]
【表１０】 [Table 10]
【００４０】表３によれば、***物中の強熱減量は、逓
減添加物を添加したものが無添加のものより明らかに減
少しているが、３％添加と５％添加とで差がなかった。
表４によれば、***物中の有機炭素量は、逓減添加物を
添加したものが無添加のものより明らかに減少し、逓減
添加物の添加量の多い方が有機炭素量が減少する傾向に
ある。表５によれば、***物中の有機窒素量は、逓減添
加物を添加したものが無添加のものより明らかに減少
し、逓減添加物の添加量の多い方が有機炭素量が減少す
る傾向にある。According to Table 3, the loss on ignition in the excrement is clearly reduced in the case where the gradually decreasing additive is added, compared with the case where the additive is not added. Did not.
According to Table 4, the amount of organic carbon in the excrement clearly decreases with the addition of the diminishing additive from that without the addition, and tends to decrease with increasing the amount of the diminishing additive. It is in. According to Table 5, the amount of organic nitrogen in the excrement clearly decreases with the addition of the decreasing additive compared with the case without the additive, and the amount of the organic carbon tends to decrease with the increasing amount of the decreasing additive. It is in.
【００４１】表６によれば、***物中のＣ／Ｎ比は、逓
減添加物を添加したものが無添加のものより明らかに減
少し、逓減添加物の添加量の多い方がＣ／Ｎ比が低くな
る傾向にあり、このことは***物中の有機炭素量の減少
が大きいことを示す。表７によれば、***物中の細菌数
は、逓減添加物を添加したものが無添加のものより明ら
かに多くなり、逓減添加物の添加量の多い方が細菌数が
多くなる傾向にある。表８によれば、***物の分解は、
逓減添加物を添加したものが無添加のものより明らかに
早く進行し、逓減添加物の添加量の多い方が***物の分
解が早く進行する傾向にある。According to Table 6, the C / N ratio in the excrement is clearly reduced when the additive is gradually added to the excrement than when no additive is added. The ratios tend to be lower, indicating a greater reduction in the amount of organic carbon in the feces. According to Table 7, the number of bacteria in the excrement is clearly higher in the case where the decreasing additive is added than in the case where no decreasing additive is added, and the number of bacteria increases when the amount of the decreasing additive added is larger. . According to Table 8, the decomposition of excrement is
The addition of the gradually decreasing additive tends to proceed clearly faster than that without the addition, and the larger the amount of the gradually decreasing additive added, the faster the decomposition of excrement tends to proceed.
【００４２】表９によれば、アンモニア態窒素は、逓減
添加物を添加したものが無添加のものより明らかに減少
し、逓減添加物の添加量の多い方がアンモニア態窒素が
減少する傾向にある。亜硝酸態窒素は、アンモニア態窒
素と逆の傾向にあり、これはアンモニア態窒素が酸化さ
れ亜硝酸態窒素に変化しているからと推定される。リン
酸態リンは、逓減添加物の添加量の多い方が無添加のも
のより減少する傾向にあるが、その差は顕著ではない。
ＣＯＤは、逓減添加物を添加したものが無添加のものよ
り明らかに低くなり、逓減添加物の添加量の多い方がＣ
ＯＤが低くなる傾向にある。溶存有機炭素は、逓減添加
物の添加量の多い方が無添加のものより減少する傾向に
あるが、その差は顕著ではない。ｐＨは、逓減添加物の
添加量の多い方が無添加のものより高い傾向にあるが、
その差は顕著ではない。表１０によれば、飼育マダイの
成長は、逓減添加物を添加したものが無添加のものより
明らかに餌料転換効率、増肉係数に優れ、１．５〜５％
の範囲であるが逓減添加物の添加量の多い方が餌料転換
効率、増肉係数に優れている傾向にある。According to Table 9, the amount of ammonia nitrogen was clearly decreased when the additive was gradually added, compared to the case where no additive was added. The ammonia nitrogen tended to decrease as the amount of the additive decreased. is there. Nitrite nitrogen has the opposite tendency to ammonia nitrogen, which is presumed to be because ammonia nitrogen is oxidized and changed to nitrite nitrogen. Phosphoric acid phosphorus tends to decrease when the amount of the gradually decreasing additive is larger than that when no additive is added, but the difference is not remarkable.
The COD is clearly lower with the addition of the diminishing additive than with the non-diminishing additive.
OD tends to be low. The dissolved organic carbon tends to decrease when the amount of the gradually decreasing additive is larger than that when no additive is added, but the difference is not remarkable. The pH tends to be higher when the amount of the gradually decreasing additive is larger than that when no additive is added,
The difference is not noticeable. According to Table 10, the growth of breeding red sea bream was clearly superior in feed conversion efficiency and meat increase coefficient, and 1.5 to 5%, when the decreasing additive was added, than when no additive was added.
However, the larger the amount of the gradually decreasing additive, the better the feed conversion efficiency and the meat increasing coefficient.
【００４３】〔実施例２〕１４ケ月令の肥育中期の黒毛
和牛を５頭１区とする。飼料は一般に市販されている肉
牛用で以下に示すものを使用し、逓減添加物は熱処理貝
化石を有効成分とするのものを５〜１５０μｍに粉砕し
たものを使用する。そして、この区における肥育牛用飼
料は以下の構成によるものとし、６ケ月間肥育し、その
間の***物の臭気、牛舎の臭気につき測定した。 とうもろこし ４９重量部 大豆粕 ２５重量部 クローバー干し草 １０重量部 小麦麦幹 ５重量部 乾燥ビール粕 １０重量部 ビタミン・ミネラル添加物 １重量部 熱処理貝化石（５〜１５０μｍ） ３重量部 なお、比較のために逓減添加物を無添加とした対照区に
ついて、１４ケ月令の肥育中期の黒毛和牛を５頭１区と
して、同様に６ケ月間肥育し、その間の***物の臭気、
牛舎の臭気につき測定した。[Example 2] Five Japanese black cattle in the middle of fattening at the age of 14 months are divided into five cows and one section. The feed used is the one shown below for beef cattle generally available on the market, and the decreasing additive used is one obtained by pulverizing a heat-treated shellfish fossil as an active ingredient into 5-150 μm. The feed for fattening cattle in this section had the following composition, was fattened for 6 months, and the odor of the excrement and the odor of the barn during that time were measured. Corn 49 parts by weight Soybean meal 25 parts by weight Clover hay 10 parts by weight Wheat and wheat trunk 5 parts by weight Dried beer meal 10 parts by weight Vitamin and mineral additives 1 part by weight Heat treated shell fossil (5-150 μm) 3 parts by weight For comparison. In the control group in which no additive was gradually added, five 14-month-old mid- fattening Japanese black cattle were treated as 5 sections, and the fattening was similarly performed for 6 months.
The odor of the barn was measured.
【００４４】臭気の測定は、アンモニアはアンモニア測
定用ドジチューブ（ガステック社製）にて行い、硫化水
素は試験紙着色法にて測定する。その結果を表１１に示
す。The odor is measured by using a dositube for measuring ammonia (manufactured by Gastec Co., Ltd.), and hydrogen sulfide is measured by a test paper coloring method. Table 11 shows the results.
【００４５】[0045]
【表１１】 [Table 11]
【００４６】表１１によれば、逓減添加物を添加した飼
料を与えた牛からの***物自体のアンモニア量は、無添
加の場合より極めて少なく、これは逓減添加物の有する
ミネラル成分と吸着性能との相乗効果であると想定され
る。牛舎の臭気の主要成分であるアンモニア、硫化水素
とも、逓減添加物を添加した飼料を与えた牛からの***
物からは劇的に減らすことが出来た。According to Table 11, the amount of ammonia in the excrement itself from cattle fed the feed to which the decreasing additive was added was much smaller than that in the case where no additive was added. It is assumed that this is a synergistic effect with Both ammonia and hydrogen sulfide, the main components of the barn odor, could be reduced dramatically from the excretion of cattle fed a diet supplemented with diminishing additives.
【００４７】[0047]
【発明の効果】以上詳述したように、本発明の環境汚染
負荷の逓減につながる添加物及びその配合飼料によれ
ば、以下のような効果がある。請求項１の発明は、環境
汚染負荷の逓減につながる添加物の有効成分である貝化
石のミネラルを動物が充分に吸収し、その結果動物の生
理活性が高まり、良好な健康状態が保持され、動物が良
好な健康状態になると、飼料中の栄養素、特に肉や血と
なる成分（有機物）が充分に消化吸収され、***物自体
に残存する有機物が減少するものとなる。したがって、
動物の***物自体に含有する有機物負荷が少なく且つ排
泄物自体の分解能が高いから、莫大な費用をかけなくて
も、水域に於ける養殖漁場及び陸上における飼育場の環
境汚染を減らすことが出来る。更に残餌に含まれる逓減
添加物により環境汚染物質の発生を防いで、水域に於け
る養殖漁場及び陸上における飼育場の環境汚染も減らす
ことが出来る。養殖漁場では自家汚染による漁場老化の
進行を遅らせるから、自然が有している浄化能力に近づ
けば、これ以上の漁場老化が無くなる。また、***物に
は未消化の逓減添加物が含まれているから、臭いが少な
く直接畑に撒いても酸性土壌の中和剤となり処分が容易
であるし、コンポスト化すれば逓減添加物によるミネラ
ル豊富な堆肥が出来上がる。As described in detail above, according to the additive of the present invention which leads to a gradual reduction of the environmental pollution load and its compound feed, the following effects can be obtained. According to the invention of claim 1, the animal sufficiently absorbs the mineral of shell fossil, which is the active ingredient of the additive, which leads to the gradual reduction of environmental pollution load. As a result, the physiological activity of the animal is increased, and a good health condition is maintained. When an animal is in good health, nutrients in the feed, particularly components (organic matter) that become meat and blood, are sufficiently digested and absorbed, and the amount of organic matter remaining in the excrement itself is reduced. Therefore,
Since the load of organic matter contained in animal excrement itself is small and the resolution of excrement itself is high, it is possible to reduce environmental pollution of aquaculture fishing grounds in water areas and breeding grounds on land without incurring huge costs. . Further, the generation of environmental pollutants can be prevented by the diminishing additives contained in the remaining bait, so that the environmental pollution of aquaculture and fishing grounds in water bodies and breeding grounds on land can be reduced. In aquaculture fishing grounds, the progress of aging of fishing grounds due to self-contamination is slowed, and if the purification capacity of nature is approached, further aging of fishing grounds will be eliminated. In addition, since excrement contains undigested decreasing additives, it has a low odor and can be easily disposed of as a neutralizing agent for acidic soil even when scattered directly in the field. A mineral-rich compost is completed.
【００４８】請求項２の発明は、上記効果に加えて、環
境汚染負荷の逓減につながる添加物に強力な吸着性能が
付与されるから、残餌による環境汚染物質の発生を防ぐ
ばかりか、飼料自体の臭気防止や保存性も高まるし、動
物の体内での有害物質をも吸着出来て、なお一層の上記
効果が期待出来る。According to the second aspect of the present invention, in addition to the above-described effects, a strong adsorption performance is imparted to an additive which leads to a gradual reduction of the environmental pollution load. The odor prevention and preservability of the substance itself are enhanced, and harmful substances in the animal body can be adsorbed, so that the above effect can be expected.
【００４９】請求項３の発明は、上記効果のある環境汚
染負荷の逓減につながる添加物を用いるから、その配合
飼料を食べた動物の***物は、残存有機物が少なく、分
解性もよく養殖漁場や釣り場並びに畜舎の環境汚染を防
ぐことになる。また、撒き餌や残った餌の投棄などの残
餌による養殖漁場、釣り場の環境汚染を防ぎ、釣り餌に
使用した場合には含有する逓減添加物の一部が溶けだし
て白濁することによる魚の誘引効果を期待できるし、更
に釣り餌を腐り難くしかつ悪臭の発生を防ぐ。The invention of claim 3 uses the above-mentioned additive which leads to the gradual reduction of the environmental pollution load. Therefore, the excrement of the animal which has eaten the compound feed has little residual organic matter, is highly degradable, and has good decomposability. And the pollution of the fishing ground and the barn. In addition, it prevents environmental pollution in aquaculture and fishing grounds and fishing grounds due to scattered baits and remaining baits such as dumping of remaining baits, and when used in fishing baits, the effect of attracting fish by dissolving some of the diminishing additives contained and becoming cloudy. And make the fishing bait harder to rot and prevent the generation of foul odors.
【００５０】請求項４の発明は、上記効果に加えて、飼
料にこの範囲の環境汚染負荷の逓減につながる添加物を
添加すれば、配合飼料としての摂餌性及び栄養価を保持
出来かつ逓減添加物の費用がかさむこともない。According to the invention of claim 4, in addition to the above-mentioned effects, if an additive which reduces the environmental load in this range is added to the feed, the feedability and nutritional value of the compound feed can be maintained and the feed can be reduced. Additives are not expensive.
Claims (4)
ランクトン、藻類、海藻等が埋没して堆積し、腐植溶性
を帯びた結晶体である貝化石を有効成分としてなり、動
物の***物及び飼料がもたらす有機物負荷を専ら逓減す
るものであることを特徴とする環境汚染負荷の逓減につ
ながる添加物。1. An excrement and feed for animals including various kinds of nekton, plankton, algae, seaweed, and the like made of calcareous or silicic acid, which are buried and deposited, and a humic-soluble crystalline shell fossil as an active ingredient. An additive that leads to a gradual reduction in the environmental pollution load, characterized in that it reduces the organic matter load brought about exclusively by water.
種ネクトン、プランクトン、藻類、海藻等が埋没して堆
積し、腐植溶性を帯びた結晶体を１５０°Ｃ〜３００°
Ｃの範囲内で加熱処理して結晶水を除去し賦活化させた
熱処理貝化石である請求項１記載の環境汚染負荷の逓減
につながる添加物。2. The fossil shellfish is formed by burying and depositing various nekton, plankton, algae, seaweed, and the like made of calcareous or silicic acid, etc., and forming a humus-soluble crystal at 150 ° C. to 300 ° C.
The additive which leads to a gradual reduction of environmental pollution load according to claim 1, which is a heat-treated fossil shell which has been activated by heat treatment within the range of C to remove water of crystallization.
の逓減につながる添加物を添加してなることを特徴とす
る配合飼料。3. A compound feed characterized by adding to the feed the additive according to claim 1 or 2, which leads to a gradual reduction of the environmental pollution load.
につながる添加物０．２〜２０重量％を添加する請求項
３記載の配合飼料。4. The combined feed according to claim 3, wherein 0.2 to 20% by weight of an additive which leads to a gradual reduction of the environmental pollution load is added to said feed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10377957A JP2000175628A (en) | 1998-12-14 | 1998-12-14 | Additive contributing to successive diminishing of environmental pollution and formula feed containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10377957A JP2000175628A (en) | 1998-12-14 | 1998-12-14 | Additive contributing to successive diminishing of environmental pollution and formula feed containing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000175628A true JP2000175628A (en) | 2000-06-27 |
Family
ID=18509282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10377957A Pending JP2000175628A (en) | 1998-12-14 | 1998-12-14 | Additive contributing to successive diminishing of environmental pollution and formula feed containing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000175628A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001037422A (en) * | 1999-07-30 | 2001-02-13 | Green Culture:Kk | Modifier for avian egg, its formula feed and obtained avian egg |
| CN105557657A (en) * | 2016-02-29 | 2016-05-11 | 高佳泉 | Fish bait for oxygen fish-gathering pit |
| JP2021040621A (en) * | 2019-09-03 | 2021-03-18 | 株式会社阿寒シェル鉱業 | Horse feed additive, horse exercise capacity enhancer, manufacturing method of horse feed additive, and horse breeding method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51141279A (en) * | 1975-06-02 | 1976-12-04 | Nippon Furotsuku Kk | Method of improving physical constitution of cattle |
| JPS63196234A (en) * | 1987-02-10 | 1988-08-15 | Green Karuchiyaa:Kk | Feed for raising marine fishes and shellfishes |
| JPH02245144A (en) * | 1989-03-17 | 1990-09-28 | Green Karuchiyaa:Kk | Culture method of red seal-bream |
| JPH08298982A (en) * | 1995-05-02 | 1996-11-19 | Aasu Giken:Kk | Complex microbial pharmaceutical preparation |
| JPH10194725A (en) * | 1996-12-29 | 1998-07-28 | Green Karuchiyaa:Kk | Ultrafine powder of fossil seashell |
-
1998
- 1998-12-14 JP JP10377957A patent/JP2000175628A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51141279A (en) * | 1975-06-02 | 1976-12-04 | Nippon Furotsuku Kk | Method of improving physical constitution of cattle |
| JPS63196234A (en) * | 1987-02-10 | 1988-08-15 | Green Karuchiyaa:Kk | Feed for raising marine fishes and shellfishes |
| JPH02245144A (en) * | 1989-03-17 | 1990-09-28 | Green Karuchiyaa:Kk | Culture method of red seal-bream |
| JPH08298982A (en) * | 1995-05-02 | 1996-11-19 | Aasu Giken:Kk | Complex microbial pharmaceutical preparation |
| JPH10194725A (en) * | 1996-12-29 | 1998-07-28 | Green Karuchiyaa:Kk | Ultrafine powder of fossil seashell |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001037422A (en) * | 1999-07-30 | 2001-02-13 | Green Culture:Kk | Modifier for avian egg, its formula feed and obtained avian egg |
| CN105557657A (en) * | 2016-02-29 | 2016-05-11 | 高佳泉 | Fish bait for oxygen fish-gathering pit |
| JP2021040621A (en) * | 2019-09-03 | 2021-03-18 | 株式会社阿寒シェル鉱業 | Horse feed additive, horse exercise capacity enhancer, manufacturing method of horse feed additive, and horse breeding method |
| JP6990940B2 (en) | 2019-09-03 | 2022-01-12 | 株式会社阿寒シェル鉱業 | Horse Feed Additives, Horse Exercise Improvers, Horse Feed Additives Manufacturing Methods and Horse Breeding Methods |
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