JP2000153285A - Advanced oxidation method - Google Patents
Advanced oxidation methodInfo
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- JP2000153285A JP2000153285A JP10326568A JP32656898A JP2000153285A JP 2000153285 A JP2000153285 A JP 2000153285A JP 10326568 A JP10326568 A JP 10326568A JP 32656898 A JP32656898 A JP 32656898A JP 2000153285 A JP2000153285 A JP 2000153285A
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- ceramic
- hydrogen peroxide
- advanced oxidation
- oxidation treatment
- liquid
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、過酸化水素水を用
いて被処理物、特に液体に対して殺菌等の処理を施す高
度酸化処理方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an advanced oxidation treatment method for subjecting an object to be treated, especially a liquid, to a treatment such as sterilization using a hydrogen peroxide solution.
【０００２】[0002]
【従来の技術】従来、過酸化水素は酸化力があり、紙・
パルプ・繊維等の製造工業において、或いは他の工業分
野において、殺菌剤として、或いは脱色、脱臭等の処理
剤として、使用されてきた。しかしながら、過酸化水素
単独では、酸化力に自ずから限界があり、これを殺菌剤
等として使用する場合にはその処理能力に限界があっ
た。そこで、「過酸化水素を用いたシステム」による高
度酸化処理方法が、幾つか提案されている。2. Description of the Related Art Conventionally, hydrogen peroxide has an oxidizing power,
It has been used as a bactericide or as a treating agent for decolorization and deodorization in the pulp and fiber manufacturing industries and in other industrial fields. However, the use of hydrogen peroxide alone has its own oxidizing power, and when it is used as a disinfectant or the like, its processing capacity is limited. Therefore, some advanced oxidation treatment methods using a "system using hydrogen peroxide" have been proposed.
【０００３】例えば、過酸化水素を他の物質と併用する
ことで、過酸化水素の本来の処理能力を向上ないし改善
する試みがなされてきた。例えば、過酸化水素と、触
媒、紫外線、オゾン等との併用である。コスト的には触
媒との併用が有利であるが、その半面、取り扱い、副生
物の生成等において難点がある。即ち、過酸化水素は、
通常水溶液（過酸化水素水）として市販されているが、
比較的不安定な液体であるため、触媒と併用する場合に
おいても、安全管理の面も含め運搬や取扱が困難であ
る、という問題があった。また、副生物を生成する場合
には、その副生物を除去するために特別の処理を必要と
する、という問題があった。[0003] For example, attempts have been made to improve or improve the original processing capability of hydrogen peroxide by using hydrogen peroxide in combination with other substances. For example, hydrogen peroxide is used in combination with a catalyst, ultraviolet light, ozone, or the like. Although it is advantageous to use the catalyst together with the catalyst in terms of cost, it has disadvantages in handling, production of by-products, and the like. That is, hydrogen peroxide is
Usually marketed as an aqueous solution (hydrogen peroxide solution),
Since it is a relatively unstable liquid, there is a problem that even when used in combination with a catalyst, it is difficult to transport and handle, including safety management. Further, when a by-product is generated, there is a problem that a special treatment is required to remove the by-product.
【０００４】[0004]
【発明が解決しようとする課題】本発明は、上記のよう
な問題点に鑑みて案出されたものであって、過酸化水素
を他の物質と併用する場合において、過酸化水素の本来
の処理能力を向上ないし改善すると共に、実際上の取り
扱いが容易で且つ安全な、高度酸化処理方法を提案する
ものである。DISCLOSURE OF THE INVENTION The present invention has been made in view of the above-mentioned problems, and has been proposed in the case where hydrogen peroxide is used in combination with another substance. An object of the present invention is to provide a high-grade oxidation treatment method which improves or improves the treatment capacity and is easy and safe in practical use.
【０００５】[0005]
【課題を解決するための手段】上記の課題を達成するた
めに、本発明によれば、過酸化水素活性化触媒を担持し
てなるセラミックに、過酸化水素を接触させて、被処理
対象物を処理することを特徴とする高度酸化処理方法が
提供される。この場合において、被処理対象物は液体で
あることを特徴とする。過酸化水素活性化触媒を担持し
たセラミックと過酸化水素とを併用することにより、処
理効率が高められ、かつ取り扱いの安全性を確保するこ
とができる。According to the present invention, in order to attain the above object, hydrogen peroxide is brought into contact with a ceramic carrying a hydrogen peroxide activating catalyst, and the object to be treated is treated. And a highly oxidizing treatment method characterized by treating In this case, the object to be processed is a liquid. By using a ceramic carrying a hydrogen peroxide activating catalyst and hydrogen peroxide together, the processing efficiency can be increased and the handling safety can be ensured.
【０００６】過酸化水素活性化触媒が、Ｐｔ，Ｒｕ，Ｒ
ｈ，Ｉｒ，Ｃｕ，Ｍｎ，Ｆｅ又はＣｒ等の遷移金属、又
はそれらの酸化物、又はそれらの水酸化物、又はそれら
の塩であることを特徴とする。或いは、過酸化水素活性
化触媒が、Ｃｏ，Ａｇ，Ｎｉ，Ｐｂ，Ｚｎ，Ｍｏ又はＳ
ｎ、又はそれらの酸化物、又はそれらの水酸化物、又は
それらの塩であることを特徴とする。[0006] Hydrogen peroxide activating catalyst is Pt, Ru, R
It is characterized by being a transition metal such as h, Ir, Cu, Mn, Fe or Cr, an oxide thereof, a hydroxide thereof, or a salt thereof. Alternatively, the catalyst for activating hydrogen peroxide is Co, Ag, Ni, Pb, Zn, Mo or S
n, or their oxides, their hydroxides, or their salts.
【０００７】セラミックが、カオリナイト、モンモリロ
ナイト、イライト属の一種、又は複数種からなる成分を
原料とする。或いは、セラミックが、石英、トリジマイ
ト、クリストバライト、シリカガラス、水和シリカ等の
シリカ成分を原料とする。或いは、セラミックが、長
石、霞石、石灰、滑石、石綿、カンラン石、雲母、ジル
コニウム鉱、水和アルミナ鉱、チタニア、トリア、グラ
ファイト等、又はその他の非粘度鉱物成分を原料とす
る。The ceramic is made from kaolinite, montmorillonite, a component of one or more genus of illite. Alternatively, the ceramic is made of a silica component such as quartz, tridymite, cristobalite, silica glass, and hydrated silica. Alternatively, the ceramic is made from feldspar, nepheline, lime, talc, asbestos, olivine, mica, zirconium ore, hydrated alumina ore, titania, thoria, graphite, or other non-viscous mineral components.
【０００８】殺菌処理すべき対象液体に、予め過酸化水
素を添加・混入せしめ、その後、該液体を当該セラミッ
クに接触させることにより該液体を殺菌処理することを
特徴とする。当該セラミックを、処理すべき対象液体中
に分散懸濁させ、又は当該セラミックを充填した容器中
に、処理すべき対象液体を通過させることにより、該液
体を処理することを特徴とする。当該セラミックが、処
理すべき対象液体に対して接触効率の良い、定形球状又
は定形角状又は不定型チップ状であることを特徴とす
る。セラミックをこのような形状とすることにより、過
酸化水素の活性化が促進され、殺菌等の処理効果が高め
られる。[0008] It is characterized in that hydrogen peroxide is added and mixed in advance to a liquid to be sterilized, and then the liquid is brought into contact with the ceramic to sterilize the liquid. The liquid is treated by dispersing and suspending the ceramic in the liquid to be treated or by passing the liquid to be treated in a container filled with the ceramic. The ceramic is characterized in that it has a fixed spherical shape, a fixed square shape, or an irregular shaped chip shape having good contact efficiency with the target liquid to be treated. By making the ceramic into such a shape, activation of hydrogen peroxide is promoted, and treatment effects such as sterilization are enhanced.
【０００９】当該セラミックは、セラミック素材中の過
酸化水素活性化触媒の含有率が、０．１ｗｔ％から５０
ｗｔ％の間、好ましくは１．０ｗｔ％から３０ｗｔ％の
間であることを特徴とする。過酸化水素活性化触媒の割
合をこのように選定することにより、過酸化水素との反
応が効果的となり、殺菌等の処理効果が高めことができ
る。In the ceramic, the content of the hydrogen peroxide activating catalyst in the ceramic material is from 0.1 wt% to 50 wt%.
wt%, preferably between 1.0 wt% and 30 wt%. By selecting the ratio of the hydrogen peroxide activating catalyst in this manner, the reaction with hydrogen peroxide becomes effective, and the treatment effect such as sterilization can be enhanced.
【００１０】当該高度酸化処理の用途が、殺菌、殺藻、
スライム除去、脱色、脱臭、過酸化水素分解、ＣＯＤ／
ＢＯＤ低減等である、ことを特徴とする。このように本
発明の高度酸化処理は特に液体の殺菌に有効であるが、
他の処理にも適用することができる。[0010] Applications of the advanced oxidation treatment include sterilization, algicidal treatment,
Slime removal, decolorization, deodorization, hydrogen peroxide decomposition, COD /
BOD reduction and the like. Thus, the advanced oxidation treatment of the present invention is particularly effective for sterilizing liquids,
It can be applied to other processes.
【００１１】[0011]
【実施例】実施例１ 大腸菌を用いて、過酸化水素水（比較例) 、及び過酸化
水素とセラミックとを併用した酸化処理剤（実施例) に
よる殺菌効果について次の実験を行った。大腸菌とし
て、Escherichia coli JCM 1649 を使用した。試験方法
は次のとおりである。 Example 1 The following experiment was carried out using Escherichia coli on the bactericidal effect of an aqueous solution of hydrogen peroxide (comparative example) and an oxidizing agent using hydrogen peroxide and ceramic (example) in combination. Escherichia coli JCM 1649 was used as E. coli. The test method is as follows.
【００１２】 試験細菌（振とう培養し減菌水で希釈
した菌液) を所定菌数となるように、フラスコ内のイオ
ン交換水に添加し、全量を200ml とした。 殺菌処理として、比較例では、過酸化水素水溶液の
みを添加した。また、実施例として、セラミックを浸漬
し、過酸化水素水溶液を添加した。なお、セラミックに
は、予め触媒として鉄（Fe）及び硫酸鉄（FeSO4 ）をそ
れぞれセラミック素材に担持させてある。また、このよ
うなセラミックは、数日間イオン交換水に浸漬し、室内
で一晩以上放置し、乾燥したものを試験用として使用し
た。[0012] Test bacteria (bacterial solution diluted with sterile water after shaking culture) were added to ion-exchanged water in a flask so as to have a predetermined number of bacteria, and the total volume was 200 ml. In the comparative example, only a hydrogen peroxide aqueous solution was added as a sterilization treatment. Further, as an example, a ceramic was immersed, and an aqueous solution of hydrogen peroxide was added. In the ceramic, iron (Fe) and iron sulfate (FeSO 4 ) are supported on the ceramic material in advance as a catalyst. Further, such a ceramic was immersed in ion-exchanged water for several days, left in a room overnight or longer, and dried, and used for testing.
【００１３】 室温にて60分間攪拌処理した後、直ち
にカタラーゼを添加し、残留過酸化水素を分解し、細菌
試験 (菌数測定) 用の試料とした。 細菌試験用試料中の大腸菌群数を測定することによ
り、過酸化水素水溶液の濃度及び併用するセラミックの
種類による殺菌効果の関係を確認した。 試験細菌の種類: Escherichia coli JCM 1649 使用したセラミック（サイコロ状) 触媒： Fe 10 個 合計約 12 gr 触媒： FeSO4 10 個 合計約 11 gr 細菌試験: JIS K-0102 による方法を適用 上記試験の結果、過酸化水素水単独の場合 (比較例) 、
及び過酸化水素とセラミックとを併用した場合 (実施
例) とを比較して、その併用効果を確認した結果を表１
並びに図１及び図２に示す。After a stirring treatment at room temperature for 60 minutes, catalase was immediately added to decompose residual hydrogen peroxide to obtain a sample for a bacterial test (measurement of the number of bacteria). The relationship between the concentration of the aqueous solution of hydrogen peroxide and the type of ceramic used in combination was confirmed by measuring the number of coliform bacteria in the sample for bacterial testing. Type of test bacteria: Escherichia coli JCM 1649 Ceramic (die) used Catalyst: 10 Fe total about 12 gr Catalyst: 10 FeSO 4 total about 11 gr Bacteria test: Apply the method according to JIS K-0102 Results of the above test , In the case of hydrogen peroxide water alone (Comparative Example),
Table 1 shows the results of confirming the effect of using hydrogen peroxide and ceramic in combination (Example).
1 and 2.
【００１４】[0014]
【表１】 [Table 1]
【００１５】表１並びに図１及び図２から明らかなよう
に、未処理のもの、即ち過酸化水素による処理を何ら行
わないもの（ＨＰ＝０）に対し、過酸化水素（ＨＰ）の
濃度を１０ｐｐｍ、５０ｐｐｍ、１００ｐｐｍと変化さ
せた場合の、過酸化水素水単独の場合 (比較例) と、過
酸化水素とセラミックとを併用したもの（実施例）とを
比較すると、比較例では大腸菌の群数〔個／ｍｌ〕が依
然としてかなり大きいのに対し、実施例では大腸菌の群
数〔個／ｍｌ〕が大幅に減少していることが理解され
る。セラミックに担持させる触媒として、鉄（Fe）を用
いたもの、硫酸鉄（FeSO4 ）を用いたものの両者の実施
例ともに、顕著な殺菌効果を示していることが確認され
た。As is clear from Table 1 and FIGS. 1 and 2, the concentration of hydrogen peroxide (HP) was set to be untreated, that is, not subjected to any treatment with hydrogen peroxide (HP = 0). A comparison of the case of hydrogen peroxide solution alone (Comparative Example) and the case of using hydrogen peroxide and ceramic in combination (Example) when changed to 10 ppm, 50 ppm, and 100 ppm shows that the group of Escherichia coli in the Comparative Example It can be seen that the number [cells / ml] is still quite large, while the number of E. coli groups [cells / ml] is significantly reduced in the examples. It was confirmed that both the examples using iron (Fe) and the examples using iron sulfate (FeSO 4 ) as the catalyst to be supported on the ceramic exhibited remarkable bactericidal effects.
【００１６】実施例２ 脱水処理前の都市下水の汚泥を試料として用い、硫黄系
悪臭の低減効果についての試験を行った。 汚泥の試料を小分けし、各々３００ｍｌのビーカに
入れた。 ビーカ内の各試料に、 Ａ：過酸化水素（ＨＰ）５０ｐｐｍを添加したもの（比
較例）、 Ｂ：セラミック１０ｇ，ＨＰ２５ｐｐｍを添加したもの
（実施例）、 Ｃ：ブランク（何も添加しないもの）、 をそれぞれ準備し、各試料とする。なお、Ｂのセラミッ
クは、触媒として硫酸鉄（FeSO4 ）を８ｗｔ％含有した
ものを使用した。このセラミックは事前にビーカに入れ
ておく。 Example 2 A test was conducted on the effect of reducing sulfur-based odor using municipal sewage sludge before dehydration treatment as a sample. Sludge samples were aliquoted and each placed in a 300 ml beaker. To each sample in the beaker: A: 50 ppm of hydrogen peroxide (HP) added (Comparative Example), B: 10 g of ceramic, 25 ppm of HP added (Example), C: Blank (No addition) And are prepared, and used as each sample. The ceramic of B used was a catalyst containing 8 wt% of iron sulfate (FeSO 4 ) as a catalyst. This ceramic is placed in a beaker in advance.
【００１７】 Ａ〜Ｃの各試料のビーカを１５〜３０
秒程良く攪拌した。 １００ｍｌのヘッドスペースポトル容器へ汚泥５０
ｍｌを小分けし直ちに密栓する。 ボトルを３０℃に保ち、気相中の臭気ガス成分を一
定時間、即ち０．５時間、３．０時間、６．０時間経過
後にそれぞれ測定する。The beakers of each sample A to C are 15 to 30.
Stir well for about a second. Sludge 50 into 100ml headspace pottle container
Aliquot aliquots and seal immediately. The bottle is kept at 30 ° C., and the odor gas component in the gas phase is measured after a certain period of time, that is, 0.5 hours, 3.0 hours, and 6.0 hours, respectively.
【００１８】測定結果を表２に示す。Table 2 shows the measurement results.
【００１９】[0019]
【表２】 [Table 2]
【００２０】表２の実験結果から明らかなように、硫化
水素（H2S)及びメチルメルカブタン(MM)共に、Ｃの何も
添加しないもの及びＡの過酸化水素のみを添加したもの
（比較例）では、臭気の値が比較的高く、脱臭効果が余
りあらわれていないのに対し、Ｂの過酸化水素とセラミ
ックとを併用したもの（実施例）では、臭気の値が低
く、脱臭効果が顕著にあらわれいてることが理解され
る。As is clear from the experimental results in Table 2, both hydrogen sulfide (H 2 S) and methyl mercaptan (MM) were those without addition of C and those with only hydrogen peroxide of A (comparative). In Example), the odor value was relatively high, and the deodorizing effect was not so much revealed. On the other hand, in the case of using hydrogen peroxide of B and ceramic together (Example), the odor value was low, and It is understood that it appears remarkably.
【００２１】なお、測定にあたっては、ガスクロマトグ
ラフィー（島津製作所製ＧＣ１７Ａ，Ver 2 ；検出器Ｆ
ＰＤ；カラム, ＧＬサイエンス，ＴＣ−１，直径0.5mm
×30m)を使用した。以上、添付図面を参照して本発明の
実施例について詳細に説明したが、本発明は上記の実施
例に限定されるものではなく、本発明の精神ないし範囲
内において種々の形態、変形、修正等が可能であること
に留意すべきである。In the measurement, gas chromatography (GC17A, Ver. 2 manufactured by Shimadzu Corporation; detector F)
PD; Column, GL Science, TC-1, 0.5mm in diameter
× 30m) was used. As described above, the embodiments of the present invention have been described in detail with reference to the accompanying drawings. However, the present invention is not limited to the above embodiments, and various forms, modifications, and corrections are made within the spirit and scope of the present invention. It should be noted that the like is possible.
【００２２】[0022]
【発明の効果】以上に説明したような、本発明によれ
ば、過酸化水素と触媒を担持したセラミックとを併用し
て液体等の処理に使用することにより、過酸化水素を用
いた酸化処理方法として、殺菌等の処理能力を向上し、
且つ実際上の取り扱いを容易で且つ安全なものとするこ
とができる。According to the present invention as described above, by using hydrogen peroxide and a catalyst-carrying ceramic in combination for the treatment of liquids, etc., the oxidation treatment using hydrogen peroxide is performed. As a method, improve the processing capacity such as sterilization,
In addition, practical handling can be made easy and safe.
【図１】本発明の実施例１による効果を比較例と共に説
明するための図であり、触媒として鉄（Fe）を用いたも
のを示す。FIG. 1 is a diagram for explaining an effect of Example 1 of the present invention together with a comparative example, and shows an example in which iron (Fe) is used as a catalyst.
【図２】本発明の実施例１による効果を比較例と共に説
明するための図であり、触媒として硫酸鉄（FeSO4 ）を
用いたものを示す。FIG. 2 is a diagram for explaining the effect of Example 1 of the present invention together with a comparative example, and shows an example using iron sulfate (FeSO 4 ) as a catalyst.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０２Ｆ 1/50 ５３１ Ｃ０２Ｆ 1/50 ５３１Ｑ ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C02F 1/50 531 C02F 1/50 531Q
Claims (12)
ラミックに、過酸化水素を接触させて、被処理対象物を
処理することを特徴とする高度酸化処理方法。An advanced oxidation treatment method comprising treating a target object by bringing hydrogen peroxide into contact with a ceramic carrying a hydrogen peroxide activation catalyst.
する請求項１に記載の高度酸化処理方法。2. The advanced oxidation treatment method according to claim 1, wherein the object to be treated is a liquid.
Ｒｈ，Ｉｒ，Ｃｕ，Ｍｎ，Ｆｅ又はＣｒ等の遷移金属、
又はそれらの酸化物、又はそれらの水酸化物、又はそれ
らの塩であることを特徴とする請求項１又は２に記載の
高度酸化処理方法。3. The method according to claim 1, wherein the catalyst for activating hydrogen peroxide is Pt, Ru,
Transition metals such as Rh, Ir, Cu, Mn, Fe or Cr;
The method according to claim 1, wherein the method is an oxide thereof, a hydroxide thereof, or a salt thereof.
Ｎｉ，Ｐｂ，Ｚｎ，Ｍｏ又はＳｎ、又はそれらの酸化
物、又はそれらの水酸化物、又はそれらの塩であること
を特徴とする請求項１又は２に記載の高度酸化処理方
法。4. The method according to claim 1, wherein the catalyst for activating hydrogen peroxide is Co, Ag,
The method according to claim 1 or 2, wherein the method is Ni, Pb, Zn, Mo, or Sn, or an oxide thereof, a hydroxide thereof, or a salt thereof.
ロナイト、イライト属の一種、又は複数種からなる成分
を原料とするものである、請求項１〜４のいずれか１項
に記載の高度酸化処理方法。5. The advanced oxidation treatment method according to claim 1, wherein the ceramic is made of one of kaolinite, montmorillonite, and illite.
リストバライト、シリカガラス、水和シリカ等のシリカ
成分を原料とするものである、請求項１〜４のいずれか
１項に記載の高度酸化処理方法。6. The advanced oxidation treatment method according to claim 1, wherein the ceramic is made from a silica component such as quartz, tridymite, cristobalite, silica glass, and hydrated silica.
石、石綿、カンラン石、雲母、ジルコニウム鉱、水和ア
ルミナ鉱、チタニア、トリア、グラファイト等又はその
他の非粘度鉱物成分を原料とするものである、請求項１
〜４のいずれか１項に記載の高度酸化処理方法。7. The ceramic whose raw material is feldspar, nepheline, lime, talc, asbestos, olivine, mica, zirconium ore, hydrated alumina ore, titania, thoria, graphite, or other non-viscous mineral components Claim 1.
The advanced oxidation treatment method according to any one of Items 4 to 4.
水素を添加・混入せしめ、その後、該液体を当該セラミ
ックに接触させることにより該液体を殺菌処理すること
を特徴とする、請求項２〜７のいずれか１項に記載の高
度酸化処理方法。8. The method according to claim 2, wherein hydrogen peroxide is previously added to and mixed with the liquid to be sterilized, and then the liquid is brought into contact with the ceramic to sterilize the liquid. The advanced oxidation treatment method according to any one of Items 1 to 7, wherein
中に分散懸濁させ、又は当該セラミックを充填した容器
中に、処理すべき対象液体を通過させることにより、該
液体を処理することを特徴とする、請求項２〜８のいず
れか１項に記載の高度酸化処理方法。9. The liquid is treated by dispersing and suspending the ceramic in a liquid to be treated or passing the liquid to be treated through a container filled with the ceramic. The advanced oxidation treatment method according to any one of claims 2 to 8, wherein
体に対して接触効率の良い、定形球状又は定形角状又は
不定型チップ状であることを特徴とする、請求項２〜９
のいずれか１項に記載の高度酸化処理方法。10. The ceramic according to claim 2, wherein said ceramic has a fixed spherical shape, a fixed square shape, or an irregular shaped chip shape having a high contact efficiency with a target liquid to be treated.
The advanced oxidation treatment method according to any one of the above.
の過酸化水素活性化触媒の含有率が、０．１ｗｔ％から
５０ｗｔ％の間、好ましくは１．０ｗｔ％から３０ｗｔ
％の間であることを特徴とする請求項１〜１０のいずれ
か１項に記載の高度酸化処理方法。11. The ceramic according to claim 1, wherein the content of the hydrogen peroxide activating catalyst in the ceramic material is between 0.1 wt% and 50 wt%, preferably between 1.0 wt% and 30 wt%.
%. The method according to any one of claims 1 to 10, wherein the amount is between 0.1% and 1.0%.
藻、スライム除去、脱色、脱臭、過酸化水素分解、ＣＯ
Ｄ／ＢＯＤ低減等である、ことを特徴とする請求項１〜
１１のいずれか１項に記載の高度酸化処理方法。12. The use of the advanced oxidation treatment includes sterilization, algicidal treatment, slime removal, decolorization, deodorization, hydrogen peroxide decomposition, CO2 decomposition, and the like.
2. The method according to claim 1, wherein D / BOD is reduced.
12. The method for advanced oxidation treatment according to any one of items 11 to 11.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10326568A JP2000153285A (en) | 1998-11-17 | 1998-11-17 | Advanced oxidation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10326568A JP2000153285A (en) | 1998-11-17 | 1998-11-17 | Advanced oxidation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000153285A true JP2000153285A (en) | 2000-06-06 |
Family
ID=18189282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10326568A Pending JP2000153285A (en) | 1998-11-17 | 1998-11-17 | Advanced oxidation method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000153285A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1607106A1 (en) * | 2004-06-19 | 2005-12-21 | KHS Maschinen- und Anlagenbau Aktiengesellschaft | Apparatus for sterilzing containers using H2O2 |
| EP1717206A1 (en) * | 2005-04-18 | 2006-11-02 | MOL Katalysatortechnik GmbH | Process for the disinfection and the elimination of biofilms |
| WO2009078459A1 (en) | 2007-12-19 | 2009-06-25 | Lion Corporation | Oxidation catalyst for bleaching and bleaching composition containing the same |
| JP2011245458A (en) * | 2010-05-31 | 2011-12-08 | Adeka Corp | Method for decomposition of organic substance, and decomposition agent kit for organic substance |
| CN104926000A (en) * | 2015-07-08 | 2015-09-23 | 中国科学院水生生物研究所 | Method for rapidly clearing away floating green alga spirogyra |
| CN105016524A (en) * | 2015-07-08 | 2015-11-04 | 中国科学院水生生物研究所 | Method for removing floating cladophora |
-
1998
- 1998-11-17 JP JP10326568A patent/JP2000153285A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1607106A1 (en) * | 2004-06-19 | 2005-12-21 | KHS Maschinen- und Anlagenbau Aktiengesellschaft | Apparatus for sterilzing containers using H2O2 |
| JP2006001649A (en) * | 2004-06-19 | 2006-01-05 | Khs Mas & Anlagenbau Ag | Vessel treating machine for sterilizing vessel by h2o2 |
| EP1717206A1 (en) * | 2005-04-18 | 2006-11-02 | MOL Katalysatortechnik GmbH | Process for the disinfection and the elimination of biofilms |
| WO2009078459A1 (en) | 2007-12-19 | 2009-06-25 | Lion Corporation | Oxidation catalyst for bleaching and bleaching composition containing the same |
| US8993504B2 (en) | 2007-12-19 | 2015-03-31 | Lion Corporation | Oxidation catalyst for bleaching, and bleaching composition using the same |
| JP2011245458A (en) * | 2010-05-31 | 2011-12-08 | Adeka Corp | Method for decomposition of organic substance, and decomposition agent kit for organic substance |
| CN104926000A (en) * | 2015-07-08 | 2015-09-23 | 中国科学院水生生物研究所 | Method for rapidly clearing away floating green alga spirogyra |
| CN105016524A (en) * | 2015-07-08 | 2015-11-04 | 中国科学院水生生物研究所 | Method for removing floating cladophora |
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