JP2000123801A - Battery with metal resin laminated film case - Google Patents

Battery with metal resin laminated film case

Info

Publication number
JP2000123801A
JP2000123801A JP10313987A JP31398798A JP2000123801A JP 2000123801 A JP2000123801 A JP 2000123801A JP 10313987 A JP10313987 A JP 10313987A JP 31398798 A JP31398798 A JP 31398798A JP 2000123801 A JP2000123801 A JP 2000123801A
Authority
JP
Japan
Prior art keywords
battery
laminated film
metal resin
resin laminated
power generating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10313987A
Other languages
Japanese (ja)
Other versions
JP4178428B2 (en
JP2000123801A5 (en
Inventor
Shigeo Komatsu
茂生 小松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Storage Battery Co Ltd
Original Assignee
Japan Storage Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Storage Battery Co Ltd filed Critical Japan Storage Battery Co Ltd
Priority to JP31398798A priority Critical patent/JP4178428B2/en
Publication of JP2000123801A publication Critical patent/JP2000123801A/en
Publication of JP2000123801A5 publication Critical patent/JP2000123801A5/ja
Application granted granted Critical
Publication of JP4178428B2 publication Critical patent/JP4178428B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

PROBLEM TO BE SOLVED: To provide a battery which takes a metal resin laminated film as a battery case and which is hard to short circuit. SOLUTION: A battery having a power generating element 5 which has an isolation body 4 for preventing short circuit of a positive pole 2, a negative pole 3, and between the positive and negative poles, and a metal resin laminated film case 6 for receiving the power generating element, includes covers 8, 9 for preventing stress deformation of end portions of the power generating element 5, on the end portions. The battery is hard to short circuit and is safe in spite of its being lightweight and compact in size.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、金属樹脂積層フ
ィルムをケースとする電池に属し、特にリチウム二次電
池等の非水電解質電池に好適に利用されうる。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a battery having a metal resin laminated film as a case, and particularly to a nonaqueous electrolyte battery such as a lithium secondary battery.

【0002】[0002]

【従来の技術】近年、携帯用無線電話、携帯用パソコ
ン、携帯用ビデオカメラ等の電子機器が開発され、各種
電子機器が携帯可能な程度に小型化されている。それに
伴って、内蔵される電池としても、高エネルギー密度を
有し、且つ軽量なものが採用されている。そのような要
求を満たす典型的な電池は、リチウム金属、リチウム合
金、リチウムイオンを保持させた炭素等のリチウム系を
負極とし、LiCIO4、LiPF6等のリチウム塩を溶
解した非プロトン性の有機溶媒を電解液とするリチウム
二次電池である。
2. Description of the Related Art In recent years, electronic devices such as a portable radio telephone, a portable personal computer, and a portable video camera have been developed, and various electronic devices have been reduced in size to be portable. Along with this, a battery having a high energy density and a light weight is also adopted as a built-in battery. A typical battery that satisfies such requirements is a lithium-based metal such as lithium metal, a lithium alloy, and lithium ions, and an aprotic organic solvent in which a lithium salt such as LiCIO 4 or LiPF 6 is dissolved. This is a lithium secondary battery using a solvent as an electrolyte.

【0003】リチウム電池に限らず電池を電源とする機
器の場合、機器全体の軽量化及び小型化の要請は尽きる
ことがない。従って、電池性能が同じで有れば軽いほど
且つ小型であるほどユーザーに好まれる。近年この要請
を充足するべく、電極、隔離体、電解質などの発電要素
を収納するケースとして、金属樹脂積層フィルムを平ら
な袋状に形成したものが提案されている(例えば特開平
9−2132854号)。
[0003] In the case of equipment using a battery as a power source as well as a lithium battery, the demand for weight reduction and miniaturization of the whole equipment has not been exhausted. Therefore, if the battery performance is the same, the lighter and the smaller, the more the user is preferred. In recent years, in order to satisfy this demand, a case in which a metal resin laminated film is formed in a flat bag shape has been proposed as a case for accommodating power generation elements such as electrodes, separators, and electrolytes (for example, JP-A-9-213854). ).

【0004】[0004]

【発明が解決しようとする課題】しかし、金属樹脂積層
フィルムを電池ケースとして使用した場合、従来の厚く
硬い材料からなるケースに比べて外部応力によって弾性
変形しやすい。従って、その応力がケースを介して発電
要素に伝わり、短絡を生じやすい。このため、電池ケー
スごと更に他の保護容器に入れて電池として完成する
か、機器に装着するまで電池に外部応力が加わらないよ
うに神経を使わなければならなかった。それ故、本発明
の目的は、金属樹脂積層フィルムを電池ケースとする短
絡しにくい電池を提供することにある。
However, when a metal resin laminated film is used as a battery case, it tends to be elastically deformed by external stress as compared with a conventional case made of a thick and hard material. Therefore, the stress is transmitted to the power generation element via the case, and a short circuit is likely to occur. For this reason, the battery case must be placed in another protective container to complete the battery, or a nerve must be used so that no external stress is applied to the battery until it is mounted on the device. Therefore, an object of the present invention is to provide a battery that is unlikely to be short-circuited using a metal resin laminated film as a battery case.

【0005】[0005]

【課題を解決するための手段】上記目的を達成するため
に、この発明の電池は、正極、負極及び正負極間の短絡
を防止する隔離体を有する発電要素と、発電要素を収納
する金属樹脂積層フィルムケースとを備えた電池におい
て、前記発電要素の端部に、その端部の応力変形を防止
するカバーを有することを特徴とする。
In order to achieve the above object, a battery according to the present invention comprises a power generating element having a separator for preventing a short circuit between a positive electrode, a negative electrode, and a positive and negative electrode, and a metal resin for housing the power generating element. In a battery including a laminated film case, an end of the power generating element is provided with a cover for preventing stress deformation of the end.

【0006】発電要素は正負極間に隔離体が介在してい
るので、その大部分の箇所では応力を受けても短絡する
ことはない。隔離体は、単に短絡を防止するだけの板状
のものに限らず、電解液を含むポリマー電解質や無機固
体電解質が兼ねていても良い。しかし、隔離体が途切れ
る端部においては応力によって一方の極が他方の極に回
り込んだり、隔離体が弾性変形したりして短絡すること
がある。例えば、リチウム電池のように極板の集電体を
金属箔や金属樹脂ラミネートフィルムで形成し、隔離体
も薄い膜状のもので形成して、それらを積層したものを
発電要素とした場合は積層体の端部にて、また渦状に巻
いたものを発電要素とした場合は巻軸方向の端部にて短
絡しやすい。
[0006] In the power generating element, since the separator is interposed between the positive electrode and the negative electrode, a short circuit does not occur even when stress is applied to most of the portions. The separator is not limited to a plate-like member simply for preventing a short circuit, but may also serve as a polymer electrolyte containing an electrolyte or an inorganic solid electrolyte. However, at the end where the separator is interrupted, stress may cause one of the poles to go around the other, or the separator may be elastically deformed and short-circuited. For example, when the current collector of the electrode plate is formed of a metal foil or a metal resin laminate film, such as a lithium battery, and the separator is also formed of a thin film, and the stacked body is used as a power generation element. When a spirally wound coil is used as a power generating element at the end of the laminated body, a short circuit is likely to occur at the end in the winding axis direction.

【0007】この特徴を備える電池によれば、電池に外
部応力が加わっても、発電要素の端部にカバーが被せら
れているので、短絡しにくい。カバーは、例えばポリプ
ロピレン(PP)、ポリエチレン(PE)などの成形し
やすく、電解液など電池構成体に対して安定な絶縁材料
からなる。大きさや形状は限定されないが、それ自体が
発電要素よりも変形し難く、且つ頭に帽子を被せる如く
発電要素の端部に被せやすいものが好ましい。
According to the battery having this feature, even if an external stress is applied to the battery, the end of the power generating element is covered with the cover, so that it is difficult to cause a short circuit. The cover is made of an insulating material, such as polypropylene (PP) or polyethylene (PE), which is easy to mold and is stable with respect to the battery structure such as an electrolyte. The size and shape are not limited, but those that are less likely to deform themselves than the power generating element and that are easy to cover the end of the power generating element such that a cap is put on the head are preferable.

【0008】ケースを構成する金属樹脂積層フィルム
は、一般に電解液を遮蔽するバリアとなるための金属層
と、この金属層に重ねられる固着性に優れた内側プラス
チック層と、金属層の反対面に重ねられる表面保護性に
優れた外側プラスチック層とからなる。もちろん、各層
が複数層であっても良いし、逆に1層で複数の層の役割
を兼ねていても良い。金属樹脂積層フィルム全体として
は、1枚でも2枚でも良い。1枚の場合は固着性に優れ
た層を内側にして折り曲げられ、2枚の場合は固着性に
優れた層を内側にして合わせられる。そして、いずれに
しても電極群や電解質などの発電要素を中に入れた状態
で周辺が互いに液密に固着されることにより袋状に形成
される。
[0008] The metal resin laminated film constituting the case is generally provided with a metal layer serving as a barrier for shielding the electrolytic solution, an inner plastic layer excellent in fixability superimposed on the metal layer, and a metal layer on the opposite side of the metal layer. And an outer plastic layer having excellent surface protection properties. Of course, each layer may be a plurality of layers, or conversely, one layer may also serve as a plurality of layers. One or two metal resin laminated films may be used as a whole. In the case of one sheet, the sheet is folded with the layer having excellent sticking property inside, and in the case of two sheets, the sheet is joined with the layer having excellent sticking property inside. In any case, the periphery is liquid-tightly fixed to each other in a state where the power generation elements such as the electrode group and the electrolyte are put inside, so that the bag is formed in a bag shape.

【0009】上記金属樹脂積層フィルムを構成する外側
プラスチック層の材質としては、表面保護性の他に耐衝
撃性、耐水性、印刷性などに優れたプラスチック、例え
ばPET、二軸延伸PP、延伸ナイロンなどが挙げられ
る。金属層の材質としては、電解液不透過性の他に加工
性に優れたアルミニウムが挙げられる。内側プラスチッ
ク層の材質としては、固着性、特に熱融着性に優れたP
E、PP、変成PE、変成PPなどが挙げられる。各層
の厚みは5〜100μm程度である。
The material of the outer plastic layer constituting the above-mentioned metal resin laminated film may be a plastic excellent in impact resistance, water resistance, printability, etc. in addition to surface protection, such as PET, biaxially stretched PP, stretched nylon. And the like. Examples of the material of the metal layer include aluminum which is excellent in processability in addition to the electrolyte impermeability. The material of the inner plastic layer is P, which is excellent in sticking property, in particular, heat fusing property.
E, PP, modified PE, modified PP, and the like. The thickness of each layer is about 5 to 100 μm.

【0010】[0010]

【実施形態】本発明の電池の実施形態を図面とともに説
明する。図1は実施形態のリチウムイオン二次電池を示
す断面図である。電池1は、薄型で、発電要素となる正
負の電極2,3及び隔離体としてのセパレータ4が長円
渦状に巻かれた電池エレメント5、電池エレメント5を
収納するケース6、並びに電池エレメント5とケース6
の外の回路とを接続する電極端子7,7を備える。セパ
レータ4には電解液が含浸されている。電池エレメント
5の巻軸方向の両端にはカバー8,9が被せられてい
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the battery of the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view showing a lithium ion secondary battery according to the embodiment. The battery 1 is thin and has a battery element 5 in which positive and negative electrodes 2 and 3 serving as power generating elements and a separator 4 as an isolator are wound in an elliptical shape, a case 6 for housing the battery element 5, and a battery element 5. Case 6
Are provided with electrode terminals 7 and 7 for connecting to circuits outside. The separator 4 is impregnated with an electrolytic solution. Covers 8 and 9 are placed on both ends of the battery element 5 in the winding axis direction.

【0011】正極2は、厚さ20μm、幅47mmのA
l箔からなる集電体に活物質としてのリチウムコバルト
複合酸化物を含む合剤層が保持されたものである。正極
合剤は、結着剤であるポリフッ化ビニリデン8部と導電
剤であるアセチレンブラック5部とを活物質87部とと
もに混合してペースト状に調製された。その合剤を、そ
の集電体材料の両面に塗布、乾燥し、加圧することによ
って正極2が製作された。
The positive electrode 2 has a thickness of 20 μm and a width of 47 mm.
A mixture layer containing a lithium-cobalt composite oxide as an active material is held on a current collector made of a 1-foil. The positive electrode mixture was prepared in the form of a paste by mixing 8 parts of polyvinylidene fluoride as a binder and 5 parts of acetylene black as a conductive agent together with 87 parts of an active material. The mixture was applied to both surfaces of the current collector material, dried, and pressed to produce a positive electrode 2.

【0012】負極3は、厚さ20μm、幅49mmのC
u箔からなる集電体にホスト物質としての黒鉛を含む合
剤層が保持されたものである。負極合剤は、黒鉛粉末8
6部と結着剤としてのポリフッ化ビニリデン14部とを
混合してペースト状に調製された。その合剤を、その集
電体材料の両面に塗布、乾燥し、加圧することによって
負極3が製作された。
The negative electrode 3 has a thickness of 20 μm and a width of 49 mm.
A current collector made of a u-foil holds a mixture layer containing graphite as a host material. The negative electrode mixture is graphite powder 8
6 parts and 14 parts of polyvinylidene fluoride as a binder were mixed to prepare a paste. The mixture was applied to both surfaces of the current collector material, dried, and pressed to produce the negative electrode 3.

【0013】セパレータ4は、ポリエチレン微多孔膜で
ある。また、電解液は、LiPF6を1mol/l含む
エチレンカーボネート:ジエチルカーボネート=1:1
(体積比)の混合液である。正極2、セパレータ4及び
負極3を重ねて長円渦状に巻いた後、巻軸方向の両端に
PP製のカバー8,9が被せられる。カバー8,9は、
巻軸線に沿って電池1の厚み方向の断面を眺めると半円
ないしU字形状をなしており、平面視においては図2及
び図3に斜視図として示すように中間部が窪んでいる。
そして、電極端子7、7が取り付けられている側の端部
に被せられるカバー8には、電極端子7,7を挿入する
孔81,81が開けられている。他方、その反対側の端
部に被せられるカバー9には、電解液を注入する孔91
と注入時の空気抜き用の孔92,92とが開けられてい
る。カバー8,9の両端の間隔dは、電池エレメント5
の巻軸線上の厚みより僅かに狭い程度である。従って、
カバー8,9は電池エレメント5の端部より両面を滑る
ように嵌合される。
The separator 4 is a microporous polyethylene membrane. The electrolyte was ethylene carbonate: diethyl carbonate = 1: 1 containing LiPF6 at 1 mol / l.
(Volume ratio). After the positive electrode 2, the separator 4, and the negative electrode 3 are stacked and wound in an elliptical spiral shape, covers 8, 9 made of PP are put on both ends in the winding axis direction. Covers 8 and 9
Viewing the cross section in the thickness direction of the battery 1 along the winding axis line, the battery 1 has a semicircular or U-shaped shape, and has an intermediate portion recessed in plan view as shown in the perspective views of FIGS. 2 and 3.
Then, holes 81, 81 for inserting the electrode terminals 7, 7 are formed in the cover 8, which is put on the end on the side where the electrode terminals 7, 7 are attached. On the other hand, the cover 9 placed on the opposite end has a hole 91 for injecting the electrolyte.
And holes 92, 92 for venting air during injection. The distance d between both ends of the covers 8 and 9 is
Is slightly narrower than the thickness on the winding axis. Therefore,
The covers 8 and 9 are fitted so as to slide on both sides from the end of the battery element 5.

【0014】ケース6は、厚さ15μmのPETフィル
ム、厚さ9μmのアルミニウム箔及び厚さ50μmの低
密度PEフィルムを順にラミネートした金属樹脂積層フ
ィルムからなる。この積層フィルムをPEフィルムが内
側になるように折り曲げて、カバー8,9の付いた電池
エレメント5を包み、電極端子7を取り出した状態で3
方の周辺を熱融着することによって、電池前駆体を得
た。この電池前駆体に電極端子と反対側の開口部より注
射器で電解液を注入し、封口した後、500mA、4.
10Vの定電流定電圧で過充電することによって、放電
容量500mAhの電池1が得られた。
The case 6 is made of a metal resin laminated film in which a 15 μm thick PET film, a 9 μm thick aluminum foil, and a 50 μm thick low density PE film are laminated in this order. The laminated film is bent so that the PE film is on the inside, the battery element 5 with the covers 8 and 9 is wrapped, and the electrode terminal 7 is taken out.
A battery precursor was obtained by heat-sealing the periphery. An electrolyte solution was injected into the battery precursor from the opening opposite to the electrode terminal with a syringe and sealed, and then sealed at 500 mA.
The battery 1 having a discharge capacity of 500 mAh was obtained by overcharging with a constant current and a constant voltage of 10 V.

【0015】比較のために、カバー8,9を電池エレメ
ント5に被せない以外は、電池1と同一条件で比較例の
電池を製作した。こうして得られた実施例の電池1及び
比較例の電池を500mA、4.35Vの定電流定電圧
で過充電したものを各10セル並べて、ケースの外から
電池エレメントの端部に相当する部分を狙って金槌でた
たいた。その結果、比較例の電池は10セルとも激しい
白煙を生じて燃焼したが、実施例の電池はいずれも全く
異常無く、50℃程度まで発熱しただけであった。
For comparison, a battery of a comparative example was manufactured under the same conditions as the battery 1 except that the covers 8 and 9 were not covered on the battery element 5. The thus obtained battery 1 of the example and the battery of the comparative example were overcharged at a constant current and a constant voltage of 500 mA and 4.35 V, and 10 cells each were arranged. A portion corresponding to the end of the battery element was placed outside the case. I slapped it with a hammer. As a result, all of the batteries of the comparative example generated intense white smoke and burned, but all of the batteries of the examples had no abnormality at all and only generated heat up to about 50 ° C.

【0016】[0016]

【発明の効果】以上のように、この発明の電池によれ
ば、軽量且つ小型であるにもかかわらず短絡し難くて安
全である。
As described above, according to the battery of the present invention, short-circuiting is difficult and safe despite its light weight and small size.

【図面の簡単な説明】[Brief description of the drawings]

【図1】実施形態の非水電解質電池を示す断面図であ
る。
FIG. 1 is a cross-sectional view illustrating a nonaqueous electrolyte battery according to an embodiment.

【図2】図1の電池に用いられるカバーを示す斜視図で
ある。
FIG. 2 is a perspective view showing a cover used for the battery of FIG. 1;

【図3】図1の電池に用いられるもう一方のカバーを示
す斜視図である。
FIG. 3 is a perspective view showing another cover used for the battery of FIG. 1;

【符号の説明】[Explanation of symbols]

1 非水電解質電池 2 正極 3 負極 4 セパレータ 5 電池エレメント 6 電池ケース 7 電極端子 8,9 カバー DESCRIPTION OF SYMBOLS 1 Non-aqueous electrolyte battery 2 Positive electrode 3 Negative electrode 4 Separator 5 Battery element 6 Battery case 7 Electrode terminal 8, 9 Cover

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】正極、負極及び正負極間の短絡を防止する
隔離体を有する発電要素と、 発電要素を収納する金属樹脂積層フィルムケースとを備
えた電池において、 前記発電要素の端部に、その端部の応力変形を防止する
カバーを有することを特徴とする電池。
1. A battery comprising: a power generating element having a separator for preventing a short circuit between a positive electrode, a negative electrode, and a positive electrode and a negative electrode; and a metal resin laminated film case accommodating the power generating element. A battery having a cover for preventing stress deformation at its end.
JP31398798A 1998-10-16 1998-10-16 Battery with metal resin laminated film as a case Expired - Fee Related JP4178428B2 (en)

Priority Applications (1)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000059063A1 (en) * 1999-03-26 2000-10-05 Matsushita Electric Industrial Co., Ltd. Laminate sheath type battery
JP2002198098A (en) * 2000-12-25 2002-07-12 Mitsubishi Cable Ind Ltd Sheet-like lithium secondary cell
JP2003124075A (en) * 2001-10-09 2003-04-25 Nissan Diesel Motor Co Ltd Method for manufacturing electric double layer capacitor
WO2005045983A1 (en) * 2003-11-05 2005-05-19 Gs Yuasa Corporation Battery
JP2006147370A (en) * 2004-11-19 2006-06-08 Toyota Motor Corp Film-armored energy storage device and terminal for energy storage device
EP1734596A1 (en) * 2004-03-09 2006-12-20 NEC Lamilion Energy, Ltd. Film enclosed electric device and collector covering member for the film enclosed electric device
JP2007317481A (en) * 2006-05-25 2007-12-06 Nec Lamilion Energy Ltd Film-armored electric device
JP2018510474A (en) * 2015-03-25 2018-04-12 ジョンソン・アイピー・ホールディング・エルエルシー Reinforced battery package with sealed anode chamber

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6743546B1 (en) 1999-03-26 2004-06-01 Matsushita Electric Industrial Co., Ltd. Laminate sheath type battery
WO2000059063A1 (en) * 1999-03-26 2000-10-05 Matsushita Electric Industrial Co., Ltd. Laminate sheath type battery
JP2002198098A (en) * 2000-12-25 2002-07-12 Mitsubishi Cable Ind Ltd Sheet-like lithium secondary cell
JP2003124075A (en) * 2001-10-09 2003-04-25 Nissan Diesel Motor Co Ltd Method for manufacturing electric double layer capacitor
JPWO2005045983A1 (en) * 2003-11-05 2007-11-29 株式会社ジーエス・ユアサコーポレーション battery
WO2005045983A1 (en) * 2003-11-05 2005-05-19 Gs Yuasa Corporation Battery
JP5063895B2 (en) * 2003-11-05 2012-10-31 株式会社Gsユアサ battery
EP1734596A1 (en) * 2004-03-09 2006-12-20 NEC Lamilion Energy, Ltd. Film enclosed electric device and collector covering member for the film enclosed electric device
EP1734596A4 (en) * 2004-03-09 2010-10-20 Nec Corp Film enclosed electric device and collector covering member for the film enclosed electric device
JP2006147370A (en) * 2004-11-19 2006-06-08 Toyota Motor Corp Film-armored energy storage device and terminal for energy storage device
JP2007317481A (en) * 2006-05-25 2007-12-06 Nec Lamilion Energy Ltd Film-armored electric device
JP2018510474A (en) * 2015-03-25 2018-04-12 ジョンソン・アイピー・ホールディング・エルエルシー Reinforced battery package with sealed anode chamber
US11152644B2 (en) 2015-03-25 2021-10-19 Johnson Ip Holding, Llc Reinforced battery package with sealed anode chamber

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