JP2000086807A - Apparatus and method for treating oversized plastic- containing waste - Google Patents
Apparatus and method for treating oversized plastic- containing wasteInfo
- Publication number
- JP2000086807A JP2000086807A JP26031898A JP26031898A JP2000086807A JP 2000086807 A JP2000086807 A JP 2000086807A JP 26031898 A JP26031898 A JP 26031898A JP 26031898 A JP26031898 A JP 26031898A JP 2000086807 A JP2000086807 A JP 2000086807A
- Authority
- JP
- Japan
- Prior art keywords
- waste
- plastic
- heat treatment
- heat medium
- treatment tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 139
- 238000000034 method Methods 0.000 title claims description 17
- 229920003023 plastic Polymers 0.000 claims abstract description 102
- 239000004033 plastic Substances 0.000 claims abstract description 102
- 238000010438 heat treatment Methods 0.000 claims abstract description 64
- 239000007789 gas Substances 0.000 claims abstract description 23
- 238000005406 washing Methods 0.000 claims abstract description 12
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 7
- 238000006392 deoxygenation reaction Methods 0.000 claims description 13
- 230000001590 oxidative effect Effects 0.000 claims description 11
- 238000012546 transfer Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 22
- 239000002184 metal Substances 0.000 abstract description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 10
- 239000001301 oxygen Substances 0.000 abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 abstract description 10
- 150000002739 metals Chemical class 0.000 abstract description 5
- 230000003635 deoxygenating effect Effects 0.000 abstract description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 39
- 229910052757 nitrogen Inorganic materials 0.000 description 19
- 238000012545 processing Methods 0.000 description 13
- 239000002904 solvent Substances 0.000 description 12
- 238000004140 cleaning Methods 0.000 description 11
- 238000000926 separation method Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 8
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000002905 metal composite material Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 239000011521 glass Substances 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 239000011280 coal tar Substances 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000000295 fuel oil Substances 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 206010011906 Death Diseases 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000006298 dechlorination reaction Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 239000013502 plastic waste Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 150000002013 dioxins Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000002828 fuel tank Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 102100023053 Band 4.1-like protein 5 Human genes 0.000 description 1
- 102100033040 Carbonic anhydrase 12 Human genes 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 101001049973 Homo sapiens Band 4.1-like protein 5 Proteins 0.000 description 1
- 101000867855 Homo sapiens Carbonic anhydrase 12 Proteins 0.000 description 1
- 101100293260 Homo sapiens NAA15 gene Proteins 0.000 description 1
- 102100026781 N-alpha-acetyltransferase 15, NatA auxiliary subunit Human genes 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000010786 composite waste Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000006148 magnetic separator Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/82—Recycling of waste of electrical or electronic equipment [WEEE]
Landscapes
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は廃棄物の処理方法に
関し、特に、廃自動車や廃家電製品等の多種類の材料が
混合した大型プラスチック含有廃棄物(以下、金属複合
廃プラスチックという。)を迅速に簡便に処理して、そ
こに含まれている金属等を金属源、及びプラスチック等
を燃料や資源として連続的に回収する処理装置に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for treating waste, and more particularly to a large-sized plastic-containing waste (hereinafter referred to as metal-composite waste plastic) in which various kinds of materials such as waste automobiles and waste home appliances are mixed. The present invention relates to a processing apparatus for quickly and simply processing and continuously collecting metals and the like contained therein as a metal source and continuously collecting plastics and the like as fuel and resources.
【0002】[0002]
【従来の技術】近年、産業廃棄物や一般廃棄物としてプ
ラスチック等の合成樹脂類が増加しており、その処理が
社会的、環境上、大きな問題となっている。なかでも高
分子系の炭化水素化合物であるプラスチックは燃焼時に
発生する発熱量が高く、焼却処理した場合の焼却炉の炉
壁を傷める等の問題から専用の焼却設備を必要とし、そ
の多くはごみ埋立て地等で投棄処理されているのが現状
である。しかし、プラスチック等の投棄は埋立て地の地
盤の低下をもたらすと共に、環境対策上好ましくなく、
また、昨今では処理費の増加とともに埋め立て地用の用
地不足が社会問題となりつつあり、このため投棄によら
ない合成樹脂類の大量処理方法の開発が切望されてい
る。特に、これらのプラスチックを含む廃車や廃家電製
品等の金属複合廃プラスチックの処理は資源のリサイク
ルが叫ばれており、その処理は社会問題化している。2. Description of the Related Art In recent years, synthetic resins such as plastics have been increasing as industrial wastes and general wastes, and their disposal has become a serious social and environmental problem. Plastics, which are high-molecular hydrocarbon compounds, generate a large amount of heat when they are burned, and require special incineration equipment due to problems such as damage to the walls of incinerators when incinerated. Currently, it is disposed of in landfills. However, dumping of plastics and the like causes deterioration of the landfill, and is not preferable in terms of environmental measures.
Further, in recent years, the shortage of land for landfills has become a social problem along with the increase in disposal costs, and therefore development of a method for mass processing of synthetic resins without dumping is keenly desired. In particular, the recycling of metal-composite waste plastics containing these plastics, such as scrap cars and household electrical appliances, has been called for to recycle resources, and the treatment has become a social problem.
【0003】この金属複合廃プラスチックの処理方法と
して、従来は、廃車の場合はエンジン、バッテリー、排
ガス処理用触媒等有価な部品類を解体、分別した後、そ
れ以外のガラをシュレッダーで粉砕し、粉砕物から磁気
選別装置で鉄を、アルミ選別装置でアルミをそれぞれ回
収する方法が採用されている。モーター類やワイヤーフ
ァーネス等の銅は手分別で回収されているが、回収率は
低い。廃車に含まれるプラスチック類はガラスやゴム、
繊維等とともにガラの約30%ものダストとして排出さ
れる。廃家電製品も同様な処理方法が採られている。こ
のダストにはプラスチックを始め有用な物質が含まれて
いるため、機械的分別法やガス化溶融処理等種々の検討
がなされているが、その分別方法は確立されておらず、
現在は埋め立て処分されている。Conventionally, as a method of treating this metal-composite waste plastic, in the case of a scrapped vehicle, valuable parts such as an engine, a battery, and an exhaust gas treatment catalyst are disassembled and separated, and then other waste is pulverized with a shredder. A method of recovering iron from a crushed material by a magnetic separator and aluminum by an aluminum separator is adopted. Although copper such as motors and wire furnaces is collected by hand, the recovery rate is low. Plastics contained in end-of-life vehicles are glass and rubber,
About 30% of the waste is discharged as dust along with the fibers. A similar treatment method is used for waste home appliances. Since this dust contains useful substances including plastics, various studies such as mechanical separation method and gasification melting treatment have been made, but the separation method has not been established,
It is currently being landfilled.
【0004】一方、廃車から有価部品を取り除いて残り
を蒸し焼きする方法は公知である(特開平10−437
08号公報)。この方法においては、プラスチックは熱
分解してガスや油状物質で回収して燃料とされ、多量の
ダイオキシン類を含んでいる熱分解残渣は高温のまま真
空処理して真空排気系に回収し、スクラップを得てい
る。On the other hand, a method of removing valuable parts from end-of-life vehicles and steaming the remainder is known (Japanese Patent Laid-Open No. Hei 10-437).
08 publication). In this method, plastic is thermally decomposed and recovered as a gas or oil to be used as fuel, and the pyrolysis residue containing a large amount of dioxins is vacuum-processed at high temperature and collected in a vacuum exhaust system, and scrap is recovered. Have gained.
【0005】[0005]
【発明が解決しようとする課題】有価部品を解体分別し
てからそれ以外のガラをシュレッダー処理する方法は、
処理に手間と時間がかかり、シュレッダー処理が高価な
ことも問題であった。有価部品を取り外した残りを蒸し
焼きにする方法も時間がかかり、さらにダイオキシンが
発生することも大きな問題であった。A method of shredding valuable parts after disassembling and separating valuable parts,
The processing is time-consuming and time-consuming, and the shredder processing is expensive. The method of steaming the remainder after removing valuable parts is also time-consuming, and the generation of dioxin has been a serious problem.
【0006】本発明の目的は、廃車や家電製品のような
大型のプラスチック含有廃棄物を、ダイオキシンをほと
んど発生させずに短時間で効率よく処理して金属やプラ
スチックを回収しうる装置と方法を提供することにあ
る。An object of the present invention is to provide an apparatus and a method for recovering metals and plastics by efficiently and efficiently treating large-sized plastic-containing wastes such as end-of-life vehicles and home electric appliances in a short time without generating dioxins. To provide.
【0007】[0007]
【課題を解決するための手段】本発明は、上記課題を解
決するべくなされたものであり、大型プラスチック含有
廃棄物の処理装置であって、該廃棄物から酸素ガスを除
去する脱酸素室と、酸素ガスを除去された廃棄物を浸漬
して非酸化性ガス雰囲気で加熱しプラスチックを分離す
る熱媒体を収容した熱処理槽と、プラスチックが分離さ
れた廃棄物を洗浄する洗浄室と、該廃棄物を脱酸素室、
熱処理槽、洗浄室の順に搬送する搬送装置よりなる大型
廃プラスチック含有廃棄物処理装置と、この装置を用
い、大型プラスチック含有廃棄物をシュレッダー処理す
ることなく処理する大型プラスチック含有廃棄物の処理
方法によってかかる目的を達成したものである。SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and is an apparatus for treating large-sized plastic-containing waste, comprising a deoxygenation chamber for removing oxygen gas from the waste. A heat treatment tank containing a heating medium for immersing the waste gas from which oxygen gas has been removed and heating it in a non-oxidizing gas atmosphere to separate the plastic, a cleaning chamber for cleaning the waste material from which the plastic has been separated, Deoxygenation room,
A large waste plastic-containing waste treatment device consisting of a transfer device that transports heat treatment tanks and a cleaning chamber in this order, and a large plastic-containing waste treatment method that uses this device to treat large plastic waste without shredding. This has been achieved.
【0008】本発明の装置を構成している各装置の詳細
は次の通りである。[0008] Details of each device constituting the device of the present invention are as follows.
【0009】(1) 脱酸素室 本装置は、大型プラスチック含有廃棄物から酸素ガスを
排除して非酸化性ガス雰囲気し、次の熱処理工程におけ
る熱媒体の劣化やダイオキシンの発生を防止するもので
ある。そのため、この室は、外気を遮断することがで
き、非酸化性ガスの供給口と排出口を有し、さらに大型
プラスチック含有廃棄物の入口と出口を有するものであ
る。室の形状は特に限定されるものではなく、箱型、ト
ンネル型等でよい。非酸化性ガスは窒素、ヘリウム、炭
酸ガス等如何なるものであってもよいが、窒素が安価で
簡便である。大型プラスチック含有廃棄物の出入口にお
ける外気の遮断方法としては、扉のほか、プラスチック
シートによるカーテン、窒素ガスによる気体カーテン等
が利用できる。脱酸素室の大型プラスチック含有廃棄物
の出口は通常外側も非酸化性ガス雰囲気に保たれている
ので、遮断手段は厳密である必要はなく、また省略する
ことも可能である。この脱酸素室で、大型プラスチック
含有廃棄物の酸素ガス濃度は5重量%以下、特に1重量
%以下にすることが好ましい。(1) Deoxygenation chamber This apparatus eliminates oxygen gas from large-sized plastic-containing waste and creates a non-oxidizing gas atmosphere to prevent deterioration of the heat medium and generation of dioxin in the next heat treatment step. is there. Therefore, this chamber can block the outside air, has a supply port and a discharge port for the non-oxidizing gas, and has an inlet and an outlet for the large-sized plastic-containing waste. The shape of the chamber is not particularly limited, and may be a box type, a tunnel type, or the like. The non-oxidizing gas may be any gas such as nitrogen, helium, carbon dioxide, etc., but nitrogen is inexpensive and simple. As a method of shutting off the outside air at the entrance of the large-sized plastic-containing waste, in addition to the door, a curtain made of a plastic sheet, a gas curtain made of nitrogen gas, or the like can be used. Since the outlet of the large plastic-containing waste in the deoxygenation chamber is usually kept outside in a non-oxidizing gas atmosphere, the shut-off means does not need to be strict and can be omitted. In this deoxygenation chamber, the oxygen gas concentration of the large plastic-containing waste is preferably 5% by weight or less, particularly preferably 1% by weight or less.
【0010】(2) 熱処理槽 本装置は、大型プラスチック含有廃棄物を非酸化性ガス
雰囲気で熱媒体に浸漬してプラスチックを分離するもの
である。熱処理槽では十分な熱処理によりプラスチック
等の有機物と金属等の無機物の複合物に含まれる有機物
は完全に溶融および溶解し、不溶プラスチックは浮上
し、比重の高い無機物ほぼその全量が沈降する。同時に
一部のプラスチックやポリウレタン等の発泡樹脂や繊維
類、及びゴム類は一部分解がおこりその容積が減少し、
金属、無機物との分離が容易となる。また、塩化ビニル
の場合は熱分解により脱HCLも起こり、HCLの発生
とともに熱分解したチャーも生成する。(2) Heat treatment tank This apparatus separates plastics by immersing large-sized plastic-containing waste in a heat medium in a non-oxidizing gas atmosphere. In a heat treatment tank, organic substances contained in a composite of an organic substance such as a plastic and an inorganic substance such as a metal are completely melted and dissolved by a sufficient heat treatment, the insoluble plastic floats, and almost all of the inorganic substance having a high specific gravity settles. At the same time, some plastics, foamed resins such as polyurethane, fibers, and rubbers partially decompose and their volume decreases,
Separation from metals and inorganic substances becomes easy. In the case of vinyl chloride, dehydrochlorination also occurs due to thermal decomposition, and thermally decomposed char is generated together with the generation of HCL.
【0011】この熱処理槽は、熱媒体を収容する槽のほ
か、楕円を外気と遮断することができ、非酸化性ガスの
供給口と排出口を有し、さらに大型プラスチック含有廃
棄物の入口と出口を有する。非酸化性ガスの供給口と排
出口はこの熱処理槽と隣接するあるいは連通する他の室
に設けられているものを兼用させることができる。大型
プラスチック含有廃棄物の出入口における外気の遮断手
段は脱酸素室で記載したものを選択することができる。
入口または出口の外側が非酸化性ガス雰囲気にある場合
には遮断手段は厳密である必要はなく、また省略するこ
とも可能である。熱媒体を加熱する加熱器は熱処理槽内
外いずれに設置することも可能である。熱媒体には大型
プラスチック含有廃棄物の熱処理によって分離された溶
融プラスチックが浮遊しており、これを回収するため熱
媒体を熱処理槽外へ抜き出して、プラスチック回収後も
との熱処理槽に戻すのがよい。その際、加熱器はこの循
環ラインに設けることもできる。加熱器の熱源には例え
ばコークス炉ガスを使用することができる。熱媒体は付
着同伴等によって減少していくので補給手段を設ける。
補給する熱媒体は熱処理槽に直接投入してもよく、前記
循環ラインの途中に導入してもよい。熱処理槽には攪拌
機を設けることもできる。This heat treatment tank, in addition to a tank containing a heat medium, can block the ellipse from the outside air, has a supply port and a discharge port for non-oxidizing gas, and has an inlet for large-sized plastic-containing waste. Has an outlet. The supply port and the discharge port of the non-oxidizing gas may be those provided in another chamber adjacent to or in communication with the heat treatment tank. As the means for shutting off the outside air at the entrance and exit of the large-sized plastic-containing waste, those described in the deoxygenation chamber can be selected.
When the outside of the inlet or the outlet is in a non-oxidizing gas atmosphere, the shut-off means does not need to be strict and can be omitted. The heater for heating the heat medium can be installed inside or outside the heat treatment tank. Molten plastic separated by heat treatment of large plastic waste is suspended in the heat medium.To recover this, the heat medium is drawn out of the heat treatment tank and returned to the original heat treatment tank after plastic recovery. Good. In this case, a heater can be provided in this circulation line. As a heat source of the heater, for example, coke oven gas can be used. Since the heat medium decreases due to entrainment and the like, a replenishing means is provided.
The replenishing heat medium may be directly charged into the heat treatment tank, or may be introduced in the middle of the circulation line. The heat treatment tank may be provided with a stirrer.
【0012】熱媒体として使用される材料は、複合廃棄
物の浸漬温度で液体として存在し、分離された金属の溶
融時に有害となるアルカリ塩等有害成分の混入が無く、
高炉用還元材や燃料にもなるものである。そのほか、こ
の浸漬温度では少なくともほとんど分解せずにその粘度
等の物理的性質が変化しないこと、かつ分離された金属
やその他の無機材料からの分離が容易なことが必要であ
る。さらに、分離されたポリマーが熱媒体から浮上分離
するものが望ましい。これらの条件を満たすものは沸点
が250℃以上であり、かつ芳香族指数が0.2以上を
有するものである。好ましくは沸点が300℃以上、特
に好ましくは350℃以上である。一方、沸点の上限は
その熱安定性から定められ、600℃以下、特に550
℃以下であることが好ましい。芳香族指数は全炭素数に
対する芳香族炭素数の比率であり、Brown−Lad
ner法(J.K.Brown,W.R.Ladner an
dN.Sheppard,Fuel,39,79(196
0)で測定することができる。芳香族指数は好ましくは
0.2以上、特に好ましくは0.25以上であり、上限は
1.0以下、特に好ましくは0.95以下のものがよい。
具体的に例示すれば、コールタール系の重質油、ピッ
チ、石炭液化油、特定の油種(カフジ等芳香族成分が多
いもの)からの石油系の減圧残油、エチレンボトム油、
改質油、FCCオイル等が挙げられる。特に、溶解炉の
排ガス処理の観点からは硫黄分の少ないコールタール系
重質油が望ましく用いられる。The material used as the heat medium exists as a liquid at the immersion temperature of the composite waste, and does not contain harmful components such as alkali salts which are harmful when the separated metal is melted.
It also becomes a reducing material and fuel for blast furnaces. In addition, at this immersion temperature, it is necessary that physical properties such as viscosity do not change at least with little decomposition, and that separation from separated metals and other inorganic materials is easy. Further, it is desirable that the separated polymer floats and separates from the heating medium. Those satisfying these conditions have a boiling point of 250 ° C. or higher and an aromatic index of 0.2 or higher. Preferably, the boiling point is at least 300 ° C, particularly preferably at least 350 ° C. On the other hand, the upper limit of the boiling point is determined from its thermal stability and is 600 ° C. or less, especially 550 ° C.
It is preferable that the temperature is not higher than ° C. The aromatic index is the ratio of the number of aromatic carbon atoms to the total number of carbon atoms, and is expressed as Brown-Lad.
ner method (JK Brown, WR Ladner an
dN. Sheppard, Fuel, 39 , 79 (196
0) can be measured. The aromatic index is preferably at least 0.2, particularly preferably at least 0.25, and the upper limit is preferably at most 1.0, particularly preferably at most 0.95.
Specific examples include coal-tar heavy oil, pitch, coal liquefied oil, petroleum-based vacuum residual oil from a specific oil type (having a large amount of aromatic components such as cuffs), ethylene bottom oil,
Modified oil, FCC oil and the like can be mentioned. In particular, coal tar heavy oil having a low sulfur content is desirably used from the viewpoint of exhaust gas treatment in a melting furnace.
【0013】浸漬温度と時間は通常ポリマーの溶融、分
解が十分に進行するように定められ、これはポリマーの
種類、使用量によって異なるが、200〜400℃程
度、好ましくは250〜350℃で、0.5〜30分間
程度、好ましくは1.5〜15分程度が適当である。The immersion temperature and time are usually determined so that the melting and decomposition of the polymer sufficiently proceed. The immersion temperature and the time vary depending on the type and amount of the polymer, but are about 200 to 400 ° C., preferably 250 to 350 ° C. About 0.5 to 30 minutes, preferably about 1.5 to 15 minutes is appropriate.
【0014】(3) 洗浄室 本装置は、プラスチックの分離が終わって熱処理槽から
取り出された廃棄物を洗浄してそこに付着している熱媒
体を除去するものである。洗浄にはスチームを利用する
のがよい。この装置も内部を外気と遮断できる構造とす
ることが好ましい。洗浄した液は熱媒体と水の混合物で
あるので、油水分離器等により熱媒体を回収して熱処理
槽に循環させることができる。(3) Cleaning Room This apparatus is for cleaning the waste taken out of the heat treatment tank after the separation of the plastic and removing the heat medium adhering thereto. It is better to use steam for cleaning. This device also preferably has a structure that can shut off the inside from the outside air. Since the washed liquid is a mixture of a heat medium and water, the heat medium can be recovered by an oil-water separator or the like and circulated to the heat treatment tank.
【0015】(4) 搬送装置 本装置は、大型プラスチック含有廃棄物を脱酸素室、熱
処理槽、洗浄室の順に搬送するものである。この搬送装
置には如何なるコンベアを用いてもよいが、吊下げるタ
イプのものが好ましい。(4) Transporting Device This device transports large-sized plastic-containing waste in the order of a deoxygenation chamber, a heat treatment tank, and a cleaning chamber. Although any conveyor may be used for the transfer device, a suspended type is preferred.
【0016】(5) 廃プラスチックの回収装置 本装置は熱処理装置に連結され、熱処理槽から熱媒体と
ともに排出される廃プラスチックを静置し、廃プラスチ
ック排出機構と熱媒体の排出機構を有する比重分離槽と
これに連結し回収された廃プラスチックから熱媒体を回
収するスクリュープレス等の固液分離装置からなる。ま
た、上記装置で回収された熱媒体は熱処理槽に連結され
たラインにより循環して再利用することが可能である。(5) Waste Plastic Recovery Apparatus This apparatus is connected to a heat treatment apparatus, where the waste plastic discharged together with the heat medium from the heat treatment tank is allowed to stand, and a specific gravity separation mechanism having a waste plastic discharge mechanism and a heat medium discharge mechanism is provided. It comprises a tank and a solid-liquid separation device such as a screw press connected to the tank and recovering the heating medium from the recovered waste plastic. Further, the heat medium recovered by the above apparatus can be circulated and reused by a line connected to the heat treatment tank.
【0017】以上説明した処理装置の他、回収した金属
複合廃プラスチックを2〜10分割に破砕処理するため
の破砕工程を具備する。切断には従来、金属を含む廃棄
物の切断に用いられるギロチンや破砕機などが使用可能
である。なお、最初の処理工程に本粉砕工程を施すこと
により廃棄物の表面に亀裂が生じるため、ダイオキシン
などの有害物質の発生防止を目的に行う、金属複合廃プ
ラスチックに含まれる酸素を除去する脱気工程での酸素
除去が容易となる上、下工程の熱処理工程でも溶融液体
が浸透しやすくなるため、金属複合廃プラスチックと溶
融液体の接触が容易となり、溶融液体中のプラスチック
が剥離して金属の回収が容易になる。分割の程度は金属
複合廃プラスチックの大きさや組成、構造により異なる
が、廃車や廃家電の場合は2分割以上、好ましくは3分
割以上、10分割程度までである。これより大きい場合
はギロチンの固定刃や押し切り刃の摩耗が大きくなる
上、その動力が増大するからである。さらに得られる分
割物も嵩密度が増大し取扱い難くなり、処理後の溶融液
体の除去も次第に困難になる。また、金属を精錬するた
めに回収された金属をプレスして利用するためのプレス
を採用することも可能である。In addition to the processing apparatus described above, a crushing step for crushing the collected metal composite waste plastic into two to ten parts is provided. Conventionally, a guillotine or a crusher used for cutting waste containing metal can be used for cutting. In addition, since the surface of the waste is cracked by performing the main pulverization step in the first processing step, deaeration to remove oxygen contained in metal-composite waste plastic is performed to prevent the generation of harmful substances such as dioxin. In addition to easy removal of oxygen in the process, the molten liquid also easily penetrates in the subsequent heat treatment step, making it easier for metal-composite waste plastic to come into contact with the molten liquid. Collection becomes easy. The degree of division varies depending on the size, composition, and structure of the metal-composite waste plastic, but in the case of scrapped cars and waste home appliances, it is divided into two or more, preferably three or more and up to about ten. If it is larger than this, the guillotine fixed blade and the push-cutting blade become worn and the power thereof increases. Further, the obtained divided material also has an increased bulk density and becomes difficult to handle, and it becomes gradually difficult to remove the molten liquid after the treatment. It is also possible to employ a press for pressing and using the collected metal for refining the metal.
【0018】[0018]
【発明の実施の形態】以下、本発明による金属複合廃プ
ラスチックの処理装置を図1〜4に示した実施の形態に
基づいて具体的に説明する。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, an apparatus for treating metal-composite waste plastic according to the present invention will be described in detail with reference to the embodiment shown in FIGS.
【0019】(実施の第1形態)まず、図1に示された
実施の第1形態による廃車の処理装置について説明す
る。1は廃車からエンジン、タイヤ、燃料タンク等を除
いた廃車ガラであり、コンベア2は連続的に廃車ガラを
脱酸素室3に移送するための手段である。脱酸素室3は
窒素4で廃車に含まれる酸素を置換して除去するための
ものである。熱処理槽8は酸素が除かれた廃車ガラ1
を、熱媒体タンク7に連結する加熱器5で250〜35
0℃に加熱した熱媒体6中に所定時間浸漬する装置であ
る。熱処理槽8は下部に設置された窒素導入口9からの
窒素による攪拌機構を有する。供給された廃車ガラに含
まれる廃プラスチックは、熱処理され金属と複合したプ
ラスチックが溶融し、その一部が溶解する。プラスチッ
クの内、ポリウレタンは一部分解し、その容積が1/1
0以下に減少し、塩化ビニルからは脱塩素によりチャー
と塩化水素が生じる。なお、塩化水素や炭酸ガス等を含
む生成ガス10を洗浄するためにスクラバー11が設置
される。また廃プラスチックから熱媒体6を分離するた
めに熱処理槽上部に浮上分離する廃プラスチック12を
熱媒体6が排出される排出口13に比重分離槽14が連
結される。回収された熱媒体6を加熱器5で再度250
〜350℃に加熱した後、熱処理槽8に循環し使用する
ための循環ラインも採用される。次にコンベア2は熱処
理槽8から引き上げられたプラスチックが除去された残
留物から熱媒体を一部除去するように配置される。洗浄
室15は熱媒体が一部付着した廃車ガラ1に高圧スチー
ム16を吹き付ける装置が設置されており、熱媒体が除
去され、製錬に適した廃車ガラ1が得られる。油水分離
器17は洗浄で排出される熱媒体と水の混合物を熱媒体
と排水18に分離するために設置され、熱媒体を加熱器
5に戻して使用する循環ラインも用いられる。以上の装
置により廃プラスチックと処理された廃車ガラ1が回収
される。(First Embodiment) First, a waste vehicle processing apparatus according to a first embodiment shown in FIG. 1 will be described. Reference numeral 1 denotes a scrap car waste obtained by removing an engine, tires, a fuel tank, and the like from the scrap car, and a conveyor 2 is a means for continuously transferring the scrap car waste to the deoxygenation chamber 3. The deoxidizing chamber 3 is for replacing and removing oxygen contained in the end-of-life vehicle with nitrogen 4. The heat treatment tank 8 is a waste car waste 1 from which oxygen has been removed.
From the heater 5 connected to the heat medium tank 7
This device is immersed in the heat medium 6 heated to 0 ° C. for a predetermined time. The heat treatment tank 8 has a stirring mechanism using nitrogen from a nitrogen inlet 9 provided at the lower part. The waste plastic contained in the supplied waste car waste is heat-treated, and the plastic composited with the metal is melted, and a part of the plastic is melted. Of plastics, polyurethane partially decomposes and its volume is 1/1
It is reduced to 0 or less, and char and hydrogen chloride are generated from vinyl chloride by dechlorination. Note that a scrubber 11 is provided to clean the generated gas 10 containing hydrogen chloride, carbon dioxide, and the like. In addition, a specific gravity separation tank 14 is connected to an outlet 13 from which the heat medium 6 is discharged from the waste plastic 12 which floats and separates on the upper part of the heat treatment tank to separate the heat medium 6 from the waste plastic. The collected heat medium 6 is again heated by the heater 5 for 250 minutes.
After heating to about 350 ° C., a circulation line for circulating and using the heat treatment tank 8 is also employed. Next, the conveyor 2 is arranged so as to partially remove the heating medium from the residue from which the plastic pulled up from the heat treatment tank 8 has been removed. The cleaning chamber 15 is provided with a device for blowing high-pressure steam 16 onto the scrap car waste 1 to which the heat medium has partially adhered, the heat medium is removed, and the scrap car waste 1 suitable for smelting is obtained. The oil-water separator 17 is provided to separate the mixture of the heat medium and water discharged in the washing into the heat medium and the waste water 18, and a circulation line for returning the heat medium to the heater 5 for use is also used. With the above-mentioned apparatus, the waste plastic waste 1 treated as waste plastic is collected.
【0020】(実施の第2形態)次に、図2に示された
実施の第2形態による装置について説明する。実施の第
2形態においてサンドブラスト装置19を組み込み、脱
酸素室3の前に前処理室20を設置した装置である。サ
ンドとして乾燥無粘土珪砂(粒径0.5〜2.5mm)を
用い、2.5気圧で廃車に所定時間吹き付けることが可
能な装置である。(Second Embodiment) Next, an apparatus according to a second embodiment shown in FIG. 2 will be described. This is a device in which a sandblasting device 19 is incorporated in the second embodiment, and a pretreatment chamber 20 is installed in front of the deoxidizing chamber 3. This is a device that uses dry clay-free silica sand (particle size: 0.5 to 2.5 mm) as a sand and can blow it to a scrapped vehicle at 2.5 atm for a predetermined time.
【0021】(実施の第3形態)次に、図3に示された
実施の第3形態による廃冷蔵庫の処理装置について説明
する。21は廃冷蔵庫からコンプレッサー、モーター等
の部品を除いたガラであり、コンベア2は連続的に脱酸
素室3に移送するための手段である。熱処理槽8は酸素
が除かれたガラ21を、熱媒体タンク7に連結する加熱
器5で250〜350℃に加熱した熱媒体6中に所定時
間浸漬する装置である。熱処理槽8は下部に設置された
窒素導入口9からの窒素による攪拌機構を有する。供給
されたガラ21に含まれる廃プラスチックは、熱処理さ
れ金属と複合したプラスチックが溶融し、その一部が溶
解する。プラスチックの内、ポリウレタンは一部分解
し、その容積が1/10以下に減少し、塩化ビニルから
は脱塩素によりチャーと塩化水素が生じる。なお、塩化
水素や炭酸ガス等を含む生成ガス10を洗浄するために
スクラバー11が設置される。また廃プラスチックから
溶剤6を分離するために熱処理槽上部に浮上分離する廃
プラスチック12を溶剤6が排出される排出口13に比
重分離槽14が連結される。回収された熱媒体6を加熱
器5で再度250〜350℃に加熱した後、熱処理槽8
に循環し使用するための循環ラインも採用される。次に
コンベア2は熱処理槽8から引き上げられたプラスチッ
クが除去された残留物から熱媒体を一部除去するように
配置される。洗浄室15は熱媒体が一部付着したガラ2
1に高圧スチーム16を吹き付ける装置が設置されてお
り、熱媒体が除去され、製錬に適したガラ21が得られ
る。油水分離器17は洗浄で排出される熱媒体と水の混
合物を熱媒体と排水18に分離するために設置され、熱
媒体を加熱器5に戻して使用する循環ラインも用いられ
る。以上の装置により廃プラスチックと処理されたガラ
21が回収される。(Third Embodiment) Next, a waste refrigerator processing apparatus according to a third embodiment shown in FIG. 3 will be described. Reference numeral 21 denotes a waste from the waste refrigerator except for components such as a compressor and a motor. The conveyor 2 is a means for continuously transferring the waste refrigerator to the deoxygenation chamber 3. The heat treatment tank 8 is a device in which the glass 21 from which oxygen has been removed is immersed in the heat medium 6 heated to 250 to 350 ° C. by the heater 5 connected to the heat medium tank 7 for a predetermined time. The heat treatment tank 8 has a stirring mechanism using nitrogen from a nitrogen inlet 9 provided at the lower part. The waste plastic contained in the supplied glass 21 is heat-treated, and the plastic combined with the metal is melted, and a part of the plastic is melted. Among plastics, polyurethane partially decomposes, its volume is reduced to 1/10 or less, and char and hydrogen chloride are generated from vinyl chloride by dechlorination. Note that a scrubber 11 is provided to clean the generated gas 10 containing hydrogen chloride, carbon dioxide, and the like. Further, a specific gravity separation tank 14 is connected to an outlet 13 from which the solvent 6 is discharged from the waste plastic 12 which floats and separates on the upper part of the heat treatment tank in order to separate the solvent 6 from the waste plastic. After the recovered heat medium 6 is heated again to 250 to 350 ° C. by the heater 5, the heat treatment tank 8 is heated.
A circulation line for circulation and use is also adopted. Next, the conveyor 2 is arranged so as to partially remove the heating medium from the residue from which the plastic pulled up from the heat treatment tank 8 has been removed. The cleaning chamber 15 is a waste glass 2 to which a heat medium is partially adhered.
1 is provided with a device for blowing high-pressure steam 16, the heat medium is removed, and the waste 21 suitable for smelting is obtained. The oil-water separator 17 is provided to separate the mixture of the heat medium and water discharged in the washing into the heat medium and the waste water 18, and a circulation line for returning the heat medium to the heater 5 for use is also used. The waste plastic and the treated waste 21 are collected by the above apparatus.
【0022】(実施の第4形態)次に、図4に示された
実施の第4形態による廃パソコン等廃OA機器の処理装
置について説明する。22は廃パソコンからプリント基
板やモーター、ハードディスク等の部品を除いたガラで
あり、23の金属製の金網で作製されたカゴ(2000
×2000×2000mm程度)に装入する。コンベア
2はこのカゴ23により連続的に脱酸素室3に移送する
ための手段である。熱処理槽8は酸素が除かれたカゴ2
3を、熱媒体タンク7に連結する加熱器5で250〜3
50℃に加熱した熱媒体6中に所定時間浸漬する装置で
ある。熱処理槽8は下部に設置された窒素導入口9から
の窒素による攪拌機構を有する。供給されたカゴ23内
に含まれる廃プラスチックは、熱処理され金属と複合し
たプラスチックが溶融し、その一部が溶解する。プラス
チックの内、ポリウレタンは一部分解し、その容積が1
/10以下に減少し、塩化ビニルからは脱塩素によりチ
ャーと塩化水素が生じる。なお、塩化水素や炭酸ガス等
を含む生成ガス10を洗浄するためにスクラバー11が
設置される。また廃プラスチックから熱媒体6を分離す
るために熱処理槽上部に浮上分離する廃プラスチック1
2を熱媒体6が排出される排出口13に比重分離槽14
が連結される。回収された熱媒体6を加熱器5で再度2
50〜350℃に加熱した後、熱処理槽8に循環し使用
するための循環ラインも採用される。次にコンベア2は
熱処理槽8から引き上げられたプラスチックが除去され
たガラ22から熱媒体を一部除去するように配置され
る。洗浄室15は熱媒体が一部付着したカゴ23に高圧
スチーム16を吹き付ける装置が設置されており、熱媒
体が除去され、製錬に適したガラ22が得られる。油水
分離器17は洗浄で排出される熱媒体と水の混合物を熱
媒体と排水18に分離するために設置され、熱媒体を加
熱器5に戻して使用する循環ラインも用いられる。以上
の装置により廃プラスチックと処理されたガラ22が回
収される。(Fourth Embodiment) Next, a processing apparatus for a waste OA device such as a waste personal computer according to a fourth embodiment shown in FIG. 4 will be described. Reference numeral 22 denotes a waste piece obtained by removing components such as a printed circuit board, a motor, and a hard disk from a waste personal computer.
× 2000 × 2000mm). The conveyor 2 is a means for continuously transferring to the deoxidizing chamber 3 by the basket 23. The heat treatment tank 8 is a basket 2 from which oxygen has been removed.
3 in the heater 5 connected to the heat medium tank 7
This is a device that is immersed in the heat medium 6 heated to 50 ° C. for a predetermined time. The heat treatment tank 8 has a stirring mechanism using nitrogen from a nitrogen inlet 9 provided at the lower part. The waste plastic contained in the supplied basket 23 is heat-treated, and the plastic composited with the metal is melted, and a part of the plastic is melted. Of plastics, polyurethane partially decomposes and its volume is 1
/ 10 or less, and char and hydrogen chloride are generated from vinyl chloride by dechlorination. Note that a scrubber 11 is provided to clean the generated gas 10 containing hydrogen chloride, carbon dioxide, and the like. In addition, the waste plastic 1 that floats and separates above the heat treatment tank to separate the heat medium 6 from the waste plastic.
2 into a discharge port 13 from which the heat medium 6 is discharged.
Are linked. The recovered heat medium 6 is again heated by the heater 5 to 2
After heating to 50 to 350 ° C., a circulation line for circulating and using the heat treatment tank 8 is also employed. Next, the conveyor 2 is arranged so as to partially remove the heat medium from the glass 22 from which the plastic pulled up from the heat treatment tank 8 has been removed. The cleaning chamber 15 is provided with a device for spraying the high-pressure steam 16 on the basket 23 to which the heat medium has been partially adhered, so that the heat medium is removed and the glass 22 suitable for smelting is obtained. The oil-water separator 17 is installed to separate the mixture of the heat medium and the water discharged in the washing into the heat medium and the waste water 18, and a circulation line for returning the heat medium to the heater 5 for use is also used. The waste plastic and the treated waste 22 are collected by the above apparatus.
【0023】(実施の第5形態)まず、装置構成を説明
する。1は廃車からエンジン、タイヤ、燃料タンク等を
除いた廃車ガラをギロチンで2分割にしたものであり、
コンベア2は連続的にこの廃車ガラを移送するための手
段である。脱気窒3は窒素4を窒素導入口5から導入
し、廃車ガラに含まれる酸素を除去するためのものであ
る。熱処理槽6は酸素が除かれた廃車ガラ1を、溶剤タ
ンク7に連結する加熱器8で250〜350℃に加熱し
た溶剤9とともに所定時間浸漬する装置である。熱処理
槽6は下部に設置された窒素導入口10からの窒素6に
よる攪拌機構を有する。塩化水素や炭酸ガス等を含む生
成ガス11を洗浄するためにスクラバー12が設置され
る。また廃プラスチックから溶剤9を分離するために熱
処理槽上部に浮上分離する廃プラスチック13を溶剤9
が排出される排出口14に比重分離槽15が連結され
る。回収された溶剤9を加熱器8で再度250〜350
℃に加熱した後、熱処理槽6に循環し使用するための循
環ラインも採用される。次にコンベア2は熱処理槽6か
ら引き上げられたプラスチックが除去された残留物から
溶剤を一部除去するように配置される。洗浄室16は溶
剤が一部付着した廃車ガラ1に高圧スチーム17を吹き
付ける装置が設置されており、溶剤が除去され、製錬に
適した廃車ガラ1が得られる。油水分離器18は洗浄で
排出される溶剤と水の混合物を溶剤と排水19に分離す
るために設置され、溶剤を加熱器7に戻して使用する循
環ラインも用いられる。以上の装置により廃プラスチッ
クと処理された廃車ガラ1が回収される。(Fifth Embodiment) First, the configuration of the apparatus will be described. 1 is a guillotine divided into two parts of a scrap car gala except the engine, tires, fuel tank, etc. from the scrap car.
The conveyor 2 is a means for continuously transferring the scrap car waste. The degassed nitrogen 3 is for introducing nitrogen 4 from the nitrogen inlet 5 to remove oxygen contained in the scrap car waste. The heat treatment tank 6 is a device for immersing the waste car waste 1 from which oxygen has been removed together with the solvent 9 heated to 250 to 350 ° C. by a heater 8 connected to a solvent tank 7 for a predetermined time. The heat treatment tank 6 has a stirring mechanism using nitrogen 6 from a nitrogen inlet 10 provided at the lower part. A scrubber 12 is provided to clean the generated gas 11 containing hydrogen chloride, carbon dioxide, and the like. Further, in order to separate the solvent 9 from the waste plastic, the waste plastic 13 which floats and separates on the upper part of the heat treatment tank is separated from the waste plastic
The specific gravity separation tank 15 is connected to the discharge port 14 from which is discharged. The recovered solvent 9 is again heated by the heater 8 to 250-350.
After heating to ° C., a circulation line for circulating and using the heat treatment tank 6 is also employed. Next, the conveyor 2 is arranged so as to partially remove the solvent from the residue from which the plastic pulled up from the heat treatment tank 6 has been removed. The washing chamber 16 is provided with a device for blowing high-pressure steam 17 onto the scrap car waste 1 to which a part of the solvent has adhered, whereby the solvent is removed and the scrap car waste 1 suitable for smelting is obtained. The oil / water separator 18 is installed to separate the mixture of the solvent and water discharged in the washing into the solvent and the drainage 19, and a circulation line for returning the solvent to the heater 7 for use is also used. With the above-mentioned apparatus, the waste plastic waste 1 treated as waste plastic is collected.
【0024】次に本装置を用いた処理方法を説明する。
まず、廃車ガラをギロチンで2分割したものをコンベア
2に釣り下げ、脱気室に搬送した。ここでは、窒素を1
Nm3/hの流量で10分間吹き付け、廃車ガラ中の酸
素を置換した。次に廃車ガラは熱処理槽に移送され、2
80℃に加熱されたコールタール重油中に浸漬した。熱
処理槽下部の窒素導入管から窒素を1Nm3/h流通させ
ながら、熱処理を20分間実施した。供給された廃車ガ
ラに含まれる廃プラスチックは、熱処理された金属と複
合したプラスチックが溶融し、その一部が溶解する。プ
ラスチックの内、ポリウレタンは一部分解し、その容積
が1/10以下に減少し、塩化ビニルからは脱塩素によ
りチャーと塩化水素が生じる。なお、熱処理槽のコール
タール重油表面に浮上分離するプラスチックは固液分離
装置に移送され、コールタール重油を分離してプラスチ
ックを回収した。回収率は廃車ガラに含まれるプラスチ
ックの81重量%であった。熱処理槽から引き上げられ
た廃車ガラはスチーム洗浄後、搬出される。搬出された
廃車ガラに付着した有機物は4重量%であった。Next, a processing method using the present apparatus will be described.
First, the scrap car waste was divided into two pieces with a guillotine, and the piece was hooked onto a conveyor 2 and transported to a degassing chamber. Here, 1 nitrogen
Spraying was performed at a flow rate of Nm 3 / h for 10 minutes to replace oxygen in the waste car waste. Next, the scrap car waste is transferred to the heat treatment tank and
It was immersed in coal tar heavy oil heated to 80 ° C. The heat treatment was performed for 20 minutes while flowing 1 Nm 3 / h of nitrogen from the nitrogen inlet tube at the bottom of the heat treatment tank. In the waste plastic contained in the supplied waste car waste, the plastic that has been composited with the heat-treated metal is melted, and a part thereof is melted. Among plastics, polyurethane partially decomposes, its volume is reduced to 1/10 or less, and char and hydrogen chloride are generated from vinyl chloride by dechlorination. The plastic floating and separating on the surface of the coal tar heavy oil in the heat treatment tank was transferred to a solid-liquid separator, where the coal tar heavy oil was separated and the plastic was recovered. The recovery rate was 81% by weight of the plastic contained in the scrap car waste. The waste car waste raised from the heat treatment tank is carried out after steam cleaning. The amount of the organic matter adhering to the scrap car waste taken out was 4% by weight.
【0025】(比較例1)図1の装置を用いて、廃車ガ
ラを2分割せずにそのまま用いた以外は実施例と同様な
処理を実施した。回収率は廃車ガラに含まれるプラスチ
ックの60重量%であった。廃車ガラに付着した有機物
は8重量%であった。Comparative Example 1 Using the apparatus shown in FIG. 1, the same processing as that of the embodiment was performed except that the scrap car waste was used without being divided into two parts. The recovery rate was 60% by weight of the plastic contained in the scrap car waste. The organic matter attached to the scrap car waste was 8% by weight.
【0026】(比較例2)図1の装置を用いて、廃車ガ
ラを12分割して用いた以外は実施例と同様な処理を実
施した。切断後のギロチンの押し切り刃の摩耗が大き
く、分割物の嵩密度は廃車ガラよりも増大していた
(0.5g/cm3程度)。さらに、回収率は廃車ガラに
含まれるプラスチックの85重量%であった。廃車ガラ
に付着した有機物は9重量%であった。(Comparative Example 2) Using the apparatus shown in FIG. 1, the same processing as in the example was performed except that the scrap car waste was divided into 12 parts. The guillotine's push-cutting blade after cutting was greatly worn, and the bulk density of the divided product was larger than that of scrap car waste (about 0.5 g / cm 3 ). Further, the recovery rate was 85% by weight of the plastic contained in the scrap car waste. The organic matter attached to the scrap car waste was 9% by weight.
【0027】[0027]
【発明の効果】以上説明したように、本発明によれば大
型プラスチック含有廃棄物の処理装置において、該プラ
スチック含有廃棄物を脱酸素する脱酸素室と、脱酸素さ
れたプラスチック含有廃棄物を、250〜350℃で一
定時間、非酸化性ガス雰囲気下、溶融液体とともに加
熱、熱処理する熱処理槽と、処理物を洗浄し、金属を回
収する装置から構成されることを特徴とする大型プラス
チック含有廃棄物の連続処理装置によって大型プラスチ
ック含有廃棄物は無公害で連続的に処理され、有価物と
してプラスチックおよび金属の回収が可能となる。As described above, according to the present invention, in the apparatus for treating large-sized plastic-containing waste, a deoxygenation chamber for deoxygenating the plastic-containing waste, and a deoxygenated plastic-containing waste, A large-sized plastic-containing waste comprising a heat treatment tank for heating and heat treatment together with a molten liquid in a non-oxidizing gas atmosphere at 250 to 350 ° C. for a certain period of time, and a device for cleaning the processed material and recovering the metal. The large-size plastic-containing waste is continuously treated with no pollution by the continuous processing apparatus for waste, and it is possible to recover plastic and metal as valuable resources.
【図1】 本発明に係わる廃車ガラからのプラスチック
および金属の回収を目的とした装置構成図である。FIG. 1 is an apparatus configuration diagram for recovering plastic and metal from scrap car waste according to the present invention.
【図2】 本発明に係わるプラスチックおよび金属の回
収を目的とした装置の構成図であり、前処理としてショ
ットブラストを行う装置構成図である。FIG. 2 is a configuration diagram of an apparatus for recovering plastic and metal according to the present invention, and is a configuration diagram of an apparatus that performs shot blast as pretreatment.
【図3】 本発明に係わる廃冷蔵庫ガラからのプラスチ
ックおよび金属の回収を目的とした装置の構成図であ
る。FIG. 3 is a configuration diagram of an apparatus for recovering plastic and metal from waste refrigerator waste according to the present invention.
【図4】 本発明に係わる廃パソコンガラからのプラス
チックおよび金属の回収を目的とした装置の構成図であ
る。FIG. 4 is a configuration diagram of an apparatus for recovering plastic and metal from waste personal computer waste according to the present invention.
1 廃車ガラ 2 コンベア 3 脱酸素室 4 窒素 5 加熱器 6 熱媒体 7 熱媒体タンク 8 熱処理槽 9 窒素導入口 10 生成ガス 11 スクラバー 12 廃プラスチック 13 排出口 14 比重分離槽 15 洗浄室 16 高圧スチーム 17 油水分離器 18 排水 19 サンドブラスト装置 20 前処理室 21 廃冷蔵庫ガラ 22 廃パソコンガラ 23 金属製カゴ DESCRIPTION OF SYMBOLS 1 Waste car waste 2 Conveyor 3 Deoxygenation chamber 4 Nitrogen 5 Heater 6 Heat medium 7 Heat medium tank 8 Heat treatment tank 9 Nitrogen inlet 10 Product gas 11 Scrubber 12 Waste plastic 13 Discharge port 14 Specific gravity separation tank 15 Washing room 16 High pressure steam 17 Oil-water separator 18 Drainage 19 Sand blasting device 20 Pretreatment room 21 Waste refrigerator waste 22 Waste personal computer waste 23 Metal basket
───────────────────────────────────────────────────── フロントページの続き (72)発明者 鹿田 勉 東京都千代田区丸の内一丁目1番2号 日 本鋼管株式会社内 (72)発明者 有山 達郎 東京都千代田区丸の内一丁目1番2号 日 本鋼管株式会社内 (72)発明者 安岡 秀憲 東京都千代田区丸の内一丁目1番2号 日 本鋼管株式会社内 (72)発明者 炭竃 隆志 東京都千代田区丸の内一丁目1番2号 日 本鋼管株式会社内 Fターム(参考) 4F301 AA11 AA21 AC04 AC08 AC12 BA01 BA02 BA21 BA29 BE37 CA09 CA12 CA22 CA36 CA53 4K001 AA10 BA22 BA24 CA00 CA09 GA19 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Tsutomu Shikata 1-1-2 Marunouchi, Chiyoda-ku, Tokyo Inside Nihon Kokan Co., Ltd. (72) Inventor Tatsuro Ariyama 1-1-2 Marunouchi, Chiyoda-ku, Tokyo Inside Nihon Kokan Co., Ltd. (72) Inventor Hidenori Yasuoka 1-2-1, Marunouchi, Chiyoda-ku, Tokyo Nihon Kokan Co., Ltd. (72) Inventor Takashi Sumiga 1-2-1, Marunouchi, Chiyoda-ku, Tokyo Japan F-term (reference) in Steel Pipe Co., Ltd. 4F301 AA11 AA21 AC04 AC08 AC12 BA01 BA02 BA21 BA29 BE37 CA09 CA12 CA22 CA36 CA53 4K001 AA10 BA22 BA24 CA00 CA09 GA19
Claims (3)
であって、該廃棄物から酸素ガスを除去する脱酸素室
と、酸素ガスを除去された廃棄物を浸漬して非酸化性ガ
ス雰囲気で加熱しプラスチックを分離する熱媒体を収容
した熱処理槽と、プラスチックが分離された廃棄物を洗
浄する洗浄室と、該廃棄物を脱酸素室、熱処理槽、洗浄
室の順に搬送する搬送装置よりなる大型廃プラスチック
含有廃棄物処理装置An apparatus for treating large-size plastic-containing waste, comprising: a deoxygenation chamber for removing oxygen gas from the waste; and a heat treatment in a non-oxidizing gas atmosphere by immersing the waste from which oxygen gas has been removed. A large-sized tank consisting of a heat treatment tank containing a heat medium for separating plastic, a washing room for washing the waste from which the plastic has been separated, and a transfer device for transferring the waste in the order of a deoxygenation chamber, a heat treatment tank, and a washing room. Waste plastic-containing waste treatment equipment
プラスチック含有廃棄物をシュレッダー処理することな
く処理する大型プラスチック含有廃棄物の処理方法2. A method for treating large-sized plastic-containing waste, which uses the treatment apparatus according to claim 1 to treat large-sized plastic-containing waste without shredding.
プラスチック含有廃棄物を2〜10に切断して処理する
大型プラスチック含有廃棄物の処理方法3. A method for treating large-size plastic-containing waste, wherein the large-size plastic-containing waste is cut into 2 to 10 and treated using the treatment apparatus according to claim 1.
Priority Applications (1)
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JP26031898A JP2000086807A (en) | 1998-09-14 | 1998-09-14 | Apparatus and method for treating oversized plastic- containing waste |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26031898A JP2000086807A (en) | 1998-09-14 | 1998-09-14 | Apparatus and method for treating oversized plastic- containing waste |
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Publication Number | Publication Date |
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JP2000086807A true JP2000086807A (en) | 2000-03-28 |
Family
ID=17346362
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JP26031898A Pending JP2000086807A (en) | 1998-09-14 | 1998-09-14 | Apparatus and method for treating oversized plastic- containing waste |
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KR102488125B1 (en) | 2019-07-10 | 2023-01-11 | 아반트가르드(상하이)인바이런먼탈 테크놀로지 컴퍼니 리미티드 | Recovery method of waste polyester material |
KR102488008B1 (en) | 2019-07-10 | 2023-01-11 | 아반트가르드(상하이)인바이런먼탈 테크놀로지 컴퍼니 리미티드 | Continuous alcohol decomposition recovery method of waste polyester |
KR102488012B1 (en) | 2019-07-10 | 2023-01-11 | 아반트가르드(상하이)인바이런먼탈 테크놀로지 컴퍼니 리미티드 | Continuous alcohol decomposition continuous transesterification recovery method of waste polyester material |
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