IT1309590B1 - Derivati di 1-alcossi-polialchil-piperidine e loro impiego comeregolatori della polimerizzazione. - Google Patents
Derivati di 1-alcossi-polialchil-piperidine e loro impiego comeregolatori della polimerizzazione.Info
- Publication number
- IT1309590B1 IT1309590B1 IT1999MI000453A ITMI990453A IT1309590B1 IT 1309590 B1 IT1309590 B1 IT 1309590B1 IT 1999MI000453 A IT1999MI000453 A IT 1999MI000453A IT MI990453 A ITMI990453 A IT MI990453A IT 1309590 B1 IT1309590 B1 IT 1309590B1
- Authority
- IT
- Italy
- Prior art keywords
- comeregulatory
- piperidins
- alcoxy
- polyalkyl
- polymerization
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
- C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D211/74—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Hydrogenated Pyridines (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98810194 | 1998-03-09 | ||
EP98810531 | 1998-06-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
ITMI990453A1 ITMI990453A1 (it) | 2000-09-05 |
IT1309590B1 true IT1309590B1 (it) | 2002-01-24 |
Family
ID=26151881
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT1999MI000453A IT1309590B1 (it) | 1998-03-09 | 1999-03-05 | Derivati di 1-alcossi-polialchil-piperidine e loro impiego comeregolatori della polimerizzazione. |
Country Status (18)
Country | Link |
---|---|
US (4) | US6353107B1 (it) |
JP (1) | JP4651137B2 (it) |
KR (1) | KR100581654B1 (it) |
CN (1) | CN1171871C (it) |
AT (1) | AT408655B (it) |
AU (1) | AU754927B2 (it) |
BE (1) | BE1012399A3 (it) |
BR (1) | BR9900977B1 (it) |
CA (1) | CA2264460A1 (it) |
CH (1) | CH693416A5 (it) |
CZ (1) | CZ78999A3 (it) |
DE (1) | DE19909767B4 (it) |
ES (1) | ES2155014B1 (it) |
FR (1) | FR2777892B1 (it) |
GB (1) | GB2335190B (it) |
IT (1) | IT1309590B1 (it) |
NL (1) | NL1011493C2 (it) |
SG (1) | SG82601A1 (it) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH693416A5 (de) * | 1998-03-09 | 2003-07-31 | Ciba Sc Holding Ag | 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler. |
WO2000007981A1 (en) * | 1998-07-31 | 2000-02-17 | Ciba Specialty Chemicals Holding Inc. | Open chain alkoxyamine compounds and their use as polymerization regulators |
ATE269362T1 (de) | 1998-10-06 | 2004-07-15 | Atofina | Verfahren zur kontrollierten radikalischen hochdruck-(co)polymerisation von ethylen in gegenwart von einem kontrollfunktionsinitiator |
TWI225483B (en) | 1998-10-16 | 2004-12-21 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization process |
DE60012738T2 (de) * | 1999-07-02 | 2005-08-04 | Ciba Specialty Chemicals Holding Inc. | Mono- und multifunktionelle alkoxyamine zur herstellung von funktionalisierten makromeren |
TW546311B (en) * | 1999-11-25 | 2003-08-11 | Ciba Sc Holding Ag | Composition and method for color improvement of nitroxyl containing polymers |
TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
ATE499375T1 (de) | 2000-05-19 | 2011-03-15 | Basf Se | Verfahren zur kontrollierten erhöhung des molekulargewichts von polyethylen und polyethylenmischungen |
TWI225492B (en) * | 2000-09-25 | 2004-12-21 | Ciba Sc Holding Ag | Composition and process for enhancing controlled free radical polymerization |
TW574236B (en) * | 2000-09-25 | 2004-02-01 | Ciba Sc Holding Ag | Process for controlled radical polymerization in aqueous dispersion |
TWI236482B (en) * | 2000-11-13 | 2005-07-21 | Ciba Sc Holding Ag | Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical |
TW557305B (en) | 2000-12-14 | 2003-10-11 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith |
TWI274053B (en) * | 2000-12-14 | 2007-02-21 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization |
US6849679B2 (en) | 2001-05-21 | 2005-02-01 | Ciba Specialty Chemicals Corporation | Pigment compositions with modified block copolymer dispersants |
EP1397349B1 (en) * | 2001-06-13 | 2010-12-15 | Basf Se | 4-imino-n-alkoxy or oxy-polyalkyl-piperidine compounds and their use as polymerization regulators |
US7868171B2 (en) * | 2001-11-12 | 2011-01-11 | Ciba Specialty Chemicals Corp. | N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators |
TW200407307A (en) * | 2001-11-26 | 2004-05-16 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
JP4602671B2 (ja) * | 2002-03-05 | 2010-12-22 | チバ ホールディング インコーポレーテッド | 制御された低温ラジカル重合のための開鎖アルコキシアミン及びそれらの相当するニトロキシド。 |
DE10212831A1 (de) * | 2002-03-22 | 2003-10-02 | Tesa Ag | Verfahren zur Herstellung copolymerer Polyacrylat-Haftklebemassen, damit erhaltene Nitroxid-modifizierte Polyacrylate und Kamm-Blockpolymere |
CN1310972C (zh) * | 2002-05-01 | 2007-04-18 | 西巴特殊化学品控股有限公司 | Pvc聚合的链终止方法 |
EP1375457A1 (en) | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | One-pot process for the preparation of functionalized alkoxyamines |
EP1375476A1 (en) * | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | A new process for the synthesis of alkoxyamines active in controlled radical polymerization |
CA2514167A1 (en) * | 2003-02-10 | 2004-08-19 | Ciba Specialty Chemicals Holding Inc. | Comb copolymers with defined side chains and process for their manufacture |
JP4107996B2 (ja) * | 2003-04-25 | 2008-06-25 | 大塚化学株式会社 | リビングラジカルポリマーの製造方法及びポリマー |
JP4046678B2 (ja) * | 2003-10-15 | 2008-02-13 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ |
US8138268B2 (en) * | 2004-06-09 | 2012-03-20 | Hitachi Chemical Company, Ltd. | Adhesive composition, circuit connecting material, connecting structure for circuit member, and semiconductor device |
KR101322668B1 (ko) * | 2005-01-11 | 2013-10-30 | 시바 홀딩 인크 | 제어된 자유 라디칼 중합반응에 의해 제조된 단독중합체 및공중합체의 후개질방법 |
JP4046734B2 (ja) | 2005-01-18 | 2008-02-13 | 横浜ゴム株式会社 | ポリマーの変性方法 |
ATE482985T1 (de) * | 2005-04-04 | 2010-10-15 | Basf Se | Verfahren zur herstellung von stern- und blockcopolymeren über epoxidfunktionelle alkoxyamine |
KR101365953B1 (ko) * | 2005-08-30 | 2014-02-21 | 시바 홀딩 인크 | 니트록실 라디칼 중합반응을 통해 수득된 중합체 |
EP2038704B9 (en) * | 2006-07-11 | 2019-03-27 | Basf Se | Color filter composition |
US20080087380A1 (en) * | 2006-10-13 | 2008-04-17 | Dow Global Technologies Inc. | Reactively-coupled articles and related methods |
US20080247975A1 (en) * | 2007-04-05 | 2008-10-09 | Dueva-Koganov Olga V | Sunscreen and personal care compositions comprising a select copolymer |
WO2008145595A1 (en) * | 2007-06-01 | 2008-12-04 | Basf Se | Modified printable surfaces |
EP2235146B1 (en) * | 2007-12-18 | 2016-04-20 | Basf Se | Biodiesel cold flow improver |
US8097045B2 (en) | 2008-01-17 | 2012-01-17 | Basf Se | Polymeric hair dyes |
WO2011068596A2 (en) | 2009-12-01 | 2011-06-09 | Silberline Manufacturing Company, Inc. | Polymer encapsulated aluminum particulates |
WO2011120947A1 (en) | 2010-03-30 | 2011-10-06 | Basf Se | End-functionalized polymers |
US9309391B2 (en) | 2010-06-29 | 2016-04-12 | Basf Se | Process for improving the flow of properties of polymer melts |
US8815982B2 (en) | 2010-07-20 | 2014-08-26 | Silberline Manufacturing Company, Inc. | Colored system |
US8912252B2 (en) | 2010-07-20 | 2014-12-16 | Silberline Manufacturing Company, Inc. | Film-forming pigments and coating system including the same |
US9051478B2 (en) | 2010-07-22 | 2015-06-09 | Basf Se | Additive combination for sealants applications |
BR112014009967A8 (pt) | 2011-10-25 | 2017-12-19 | Henkel Ag & Co Kgaa | Uso de um ou mais copolímeros em pente ou em bloco, método para evitar redeposição de sujeira sobre têxteis e para liberação de sujeira dos têxteis durante um processo aquoso de lavagem de roupas, e, composições detergentes |
US9587105B2 (en) | 2012-02-23 | 2017-03-07 | Basf Se | Fluorinated acrylate block copolymers with low dynamic surface tension |
CN103073695B (zh) * | 2012-12-27 | 2015-03-11 | 中山大学 | 一种本征型室温自修复结晶性聚合物 |
US9790452B2 (en) | 2013-03-27 | 2017-10-17 | Basf Se | Block copolymers as soil release agents in laundry processes |
AU2014288890B9 (en) | 2013-07-08 | 2018-05-10 | Basf Se | Novel light stabilizers |
KR101595087B1 (ko) * | 2015-09-23 | 2016-02-18 | 주식회사 엘림산업 | 피혁용 버핑머신 구동롤러 |
KR101595084B1 (ko) * | 2015-09-23 | 2016-02-29 | 주식회사 엘림산업 | 피혁용 버핑머신 |
KR101635582B1 (ko) * | 2015-10-02 | 2016-07-20 | (주)이미인 | 원단 유연화 장치 |
EP3700988B1 (en) | 2017-10-23 | 2021-08-18 | Basf Se | Aqueous silicone polymer emulsion |
EP4251665A1 (en) | 2020-11-30 | 2023-10-04 | Basf Se | Process of producing polymer dispersions |
US20240182746A1 (en) | 2021-03-26 | 2024-06-06 | Basf Se | Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1173290A (en) * | 1966-08-24 | 1969-12-03 | Sankyo Co | Piperidine Nitroxides and process for preparing the same |
JPS4940557B1 (it) * | 1969-03-06 | 1974-11-02 | ||
US3975357A (en) | 1973-04-19 | 1976-08-17 | Sankyo Company Limited | Stabilized synthetic polymer compositions |
JPS5848580B2 (ja) * | 1975-05-28 | 1983-10-29 | 三共株式会社 | ゴウセイコウブンシザイリヨウヨウアンテイザイ |
GB1478261A (en) * | 1975-05-28 | 1977-06-29 | Ciba Geigy Ag | Derivatives of 4-oxopiperidines |
GB1496844A (en) * | 1975-05-28 | 1978-01-05 | Ciba Geigy Ag | Stabilization of polymers |
GB1492494A (en) * | 1975-05-28 | 1977-11-23 | Sankyo Co | Derivatives of 4-aminopiperidine |
GB1493996A (en) * | 1975-05-28 | 1977-12-07 | Sankyo Co | 4-siloxy derivatives of polyalkylated piperidines |
US4141883A (en) | 1975-05-28 | 1979-02-27 | Sankyo Company, Limited | Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives |
KR930000892B1 (ko) * | 1983-07-11 | 1993-02-11 | 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 | 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법 |
JPS6089452A (ja) * | 1983-07-11 | 1985-05-20 | コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン | 遊離基重合開始用化合物 |
AU571240B2 (en) * | 1983-07-11 | 1988-04-14 | Commonwealth Scientific And Industrial Research Organisation | Alkoxy-amines, useful as initiators |
EP0155912A3 (de) * | 1984-03-20 | 1986-06-04 | Ciba-Geigy Ag | Strahlenstabilisierte polymere Zusammensetzungen |
US5185448A (en) | 1991-05-07 | 1993-02-09 | Ciba-Geigy Corporation | Substituted 1-oxy-4-acyloxypiperidine and 1-oxy-4-acylaminopiperidine stabilizers |
TW270131B (it) * | 1993-07-13 | 1996-02-11 | Ciba Geigy | |
EP0638617A1 (de) | 1993-08-13 | 1995-02-15 | Ciba-Geigy Ag | Pigmentsalze |
US5608023A (en) | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
TW358820B (en) | 1995-04-11 | 1999-05-21 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
EP0792911A3 (en) | 1996-02-27 | 1998-01-14 | Fmc Corporation | Flame resistant polyolefin compositions |
DE69701517T2 (de) * | 1996-03-29 | 2000-11-09 | The Dow Chemical Co., Midland | In situ blockcopolymerbildung während der polymerisation eines vinylaromatischen monomers |
TW467931B (en) | 1996-08-22 | 2001-12-11 | Ciba Sc Holding Ag | Stabilizer mixtures |
WO1998013392A1 (en) | 1996-09-25 | 1998-04-02 | Akzo Nobel N.V. | No-compounds for pseudo-living radical polymerization |
JP2001508485A (ja) | 1997-01-10 | 2001-06-26 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリマーの分子量および構造の制御方法 |
US6281311B1 (en) | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
DE69812633T2 (de) * | 1997-07-15 | 2003-10-23 | Ciba Speciality Chemicals Holding Inc., Basel | Von nitrone- oder nitroso-verbindungen abgeleitete alkoxyaminverbindungen-enthaltende polymerisierbare zusammensetzungen |
SG74700A1 (en) | 1998-02-25 | 2000-08-22 | Ciba Sc Holding Ag | Preparation of sterically hindered amine ethers |
CH693416A5 (de) * | 1998-03-09 | 2003-07-31 | Ciba Sc Holding Ag | 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler. |
TW495515B (en) * | 1998-03-09 | 2002-07-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives, a polymerizable composition containing the same and a process for polymerization |
CA2341372A1 (en) * | 1998-09-03 | 2000-03-16 | Ciba Specialty Chemicals Holding Inc. | Grafting of ethylenically unsaturated monomers onto polymers |
TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
-
1999
- 1999-03-02 CH CH00379/99A patent/CH693416A5/de not_active IP Right Cessation
- 1999-03-02 SG SG9901047A patent/SG82601A1/en unknown
- 1999-03-04 US US09/262,804 patent/US6353107B1/en not_active Expired - Lifetime
- 1999-03-04 BE BE9900152A patent/BE1012399A3/fr not_active IP Right Cessation
- 1999-03-05 CA CA002264460A patent/CA2264460A1/en not_active Abandoned
- 1999-03-05 DE DE1999109767 patent/DE19909767B4/de not_active Expired - Lifetime
- 1999-03-05 CZ CZ99789A patent/CZ78999A3/cs unknown
- 1999-03-05 IT IT1999MI000453A patent/IT1309590B1/it active
- 1999-03-08 ES ES009900470A patent/ES2155014B1/es not_active Expired - Fee Related
- 1999-03-08 GB GB9905152A patent/GB2335190B/en not_active Expired - Lifetime
- 1999-03-08 CN CNB991020987A patent/CN1171871C/zh not_active Expired - Lifetime
- 1999-03-08 AT AT0038799A patent/AT408655B/de not_active IP Right Cessation
- 1999-03-08 AU AU18636/99A patent/AU754927B2/en not_active Ceased
- 1999-03-08 FR FR9902814A patent/FR2777892B1/fr not_active Expired - Lifetime
- 1999-03-08 JP JP06019899A patent/JP4651137B2/ja not_active Expired - Lifetime
- 1999-03-09 NL NL1011493A patent/NL1011493C2/nl not_active IP Right Cessation
- 1999-03-09 BR BRPI9900977-3B1A patent/BR9900977B1/pt active IP Right Grant
- 1999-03-09 KR KR1019990007738A patent/KR100581654B1/ko not_active IP Right Cessation
-
2001
- 2001-12-11 US US10/013,884 patent/US6683142B2/en not_active Expired - Lifetime
-
2003
- 2003-04-24 US US10/422,497 patent/US6927295B2/en not_active Expired - Lifetime
-
2005
- 2005-01-14 US US11/035,915 patent/US7402639B2/en not_active Expired - Fee Related
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