IT1264697B1 - Elettrolita polimerico solido costituito da un polietere reticolato inglobante un composto ionico ed un plastificante liquido - Google Patents
Elettrolita polimerico solido costituito da un polietere reticolato inglobante un composto ionico ed un plastificante liquidoInfo
- Publication number
- IT1264697B1 IT1264697B1 IT93MI001488A ITMI931488A IT1264697B1 IT 1264697 B1 IT1264697 B1 IT 1264697B1 IT 93MI001488 A IT93MI001488 A IT 93MI001488A IT MI931488 A ITMI931488 A IT MI931488A IT 1264697 B1 IT1264697 B1 IT 1264697B1
- Authority
- IT
- Italy
- Prior art keywords
- plasticizer
- copolymer
- allyl
- solid polymeric
- polymeric electrolyte
- Prior art date
Links
- 239000004014 plasticizer Substances 0.000 title abstract 4
- 239000007787 solid Substances 0.000 title abstract 4
- -1 ION COMPOUND Chemical class 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 title abstract 2
- 239000005518 polymer electrolyte Substances 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 4
- 239000003792 electrolyte Substances 0.000 abstract 3
- 238000004132 cross linking Methods 0.000 abstract 2
- 150000008040 ionic compounds Chemical class 0.000 abstract 2
- 239000012528 membrane Substances 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- ZXABMDQSAABDMG-UHFFFAOYSA-N 3-ethenoxyprop-1-ene Chemical compound C=CCOC=C ZXABMDQSAABDMG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004971 Cross linker Substances 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical compound C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 abstract 1
- ITAHRPSKCCPKOK-UHFFFAOYSA-N ethyl trimethyl silicate Chemical group CCO[Si](OC)(OC)OC ITAHRPSKCCPKOK-UHFFFAOYSA-N 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
- G01N27/4045—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors for gases other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Analytical Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Pathology (AREA)
- General Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Immunology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Conductive Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Silicon Polymers (AREA)
- Secondary Cells (AREA)
- Fuel Cell (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyethers (AREA)
Abstract
Un elettrolita polimerico solido, in forma di membrana, costituito da una soluzione di un composto ionico in un polietere reticolato inglobante un plastificante liquido, viene ottenuto:a) copolimerizzando un vinil etere di formula:R-(O-CH2-CH-)n -O-CH=CH2 (I)dove: R indica il radicale metile o etile;n è un numero intero variabile da 1 a 16con un allil vinil etere di formula:CH2=CH-CH2-(O-CH2-CH2-)m -O-CH=CH2 (II)dove: m è un numero intero variabile da 1 a 10,con un rapporto molare tra (I) e (II) compreso tra 70/30 e 95/5, per ottenere un copolimero dotato di insaturazioni alliliche;b) idrosililando il doppio legame allilico del copolimero ottenuto nello stadio (a) per reazione con un alcossi silano scelto tra trimetossi e trietossi silano, per ottenere un copolimero idrosililato;c) reticolando il copolimero idrosililato ottenuto nello stadio (b) per mezzo di un reticolante diprotico, operando in soluzione in un plastificante, scelto tra un oligomero o un solvente dipolare aprotico in quantità da 20 a 80% in peso, in presenza di un composto ionico ed evaporando i composti bassobollenti formatisi nella reazione di reticolazione per ottenere una membrana in grado di tenere inglobato il plastificante.Detto elettrolita polimerico solido è meccanicamente resistente, dimensionalmente stabile e altamente conduttore anche a basse temperature. L'elettrolita polimerico solido può essere utilizzato quale separatore elettrolitico in dispositivi elettrochimici, in display ottici ed in sensori.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001488A IT1264697B1 (it) | 1993-07-09 | 1993-07-09 | Elettrolita polimerico solido costituito da un polietere reticolato inglobante un composto ionico ed un plastificante liquido |
US08/267,521 US5501920A (en) | 1993-07-09 | 1994-06-29 | Solid polymeric electrolyte including a cross-linked polyether encompassing an ion compound and a liquid plasticizer |
ES94201904T ES2132323T3 (es) | 1993-07-09 | 1994-07-01 | Electrolito polimerico solido que incluye un polieter reticulado que abarca un compuesto ionico y un plastificante liquido. |
SI9430254T SI0633578T1 (en) | 1993-07-09 | 1994-07-01 | Solid polymeric electrolyte including a cross-linked polyether encompassing an ionic compound and a liquid plasticizer |
AT94201904T ATE179545T1 (de) | 1993-07-09 | 1994-07-01 | Fester polymerelektrolyte mit in vernetztem polyether verlegter ionen-verbindung und flüssigem weichmacher |
DK94201904T DK0633578T3 (da) | 1993-07-09 | 1994-07-01 | Fast polymerelektrolyt inkluderende en tværbundet polyether omfattende en ionforbindelse og et flydende blødgøringsmiddel |
EP94201904A EP0633578B1 (en) | 1993-07-09 | 1994-07-01 | Solid polymeric electrolyte including a cross-linked polyether encompassing an ionic compound and a liquid plasticizer |
DE69418104T DE69418104T2 (de) | 1993-07-09 | 1994-07-01 | Fester Polymerelektrolyte mit in vernetztem Polyether verlegter Ionen-Verbindung und flüssigem Weichmacher |
JP6176200A JPH0729413A (ja) | 1993-07-09 | 1994-07-06 | 固体高分子電解質 |
GR990401488T GR3030394T3 (en) | 1993-07-09 | 1999-06-02 | Solid polymeric electrolyte including a cross-linked polyether encompassing an ion compound and a liquid plasticizer. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT93MI001488A IT1264697B1 (it) | 1993-07-09 | 1993-07-09 | Elettrolita polimerico solido costituito da un polietere reticolato inglobante un composto ionico ed un plastificante liquido |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI931488A0 ITMI931488A0 (it) | 1993-07-09 |
ITMI931488A1 ITMI931488A1 (it) | 1995-01-09 |
IT1264697B1 true IT1264697B1 (it) | 1996-10-04 |
Family
ID=11366562
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT93MI001488A IT1264697B1 (it) | 1993-07-09 | 1993-07-09 | Elettrolita polimerico solido costituito da un polietere reticolato inglobante un composto ionico ed un plastificante liquido |
Country Status (10)
Country | Link |
---|---|
US (1) | US5501920A (it) |
EP (1) | EP0633578B1 (it) |
JP (1) | JPH0729413A (it) |
AT (1) | ATE179545T1 (it) |
DE (1) | DE69418104T2 (it) |
DK (1) | DK0633578T3 (it) |
ES (1) | ES2132323T3 (it) |
GR (1) | GR3030394T3 (it) |
IT (1) | IT1264697B1 (it) |
SI (1) | SI0633578T1 (it) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1276151B1 (it) * | 1995-11-17 | 1997-10-27 | Eniricerche Spa | Membrana elettrolitica e procedimento per la sua foto-reticolazione su membrana catodica |
US5964903A (en) * | 1997-04-23 | 1999-10-12 | Valence Technology, Inc. | Method of preparing electrochemical cells |
EP1693390B1 (fr) | 1998-06-25 | 2010-10-13 | Hydro-Quebec | Polymères à base de monomères polymérisables en séquences et leur utilisation dans la production de conducteurs ioniques. |
US7101643B2 (en) * | 2001-05-31 | 2006-09-05 | The Regents Of The University Of California | Polymeric electrolytes based on hydrosilyation reactions |
US6956083B2 (en) * | 2001-05-31 | 2005-10-18 | The Regents Of The University Of California | Single ion conductor cross-linked polymeric networks |
JP4990624B2 (ja) * | 2003-05-28 | 2012-08-01 | トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ,インコーポレイティド | アルキルオキシシラングラフト化熱可塑性ポリマーに基づくハイブリッド無機−有機ポリマー電解質膜(pem) |
JP4599909B2 (ja) | 2004-06-30 | 2010-12-15 | 日立工機株式会社 | 卓上丸鋸 |
CN102623686B (zh) | 2007-06-22 | 2014-10-08 | 松下电器产业株式会社 | 全固体型聚合物电池 |
JP6885780B2 (ja) * | 2017-05-10 | 2021-06-16 | トヨタ自動車株式会社 | 固体高分子電解質膜 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1222929B (it) * | 1987-10-16 | 1990-09-12 | Enirecherche S P A | Elettrolita polimerico solido e generatori elettrochimici che lo contengono |
US5138013A (en) * | 1990-12-17 | 1992-08-11 | Ford Motor Company | Epoxy curable ion-conducting electrolyte useful in electrochromic devices |
IT1244483B (it) * | 1990-12-21 | 1994-07-15 | Eniricerche Spa | Elettrolita polimerico solido a base di poliviniletere reticolato |
EP0499115B1 (de) * | 1991-02-09 | 1996-05-01 | Dornier Gmbh | Polymerer Festelektrolyt |
IT1254491B (it) * | 1992-03-04 | 1995-09-25 | Eniricerche Spa | Procedimento per la preparazione di un elettrolita polimerico solido abase di polivinileteri |
IT1254941B (it) * | 1992-04-28 | 1995-10-11 | Eniricerche Spa | Elettrolita polimerico solido a base polieterea |
-
1993
- 1993-07-09 IT IT93MI001488A patent/IT1264697B1/it active IP Right Grant
-
1994
- 1994-06-29 US US08/267,521 patent/US5501920A/en not_active Expired - Fee Related
- 1994-07-01 ES ES94201904T patent/ES2132323T3/es not_active Expired - Lifetime
- 1994-07-01 DK DK94201904T patent/DK0633578T3/da active
- 1994-07-01 EP EP94201904A patent/EP0633578B1/en not_active Expired - Lifetime
- 1994-07-01 SI SI9430254T patent/SI0633578T1/xx unknown
- 1994-07-01 DE DE69418104T patent/DE69418104T2/de not_active Expired - Fee Related
- 1994-07-01 AT AT94201904T patent/ATE179545T1/de not_active IP Right Cessation
- 1994-07-06 JP JP6176200A patent/JPH0729413A/ja active Pending
-
1999
- 1999-06-02 GR GR990401488T patent/GR3030394T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
US5501920A (en) | 1996-03-26 |
GR3030394T3 (en) | 1999-09-30 |
DK0633578T3 (da) | 1999-11-08 |
EP0633578A2 (en) | 1995-01-11 |
SI0633578T1 (en) | 1999-08-31 |
DE69418104D1 (de) | 1999-06-02 |
JPH0729413A (ja) | 1995-01-31 |
ATE179545T1 (de) | 1999-05-15 |
EP0633578A3 (en) | 1995-06-14 |
DE69418104T2 (de) | 1999-10-14 |
ITMI931488A0 (it) | 1993-07-09 |
ITMI931488A1 (it) | 1995-01-09 |
ES2132323T3 (es) | 1999-08-16 |
EP0633578B1 (en) | 1999-04-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970710 |