IN2014MN01013A - - Google Patents

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Publication number
IN2014MN01013A
IN2014MN01013A IN1013MUN2014A IN2014MN01013A IN 2014MN01013 A IN2014MN01013 A IN 2014MN01013A IN 1013MUN2014 A IN1013MUN2014 A IN 1013MUN2014A IN 2014MN01013 A IN2014MN01013 A IN 2014MN01013A
Authority
IN
India
Prior art keywords
dialkyl
reaction
tetrahydrofuran
stage
butanediol
Prior art date
Application number
Inventor
Flavio Simola
Marco Scarsella
Filippis Paolo De
Original Assignee
Conser Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Conser Spa filed Critical Conser Spa
Publication of IN2014MN01013A publication Critical patent/IN2014MN01013A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C07D307/08—Preparation of tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/20—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form

Abstract

A process is described for the production of 1 4 butanediol and tetrahydrofuran by catalytic hydrogenation of dialkyl maleates. The process consists essentially in the following steps: a) hydrogenating a stream of dialkyl maleate in a first stage of reaction over suitable catalysts to produce dialkyl succinate; b) further hydrogenating the dialkyl succinate in a second stage of reaction by using a different suitable catalyst for producing mainly 1 4 butanediol together with gamma butyrolactone and tetrahydrofuran as co products. In both stages of reaction the conditions as hydrogen/ organic feed ratio pressure and temperature are such to maintain the reactors in mixed liquid/vapor phase.
IN1013MUN2014 2011-11-25 2011-11-25 IN2014MN01013A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IT2011/000387 WO2013076747A1 (en) 2011-11-25 2011-11-25 Process for producing 1,4- butanediol by hydrogenating dialkyl maleate in mixed liquid/vapor phase

Publications (1)

Publication Number Publication Date
IN2014MN01013A true IN2014MN01013A (en) 2015-07-03

Family

ID=45498081

Family Applications (1)

Application Number Title Priority Date Filing Date
IN1013MUN2014 IN2014MN01013A (en) 2011-11-25 2011-11-25

Country Status (5)

Country Link
US (1) US9040756B2 (en)
EP (1) EP2782893B1 (en)
CN (1) CN103946201B (en)
IN (1) IN2014MN01013A (en)
WO (1) WO2013076747A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201507234D0 (en) * 2015-04-28 2015-06-10 Johnson Matthey Davy Technologies Ltd Process
CN107537516B (en) * 2016-06-28 2020-05-12 中国石油化工股份有限公司 Catalyst for preparing sec-butyl alcohol and preparation method thereof
GB201615385D0 (en) * 2016-09-09 2016-10-26 Intensichem Group Ltd Hydrogenation process
CN109201056B (en) * 2017-06-30 2021-07-09 中国石油化工股份有限公司 Catalyst for preparing 1, 4-butanediol from dimethyl maleate
US11306039B1 (en) * 2018-06-05 2022-04-19 Triad National Security, Llc System and method for making fuels
CN110218152B (en) * 2019-05-10 2021-08-13 中国科学技术大学 Process for the preparation of 1, 4-butanediol and its dicarboxylic acid esters
CN112279824A (en) * 2020-11-02 2021-01-29 山东长信化学科技股份有限公司 Dehydrogenation reaction system
WO2022190141A1 (en) * 2021-03-12 2022-09-15 Conser S.P.A. Process for the co-production of dialkyl succinate and 1,4-butanediol by hydrogenating dialkyl maleate in two stages.
CN113277996B (en) * 2021-06-03 2023-01-17 上海贯新科技有限公司 Method for flexibly producing tetrahydrofuran and gamma-butyrolactone
CN113512183A (en) * 2021-08-10 2021-10-19 山东海成石化工程设计有限公司 Continuous production method of poly (butylene succinate)
CN113731442B (en) * 2021-08-20 2024-02-02 河南省生物基材料产业研究院有限公司 Catalyst for dimethyl maleate hydrogenation reaction and preparation method and application thereof
KR20230113696A (en) 2022-01-21 2023-08-01 대상 주식회사 1,4-Butanediol producing microorganism and method for producing 1,4-butanediol using the same
GB202203264D0 (en) 2022-03-09 2022-04-20 Johnson Matthey Davy Technologies Ltd Process for producing a refined 1,4-butanediol stream

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US2110488A (en) 1934-02-16 1938-03-08 Justement Louis Building construction
US4032458A (en) 1975-08-08 1977-06-28 Petro-Tex Chemical Corporation Production of 1,4-butanediol
US4172961A (en) 1975-08-08 1979-10-30 Denka Chemical Corporation Production of 1,4-butanediol
IT1190783B (en) 1981-04-29 1988-02-24 Davy Mckee Oil & Chem PROCESS FOR HYDROGENOLYSIS OF ESTERS OF CARBOXYLIC ACIDS
GB8331793D0 (en) 1983-11-29 1984-01-04 Davy Mckee Ltd Process
GB8514002D0 (en) 1985-06-04 1985-07-10 Davy Mckee Ltd Process
US4656297A (en) 1985-03-11 1987-04-07 Amoco Corporation Coproduction of butanediol and tetrahydrofuran and their subsequent separation from the reaction product mixture
ZA972614B (en) 1996-03-29 1997-12-22 Kvaerner Process Tech Ltd Process for the production of butane-1,4-diol.
ZA973972B (en) 1996-05-14 1998-03-23 Kvaerner Process Tech Ltd A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran.
DE19648761A1 (en) * 1996-11-25 1998-05-28 Bayer Ag Process for the preparation of succinic acid dialkyl esters
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BE1011698A6 (en) 1998-01-08 1999-12-07 Pantochim Sa Method for producing tetrahydrofuran, gamma-butyrolactone and butanediol.
BE1012342A6 (en) * 1998-01-08 2000-10-03 Pantochim Sa Method for producing butanediol by liquid phase hydrogenation.
BE1011699A6 (en) 1998-01-08 1999-12-07 Pantochim Sa Method for producing and gamma-tetrahydrofuran butyrolactone.
EP0962438B1 (en) 1998-03-23 2001-06-06 Basf Aktiengesellschaft Process for the preparation of 1,4-butanediol, butyrolactone and tetrahydrofuran.
BE1011870A6 (en) 1998-04-09 2000-02-01 Pantochim Sa Butanediol production process.
DE19818340A1 (en) 1998-04-23 1999-10-28 Basf Ag Production of butan-1,4-diol, tetrahydrofuran and gamma-butyrolactone
DE19818248A1 (en) * 1998-04-23 1999-10-28 Basf Ag Production of highly pure butan-1,4-diol, useful for producing polyesters, gamma-butyrolactone and tetrahydrofuran
BE1012274A7 (en) 1998-11-10 2000-08-01 Pantochim Sa High productivity process for the preparation of gamma and tetrahydrofuran butyrolactone.
MY139259A (en) 1999-10-12 2009-09-30 Kvaerner Process Tech Ltd Process
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GB0117090D0 (en) 2001-07-12 2001-09-05 Kvaerner Process Tech Ltd Process
GB0329152D0 (en) 2003-12-16 2004-01-21 Davy Process Techn Ltd Process
GB0421928D0 (en) 2004-10-01 2004-11-03 Davy Process Techn Ltd Process
CN101307042B (en) 2007-05-18 2011-04-20 中国石油化工股份有限公司 Method for producing 1,4-butanediol and coproducing tetrahydrofuran, and gamma-butyrolactone
CN101747149B (en) 2008-12-11 2013-02-20 浙江杭州鑫富药业股份有限公司 Method for preparing 1,4-butanediol by two-section hydrogenation of maleic acid dialkyl ester
CN101891592B (en) * 2010-08-12 2013-03-13 湖南长岭石化科技开发有限公司 Method for preparing 1,4-butanediol and co-producing tetrahydrofuran and gamma-butyrolactone

Also Published As

Publication number Publication date
WO2013076747A1 (en) 2013-05-30
US20140316146A1 (en) 2014-10-23
EP2782893A1 (en) 2014-10-01
US9040756B2 (en) 2015-05-26
CN103946201A (en) 2014-07-23
CN103946201B (en) 2017-03-08
EP2782893B1 (en) 2017-08-23

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