IN2014DN10414A - - Google Patents

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Publication number
IN2014DN10414A
IN2014DN10414A IN10414DEN2014A IN2014DN10414A IN 2014DN10414 A IN2014DN10414 A IN 2014DN10414A IN 10414DEN2014 A IN10414DEN2014 A IN 10414DEN2014A IN 2014DN10414 A IN2014DN10414 A IN 2014DN10414A
Authority
IN
India
Prior art keywords
catalyst
mol
polyethylene
average molecular
product
Prior art date
Application number
Inventor
Matthew James Overett
Elzet Grobler
Stephen John Evans
Kevin Blann
Original Assignee
Sasol Tech Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd filed Critical Sasol Tech Pty Ltd
Publication of IN2014DN10414A publication Critical patent/IN2014DN10414A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/10—Non-coordinating groups comprising only oxygen beside carbon or hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/20—Non-coordinating groups comprising halogens
    • B01J2540/22—Non-coordinating groups comprising halogens comprising fluorine, e.g. trifluoroacetate
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyethers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A process for the tetramerisation of ethylene under solution phase conditions is carried out in the presence of an activated catalyst at a temperature above 80° C and up to a temperature of about 115°C. The activated catalyst is provided by combining a source of chromium a diphosphine ligating compound and optionally a catalyst activator or combination of catalyst activators. The process forms at least 30% 1 octene and a polyethylene co product that together with any other reaction products remains substantially dissolved in the liquid phase. The polyethylene co product has a weight average molecular weight (Mw) of less than 200 000 g/mol a number average molecular weight (Mn) of less than 3 000 g/mol and a melt flow index of more than 20 g/10 minutes.
IN10414DEN2014 2012-05-09 2013-05-08 IN2014DN10414A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261644744P 2012-05-09 2012-05-09
PCT/IB2013/053691 WO2013168102A1 (en) 2012-05-09 2013-05-08 Tetramerisation of ethylene

Publications (1)

Publication Number Publication Date
IN2014DN10414A true IN2014DN10414A (en) 2015-08-14

Family

ID=48699873

Family Applications (1)

Application Number Title Priority Date Filing Date
IN10414DEN2014 IN2014DN10414A (en) 2012-05-09 2013-05-08

Country Status (13)

Country Link
US (1) US9499456B2 (en)
EP (1) EP2847148B1 (en)
KR (1) KR102102347B1 (en)
CN (2) CN104245640B (en)
BR (1) BR112014027792B1 (en)
CA (1) CA2867667C (en)
ES (1) ES2656088T3 (en)
IN (1) IN2014DN10414A (en)
MX (1) MX2014011729A (en)
MY (1) MY164873A (en)
SG (1) SG11201407130XA (en)
WO (1) WO2013168102A1 (en)
ZA (1) ZA201406074B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102138685B1 (en) * 2012-05-09 2020-07-29 사솔 테크날러지 (프로프라이어터리) 리미티드 Tetramerisation of ethylene
KR101657259B1 (en) 2013-11-19 2016-09-13 주식회사 엘지화학 Ligand compound, catalyst system for olefin oligomerization, and method for olefin oligomerization using the same
KR101679515B1 (en) * 2015-02-12 2016-11-24 주식회사 엘지화학 Method of preparing catalyst system for oligomerization and catalyst sysyem for oligomerization prepared thereby
EP3268129A2 (en) 2015-03-13 2018-01-17 Dow Global Technologies LLC Olefin oligomerisation process with a catalyst comprising a chromium complex with a phosphacycle-containing ligand
CN105344381B (en) * 2015-11-11 2018-02-13 天津科技大学 A kind of double-core chrome catalysts for ethylene oligomerization and preparation method thereof
FR3051683B1 (en) 2016-05-31 2020-10-09 Ifp Energies Now CATALYTIC COMPOSITION BASED ON CHROME AND A LIGAND BASED ON PHOSPHINE AND ITS USE IN A PROCESS FOR PROCESSING OCTENS
EP3484839B1 (en) 2016-07-15 2020-12-30 Public Joint Stock Company "Sibur Holding" Method of oligomerization of olefins
CN113597419A (en) 2019-03-13 2021-11-02 Tpc集团有限责任公司 Elastomeric manufacturing system for selectively producing different linear alpha-olefins
CN113731505B (en) * 2021-09-13 2024-05-03 万华化学集团股份有限公司 Ethylene oligomerization catalyst system and application
CN114014895A (en) * 2021-10-26 2022-02-08 浙江大学 Ferrocenyl phosphine ligand compound and synthesis method thereof

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Also Published As

Publication number Publication date
BR112014027792A2 (en) 2017-07-18
US20150080629A1 (en) 2015-03-19
CN104245640B (en) 2017-10-27
MX2014011729A (en) 2015-01-20
EP2847148B1 (en) 2017-11-15
ZA201406074B (en) 2015-11-25
CN107652153A (en) 2018-02-02
EP2847148A1 (en) 2015-03-18
CN107652153B (en) 2020-06-16
WO2013168102A1 (en) 2013-11-14
KR20150017724A (en) 2015-02-17
CN104245640A (en) 2014-12-24
SG11201407130XA (en) 2014-11-27
ES2656088T3 (en) 2018-02-23
BR112014027792B1 (en) 2020-03-24
CA2867667A1 (en) 2013-11-14
MY164873A (en) 2018-01-30
CA2867667C (en) 2021-05-25
US9499456B2 (en) 2016-11-22
KR102102347B1 (en) 2020-04-21

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