IL96681A - Substituted (1 2 4-triazol-1-yl)-and (imidazol-1-yl)methyl)- cycloalkanols their preparation and fungicidal and plant-growth regulating compositions comprising them - Google Patents

Substituted (1 2 4-triazol-1-yl)-and (imidazol-1-yl)methyl)- cycloalkanols their preparation and fungicidal and plant-growth regulating compositions comprising them

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Publication number
IL96681A
IL96681A IL9668190A IL9668190A IL96681A IL 96681 A IL96681 A IL 96681A IL 9668190 A IL9668190 A IL 9668190A IL 9668190 A IL9668190 A IL 9668190A IL 96681 A IL96681 A IL 96681A
Authority
IL
Israel
Prior art keywords
represent
image
substituted
alkyl
hydrogen
Prior art date
Application number
IL9668190A
Other versions
IL96681A0 (en
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE3941593A external-priority patent/DE3941593A1/en
Priority claimed from DE4020432A external-priority patent/DE4020432A1/en
Priority claimed from DE4022784A external-priority patent/DE4022784A1/en
Priority claimed from DE4029197A external-priority patent/DE4029197A1/en
Application filed by Basf Ag filed Critical Basf Ag
Publication of IL96681A0 publication Critical patent/IL96681A0/en
Publication of IL96681A publication Critical patent/IL96681A/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C07D233/60—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with hydrocarbon radicals, substituted by oxygen or sulfur atoms, attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/34—Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/08—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing alicyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/08—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing alicyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
    • C07D407/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings
    • C07D407/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
    • C07D407/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings
    • C07D407/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/10—Spiro-condensed systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Epoxy Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Steroid Compounds (AREA)

Abstract

Azolylmethylcycloalkanols of the general formula I <IMAGE> in which R<1> and R<5> are identical or different and represent hydrogen or alkyl; R<1> and R<5> together represent <IMAGE> or <IMAGE> where Z is CH2, O, S, SO, SO2 or N-R<8>; R<7> represents alkyl, phenyl, biphenyl, naphthyl, heteroaryl, benzyl or cycloalkyl, it being possible for each of these radicals to be substituted, and also tetrahydropyranyl; R<2> and R<3> in each case represent a hydrogen atom or an alkyl group; or in the event that R<1> and R<5> represent a <IMAGE> together and additionally represent =CH-R<7>; R<4> and R<8> represent hydrogen or alkyl; or R<3> and R<4> together with the carbon atoms of which they are substituents represent a saturated or unsaturated 5- or 6-membered carbocyclic ring or R<2>, R<3>, R<4> and R<9> together with the carbon atoms of which they are substituents represent an optionally halogen-substituted phenyl ring or in the event that R<1> and R<5> are a <IMAGE> R<2> and R<3> together can additionally represent =CH-R<7>, R<6>, R<9> to R<12> are hydrogen, alkyl, phenyl, biphenyl, naphthyl, heteroaryl, benzyl, dioxolanyl or cycloalkyl, it being possible for each of these radicals to be substituted; T represents the radical (CH2)n = CR<11>, R<12> O or S, n is an integer from 1 to 5, with the proviso that R<1> to R<12> do not simultaneously represent hydrogen, and with the proviso that R<1> and R<5> together do not represent <IMAGE> when R<2> to R<4> and R<6> to R<12> represent hydrogen, and X represents the radical CH or N, and their acid addition salts and metal complexes which are tolerated by plants, and the fungicides and growth regulators containing these compounds.
IL9668190A 1989-12-16 1990-12-16 Substituted (1 2 4-triazol-1-yl)-and (imidazol-1-yl)methyl)- cycloalkanols their preparation and fungicidal and plant-growth regulating compositions comprising them IL96681A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE3941593A DE3941593A1 (en) 1989-12-16 1989-12-16 Azolyl:methyl:cycloalkanol derivs. - for use as fungicides and growth regulators
DE4020432A DE4020432A1 (en) 1990-06-27 1990-06-27 New azolyl:methyl-substd. cyclic alcohol derivs.
DE4022784A DE4022784A1 (en) 1990-07-18 1990-07-18 New azolyl:methyl-substd. cyclic alcohol derivs.
DE4029197A DE4029197A1 (en) 1990-09-14 1990-09-14 New azolyl:methyl-substd. cyclic alcohol derivs.

Publications (2)

Publication Number Publication Date
IL96681A0 IL96681A0 (en) 1991-09-16
IL96681A true IL96681A (en) 1995-12-08

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ID=27434812

Family Applications (1)

Application Number Title Priority Date Filing Date
IL9668190A IL96681A (en) 1989-12-16 1990-12-16 Substituted (1 2 4-triazol-1-yl)-and (imidazol-1-yl)methyl)- cycloalkanols their preparation and fungicidal and plant-growth regulating compositions comprising them

Country Status (12)

Country Link
EP (1) EP0433780B1 (en)
JP (1) JPH03197464A (en)
KR (1) KR0163185B1 (en)
AT (1) ATE136301T1 (en)
AU (1) AU652926B2 (en)
CA (1) CA2032285A1 (en)
DE (1) DE59010258D1 (en)
DK (1) DK0433780T3 (en)
ES (1) ES2085877T3 (en)
GR (1) GR3019879T3 (en)
HU (1) HU208612B (en)
IL (1) IL96681A (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4034337A1 (en) * 1990-10-29 1992-04-30 Basf Ag AZOLYL METHYLCYCLOHEXANOLS AND FUNGICIDES CONTAINING THEM
EP0524439A1 (en) * 1991-07-24 1993-01-27 F.Hoffmann-La Roche & Co. Aktiengesellschaft Novel cyclohexane and tetrahydropyran derivatives and antifungal compositions containing these derivatives
US5449785A (en) * 1991-07-24 1995-09-12 Hoffmann-La Roche Inc. Cyclohexane derivatives
US5489597A (en) * 1992-02-15 1996-02-06 Kureha Chemical Industry Co., Ltd. Azole derivative and pharmaceutical composition
US5547973A (en) * 1992-02-15 1996-08-20 Kureha Chemical Industry Co., Ltd. Method of inhibiting aromatase
US5571831A (en) * 1992-02-15 1996-11-05 Kureha Chemical Industry Co., Ltd. Imidazole derivative, and pharmaceutical composition
FR2690441A1 (en) * 1992-04-08 1993-10-29 Rhone Poulenc Agrochimie New triazole derivatives and imidazole fungicides.
FR2704388B1 (en) * 1993-04-27 1995-06-09 Rhone Poulenc Agrochimie PROCESS FOR IMPROVING THE VIGOR AND OR THE HEALTH OF PLANTS SUCH AS CEREALS BY ACTION OF A TRIAZOLE DERIVATIVE.
DE4425948A1 (en) * 1994-07-21 1996-01-25 Bayer Ag Azolylmethyl-substituted cycloalkanols or microbicides
DE4425949A1 (en) * 1994-07-21 1996-01-25 Bayer Ag Azolylmethylcyclopentanol derivatives as microbicides
US5506250A (en) * 1994-11-14 1996-04-09 Rhone-Poulenc Inc. Method of treating turf
DE19520096A1 (en) * 1995-06-01 1996-12-05 Bayer Ag Cycloalkane benzylidene derivatives
ATE469907T1 (en) 2000-10-02 2010-06-15 Univ Emory TRIPTOLIDE ANALOGUES FOR THE TREATMENT OF AUTOIMMUNE DISEASES AND INFLAMMATION
AR076428A1 (en) * 2009-04-24 2011-06-08 Basf Se TRIAZOL COMPOUNDS THAT CARRY A SUBSTITUTE OF Sulfur III
WO2010122167A1 (en) * 2009-04-24 2010-10-28 Basf Se 5 -mercapto- [1, 2, 4] triazolylmethyl-cyclopentanol compounds and their agricultural and pharmaceutical uses
AR076429A1 (en) * 2009-04-24 2011-06-08 Basf Se TRIAZOL COMPOUNDS THAT CARRY A SUBSTITUTE OF SULFUR IV
AR076430A1 (en) * 2009-04-24 2011-06-08 Basf Se DERIVATIVES OF TRIAZOL AS FUNGICIDES IN AGRICULTURAL COMPOSITIONS AND THEIR USE AS ANTIVIRALS AND IN THE TREATMENT OF CANCER AND INTERMEDIARIES TO PRODUCE THEM
AR076427A1 (en) * 2009-04-24 2011-06-08 Basf Se TRIAZOL COMPOUNDS THAT CARRY A SUBSTITUTE OF SULFUR II
WO2014095249A1 (en) 2012-12-19 2014-06-26 Basf Se Fungicidal imidazolyl and triazolyl compounds
EP2746256A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
RU2730490C1 (en) * 2019-11-21 2020-08-24 Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) Substituted 4-(azol-1-ylmethyl)-1,6-bisphenyl-dispiro[2_1_2_3]decan-4-ol, a method for production thereof and a fungicidal composition based thereon

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4414210A (en) * 1979-10-02 1983-11-08 Rohm And Haas Company 2-Hydroxyarylethyltriazole fungicides
FR2472559A1 (en) * 1979-12-31 1981-07-03 Cerm Cent Europ Rech Mauvernay 2-Phenoxy-1-amino-methyl-cyclohexanol derivs. - useful as antidepressants
EP0052425A3 (en) * 1980-11-13 1982-08-11 Imperial Chemical Industries Plc Triazole and imidazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them
DE3617071A1 (en) * 1985-06-05 1986-12-11 Merck Patent Gmbh, 6100 Darmstadt Cyclohexane derivatives
DE3630614A1 (en) * 1986-09-09 1988-03-17 Basf Ag METHOD FOR THE PRODUCTION OF 4-FORMYLTETRAHYDROPYRANS AND NEW 4-FORMYLTETRAHYDROPYRANS
JPH0625140B2 (en) * 1986-11-10 1994-04-06 呉羽化学工業株式会社 Novel azole derivative, method for producing the same and agricultural / horticultural drug of the derivative
JPH0819108B2 (en) * 1986-12-22 1996-02-28 呉羽化学工業株式会社 Novel azole derivative, production method thereof, and agricultural / horticultural fungicide containing the derivative as an active ingredient
JPH0739396B2 (en) * 1988-01-14 1995-05-01 呉羽化学工業株式会社 Novel azole-substituted cycloalkanol derivative, method for producing the same, and use of the derivative as fungicide for agriculture and horticulture
DE68912100T4 (en) * 1988-12-21 1994-10-20 Firmenich & Cie 4,4,5,8-tetramethyl-1-oxaspiro (2.5) octane, process for its preparation and its use as a starting material in the production of 2,2,3,6-tetramethyl-cyclohexane-carboxaldehyde.
MA21706A1 (en) * 1988-12-29 1990-07-01 Rhone Poulenc Agrochimie BENZOLIDENE AZOLYLMETHYLCYCLOALCANE AND USE AS A FUNGICIDE.
DE3902031A1 (en) * 1989-01-25 1990-07-26 Hoechst Ag Substituted azolylmethylcycloalkane derivatives, their preparation and use, and medicaments containing these

Also Published As

Publication number Publication date
AU652926B2 (en) 1994-09-15
HU908283D0 (en) 1991-06-28
EP0433780B1 (en) 1996-04-03
DE59010258D1 (en) 1996-05-09
GR3019879T3 (en) 1996-08-31
HU208612B (en) 1993-12-28
AU6809390A (en) 1991-06-20
ES2085877T3 (en) 1996-06-16
DK0433780T3 (en) 1996-05-13
HUT55956A (en) 1991-07-29
KR910011806A (en) 1991-08-07
IL96681A0 (en) 1991-09-16
CA2032285A1 (en) 1991-06-17
KR0163185B1 (en) 1998-12-01
JPH03197464A (en) 1991-08-28
ATE136301T1 (en) 1996-04-15
EP0433780A1 (en) 1991-06-26

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