IL110338A - Food mixture comprising legume with low fat absorption upon frying - Google Patents

Food mixture comprising legume with low fat absorption upon frying

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Publication number
IL110338A
IL110338A IL11033894A IL11033894A IL110338A IL 110338 A IL110338 A IL 110338A IL 11033894 A IL11033894 A IL 11033894A IL 11033894 A IL11033894 A IL 11033894A IL 110338 A IL110338 A IL 110338A
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IL
Israel
Prior art keywords
food
frying
legume
salt
chick pea
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IL11033894A
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IL110338A0 (en
Inventor
Saguy Israel
Pintus Eli
Wineberg Pnina
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Yissum Res Dev Co
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Publication date
Application filed by Yissum Res Dev Co filed Critical Yissum Res Dev Co
Priority to IL11033894A priority Critical patent/IL110338A/en
Publication of IL110338A0 publication Critical patent/IL110338A0/en
Priority to AU30070/95A priority patent/AU3007095A/en
Priority to EP95926250A priority patent/EP0798969A1/en
Priority to PCT/US1995/008706 priority patent/WO1996002149A1/en
Publication of IL110338A publication Critical patent/IL110338A/en

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Classifications

    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/04Products made from materials other than rye or wheat flour
    • A21D13/045Products made from materials other than rye or wheat flour from leguminous plants
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/04Products made from materials other than rye or wheat flour
    • A21D13/043Products made from materials other than rye or wheat flour from tubers, e.g. manioc or potato
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/40Products characterised by the type, form or use
    • A21D13/44Pancakes or crêpes
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/60Deep-fried products, e.g. doughnuts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L11/00Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
    • A23L11/05Mashed or comminuted pulses or legumes; Products made therefrom
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/10Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops
    • A23L19/12Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops of potatoes
    • A23L19/18Roasted or fried products, e.g. snacks or chips
    • A23L19/19Roasted or fried products, e.g. snacks or chips from powdered or mashed potato products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/117Flakes or other shapes of ready-to-eat type; Semi-finished or partly-finished products therefor
    • A23L7/13Snacks or the like obtained by oil frying of a formed cereal dough
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/157Farinaceous granules for dressing meat, fish or the like
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P20/00Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
    • A23P20/10Coating with edible coatings, e.g. with oils or fats
    • A23P20/12Apparatus or processes for applying powders or particles to foodstuffs, e.g. for breading; Such apparatus combined with means for pre-moistening or battering

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Botany (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • General Preparation And Processing Of Foods (AREA)

Abstract

The invention provides novel foods comprising from 1 % to 10 % by weight of ground legume together with from 0.2 % to 1.5 % of GRAS salt, the balance being conventional food mixtures. Upon frying the foods of the invention the oil uptake is significantly reduced compared with the oil uptake of the conventional food products not containing legume. Chick peas and lentils are the preferred legume of the invention. [WO9602149A1]

Description

Twos flaw. ¾>n iwa» ΤΛ n jop Food Mixture Comprising Legume With Low Fat Absorption Upon Frying YISSUM RESEARC minn OW" OF THE HEBREW Γ)ϋ>ση >ί1Νη Inventors: Israel SAGUY Eli PINTUS Pnina WINEBERG niW Π)">3£) Brief Description of the Invention The invention relates to novel food mixtures. More particularly, the invention concerns food mixtures which upon frying absorb a relatively small amount of oil.
Background of the Invention Fats and oils have a unique universal appeal. As yet, they have not been matched in functionality by any other food component. They offer unique properties that includes flavor and smooth mouthfeel, improving the overall food palatability. Deep-fat frying is a very important process in modern food preparation, utilized widely by both the food industry and consumers. Numerous processed foods are prepared by deep-fat frying. One of the most important quality parameters of those products is the amount of fat absorbed during the frying process. Recent consumers' trend toward healthier foods is creating significant pressure to reduce the amount of fat in the end-products. Despite such market forces, fried food products still contain huge amounts of fat, often reaching in some cases 49% of the total product.
A wide spectrum of factors has been reported to affect oil uptake, including oil quality, frying temperature duration of frying, product shape, its content (e.g., moisture, solids, fat, protein), porosity, pre-frying treatments (e.g., drying, blanching) and coating, as reviewed by Selman and Hopkins, in Tech. Memorandum 475. Campden Food & Drink Res. Assoc. Chipping Campden, Gloucestershire, U.K., 1989. Gel-strength was proved to be another significant factor which affects oil uptake as described in Pinthus et al., 1992 in J. Food Science 57: 1359-60.
Duxbury, D.D. in Food Proc. 50(2):66, 1989 shows that batters and breadings can influence oil absorption. U.S. Patent no. 5,019,409 discloses that the incorporation of long-fiber cellulose into batters or donut mixes reduces oil uptake during deep-fat frying. Also, methocel was found significantly more effective than powdered cellulose in reducing the amount of oil uptake as described by Pintus, E.J., Weinberg, P. and Saguy, I.S. in J. Food Science 58: 204-205,222, 1993.
Initial and final water content has a major impact on the amount of oil uptake during deep-fat frying of foods. As water retention is strongly affected by some food additives, the addition of alginates or cellulose could play a major role in changing the amount of oil uptake and moisture loss during deep-fat frying as explained by Duxbury 1989, ibid.
US Patents nos. 5,021,248, 5, 126, 152, 5,145,702, 5, 182, 130 and 5,217,736 describe methods of reducing oil uptake by coating the foods, prior to frying, with an edible oil barrier film created by prolamines proteins. It has been disclosed, such as by Mathur et al., 1968. Ind Jour Med Res 56(6):863-866, that prolamine proteins are non-existent in legumes (e.g., Bengal gram, Cicer arietinum), or their concentration is very low.
US Patent nos. 5,100,684 and 5,192,572 describe a method of preparing potato pieces such as potato slices, french fries, potato cubes and potato skins, with a lower fat content by frying the potato pieces in oil comprising from about 0.5% to about 2% of a hydrophobic, or a hydrophilic silica.
Proteins such as soy flour, or gluten are known to reduce fat absorption in foods undergoing deep-fat frying. Yet, the mechanism by which this occurs in unclear. The utilization of soy flour in cake donuts to reduce fat absorption was reported in the literature by Martin and Davis, Cereal Chemistry 63(3):252-255, 1968 and by Wolf, J.W., J. Agric, Food Chem. 6:969, 1970. When such proteins are added to the basic formula of a food product, high quality proteins are used. Although these proteins may be available commercially, high purity and specific physical properties are required, which significantly effect their price, which may be prohibitive for regular usage.
From the above, it is obvious that water soluble proteins, sugars and other constituents of chick pea and lentil are not prolamines. In fact, chick pea is prolamine free (Mathur et al. 1968, ibid).
Based on the above and on the results shown in Example 7 the following may be determined: 1. Chick pea do not contain prolamines. 2. Alcohol (70%) treated chick pea significantly increases oil uptake of a restructured potato product. Both the supernatant and the precipitate impact negatively on oil uptake. 3. The effect of chick pea is therefore unrelated to prolamines.
Several other patents relate to decreasing of oil uptake in fried foods. Japan patent publication no. 3,143,344 discloses deep fried food products, such as doughnuts, containing bean curd in dough wherein oil absorbtion is significantly reduced. It is reported that 5-100% of bean (in case of powder bean 1-60%) is contained. Japan Patent publication no. 2,020,258 describes bread crumbs with low oil absorption, said crumbs are pulverized of bread made of dough containing fibre cell membrane from bean extract, wheat flour, water, yeast and other additives (e.g. edible salt, glucose, or oil and fat).
Summery of the Invention It is the object of the present invention to provide a method for decreasing the oil uptake during frying of foods.
It is a further object of the present invention to provide food mixtures with additives which decrease the amount of oil absorbed during frying compared with the amount of oil absorbed in frying of similar food mixtures which do not contain said additives.
In accordance with the present invention there are provided food mixtures for producing fried food products comprising from 1 % to 10% by weight of ground legume together with from 0.2 % to 1.5 % of GRAS salts, the balance being conventional food mixes.
It has been surprisingly found in accordance with the invention that the addition of between 1 % to 10 % of legume together with between 0.2% to 1.5 % of GRAS salt to conventional foods significantly reduce the oil uptake upon frying. Thus upon frying the food mixtures of the invention, the oil uptake is significantly reduced compared with the oil uptake of the conventional foods which form the balance in the mixtures of the invention.
It has been further found that the interfacial tension of the food mixtures according to the invention is higher than the interfacial tension of the corresponding conventional food mixes, which do not contain between 1 % to 10% legume. Thus, the change in the interfacial tension, resulting probably from the formation of a hydrophilic film on the food product, provides the physical explanation for the surprising effect of legume in the presence of salt, on the oil uptake of conventional foods.
It has been further found that the initial porosity of the food mixtures according to the invention is lower compared to the corresponding conventional food mixes, which do not contain legume. This reduction in initial porosity is increasing during the frying process. Thus, the change in the porosity, resulting probably from the formation of a hydrophilic film on the food product, increases interfacial tension and on the other hand, reduces porosity. This provides an explanation to the surprising effect of legume in the presence of salt, on oil uptake of conventional food.
Conventional foods are any foods including natural foods, e.g. fresh potatoes, vegetables, fish and meat, reconstructed food, e.g. croquettes, potato waffles, potato savories, and pancakes, engineered foods, e.g. onion rings and corn or potato snacks and coated foods, e.g. battered and breaded fish, vegetable, or meat. When referring to coated foods, the mixtures of the invention relate to the coating, i.e., to the batter, or the breading mixture.
The salt added to the mixtures of the invention may be any food acceptable GRAS ("generally recognized as safe", as defined by the FDA) salt, preferably NaCl.
The legumes are any material selected from the family Leguminosae, which includes over 12,000 species in about 500 genera. Of these, only few are of economic value as foods, e.g., peas, beans, chick pea, lentils, peanuts and soybean. The preferred legume added to the conventional foods are chick pea and lentil.
The mixtures of the invention may be used as dry or as wet mixtures.
The mixtures of the invention may undergo frying in various forms and shapes and can be used for the coating of other foods which undergo frying, the coating can be in the dry form such as crumbs for breading, or moist such as a batter.
Detailed Description of the Invention The invention is described in more detail by the following non-limiting examples: The invention extends also to the food mixtures of the invention which undergo frying and to a method for decreasing the oil uptake of foods during frying. Thus, fried food products containing between 1 % to 10% legume are within the scope of the invention.
Example 1 Effect of Chick Pea and Salt on Oil Uptake of Restructured Potato Product A restructured potato product mass was prepared from the following ingridients: Potato flakes (Idaho), 230 g; Water, 753 g; Alginate (Manugel DMB, Kelco, San Diego, CA), 6 g; Calcium sulphate dihydrate (Terra Alba F+P Grade U.S. Gypsum), 4.5 g; and Tetrasodium pyrophosphate (FMC, Philadelphia, PA), 1 g. To this basic formula chick pea powder, prepered as described below, and NaCl were added as stated below.
The restructured product was prepared as follows: The alginate solution was dissolved in water utilizing a high speed Ultra Turax. The alginate solution and the potato flakes were added to a mixer bowl, mixed for one minute in a Hobart kitchen mixer at speed " 1", and 1.5 min on speed "2". The remaining dry ingredients were added and mixing continued for another 1.5 min on speed "2." Chick pea powder was added to the potato flakes and was dry mixed thoroughly to assure homogenous mass. The weight of the chickpea used is specified for each experiment. The exact weight of chick pea was subtracted from the potato flakes basic formula, thus the total weight of the sample remained constant. The mass was transferred to a bench scale "hot dog" 9 L extruder (CGT Misanoa, Italy) and extruded into synthetic casing sleeves, 22 mm diameter. The external sleeve was soaked in tap water for ca. 10 min before extrusion.
The filled sleeves were kept at ambient temperature (25 ± 2°C) for 90 min, before freezing at -20 °C. The samples were kept frozen until evaluated. Prior to frying, the sleeves were allowed to defrost at ambient temperature, cut to cylindrical pieces, 27 mm length yielding ca. 8.3 g. The synthetic sleeve was carefully removed and the restructured potato cylindrical pieces were left at ambient temperature for an additional 15 min. The average temperature of the samples prior to frying was 16 ± 2°C. Samples were fried in a bench-top deep-fat fryer (12 cm depth) containing 2.5 liters of soy oil at 170 °C. The oil was preheated for 2 hr to break it in prior to frying as described by, Blumenthal, M.M., in Food Technol. 45(2):68-71, 1991, and discarded after 6 hr. Samples were fried for 5 min, removed from the frier and allowed to cool to room temperature, while being wiped on a paper towel.
Chick pea (Cicer arietinum) was prepared as follows: 200 g, were soaked overnight in 800 mL distilled water containing 0.46 g NaHC03. The chick pea were washed with tap water, and dried on a paper towel. Then a food processor (Moulinex, France) was utilized for 1 min to grind the seeds. The chick pea were left at ambient temperature to dry and a coffee grinder (Krups 75, Germany) was utilized for size reduction. The powder passing through a 0.71 mm sieve (25 Mesh) was utilized. Various levels of chick pea and salt were tested.
Fat Analysis is based on Method 28.074. In: "The Official Methods of Analysis", 14th ed. , AOAC, Arlington, VA. A Soxhlet extraction (AOAC, 1984) of the dried samples was utilized. A mass balance taking into consideration the sample solids and moisture before and after frying was also carried out. This method was calibrated against the Soxhlet extraction.
All analyses were carried out on 4 to 6 replicates.
The effect of added chick pea and salt is summarized in Tables 1 and 2 in terms of percentage of oil uptake and oil uptake ratio - UR wherein the value of UR expresses the weight ratio between the amount of oil uptake and water removed, as described by Pinthus etal, 1993, ibid.
Ground samples were oven dried at 105 °C for 20 h and moisture content was calculated from the weight of the dry sample and expressed as percentage.
Table 1 - Effect of chick pea concentration on oil uptake and UR in a restructured potato product (0.5 % salt; 5 min frying time).
Chick Pea Oil uptake UR Initial Moisture (%) (%) ( ) 0 11.3 0.58 73.6 . 1 4.3 0.32 73.8 2 2.8 0.22 74.0 3 1.7 0.14 73.8 5 4.5 0.32 74.8 6 2.3 0.16 73.3 8 2.6 0.17 73.2 Effect of salt concentration on oil uptake and UR in a restructured potato product (5 min frying time).
These data clearly show that both chick pea and salt had a significant synergistic effect on reducing oil uptake. At 2% chick pea and 0.5% salt, the reduction in oil uptake was more than 84% compared to control (no chick pea or salt added), and more than 75 % compared to samples with 0.5 % salt and no chick pea.
Example 2 Comparison between the effect of Chick Pea and Typical Additives on Oil Uptake During Frying of Restructured Potato Product Restructed potato product as described in Example 1 was utilized to compare the effectiveness of added chick pea to the effectiveness of the following known food additives: Soy protein, 1 % (Purina 590, Purina, Brussels, Belgium) and Vital wheat gluten - gluten 1 % (Amylum, Aalst, Belgium).
The raw materials of above ingredients are available commercially from various suppliers and the desired products are obtained by following various concentration and separation steps impacting their overall cost. It should be noted that 1 % gluten is by far more expensive than 1 % or 3% chick pea.
Table 3 - Effect of chick pea , gluten and soy protein on oil uptake of a restructured potato product during deep-fat frying at various frying times. a Oil uptake % The data clearly shows that 2 and 3% chick pea were very effective to reduce oil uptake. The data not only shows that chick pea was effective throughout the frying process, it also shows that it had a similar effect compared to 1 % gluten or soy protein.
Example 3 Effect of Added Lentil and Chick Pea on Oil Uptake of deep-frying of Commercial "Latkes" Commercial "Latkes" - Potato pancake mix (produced by TELMA, Haifa) and comprising dried potato, potato starch, onion, palm oil, salt, MSG and flavors were prepared by adding 86 g of a commercial mix with 190 mL tap water and 55 g egg. The slurry was mixed in a Kenwood Mixer for 2 min (velocity "2") and 1 min (velocity "3"), and allowed to rest for 5 min. The rested slurry was then rounded into cylinder shapes of 30 mm diameter and 10 mm height and fryed as in the frying process described in Example 1. The frying duration was 5 minutes. Experiments were carried out in 4 to 6 replicates. The effect of addition of various additives to the "Latkes" mixture was measured and the results are summerized in Table 4. When an additive was added, the equivalent weight of the Latkes mix was subtracted to keep the same formula.
These following additives were tested: 1. Methyl cellulose 1 % (Methocel K100M, Dow Corp. Midland, MI). 2. Soy protein, as described in Example 2. 3. Beans 3 %. Beans were prepared following the same procedure outlined for chick pea as described in Example 1. 4. Lentil 3%. Prepared similarly to the procedure described in Example 1. (Sieve size used was 18 Mesh = 1000 μπι).
Table 4 - Effect of Various Additives on Oil Uptake and UR in Commercial Potato Latkes (5 min Frying Time): These data clearly show that both chick pea and lentil are very effective mean to reduce oil-uptake during deep-fat frying of a commercial product. The reduction in oil uptake was more than 29% and 31 % for chick pea and lentil, respectively.
Example 4 Effect of Added Lentil and Chick Pea on Oil Uptake of "home made" as distinguished from commercial Potato "Latkes" Potato Latkes were prepared using a basic formula of: 112.5g of grinded potatoes (using a kitchen grater; and excess water was removed), 7g mixed fresh egg, 2.81 flour and 0.56g salt (0.5%). The mix was allowed to rest for 5 min, rounded into a cylinder shape (30 mm diameter x 10 mm height). The frying procedure was as described in Example 1. The frying duration was 5 min. Experiments were carried out in 4 to 6 replicates. When chick pea or lentil was added, the equivalent weight of potato was subtracted to keep the same formula.
Due to the natural variability of the potato, each experiment was compared to a control. The control was set as 100% and used as the reference. Results are reported as percent of the control.
Table 5 - Effect of Chick pea and Lentil on Oil Uptake and UR of deep-fried Potato Latkes (5 min Frying Time; 0.5% salt) These data shows that the optimal range of chick pea was 3% and 2% for Lentil. Chick pea was significantly more effective than Lentil at 3% but less effective at 2 %. Optimum conditions of 3% chick pea reduced oil uptake by 34%.
Example 5 Effect of Added Chick Pea on Oil Uptake During Deep-Fat Frying of Donuts The basic formulation for the preparation of the donuts used in the frying experiments is as follows: Flour, 246.50g; Sugar, 90.00g; Baking powder, 3.25g; Salt, 3.00g; Sodium bicarbonate, 2.25g; Egg 50.00g; and Water, 95.00g.
Chick pea was added at 0 to 2 % . The flour weight was reduced to account for the added chick pea. The donuts were prepared by mixing the donut formulation which excluded the water and eggs, utilizing a Hobart Kitchenaid mixer at speed " 1". Eggs and water were then added and mixed at speed "2" for 105 sec until a thick, uniform batter was obtained. The batter was rolled out on a floured table to a thickness of about 0.8 cm and cut into round pieces of 5 cm diameter. The initial moisture content of the dough before rolling was 34.1 %. As a result of the flowered table and atmospheric dehydration, the moisture content of the donuts after rolling and cutting dropped to 30.1 - 32.7% . Each donut was fried in a 190°C pre-heated bench top deep-fat fryer as described in Example 1. The donuts were fried for 75 sec on each side, removed from the fryer and allowed to cool on a paper towel at ambient temperature. The donuts were fried in 8-10 replicates. The results are summerized in Table 6.
Table 6 - Effect of chick pea on oil uptake and UR in donuts (2.5 min frying time) Additive % Oil uptake uR (%) Control 0.0 15.1 1.47 Chick pea 1.0 14.6 1.42 Chick pea 1.5 12.2 1.26 Chick pea 1.9 11.5 1.20 Chick pea 2.0 11.3 1.16 Example 6 Effect of Chick Pea on Interfacial Tension To demonstrate the effect of chick pea on interfacial tension of a food product, the formulation of Example 1 was utilized. Interfacial tension was derived from the equation developed by Pinthus and Saguy (1994) J. Food Sci. 59(2):(in press): Ts1 = [1 - Cos (θβ)]2 4 Where: θβ - contact angle at equilibrium; τ - surface tension (dyne/cm); s - solid; and 1 - liquid.
Liquid surface tension (τ,) was determined at room temperature on a Tensiometer (Lauda, Konigshofen, Germany), using the De Nouy method [DIN (Deutsches Inst, fur Normung eV, Berlin, Germany) #53914, 1980.]. The equilibrium contact angle (9e) between the frying media and the sample were measured on a Goniometer (NRL C.A. Model 100; Rame-Hart Inc., N.J.). The restructured potato product cylinders were peeled from the casing sleeves and allowed to equilibrate to room temperature for 15 min prior to measurement. It is worth noting that shorter equilibration periods resulted in inconsistent results. The equilibration period allowed for the sample external surface to reach a dryness which ensured reproducible results. Droplets of 0.1 ml liquid were deposited with great care from a pipette. The equilibrium contact angle was read several times on both sides of at least 3 drops. The values reported are mean values with a standard deviation of about + 3°. The contact angle did not vary for about 2 minutes during the measurement.
The effect of added chick pea on the intial interfacial tension between the food and the frying medium is demonstrated in Table 7.
Table 7 - Effect of added chick pea on interfacial tension (measured at room temperature) Table 7 clearly shows that the addition of chick pea together with salt to a reconstructed potato product, increases the interfacial tension of the product, possibly therby, decreasing the oil uptake of the fried product.
Example 7 Effect of Chick pea fractionation on oil uptake Fractionation of chick pea was obtained by mixing chick pea prepared as in Example 1 in ethanol (70%). This was done to test the possibility that residual concentration of prolamines that normally are known not to exist in chick pea, may still have some residual effectiveness. chick pea (50 g) were dissolved in 500 mL of 70% alcohol at 40 °C for 2 h; the alcohol was filtered and both the precipitate and supernatant were vacuum-dried. The dried products were added separately to a restructured potato product (described in Example 1) at an equivalent of 2% initial chick pea based on the dry formula of the restructured potato. Oil uptake of the supernatant was 23.0% and a UR of 0.78 compared to 2.8% oil uptake and a UR of 0.22 in the control. Simultaneously, the oil uptake of the precipitate prepared according to the same procedure was 15.4% oil uptake and the UR was 0.63.
Table 8 - Effect of chick pea fractionation on interfacial tension a Chick pea was precipitated with ethanol b Chick pea was precipitated with ethanol and only the supernatant was used.
The above data clearly show that both the precipitant and the superantatant obtained when chick pea was dissolved in ethanol 70% were not effective in reducing oil uptake during deep-fat frying. The data also show that the frationation increased significantly oil uptake. Thus, it was concluded that chick peas do not contain prolamines, the alcohol (70%) treated chick pea significantly increased oil uptake of a restructured potato product, both the supernatant and the precipitate impact negatively on oil uptake, and the effect of chick peas is therefore unrelated to prolamines.
Example 8 Effect of Chick Pea on Oil Uptake of Breaded Fish Frozen fish (Hake) was placed for overnight in a refrigerator for thawing. Excess water was removed, and the fish was cut into slabs (ca.3.5 x 3.5 x 1.0 cm). Egg mixture was prepared by adding 6.6ml salt (NaCl) solution (25%) to 55 g fresh egg. The egg mixture was whipped with a fork until a homogeneous mixture was obtained. The egg mixture was let to rest for 2 min. The fish slabs were dipped into the egg mixture for 30 s. The fish was then placed on a screen allowing excess egg to drip off before it was transferred to a plastic bag containing bread crumbs coated with chick pea, wherein the chick pea constituted 5 % of the total weight of the breading. The coated bread crumbs were prepared as follows: 1.5 g chick pea powder (prepared according to Example 1) was dissolved in 3 ml. tap water containing 0.0075 g salt (0.5 % of the breading), 28.5 g commercial breading were added and the slurry was dried at room temperature. Afterwards, the fish was coated with the bread crumbs containing 5% chick pea. The breaded fish was removed from the bag, excess breading was removed and the fish was fried. Frying conditions were: 170°C for 5 min. The fish slabs were turned from one side to the other in the fryer after 2.5 min to ensure equal frying. The oil was treated as explained in Example 1. The control contained no chick pea (i.e. , 30 g bread crumbs), and prepared as described above. The results obtained (average of 4 replicates) are shown in Table 9.
Table 9 - Effect of added chick pea on oil uptake of breaded fish.
The data clealy shows that a significant reduction in oil uptake and UR were obtained, when 5 % chick pea was utilized to coat the bread crumbs.
Example 9 Effect of Chick Pea on Oil Uptake of Battered Fish Frozen fish (Hake) was thawed and cut into slabs as outlined in Example 8. The control batter was prepared as follows: Egg mix: to a fresh egg (55 g), 0.4 g salt (dissolved in 6 ml. tap water) was added and the mixture mixed with a fork, and let to rest for 10 min. Wheat flour (20.0 g), was then added and the batter was mixed thoroughly with a fork until a homogeneous batter was received. The fish cubes were dipped into the batter until full coverage was obvious. The batter containing chick pea was prepared as follows: 2.4 g chick pea was dissolved in 5 ml. tap water containing salt, the final content of chick pea and salt in batter being 3 % and 0.5 % respectively. The slurry was allowed to rest for 10 min. The slurry and 1 ml. additional tap water were added to fresh egg (55 g), mixed with a fork, and let to rest for 10 min. Wheat flour (17.6 g) was added and the batter was prepared as outlined above. The battered fish was placed on a screen allowing excess batter drip off before frying. Frying conditions were as outlined in Example 9. The results obtained are shown in Table 10.
Table 10 - Effect of added chick pea on oil uptake battered fish.
The data clearly shows a significant reduction in oil uptake at chick pea content of 3 % .
Example 10 Effect of Chickpea on Porosity and Oil Uptake Restructured potato product without and with added 3% chick pea, together with 0.5% NaCl, as described in Example 1, was utilized to elucidate the effect of chick pea on product porosity and oil uptake. Porosity is defined as: "the volume fraction of the air or the void fraction in the sample' and is expressed as follows: Porosity = 1 - pb/ps Where: pb - Bulk density ps - Particle density.
Particle density was measured on a Multi-Pycnometer (Quantachrome, Syosset, NY), bulk density was calculated from the sample weight divided by bulk volume, which was determined as volume of glass beads 100μ displacement.
Table 11 - Effect of added chick pea on restructured potato product porosity.
The above data clearly shows that added chick pea has a significant effect of reducing the porosity of the restructured potato product. It also shows that the reduction of the porosity in the product containing chick pea increases with frying time.
To demonstrate the importance of product initial porosity on oil uptake as measured by Up, the restructured potato was stored at fluctuating sub-freezing temperature of -16 2C and storage duration was up to 21 days. Samples were removed periodically and moved to -70C to ensure that no further changes in porosity will occur. The porosity and oil uptake are listed in Table 12.
Table 12 - Effect of initial porosity on oil uptake of a restructured potato product.
The data of Table 12 shows a linear relationship (R2=0.999) between porosity and oil uptake. These data emphasize the fact that the higher the initial porosity of the product, more oil is adsorbed by it.
Hence, it could be concluded bases on the data of Tables 11 and 12, that reducing initial porosity, as has been demonstrated by adding 3 % chick pea, reduces significantly oil uptake.

Claims (1)

Food mixtures for producing fried food products comprising from 1% to 10% by weight of ground legume together with from 0.2% to 1.5% of GRAS salt as defined in the specification, the balance being conventional food mixes, wherein upon frying said food mixture, the oil uptake is significantly reduced compared with the oil uptake of the conventional food mix which form the balance in said mixture. Food mixtures according to claim 1 wherein the interfacial tension of said food mixture is higher than the interfacial tension of the corresponding conventional food mix. Food mixtures according to claim 1 wherein the porosity of said food mixture is significantly reduced compared with the porosity of the corresponding conventional food mix. Food mixtures according to claims 1 to 3 wherein the conventional food mixes comprises natural foods, reconstructed food products, engineered food, coatings, water, and/or mixtures thereof together with acceptable food additives. Food mixtures according to claims 1 to 4 wherein the legume is selected from lentil and chick pea. Food mixtures according to claims 1 to 5 wherein the legume constitute between 2% and 4% of the mixture. 7. Food mixtures according to claim 5 wherein one of the food additives is alginate. Food mixtures according to claims 1 to 7 wherein the salt is NaCl. A method for obtaining fried food products with decreased oil uptake comprising: a. covering said food with a coating selected from conventional crumbs for breading and conventional batter further comprising from 1% to 10% of ground legume together with from 0.2% to 1.5% of GRAS salt, or alternatively, b. adding to a conventional food mix an additive comprising a mixture of ground legume and GRAS salt, the content of said additive in the final mixture being from 1% to 10% of ground legume and from 0.2% to
1.5% of said salt, and subsequently, c. frying said food containing legume and salt by known frying methods. Fried food products obtained according to the method of claim 9. For the Applicants "t 4S. L Dr. Ruth Sella Patent Attorney r.claim.yisum.5
IL11033894A 1994-07-15 1994-07-15 Food mixture comprising legume with low fat absorption upon frying IL110338A (en)

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IL11033894A IL110338A (en) 1994-07-15 1994-07-15 Food mixture comprising legume with low fat absorption upon frying
AU30070/95A AU3007095A (en) 1994-07-15 1995-07-12 Food mixtures comprising legume with low fat absorbtion upon frying
EP95926250A EP0798969A1 (en) 1994-07-15 1995-07-12 Food mixtures comprising legume with low fat absorbtion upon frying
PCT/US1995/008706 WO1996002149A1 (en) 1994-07-15 1995-07-12 Food mixtures comprising legume with low fat absorbtion upon frying

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GB2461520A (en) 2008-07-01 2010-01-06 Magsnack Bv Manufacturing crumb for the coating of food products
GB201000647D0 (en) 2010-01-15 2010-03-03 Crisp Sensation Holding Sa Microwaveable batter
US8765202B2 (en) 2010-01-15 2014-07-01 Crisp Sensation Holding S.A. Coated stabilised microwave heated foods
EP2624707A4 (en) * 2010-10-04 2014-01-29 Proteus Industries Inc Process for reducing oil and fat content in cooked food with pea protein
US9326537B2 (en) 2011-01-27 2016-05-03 Crisp Sensation Holding S.A. Microwaveable coated food product, and method and apparatus for the manufacture thereof
US9326536B2 (en) 2011-01-27 2016-05-03 Crisp Sensation Holding S.A. Production of microwaveable coated food products
US20130156925A1 (en) 2011-12-20 2013-06-20 Crisp Sensation Holding S.A. Crumb manufacture

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US4084016A (en) * 1976-12-28 1978-04-11 The United States Of America As Represented By The Secretary Of Agriculture Preparation of legume chips
US4218480A (en) * 1978-12-29 1980-08-19 The Griffith Laboratories, Limited Production of particulated stale bread
US4364961A (en) * 1981-03-30 1982-12-21 The Griffith Laboratories, Limited Manufacture of bread crumb-like product
US4423078A (en) * 1982-04-14 1983-12-27 The Griffith Laboratories, Limited Production of oriental-style breading crumbs
US4517204A (en) * 1984-02-27 1985-05-14 Frito-Lay, Inc. Reduced calorie puffed snack food products
US4963378A (en) * 1988-08-08 1990-10-16 Bhardwaj Satish C Method of cooking involving high protein frying batter that eliminates the need for breading and produces crispy and chewy crust

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WO1996002149A1 (en) 1996-02-01

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