IES85072Y1 - An article for use in washing textile articles - Google Patents
An article for use in washing textile articlesInfo
- Publication number
- IES85072Y1 IES85072Y1 IE2008/0364A IE20080364A IES85072Y1 IE S85072 Y1 IES85072 Y1 IE S85072Y1 IE 2008/0364 A IE2008/0364 A IE 2008/0364A IE 20080364 A IE20080364 A IE 20080364A IE S85072 Y1 IES85072 Y1 IE S85072Y1
- Authority
- IE
- Ireland
- Prior art keywords
- article
- substrate material
- bag
- substance
- sachet
- Prior art date
Links
- 238000005406 washing Methods 0.000 title claims abstract description 12
- 239000004753 textile Substances 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 52
- 239000000758 substrate Substances 0.000 claims abstract description 47
- 239000000843 powder Substances 0.000 claims abstract description 19
- 239000000126 substance Substances 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 230000002000 scavenging Effects 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 10
- -1 non ionic Chemical group 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 4
- 102000004190 Enzymes Human genes 0.000 claims abstract description 3
- 108090000790 Enzymes Proteins 0.000 claims abstract description 3
- 125000000129 anionic group Chemical group 0.000 claims abstract description 3
- 238000005282 brightening Methods 0.000 claims abstract description 3
- 125000002091 cationic group Chemical group 0.000 claims abstract description 3
- 239000003352 sequestering agent Substances 0.000 claims abstract description 3
- 239000004094 surface-active agent Substances 0.000 claims abstract description 3
- 239000004902 Softening Agent Substances 0.000 claims abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive Effects 0.000 claims description 5
- 239000007844 bleaching agent Substances 0.000 claims description 5
- 239000001187 sodium carbonate Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 2
- NQMRYBIKMRVZLB-UHFFFAOYSA-N methylamine hydrochloride Chemical compound [Cl-].[NH3+]C NQMRYBIKMRVZLB-UHFFFAOYSA-N 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims 1
- 239000012459 cleaning agent Substances 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 27
- 238000005245 sintering Methods 0.000 description 5
- 239000004698 Polyethylene (PE) Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- MWNQXXOSWHCCOZ-UHFFFAOYSA-M Sodium percarbonate Chemical compound [Na+].OOC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-M 0.000 description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N Trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010412 laundry washing Methods 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000003700 epoxy group Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- SLNYWOSSHFWMTN-UHFFFAOYSA-N methyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[NH2+]CC1CO1 SLNYWOSSHFWMTN-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-O propan-1-aminium Chemical compound CCC[NH3+] WGYKZJWCGVVSQN-UHFFFAOYSA-O 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propanol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
Abstract
ABSTRACT An article for use in a washing machine for washing textile items in a liquid is disclosed. The article comprises a porous substrate material supporting a dye scavenging compound; the substrate material being in the form of a bag or sachet or the like. Enclosed therein is a substance such as a powder or the like having properties for assisting in appropriate or advantageous treatment of the textile items in the liquid. The dye scavenging compound is selected from the group consisting of a N-trisubstituted ammonium 2—hydroxy—3—halopropyl compound. The substance could comprise a cleaning agent with or without a binder; a water softening agent; an enzyme, a brightening agent, a sequestering agent or a surfactant (anionic, non-ionic, or cationic) or any combination thereof.
Description
Article for Use in Washing Textile Articles
This invention relates to improvements in or relating to an article for removing extraneous
dye or dyes from laundry washing applications.
The problem of extraneous dyes in laundry washing applications is Well known and does not
required detailed discussion here. Attempts to overcome the presence of such dyes are well
known. For example, United States Patent Specification No. US-A-4 380 453 discloses the
use of N-trisubstituted ammoniumhydroxyhalopropyl compounds and salts of epoxy
propyl ammonium as dye scavenge compounds.
International Patent Specification No. WO-A-97/48789 discloses a method for the production
of a dye scavenging substrate and its use. The substrate can be added to a laundry wash and
the active ingredient therein (an N—trisubstituted amrnoniumhydroxy-halopropyl
compound) causes extraneous dyes in the wash to be preferentially absorbed onto the
substrate rather than to other items of clothing in the wash.
It is an object of the present invention to provide an improvement in the use of a substrate
material in a laundry application.
The invention, therefore, provides an article for use in Washing textile items in a liquid in, for
cxample, a clothes washing machine, the article comprising a porous substrate material
supporting a dye scavenging compound; the substrate material being in the form of a bag or
sachet or the like having enclosed therein a substance such as a powder or the like having
properties for assisting in appropriate or advantageous treatment of the textile items in the
liquid.
Preferably, the substrate material comprises a cellulosic material. Preferably, the substrate
material has incorporated therein a dye—scavenging compound selected from the group
consisting of a N-trisubstituted ammonium 2—hydroxyhalopropyl compound having the
general fomiula
(IN
on
m
c:
~:
to
R
/
X~CH;—CHOH~CH2—N-R Y"
+ \
R
and a salt of epoxy propyl ammonium having the general formula.
R
/
CH2-CH—CH2—N-R Y’
\ / +\
O R
wherein x is a halogen radical, Y is a chloride, bromide, sulphate or sulphonate, and the Rs
are the same or different and are methyl, ethyl, butyl or benzyl groups or an hydroxyl
substituted derivative thereof. A preferred compound is glycidly methyl-ammonium chloride
(GMAC).
The substrate material can comprise a dye scavenging substrate made in accordance with the
method disclosed in International Patent Specification No. WO 97/48789. The substrate
material can be made into a bag or sachet or the like by folding a suitably sized sheet of the
substrate material and securing the sides along their periphery with the substance enclosed
therein.
Alternatively, the wall of the bag or sachet may consist of two sheets of substrate material
secured together about their periphery with the substance enclosed therein.
Depending on the nature of the substance to be enclosed within the bag, it may be desirable to
provide a face of the substrate material with a polymeric material which face eventually
comprises the inner wall of the bag or sachet. The polymeric material may be sprayed onto
the face of the substrate or otherwise suitably added or applied to it. Where such a polymeric
material is used, it will be understood that, to achieve the same effective dye scavenging
ability as the substrate material without the polymeric material, the surface area of the
substrate material may need to be increased or the composition of the dye scavenging
compound as taught in International Patent Specification No. WO 97/48789 may need to be
modified. Such modification can be achieved in a variety of techniques. For example, a
binder, such as a polyvinyl alcohol can be used in the manufacture of the substrate material.
The percent binder used (by weight) should be of the order of 12% or less (preferably not less
than 10%) so as to provide sufficient sites for the dye scavenging material.
The use of a polymeric material provides a number of advantages. Firstly, the presence of the
polymeric material on what are effectively opposing faces of the bag or sachet enables the bag
to be sealed around the periphery thereof. Secondly, the presence of the polymeric material
prevents or substantially reduces the contact between powder in the bag and the dye
scavenging compound of the substrate material when the bag or sachet is not in the “in use"
condition in a washing machine. Thirdly, the presence of the polymeric material at least
initially enables the bag or sachet to float in the in use condition when the powder in the bag
is, for example, an oxygen producing compound such as sodium carbonate peroxyhydrate or
sodium carbonate or a combination thereof. When the powder comes into contact with the
water in the washing machine, oxygen is rapidly produced which is temporarily retained in
the bag or sachet which effectively becomes balloon like in character thereby leading to
greater buoyancy and improved operating characteristics. It will be appreciated that, once the
powder/water reaction has finished, the oxygen thus produced will eventually dissipate and
the bag will function as a dye scavenging substrate.
It is desirable that, in making the bag or sachet, certain characteristics are present. Ideally, all
of them should be present but this is not essential. These characteristics for the bag or sachet
include good scalability, good porosity, good dye pick up, good wash durability and good
buoyancy. Good scalability is desirable so that the bag or sachet does not break open or
prematurely disintegrate in the washing machine when in use. Good porosity is desired to
enable the powder in the bag or sachet to leach out from the bag or sachet in the washing
machine when in use. Good wash durability is desirable as the bag or sachet can carry
powder of about 30g and be capable of withstanding wash temperatures of up to 95°C. Good
buoyancy can improve the effectiveness of the article in use in the washing machine.
The substance within the bag or sachet can be selected from appropriate substances which are
suitable for assisting in the appropriate or advantageous treatment of the textile items in the
wash. For example the substance could comprise a cleaning agent with or without a binder; a
water—softe11ing agent; an enzyme, a brightening agent, a sequestering agent or a surfactant
(anionic, non—ionic or cationic) or any combination thereof.
A preferred substance is a bleach additive. Such a bleach additive can be, for example,
sodium carbonate peroxyhydrate or sodium carbonate or a combination thereof. A suitable
combination is sold under the brand name Oxyper S C B from Solvay Chemicals International
SA, Brussels, Belgium.
As disclosed in lntemational Patent Specification No. WO—A—97/48789, the method for the
production of the substrate material may comprise the steps of:-
(a) providing a ccllulosic substrate;
(b) passing the substrate through a bath containing an alkaline solution of an N-
trisubstituted ammonium 2-hydroxyhalopropyl compound having the general formula:
R
/
X—CHg—CHOH—CH2—N-R Y’
+ \
R
or a salt of epoxy propyl ammonium having the general formula:
R
/
CH2-CH—CH2-N-R Y’
\ / + \
O R
wherein X is a halogen radical, Y is a chloride, bromide, sulfate or sulfonate, and the R's are
methyl, ethyl, butyl or benzyl groups or an hydroxyl substituted derivative thereof;
(c) subjecting the substrate to a pressure of between 069-] .37MPa (100-200 psi);
(d) heating the substrate to a temperature of between approximately 35°C or 45°C;
ix)
Us
(e) wrapping the substrate in a water impermeable material and rotating the material at
a temperature of between 15°C and 100°C for a period of between 1 hour and 12
hours;
(t) removing the water impermeable material and passing the substrate through an acid
bath;
(g) subjecting the substrate to a pressure of between 1.03 - 1.72Mpa (1 50-250 psi);
(h) drying the substrate.
The substrate material prior to the incorporation of the dye—scavenging chemical preferably
comprises pulp (approximately 68% by weight), viscose (approximately 20% by weight) and
a binder (approximately 12% by weight). The dye scavenger formulation preferably
comprises glycidyl methyl—ammonium chloride (approximately 7.6% by weight), sodium
hydroxide (approximately 3.2% by weight) and water (approximately 89.2% by weight).
In order to provide the polymeric material on one face of the substrate material, a process
known as sintering is used. Sintering does not form a continuous coating thus preserving the
porosity of the substrate material. This is required so that the substance enclosed within the
bar or sachet can come into contact with the liquid when the bag or sachet is in use. The
primary purpose of the polymeric material is to enable the bag or sachet to be sealed. The
polymeric material could, if desired, be applied to the periphery of the substrate material for
enabling the bag or sachet to be sealed but it has been found from a cost perspective that the
sintering technique of applying the polymeric power to the entire face of the substrate
material rather than a part of the material is preferred. Thus, as an example of the sintering
process, a roll of treated non-woven material is unwound into a sintering machine. Villars and
Keller of Switzerland produce such a machine. A hopper is fed with thermoplastic
polyethylene powder. The thermoplastic powder is available from Schaetti AG. Birgistrasec
CH—8304 Wallisellen and is known as Schaetti Fix powder. The powder can be fed onto a
shaker roller which scatters the powder evenly onto the web. The web then enters an infrared
tunnel at approximately 130°C. This melts the powder onto the web. It is then passed
thorough a cooling roller and a nip roller and rewound.
In order to assess the preferred level of polyethylene powder commensurate with the desired
scalability, porosity, wash durability, buoyancy and dye pick up, a number of tests was carried
out and the following results were obtained.
GSM (g.m 2) 15g 25g 35g
Sealability Poor Very good Excellent
Porosity Excellent Very good Poor
Wash durability 90°C Good Very good Excellent
Buoyancy Good Very good Excellent
Dye Pick Up Very good Very good Very Poor
Note: GSM refers to grams of polyethylene powder per square meter of substrate material.
It will be appreciated that a preferred concentration of polyethylene material is at the weight
of around 25g.m'2.
When the substance used is, for example, the bleach additive comprising a combination of
sodium carbonate peroxyhydrate and sodium carbonate, a by-product of a chemical reaction
between the bleach additive and the substrate material in the form of trimethylamine (TMA)
can be generated where the pre-cursor of the GMAC is glycol and propanol rcagens. TMA is
detected as having a strong amine-like odour. If it is desired to overcome this problem, a
rinse stage may be used in addition to the steps outlined above: A roll of substrate 12% - 18%
binder type is treated in a 3rd pass through a padding machine at 50 m per minute. The nip
pressure of the rollers is approximately 1 bar (100kPa) +/- 10%. The volume of rinse water
used may be between 500 -700 1 for 4140 sq m of substrate and may be applied using a spray
f\)
'J‘u
bar with a wetting bar. The temperature of the rinse water can be between about 13°C and
“C. Subsequently the substrate may be passed through a second padding machine which has
several integrated drying steams cans. The speed of the machine may be set at about 45 in per
minute. The nip pressure of the rollers may be approximately 1 bar (l00kPa) +/- 10%.
The following example relates to a bag or sachet with GMAC as the dye scavenger.
A l00mg.l" solution of Direct Red Dye is made up accurately and used for the following
analysis. (The dimensions of the sample bag or sachet are approximately l05.75mm x
l l3.81mm containing approximately 30g of powder.)
. A single bag or sachet is placed in a 51 beaker and 400ml of water are added. The
water is heated to approximately 65°C and the bag is stirred until all the powder has
been dissolved. The bag is then removed from the beaker and any excess moisture is
removed by wringing it out by hand.
A 200ml aliquot of the dye solution is heated in a 200ml beaker to 65°C.
The bag is placed in the beaker, ensuring that the bag is immersed completely in the
dye solution and stirred.
The bag is stirred continuously for a period of not less than 1 minutes or more than 3
minutes after which time the bag is removed.
The temperature of the solution should be maintained at approximately 65°C for the
duration of the test.
The solution is then filtered immediately to remove all traces of any loose fibres from
the bag.
The resultant solution is tested using a Hach Spectrophotometer for any residual dye
content and the result is recorded.
. A pass or fail result is assigned depending on the amount of dye remaining in the
solution.
9. Less than or equal to 6mg.l‘I is a pass whereas 7mg.l" or over is deemed to be a fail.
A 200ml aliquot of a 1O0mg.l"1 dye solution contains 20mg of dye. For a pass result each bag
should preferably be capable of absorbing 18.8mg of dye or greater, leaving 1.2mg of dye or
less in the beaker. (To convert from mg.l" to mg of dye in the 200ml aliquot, divide the Hach
result by 5).
It should be noted that the Hach Spectrophotometer is only capable of reading sensitivity of
not less than 1mg.l". The fail point is less that about 7mg.l" therefore it is reported that a
value of 6mg.l'1 or less is a pass.
The results of the test are illustrated in Figures 1 and 2 attached.
The invention is not limited to the disclosure described herein, which may be modified or
varied without departing from the scope of the invention.
Claims (5)
1. An article for use in washing textile items in a liquid, the article comprising a porous substrate material, optionally a cellulosic material, supporting a dye scavenging 5 compound; the substrate material being in the form of a bag or sachet or the like having enclosed therein a substance such as a powder or the like having properties for assisting in appropriate or advantageous treatment of the textile items in the liquid and, further optionally, wherein the substrate material has incorporated therein a dye scavenging compound selected from the group consisting of a N-trisubstituted ammonium 2- 10 hydroxy—3-halopropyl compound having the general formula R / I5 X—CHg~CHOH—CH2—N-R Y" + \ R and a salt of epoxy propyl ammonium having the general formula 20 R / CH2—CH-CH2-N-R Y' \ / +\ 25 O R wherein x is a halogen radical, Y is a chloride, bromide, sulphate or sulphonate, and the Rs are the same or different and are methyl, ethyl, butyl or benzyl groups or an hydroxyl substituted derivative thereof; and, still further optionally, wherein the compound is glycidly 30 methyl—ammonium chloride (GMAC).
2. An article as claimed in claim 1 wherein the bag or sachet comprises (a) a suitably sized sheet of the substrate material folded and secured around the periphery thereof with the substance enclosed therein; or P85l45IE0l /June 3, 20 (b) two sheets of substrate material secured together about their periphery with the substance enclosed therein.
3. An article as claimed in claim 1 or claim 2 wherein a face of the substrate material, 5 which face comprises the inner wall of the bag or sachet, incorporates a polymeric material and, optionally, wherein the polymeric material is in the form of a binder such as polyvinyl alcohol.
4. An article as claimed in any of claims 1-3 wherein the substance comprises a cleaning 10 agent with or without a binder; a water softening agent; an enzyme, a brightening agent, a sequestering agent or a surfactant (anionic, non ionic, or cationic) or any combination thereof and, optionally, wherein the substance is a bleach additive such as sodium carbonate pcroxyhyorate or sodium carbonate or a combination thereof. 15
5. An article substantially as hereinbefore described.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IEIRELAND09/05/2007S2007/0344 |
Publications (2)
Publication Number | Publication Date |
---|---|
IES85072Y1 true IES85072Y1 (en) | 2008-12-10 |
IE20080364U1 IE20080364U1 (en) | 2008-12-10 |
Family
ID=
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