IE42111B1 - Tobacco composition - Google Patents
Tobacco compositionInfo
- Publication number
- IE42111B1 IE42111B1 IE2551/74A IE255174A IE42111B1 IE 42111 B1 IE42111 B1 IE 42111B1 IE 2551/74 A IE2551/74 A IE 2551/74A IE 255174 A IE255174 A IE 255174A IE 42111 B1 IE42111 B1 IE 42111B1
- Authority
- IE
- Ireland
- Prior art keywords
- tobacco
- nitrate
- composition
- zinc oxide
- weight
- Prior art date
Links
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 72
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 244000061176 Nicotiana tabacum Species 0.000 title 1
- 241000208125 Nicotiana Species 0.000 claims abstract description 71
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000011787 zinc oxide Substances 0.000 claims abstract description 35
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 22
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 21
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000000737 periodic effect Effects 0.000 claims abstract description 3
- 235000019504 cigarettes Nutrition 0.000 claims description 27
- 230000000391 smoking effect Effects 0.000 claims description 11
- 239000011777 magnesium Substances 0.000 claims description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Inorganic materials [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical group [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 235000019506 cigar Nutrition 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 33
- 239000000779 smoke Substances 0.000 description 24
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 150000002823 nitrates Chemical class 0.000 description 12
- 239000000654 additive Substances 0.000 description 11
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 5
- 238000000197 pyrolysis Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- -1 zinc oxide Chemical compound 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 230000004071 biological effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000037361 pathway Effects 0.000 description 4
- 235000010333 potassium nitrate Nutrition 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000011133 lead Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910001960 metal nitrate Inorganic materials 0.000 description 3
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical class [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 244000062939 Leptospermum ericoides Species 0.000 description 2
- 235000017763 Leptospermum ericoides Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000002826 nitrites Chemical class 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 150000003254 radicals Chemical group 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 235000019505 tobacco product Nutrition 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
- A24B15/241—Extraction of specific substances
- A24B15/246—Polycyclic aromatic compounds
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/287—Treatment of tobacco products or tobacco substitutes by chemical substances by inorganic substances only
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Tobacco Products (AREA)
- Catalysts (AREA)
- Inorganic Insulating Materials (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
1481718 Tobacco composition LIGGETT & MYERS INC 10 Dec 1974 [19 Dec 1973] 53408/74 Heading A2C A tobacco composition comprises tobacco; zinc oxide in an amount of 0.1 to 15 weight % based on the weight of tobacco; and a nitrate of an element selected from Group IIA or Group IIB of the Periodic Table in an amount of from 0.25 to 0.75 weight percent calculated as nitrate nitrogen based on the weight, of tobacco.
Description
This invention relates to a smoking composition containing tobacco and having a combination of a catalytic agent and an additive releasing nitric oxide associated with the tobacco for reducing the concentration of polycyclic aromatic hydrocarbons in tobacco smoke. More particularly it relates to such compositions wherein the catalytic agent is zinc oxide and the nitric oxide releasing additive is selected from the group consisting of magnesium, calcium and zinc nitrates.
Observations of the mechanism of combustion in tobacco compositions such as cigarettes, indicate that the smoke components responsible for biological activity of smoke are formed in the pyrolysis zone of the cigarette cone. It is widely accepted that much of the biological activity observed in connection with cigarette smoke condensate resides in the neutral smoke fraction and more specifically within the subfraction which contains the polycyclic aromatic hydrocarbons (PCAH).
It has been generally accepted that it would be desirable to decrease the levels of PCAH compounds in cigarette smoke and this led to a substantial amount of research aimed at reducing the proportion of such compounds in cigarette smoke.
It has been postulated that there are several pathways by which the tobacco components are converted into polycyclic aromatic hydrocarbons. One major route is the thermal degradation of various organic materials siich as, e.g., cellulose into unsaturated free radical structures consisting of two, four or five carbon atoms and, in the case of the longer fragments, of conjugated double bonds, the free radical structures subsequently participate in the pyrogenesis of aromatic ring structures, the two and four carbon fragments giving rise to unsubstituted PCAH and the five carbon branched structure giving rise to methyl substituted PCAH. Another major route is the formation of PCAH from pre-extant skeletal structures already present in tobacco such as steroids. In the latter case only minor thermally induced modifications are necessary to produce PCAH molecules. Many other routes, such as ring closures of si dechai ns, are possible.
Since the possible pathways of PCAH formation are widely different it is highly unlikely that any one catalytic agent or other additive would interfere with all of the different formation processes. For instance, in US Patent No 3 720 214 there is disclosed a smoking composition comprising tobacco in association with finely divided zinc oxide. This material is disclosed to result in a tobacco composition wherein the polycyclic aromatic hydrocarbon (PCAH) content arising from the pyrolytic reactions within this composition is substantially reduced when compared to a control cigarette. It has now been found, however, that zinc oxide catalyst alone, while apparently very efficient in eliminating the production of PCAH by some of the pyrosynthetic routes, has its limitations and does not affect all of the pathways.
The addition of nitrates and nitrites to tobacco has been previously described in various patents and publications. Thus French Patent No 1 180 320 teaches the addition of unspecified amounts of nitrites to tobacco and cigarette paper to reduce the PCAH yield and US Patent No 3 121 433 describes the addition of potassium nitrate to reconstituted tobacco sheet to improve its burning characteristics. United States Patent No 3 380 458 teaches the addition of 5.5 to 10% of potassium and sodium nitrates to tobacco (NaNOg :0.91 - 1.65% of nitrate nitrogen KN0g:0.76 - 1.39:5 nitrate nitrogen) and it discloses a reduction in cigarette tar yield which is caused by the concomitant increased burn rate of the cigarette.
Bentley and Burgan (Analyst 85, 727-730, 1960) describe the addition of various nitrates to tobacco in an attempt to reduce the yield of 3.4- benzopyrene. They achieved a reduction only with copper and potassium nitrates and increased with lead, silver and zinc nitrates.
Wynder & Hoffman (Acta Pathol.Microbiol. Scand. 52, 119-132 1961, and Deutch. Med. Wochenschr. 88, 623-628, 1963) using cigarettes treated with 5% copper nitrate (0.50% nitrate nitrogen) confirmed Bentley & Burgan's finding that copper nitrate reduced the 3,4-benzopyrene yield of cigarettes. Hoffman and Wynder also demonstrated (Cancer Res. 27, 172-174, 1967) that the addition of 8.3% of sodium nitrate (1.37% nitrate nitrogen) resulted in a significant reduction of cigarette 3.4- benzopyrene yield as well as in a reduction of the biological activity of the smoke condensate. Pyriko et al (Ber. Inst. Tabakforsch, Dresden, 12, 37-55, 1965), on the other hand, have shown that the addition of 4% of potassium nitrate (0.55% nitrate nitrogen) increased the level of 3,4-benzopyrene in cigarette smoke by 40%.
While most of the past investigators have expressed their research results in terms of the effect of the additive on cigarette 3,4-benzopyrene yield, it is now becoming widely recognized that this compound probably plays at most only a minor role in the biological activity of tobacco smoke condensate. It is also now recognized that the yield of 3,4-benzopyrene, which is a very minor constituent of the PCAH fraction, is not necessarily a reliable indicator of the additives' effect on the bulk of the PCAH.
It has been postulated that the effect of nitrates on the composition of cigarette smoke stems from two properties of nitrates: a) their capacity to oxidize and b) their capacity to form the unpaired electron species, nitric oxide, in the pyrolysis zone of the cigarette that acts as a free radical scavenger. Provided a sufficiently high level is 43111 added, all nitrates tend to lower the PCAH yield of cigarettes to some degree, but depending on the particular cation not necessarily the concentration of PCAH in the smoke condensate.
The nitrates' capacity to reduce PCAH concentration is particularly dependent on the ability of the salt to form nitric oxide in the appropriate temperature region of the combustion zone. Many of the nitrates and, in particular, nitrates of Group Ia metals, are good combustion promoters. When they are added to tobacco the burn rate of cigarettes is accelerated and the total smoke yield is decreased. The concentra10 tion of PCAH within the smoke condensate is, however, not necessarily decreased and is at times increased. The nitric oxide yield from such nitrates is relatively low. Hence, nitrates of Group la metals have to be added at relatively High levels to reduce the concentration of PCAH in tobacco smoke.
All added nitrates, and in particular those that accelerate burn rate impart a disagreeable taste to the main stream smoke and an obnoxious odour to the side stream aroma. For this reason, additive levels such as have been claimed to show beneficial effects in some of the previous work (5-10%) are unacceptable from the point of view of a palatable cigarette. In sum, nitrate, like zinc oxide, even though being an efficient agent for disrupting some of the pathways of PCAH formation, has not proven to be a universal eliminator for PCAH, particularly at levels compatible with acceptable taste and smell of cigarette smoke.
In accordance with this invention there is provided a smoking tobacco composition comprising: (a) tobacco; (b) finely divided zinc oxide in a catalytic amount based on the - 5 Τ2Π11 weight of tobacco, of from 0.1 to 15 weight per cent; and (c) a nitrate of an element selected from Group Ila or Group lib of the Periodic Table in an amount of from 0.25 to 0.75 weight per cent calculated as nitrate nitrogen, based upon the weight of said tobacco.
This invention also provides a process for making such a smoking composition comprising admixing the said amounts of zinc oxide, said nitrate and tobacco to provide a uniform dispersion of said zinc oxide and said nitrate throughout said tobacco.
In accordance with the present invention, the concentration of PCAH is substantially reduced without adverse organoleptic effect on tobacco smoke by incorporating both zinc oxide and a Group Ila or lib nitrate in tobacco. Unlike the Group la metal nitrates, the Group Ila and lib metal nitrates do not accelerate cigarette burn rate. In addition, they yield more nitric oxide per mole under the conditions extant in the cigarette cone. Hence, they effect more efficient reductions in the PCAH concentration in smoke condensate.
The incorporation of the nitrate compound enables reduction of the PCAH concentration to levels below those achieved with zinc oxide alone.
This effect is achieved with nitrate concentrations well below the levels having objectionable effects on the organoleptic properties of smoke.
In particular, substantial reductions in PCAH concentrations are achieved at nitrate levels below 0.75$ nitrate nitrogen, based upon the weight of the tobacco.
The zinc oxide which has been found to be particularly effective in combination with tobacco to provide the smoking composition of this invention is A.C.S. grade zinc oxide which contains (on a weight basis) less than about 0.005% lead, 0.004% sulfate ion, 0.002% nitrate ion and 0.001% chloride ion. The particle size of the zinc oxide is finer than about 50 US mesh. Generally, the particle size is within the range of - 200 US mesh with the greater portion of the material being preferably finer than 100 US mesh.
The catalytic amount of zinc oxide associated with the tobacco in the smoking composition is in the range of between 0.1',ί to 15% by weight of the tobacco used to prepare the smoking composition.
Although the reduced yield of polycyclic compounds arising from pyrolytic reactions of the composition have been achieved at these levels, it has been found that the best results are obtained when the zinc oxide is in the preferred range of from 0.555 to 8% based upon the weight of the tobacco.
The nitrates which are employed in accordance with this invention are the Group Ila and lib metal nitrates, with calcium, magnesium and zinc nitrates being preferred. A nitrate which has been particularly effective in combination with zinc oxide and tobacco to provide the smoking composition of this invention is A.C.S grade Mg(N03)2.6H20 which contains (on a weight basis) less than about 0.000555 chloride ion, 0.005%. sulfate' ion and 0.0004% heavy metals (calculated as lead).
As noted above, the proportion of nitrate associated wiht zinc oxide and tobacco in the .smoking composition is in the range of from 0.25% to 0.7555 calculated as nitrate nitrogen. Although the amount of reduction of PCAH yield that is due to the nitrate can be increased as the level of nitrate is increased, the taste and aroma of smoke becomes progressively more obnoxious as the nitrate level is increased. Hence, in combination with zinc oxide we prefer to operate in the 0.25 to 0.60% nitrate nitrogen range.
The additives should be well dispersed throughout the tobacco so that they will be uniformly effective during the entire period during which the composition is smoked. Furthermore, it is important to ensure that the dispersion effectively contacts a maximum volume of smoke which is inhaled by the user. Since the catalytic activity of the zinc oxide is most likely a surface phenomenon, the greatest likelihood of maximum contact between the smoke being drawn in by the user and the zinc oxide is obtained when the area/volume ratio of the zinc oxide particles is maximized for a given weight of zinc oxide. For this reason, it is employed as a fine powder of particle size, preferably smaller than about 100 US mesh.
The calcium, magnesium and zinc nitrates are very soluble in water io and can be applied as a relatively concentrated solution which avoids the excessive wetting of tobacco and yet assures good distribution throughout the tobacco mass.
We have found that the combination of zinc Oxide and nitrate compound is most efficiently applied in a conventional casing solution of glycerin and propylene glycol wherein the zinc oxide crystals have been suspended and by adding a sufficient amount of water to solubilize the requisite amount of nitrate compound. Such a suspension-solution can be conveniently atomized on uncut tobacco strip by conventional casing apparatus.
Another method of application of the additives to the tobacco is to dry blend the zinc oxide, ground tobacco, a fibrous material and a binder. Dry blending, as in a conventional double cone blender effectively distributes the zinc oxide over the surface of the tobacco, including the pores within the tobacco surface which are large enough to accept the zinc oxide particles.
When required, dry blending is followed by wet mixing with water and casing materials in proportions sufficient to provide the resulting mixture with the appropriate consistency for conventional reconstituted tobacco sheet manufacturing operations. The sheet is then cut into strips and a solution of nitrate compound in water is applied to the strips. This is followed by a drying step if the tobacco moisture level needs to be adjusted. This material can be used in cigarette manufacture as such or it can be blended in any desired proportion with regular tobacco.
The fibrous material which is a constituent of the dry blend can be for example, α-cellulose or fibrous tobacco stem material. The binder portion of the dry blend may be sodium carboxymethyl cellulose, or a natural gum such as guar gum. The casing materials used in the wet mixing step are usually glycerine and propylene glycol. Of course, any other known fibrous material, binder or casing materials known to be useful in combination with tobacco products can be used in combination with or in place of those herein set forth.
The weight proportions of the additives described above for use in reconstituted tobacco sheets are within the following approximate weight ranges. The proportions shown are within the usual range required to provide useful tobacco products.
Material Height % Fibrous 4-8 Binder 1 - 20 Casing about 3-9 Comprising: a) Glycerin 4-6 b) propylene glycol 0.5-2 Tobacco balance to 100% The smoking composition may be further processed and formed into any desired shape or used loosely, e.g., cigars, cigarettes, and pipe tobacco in a manner well-known to those skilled in the tobacco art.
The following Example is illustrative: Example .58 lbs of ZnO and 28.52 lbs of Mg(N03)2.6H20 were suspended and dissolved respectively in a mixture of glycerin5 propylene glycol casing solution and water and sprayed in a conventional casing applicator onto 294 lbs of uncut strip tobacco blend. The treated tobacco was blended with 38.5 lbs of reconstituted tobacco sheet and 17.5 lbs of stems. The resulting blend was cut at 32 cuts per inch.
Blends containing only the zinc oxide and only the magnesium nitrate as well as a control blend containing neither additive were prepared in a similar manner.
All four samples were pyrolyzed in a special pyrolysis reactor consisting of a steel cylinder about 4 inches in diameter and 5 inches along with an annular space at the central perimeter covered with a stainless steel screen. Cut tobacco was packed into this reactor at densities similar to cigarette densities and the tobacco was lit at the exposed perimeter. The burning tobacco itself thus produced the necessary heat for pyrolysis and the reactor closely approximated on a large scale the conditions extant in a burning cigarette cone, The combustion and pyrolysis products were pumped out through a small tube positioned concentrically with the cylinder and the dry solids in the smoke were analyzed for PCAH content. The concentrations of PCAH in the test tobaccos, as a percent of the concentration of PCAH in the control tobacco are tabulated below for a typical run: - 10 42111 Sample ZnO Additive, wt% Mg(NO3)2* Concentrati on PCAH Relative Weight basis of to IR Control Analysis' 1 5.0 — 83 71 2 — 0.55 78 78 3 5.0 0.55 58 65 Control — 100 100 * As nitrate nitrogen ** From infrared spectral absorption in the region of aromatic C-H bonding vibrations. (11.9 - 14.0 u).
As is evident, sample No 3, illustrative of this invention, afforded materially lower concentrations of PCAH than were obtained with either zinc oxide or magnesium oxide alone.
Claims (9)
1. A smoking tobacco composition comprising: (a) tobacco; (b) finely divided zinc oxide in an amount, based on the weight of tobacco, of from O.T to 15 weight per cent; and (c) a nitrate of an element selected from Group Ila or Group lib of the Periodic Table in an amount of from 0.25 to 0.75 weight per cent calculated as nitrate nitrogen, based upon the weight of said tobacco.
2. A composition as claimed in Claim 1 wherein the said nitrate is a nitrate of calcium, magnesium or zinc.
3. A composition as claimed in Claim 1 or Claim 2, wherein the concentration of zinc oxide is from 0.5 to 8 weight per cent and the concentration of said nitrate is from 0.25 to 0.6 weight per cent calculated as nitrate nitrogen, based upon the weight of said tobacco.
4. A composition as claimed in Claim 1, wherein said nitrate is magnesium nitrate.
5. A composition as claimed in Claim 1 substantially as described herein with reference to the Example.
6. A cigarette containing a tobacco composition as claimed in any preceding claim.
7. A cigar containing a tobacco composition as claimed in any of Claims 1 to 5.
8. A pipe tobacco containing a tobacco composition as claimed in 25 any of Claims 1 to 5.
9. A process for making a composition as claimed in any of Claims 1 to 5 comprising admixing the said amounts of zinc oxide, said nitrate and tobacco to provide a uniform dispersion of said zinc oxide and nitrate throughout said tobacco.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US426114A US3893464A (en) | 1973-12-19 | 1973-12-19 | Tobacco composition |
Publications (2)
Publication Number | Publication Date |
---|---|
IE42111L IE42111L (en) | 1975-06-19 |
IE42111B1 true IE42111B1 (en) | 1980-06-04 |
Family
ID=23689354
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE2551/74A IE42111B1 (en) | 1973-12-19 | 1974-12-11 | Tobacco composition |
Country Status (15)
Country | Link |
---|---|
US (1) | US3893464A (en) |
JP (1) | JPS5238118B2 (en) |
AR (1) | AR209288A1 (en) |
AU (1) | AU466727B2 (en) |
BE (1) | BE823595A (en) |
BR (1) | BR7410542D0 (en) |
CA (1) | CA1026544A (en) |
CH (1) | CH595782A5 (en) |
DE (1) | DE2459891A1 (en) |
FR (1) | FR2255022B1 (en) |
GB (1) | GB1481718A (en) |
IE (1) | IE42111B1 (en) |
NL (1) | NL7416562A (en) |
PH (1) | PH11279A (en) |
ZA (1) | ZA747967B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6153119A (en) * | 1997-05-09 | 2000-11-28 | Sung; Michael | Method and product for reducing tar and nicotine in cigarettes |
WO2002037990A2 (en) * | 2000-11-10 | 2002-05-16 | Vector Tobacco Ltd. | Method and product for removing carcinogens from tobacco smoke |
EP1441603A2 (en) * | 2001-11-09 | 2004-08-04 | Vector Tobacco Inc. | Method and composition for mentholation of charcoal filtered cigarettes |
EP1455609A2 (en) * | 2001-12-19 | 2004-09-15 | Vector Tobacco Inc. | Method and compositions for imparting cooling effect to tobacco products |
DE60215385T2 (en) * | 2001-12-19 | 2007-10-25 | Vector Tobacco Inc.(N.D.Ges.D.Staates Virginia) | METHOD AND COMPOSITION FOR THE MENTHOLENREICHICHUNG OF CIGARETTES |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2429567A (en) * | 1941-12-31 | 1947-10-21 | American Mach & Foundry | Denicotinizing tobacco |
US3003895A (en) * | 1957-12-06 | 1961-10-10 | Heinr Borgwaldt | Tobacco product and method of making the same |
DE1517321A1 (en) * | 1962-07-12 | 1969-09-04 | Reemtsma H F & Ph | Process for treating tobacco to improve its smoking properties and the coloring of the ashes |
US3380458A (en) * | 1966-02-15 | 1968-04-30 | Eastman Kodak Co | Method for producing a cigarette with low tar yield |
US3720214A (en) * | 1970-12-03 | 1973-03-13 | Liggett & Myers Inc | Smoking composition |
ZA723458B (en) * | 1971-06-11 | 1973-03-28 | British American Tobacco Co | Improvements relating to reconstituted-tobacco smoking materials |
-
1973
- 1973-12-19 US US426114A patent/US3893464A/en not_active Expired - Lifetime
-
1974
- 1974-12-10 GB GB53408/74A patent/GB1481718A/en not_active Expired
- 1974-12-11 IE IE2551/74A patent/IE42111B1/en unknown
- 1974-12-12 FR FR7440970A patent/FR2255022B1/fr not_active Expired
- 1974-12-12 PH PH16613A patent/PH11279A/en unknown
- 1974-12-13 ZA ZA00747967A patent/ZA747967B/en unknown
- 1974-12-16 AU AU76484/74A patent/AU466727B2/en not_active Expired
- 1974-12-17 CA CA216,240A patent/CA1026544A/en not_active Expired
- 1974-12-17 BR BR10542/74A patent/BR7410542D0/en unknown
- 1974-12-18 AR AR256966A patent/AR209288A1/en active
- 1974-12-18 DE DE19742459891 patent/DE2459891A1/en active Pending
- 1974-12-18 CH CH1690274A patent/CH595782A5/xx not_active IP Right Cessation
- 1974-12-18 JP JP49145485A patent/JPS5238118B2/ja not_active Expired
- 1974-12-19 BE BE151717A patent/BE823595A/en unknown
- 1974-12-19 NL NL7416562A patent/NL7416562A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
AR209288A1 (en) | 1977-04-15 |
AU7648474A (en) | 1975-11-06 |
GB1481718A (en) | 1977-08-03 |
ZA747967B (en) | 1975-12-31 |
DE2459891A1 (en) | 1975-06-26 |
JPS5238118B2 (en) | 1977-09-27 |
CH595782A5 (en) | 1978-02-28 |
NL7416562A (en) | 1975-06-23 |
US3893464A (en) | 1975-07-08 |
AU466727B2 (en) | 1975-11-06 |
IE42111L (en) | 1975-06-19 |
FR2255022A1 (en) | 1975-07-18 |
BR7410542D0 (en) | 1975-09-02 |
PH11279A (en) | 1977-11-02 |
FR2255022B1 (en) | 1977-11-10 |
JPS5094198A (en) | 1975-07-26 |
BE823595A (en) | 1975-04-16 |
CA1026544A (en) | 1978-02-21 |
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