IE34185B1 - A process for epoxidizing olefins with organic hydroperoxides - Google Patents
A process for epoxidizing olefins with organic hydroperoxidesInfo
- Publication number
- IE34185B1 IE34185B1 IE401/70A IE40170A IE34185B1 IE 34185 B1 IE34185 B1 IE 34185B1 IE 401/70 A IE401/70 A IE 401/70A IE 40170 A IE40170 A IE 40170A IE 34185 B1 IE34185 B1 IE 34185B1
- Authority
- IE
- Ireland
- Prior art keywords
- silica
- catalysts
- molybdenum
- didymium
- april
- Prior art date
Links
- 150000002432 hydroperoxides Chemical class 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 6
- 239000000377 silicon dioxide Substances 0.000 abstract 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 3
- 229910052750 molybdenum Inorganic materials 0.000 abstract 3
- 239000011733 molybdenum Substances 0.000 abstract 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- 229910000722 Didymium Inorganic materials 0.000 abstract 2
- 241000224487 Didymium Species 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052796 boron Inorganic materials 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000006735 epoxidation reaction Methods 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229910052909 inorganic silicate Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- -1 miobium Chemical compound 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 239000010955 niobium Substances 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyurethanes Or Polyureas (AREA)
- Epoxy Compounds (AREA)
Abstract
1,249,079. Epoxidation catalysts. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 1 April, 1970 [2 April, 1969], No. 15373/70. Heading B1E. [Also in Division C2] Catalysts used in the epoxidation of olefinic compounds with organic hydroperoxides comprise titanium in chemical combination with a solid silica and/or an inorganic silicate. In addition the catalyst may contain a promoter e.g. a compound of magnesium, calcium, strontium or barium and also an oxide or hydroxide of boron, tin, miobium, tantalum, chromium, molybdenum, rhenium, uranium, bismuth or rare earth metals (atomic numbers 57-71). Preferably the catalyst has a specific surface area of at least 1m<SP>2</SP>/g. In the examples catalysts are used comprising in addition to the titanium compound the following:-(a) zirconium, (b) niobium, (c) boron, (d) tin, (e) "didymium" (a complex mixture of rare earth metals), (f) molybdenum, (g) molybdenum and didymium and (h) alumina alone or with magnesium or calcium. For comparative purposes examples are given of the use of other catalysts e.g. mixtures of titania and silica or silicates, various other metals are silica and various metal compounds without silica.
[GB1249079A]
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US81292069A | 1969-04-02 | 1969-04-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
IE34185L IE34185L (en) | 1970-10-02 |
IE34185B1 true IE34185B1 (en) | 1975-03-05 |
Family
ID=25210968
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE401/70A IE34185B1 (en) | 1969-04-02 | 1970-04-01 | A process for epoxidizing olefins with organic hydroperoxides |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS5030049B1 (en) |
AT (1) | AT302983B (en) |
BE (1) | BE748314A (en) |
BR (1) | BR7017923D0 (en) |
CH (1) | CH543497A (en) |
DE (1) | DE2015503C3 (en) |
DK (1) | DK133746B (en) |
ES (1) | ES378130A1 (en) |
FR (1) | FR2042772A5 (en) |
GB (1) | GB1249079A (en) |
IE (1) | IE34185B1 (en) |
NL (1) | NL145233C (en) |
NO (1) | NO127499B (en) |
SE (1) | SE375530B (en) |
ZA (1) | ZA702171B (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3322745A1 (en) * | 1983-06-24 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING OXIRANES |
GB8813484D0 (en) | 1988-06-08 | 1988-07-13 | Shell Int Research | Process for preparation of oxirane compound |
US5795555A (en) * | 1994-11-24 | 1998-08-18 | Alive; Keshavaraja | Micro-meso porous amorphous titanium silicates and a process for preparing the same |
US5723637A (en) * | 1995-12-06 | 1998-03-03 | Sumitomo Chemical Company, Limited | Process for producing propylene oxide |
US5840933A (en) * | 1996-10-29 | 1998-11-24 | Arco Chemical Technology, L.P. | Catalytic converter system and progress |
US5760253A (en) * | 1997-01-29 | 1998-06-02 | Arco Chemical Technology, L.P. | Catalytic converter and method for highly exothermic reactions |
US5932751A (en) * | 1998-06-23 | 1999-08-03 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
MY131860A (en) * | 2000-06-21 | 2007-09-28 | Shell Int Research | Process for preparation of catalyst and use there of |
JP4694712B2 (en) * | 2001-01-15 | 2011-06-08 | 丸善石油化学株式会社 | Titanium-containing solid catalyst and method for producing epoxy compound using the same |
CN1216045C (en) * | 2001-02-19 | 2005-08-24 | 隆萨股份公司 | Process and catalyst for preparation of acetylpyridines |
US7067673B2 (en) | 2001-02-19 | 2006-06-27 | Lonza Ag | Process and catalyst for the preparation of acetylpyridines |
US6562987B1 (en) | 2002-02-28 | 2003-05-13 | Arco Chemical Technology, L.P. | Method for highly exothermic epoxidation reactions |
FR2841797B1 (en) * | 2002-07-03 | 2005-08-05 | Centre Nat Rech Scient | CATALYSTS BASED ON TUNGSTEN |
DE102006040432A1 (en) | 2006-08-29 | 2008-03-20 | Oxeno Olefinchemie Gmbh | Catalyst and process for the preparation of isoolefins |
CN101518729B (en) * | 2008-02-26 | 2013-04-24 | 拜耳材料科技(中国)有限公司 | Catalyst used for synthesizing alkyl carbamate and preparing method and application thereof |
CN111377951B (en) * | 2018-12-28 | 2022-09-20 | 万华化学集团股份有限公司 | Rare earth metal compound, preparation method, composition and method for catalyzing olefin epoxidation |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1518644A1 (en) * | 1965-04-09 | 1969-04-03 | Huels Chemische Werke Ag | Process for the catalytic epoxidation of olefinic compounds |
-
1970
- 1970-04-01 NO NO01186/70*[A patent/NO127499B/no unknown
- 1970-04-01 ES ES378130A patent/ES378130A1/en not_active Expired
- 1970-04-01 BE BE748314D patent/BE748314A/en not_active IP Right Cessation
- 1970-04-01 NL NL7004582.A patent/NL145233C/en not_active IP Right Cessation
- 1970-04-01 JP JP45027353A patent/JPS5030049B1/ja active Pending
- 1970-04-01 BR BR217923/70A patent/BR7017923D0/en unknown
- 1970-04-01 DE DE2015503A patent/DE2015503C3/en not_active Expired
- 1970-04-01 IE IE401/70A patent/IE34185B1/en unknown
- 1970-04-01 CH CH482970A patent/CH543497A/en not_active IP Right Cessation
- 1970-04-01 SE SE7004441A patent/SE375530B/xx unknown
- 1970-04-01 FR FR7011643A patent/FR2042772A5/fr not_active Expired
- 1970-04-01 ZA ZA702171A patent/ZA702171B/en unknown
- 1970-04-01 GB GB05373/70D patent/GB1249079A/en not_active Expired
- 1970-04-01 AT AT297770A patent/AT302983B/en active
- 1970-04-01 DK DK163670AA patent/DK133746B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE2015503A1 (en) | 1970-10-29 |
ES378130A1 (en) | 1972-06-01 |
GB1249079A (en) | 1971-10-06 |
ZA702171B (en) | 1971-11-24 |
NL145233B (en) | 1975-03-17 |
AT302983B (en) | 1972-11-10 |
CH543497A (en) | 1973-10-31 |
NL145233C (en) | 1980-12-15 |
BR7017923D0 (en) | 1973-01-11 |
DE2015503C3 (en) | 1981-04-09 |
NO127499B (en) | 1973-07-02 |
DK133746B (en) | 1976-07-12 |
DK133746C (en) | 1976-11-29 |
JPS5030049B1 (en) | 1975-09-29 |
NL7004582A (en) | 1970-10-06 |
DE2015503B2 (en) | 1980-04-24 |
IE34185L (en) | 1970-10-02 |
FR2042772A5 (en) | 1971-02-12 |
SE375530B (en) | 1975-04-21 |
BE748314A (en) | 1970-10-01 |
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