HUP0004247A2 - Ikerionos katalizátoraktivátor - Google Patents

Ikerionos katalizátoraktivátor

Info

Publication number
HUP0004247A2
HUP0004247A2 HU0004247A HUP0004247A HUP0004247A2 HU P0004247 A2 HUP0004247 A2 HU P0004247A2 HU 0004247 A HU0004247 A HU 0004247A HU P0004247 A HUP0004247 A HU P0004247A HU P0004247 A2 HUP0004247 A2 HU P0004247A2
Authority
HU
Hungary
Prior art keywords
group
atoms
hydrogen
activator
regardless
Prior art date
Application number
HU0004247A
Other languages
English (en)
Inventor
Edmund M. Carnahan
Grant B. Jacobsen
Jerzy Klosin
David R. Neithamer
Peter N. Nickias
David J. Schwartz
Original Assignee
The Dow Chemical Co.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Co. filed Critical The Dow Chemical Co.
Publication of HUP0004247A2 publication Critical patent/HUP0004247A2/hu
Publication of HUP0004247A3 publication Critical patent/HUP0004247A3/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A találmány katalizátor aktivátor vegyületekre vonatkozik, amelyektelítetlen vegyületek addíciós polimerizációjában alkalmazhatók egy 3-10 csoportbeli fém komplexével együtt. Az aktivátor egy (I) vagy (II)általános képletű ikerionos vegyületet tartalmaz, ahol a képletben L+jelentése az Elemek Periódusos Rendszerének 15. csoportjába tartozóelem protonált származéka, amely további két hidrokarbil-szubsztituenst hordoz, amelyek egyenként 1-50 szénatomot tartalmaznak,vagy egy, az Elemek Periódusos Rendszerének 14. csoportjába tartozóelem pozitívan töltött származéka, amely 14. csoportbeli elem háromhidrokarbil-szubsztituenssel szubsztituált, amelyek egyenként 1-50szénatomot tartalmaznak; Rl jelentése kétértékű, 1-40 hidrogénatomtóleltérő atomot tartalmazó kapcsolódó csoport; R2 jelentése -függetlenül az egyes előfordulásainál - 1-50 hidrogénatomtól eltérőatomot tartalmazó ligandumcsoport, azzal a megkötéssel, hogy atöltésegyensúlyhoz megfelelő számban fordul elő, R2 jelentése L+-R1-;R4 jelentése áthidaló hidrid- vagy halogenidcsoport, vagy egykétértékű kapcsolódó csoport, amely 1-40 hidrogénatomtól eltérő atomottartalmaz; M1 jelentése bór-, alumínium- vagy galliumatom; Arfjelentése - függetlenül az egyes előfordulásainál - egyvegyértékű,fluorozott szerves csoport, amely 6-100 hidrogénatomtól eltérő atomottartalmaz; Y jelentése 15. csoportba tartozó elem; és Z jelentése 14. csoportba tartozó elem. A találmány vonatkoziktovábbá az aktivátor vegyületeket tartalmazó katalizátorrendszerekreés az ezek jelenlétében kivitelezett a-olefin polimerizációs eljárásrais. Ó
HU0004247A 1997-08-01 1998-06-29 Zwitterionic catalyst activator HUP0004247A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5458897P 1997-08-01 1997-08-01
PCT/US1998/013504 WO1999006449A1 (en) 1997-08-01 1998-06-29 Zwitterionic catalyst activator

Publications (2)

Publication Number Publication Date
HUP0004247A2 true HUP0004247A2 (hu) 2001-05-28
HUP0004247A3 HUP0004247A3 (en) 2001-06-28

Family

ID=21992140

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0004247A HUP0004247A3 (en) 1997-08-01 1998-06-29 Zwitterionic catalyst activator

Country Status (19)

Country Link
US (1) US6344529B1 (hu)
EP (1) EP1000093B1 (hu)
JP (1) JP2001512141A (hu)
KR (1) KR20010014290A (hu)
CN (1) CN1261898A (hu)
AR (1) AR016576A1 (hu)
AT (1) ATE210685T1 (hu)
AU (1) AU733487B2 (hu)
BR (1) BR9815185A (hu)
CA (1) CA2291616A1 (hu)
DE (1) DE69802939T2 (hu)
HU (1) HUP0004247A3 (hu)
ID (1) ID23037A (hu)
NO (1) NO996322D0 (hu)
PL (1) PL337711A1 (hu)
TR (1) TR199903150T2 (hu)
TW (1) TW482777B (hu)
WO (1) WO1999006449A1 (hu)
ZA (1) ZA986886B (hu)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100674073B1 (ko) * 2000-03-07 2007-01-26 신에쓰 가가꾸 고교 가부시끼가이샤 화학 증폭 포지티브형 레지스트 재료
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
JP2004513193A (ja) * 2000-11-06 2004-04-30 エクソンモービル・ケミカル・パテンツ・インク オレフィン重合のためのフッ素化両性助触媒活性剤
US6660679B2 (en) * 2001-06-18 2003-12-09 Univation Technologies, Llc Catalyst system and its use in a polymerization process
EP1599514A2 (en) * 2003-03-06 2005-11-30 Basell Polyolefine GmbH Catalyst system for the polymerization of olefins
ATE504349T1 (de) 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
JP5399072B2 (ja) * 2005-09-12 2014-01-29 アベラ ファーマスーティカルズ インコーポレイテッド ジメチルスルホキシド（ｄｍｓｏ）若しくは関連化合物、又はそれに関連する臭気を除去するシステム
WO2008125911A2 (en) 2006-11-14 2008-10-23 Stephan Consulting Corporation Hydrogen splitting composition
SG11202110448UA (en) * 2019-03-28 2021-10-28 Dow Global Technologies Llc Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators
CN113490692B (zh) 2019-08-26 2023-03-28 株式会社Lg化学 催化剂组合物和使用该催化剂组合物制备烃类树脂的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5447895A (en) * 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts

Also Published As

Publication number Publication date
ID23037A (id) 2000-01-06
AU733487B2 (en) 2001-05-17
DE69802939D1 (de) 2002-01-24
NO996322L (no) 1999-12-20
EP1000093B1 (en) 2001-12-12
NO996322D0 (no) 1999-12-20
PL337711A1 (en) 2000-08-28
ATE210685T1 (de) 2001-12-15
WO1999006449A1 (en) 1999-02-11
CA2291616A1 (en) 1999-02-11
CN1261898A (zh) 2000-08-02
EP1000093A1 (en) 2000-05-17
DE69802939T2 (de) 2002-11-21
BR9815185A (pt) 2000-10-10
TR199903150T2 (en) 2000-07-21
TW482777B (en) 2002-04-11
JP2001512141A (ja) 2001-08-21
US6344529B1 (en) 2002-02-05
AU8473698A (en) 1999-02-22
AR016576A1 (es) 2001-07-25
ZA986886B (en) 2000-01-31
HUP0004247A3 (en) 2001-06-28
KR20010014290A (ko) 2001-02-26

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