HK1163589A1 - Processes for making ethanol from acetic acid - Google Patents

Processes for making ethanol from acetic acid

Info

Publication number
HK1163589A1
HK1163589A1 HK12104379.9A HK12104379A HK1163589A1 HK 1163589 A1 HK1163589 A1 HK 1163589A1 HK 12104379 A HK12104379 A HK 12104379A HK 1163589 A1 HK1163589 A1 HK 1163589A1
Authority
HK
Hong Kong
Prior art keywords
processes
acetic acid
making ethanol
ethanol
making
Prior art date
Application number
HK12104379.9A
Other languages
Chinese (zh)
Inventor
．約翰斯頓
．陳
．金米奇
．查普曼
．津克
．魏納
．波茨
．耶夫蒂奇
Original Assignee
國際人造絲公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by 國際人造絲公司 filed Critical 國際人造絲公司
Publication of HK1163589A1 publication Critical patent/HK1163589A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
HK12104379.9A 2009-10-26 2012-05-04 Processes for making ethanol from acetic acid HK1163589A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
PCT/US2010/022947 WO2011053365A1 (en) 2009-10-26 2010-02-02 Processes for making ethanol from acetic acid

Publications (1)

Publication Number Publication Date
HK1163589A1 true HK1163589A1 (en) 2012-09-14

Family

ID=46506678

Family Applications (1)

Application Number Title Priority Date Filing Date
HK12104379.9A HK1163589A1 (en) 2009-10-26 2012-05-04 Processes for making ethanol from acetic acid

Country Status (11)

Country Link
EP (1) EP2493608A1 (en)
JP (1) JP2013508362A (en)
CN (1) CN102271805B (en)
AU (1) AU2010313767A1 (en)
BR (1) BR112012009825A2 (en)
CA (1) CA2777754A1 (en)
HK (1) HK1163589A1 (en)
IL (1) IL219398A0 (en)
MX (1) MX2012004837A (en)
RU (1) RU2012121861A (en)
WO (1) WO2011053365A1 (en)

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US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
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US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
AU2011213125B2 (en) * 2010-02-02 2014-07-17 Celanese International Corporation Process for purifying ethanol
US8552224B2 (en) 2010-05-07 2013-10-08 Celanese International Corporation Processes for maximizing ethanol formation in the hydrogenation of acetic acid
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
WO2011097193A2 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8222466B2 (en) * 2010-02-02 2012-07-17 Celanese International Corporation Process for producing a water stream from ethanol production
US8541633B2 (en) 2010-02-02 2013-09-24 Celanese International Corporation Processes for producing anhydrous ethanol compositions
CA2787419A1 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Preparation and use of a catalyst for producing ethanol comprising a crystalline support modifier
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
WO2011097220A2 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Process for producing ethanol using an extractive distillation column
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8680342B2 (en) 2010-05-07 2014-03-25 Celanese International Corporation Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water
US9024083B2 (en) 2010-07-09 2015-05-05 Celanese International Corporation Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US9024085B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Process to reduce ethanol recycled to hydrogenation reactor
US9024082B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Using a dilute acid stream as an extractive agent
US9000232B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Extractive distillation of crude alcohol product
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8927788B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process to recover alcohol with reduced water from overhead of acid column
US8933278B2 (en) 2011-04-26 2015-01-13 Celanese International Corporation Process for producing ethanol and reducing acetic acid concentration
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
US8884081B2 (en) 2011-04-26 2014-11-11 Celanese International Corporation Integrated process for producing acetic acid and alcohol
US8927787B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process for controlling a reboiler during alcohol recovery and reduced ester formation
US9024084B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Reduced energy alcohol separation process having controlled pressure
US8877987B2 (en) 2011-08-03 2014-11-04 Celanese International Corportation Process for producing anhydrous ethanol using extractive distillation column
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
CA2851254A1 (en) 2011-10-05 2013-04-11 Shadi MOGHADDAS Efficient processes for large scale preparation of phophaplatins antitumor agents
US8637715B2 (en) * 2011-12-21 2014-01-28 Celanese International Corporation Catalysts comprising secondary noble metals and process for producing ethanol
CN103282333A (en) * 2011-12-22 2013-09-04 国际人造丝公司 Ethanol process using hydrogenation catalysts having an amorphous support
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
US8455702B1 (en) 2011-12-29 2013-06-04 Celanese International Corporation Cobalt and tin catalysts for producing ethanol
WO2013101305A1 (en) * 2011-12-30 2013-07-04 Celanese International Corporation Pressure driven distillation for producing and recovering ethanol from hydrogenation process
BR112014015584A8 (en) * 2012-01-06 2017-07-04 Celanese Int Corp cobalt modified support hydrogenation catalysts
CN103874545B (en) * 2012-01-06 2016-08-24 国际人造丝公司 Utilize the method that the hydrogenation catalyst prepared by polyoxometallate precursor produces ethanol
US9051235B2 (en) 2012-02-07 2015-06-09 Celanese International Corporation Process for producing ethanol using a molar excess of hydrogen
US9050585B2 (en) 2012-02-10 2015-06-09 Celanese International Corporation Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
US8927786B2 (en) 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
US9073042B2 (en) 2012-03-14 2015-07-07 Celanese International Corporation Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter
US8975452B2 (en) 2012-03-28 2015-03-10 Celanese International Corporation Process for producing ethanol by hydrocarbon oxidation and hydrogenation or hydration
CN103787827B (en) * 2012-10-31 2015-10-07 中国石油化工股份有限公司 Carboxylic acid selec-tive hydrogenation prepares the method for alcohol
CN103787828B (en) * 2012-10-31 2015-10-07 中国石油化工股份有限公司 A kind of method applied cobalt B catalyst and alcohol prepared by carboxylic acid gas phase hydrogenation
CN103170352B (en) * 2013-03-28 2015-01-14 湖南长岭石化科技开发有限公司 Sec-butyl acetate hydrogenation catalyst and preparation method and application thereof
CN104117354A (en) * 2013-04-26 2014-10-29 中国科学院大连化学物理研究所 Method for preparation of monohydric alcohol or dihydric alcohol by low temperature selective hydrogenation of organic acid water phase
CN103433039B (en) * 2013-09-11 2015-11-11 神华集团有限责任公司 A kind of preparation method of acetic ester hydrogenation catalyst
CN108358752A (en) * 2018-04-18 2018-08-03 肖锦 A kind of method of acetic acid hydrogenation ethyl alcohol
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Also Published As

Publication number Publication date
WO2011053365A1 (en) 2011-05-05
AU2010313767A1 (en) 2012-05-17
MX2012004837A (en) 2012-05-29
BR112012009825A2 (en) 2016-10-18
EP2493608A1 (en) 2012-09-05
CN102271805A (en) 2011-12-07
CN102271805B (en) 2014-07-09
CA2777754A1 (en) 2011-05-05
RU2012121861A (en) 2013-12-10
AU2010313767A2 (en) 2012-07-26
JP2013508362A (en) 2013-03-07
IL219398A0 (en) 2012-06-28

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PC Patent ceased (i.e. patent has lapsed due to the failure to pay the renewal fee)

Effective date: 20190129