GB998604A - Thiophosphonates and compositions containing the same - Google Patents
Thiophosphonates and compositions containing the sameInfo
- Publication number
- GB998604A GB998604A GB835762A GB835762A GB998604A GB 998604 A GB998604 A GB 998604A GB 835762 A GB835762 A GB 835762A GB 835762 A GB835762 A GB 835762A GB 998604 A GB998604 A GB 998604A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halogen
- hydrocarbon group
- aryl
- free
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical group 0.000 abstract 6
- 235000013350 formula milk Nutrition 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 229910052794 bromium Inorganic materials 0.000 abstract 3
- 229910052801 chlorine Inorganic materials 0.000 abstract 3
- 125000005843 halogen group Chemical group 0.000 abstract 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- 229910052731 fluorine Inorganic materials 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 239000005645 nematicide Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000008188 pellet Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- -1 thiophosphoryl halide Chemical class 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4084—Esters with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises O-aryl thiophos-phonates having the general formula <FORM:0998604/C2/1> in which n is 1 or 2, R1 is a hydrocarbon group having 1 to 8 carbon atoms which is free from olefinic and acetylenic unsaturation and R is a hydrocarbon group having 1 to 8 carbon atoms or a halogen-substituted C2-C6 aliphatic hydro carbon group which contains only halogen atoms having an atomic number of from 8 to 36 (i.e. Cl, Br or F) and in which the a -carbon atom thereof is free from halogen-substituents. They may be obtained by reacting a thiophosphoryl halide of the formula <FORM:0998604/C2/2> wherein Z is Cl or Br, with a phenol of the for mula <FORM:0998604/C2/3> in the presence of an acid acceptor e.g. sodium or potassium carbonate or a tertiary amine. R1 and R (when hydrocarbon) may be alkyl, aryl, alkaryl, aralkyl or cycloalkyl and R may additionally be an alkenyl or alkynyl group. Preferred reaction temperatures are from 10 DEG to 120 DEG C. and an inert organic solvent may be present, e.g. benzene, toluene, xylene, acetone, butanone or dioxane. Several examples are given and the products have pesticidal proper ties (see Division A5).ALSO:An insecticidal composition comprises an inert solid or liquid carrier and an O-aryl thiophosphonate having the general formula <FORM:0998604/A5-A6/1> wherein n is 1 or 2, R1 is a C1-C8 hydrocarbon group free from olefinic or acetylenic unsaturation and R is a C1-C8 hydrocarbon group or a halogen-substituted C2-C6 aliphatic hydrocarbon group which contains only halogen atoms having an atomic number of from 8 to 36 (i.e. Cl, Br or F) and in which the a -carbon atom thereof is free from halogen substituents (see Division C2). The composition may be in the form of pellets, granules, powder, dust, aerosol, spray concentrate, suspension, or emulsion or in semi-solid form. Other pesticides including nematocides, bactericides and herbicides may also be present. The radical R1 in the formula and the radical R when hydrocarbon may be alkyl, aryl, alkaryl, aralkyl or cycloalkyl and R may additionally be an alkenyl or alkynyl group.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US93043A US3082147A (en) | 1961-03-03 | 1961-03-03 | Insecticidal o-(aryl) phosphonothioates |
| US93311A US3082148A (en) | 1961-03-06 | 1961-03-06 | Insecticidal phosphonothioates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB998604A true GB998604A (en) | 1965-07-14 |
Family
ID=26786746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB835762A Expired GB998604A (en) | 1961-03-03 | 1962-03-05 | Thiophosphonates and compositions containing the same |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB998604A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9398771B2 (en) | 2011-11-23 | 2016-07-26 | Roderick William Phillips | Spray apparatuses, uses of diatomaceous earth, and methods of controlling insect populations |
| US10485351B2 (en) | 2011-05-03 | 2019-11-26 | Roderick William Phillips | Headboard apparatus for holding a decorative cover |
-
1962
- 1962-03-05 GB GB835762A patent/GB998604A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10485351B2 (en) | 2011-05-03 | 2019-11-26 | Roderick William Phillips | Headboard apparatus for holding a decorative cover |
| US11140993B2 (en) | 2011-05-03 | 2021-10-12 | Roderick William Phillips | Headboard apparatus for holding a decorative cover and having diatomaceous earth incorporated therein for pest control |
| US9398771B2 (en) | 2011-11-23 | 2016-07-26 | Roderick William Phillips | Spray apparatuses, uses of diatomaceous earth, and methods of controlling insect populations |
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