GB998439A - Thermoplastic compositions - Google Patents

Thermoplastic compositions

Info

Publication number
GB998439A
GB998439A GB5064063A GB5064063A GB998439A GB 998439 A GB998439 A GB 998439A GB 5064063 A GB5064063 A GB 5064063A GB 5064063 A GB5064063 A GB 5064063A GB 998439 A GB998439 A GB 998439A
Authority
GB
United Kingdom
Prior art keywords
acid
copolymer
blended
diamine
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5064063A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB998439A publication Critical patent/GB998439A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule

Abstract

A thermoplastic composition comprises a mixture of from 1 to 50% by weight of an olefin copolymer in the form of particles having a diameter of less than 5 microns dispersed in from 99 to 50% by weight of a linear polyamide, the olefin copolymer containing from 0.1 to 10% mole of acid groups. Specified polyamides are those derived from dicarboxylic acids, e.g. oxalic, succinic, adipic, suberic, sebacic and terephthalic acid and diamines, e.g. hydrazine, ethylene diamine, pentamethylene diamine, hexamethylene diamine, decamethylene diamine, tetramethylene diamine, bis-(p-aminocyclohexyl) methane, p-phenylene diamine and m-phenylene diamine; or from amino acids or derivatives thereof, e.g. carbamic acid, 6-aminocaproic 11-aminoundecanoic acid, 12-aminostearic acid, leucine, b -phenylalanine and 1-aminocyclohexane carboxylic acid and copolyamides thereof. Specified copolymers are those derived from 1-olefines and a : b -unsaturated monocarboxylic acids; by graft polymerization of the acid comonomer to polyolefines and sulphonated ethylene-styrene copolymers. In the Examples: (1), (2), (3a) to (3c), (4), (5), (11) and (13) polyhexamethylene adipamide is blended with a copolymer of ethylene and methacrylic acid; (3d) to (3f) a copolymer of hexamethylene diamine, adipic acid and caprolactam is blended with a copolymer of ethylene and methacrylic acid; (6) polyhexamethylene adipamide is blended with a copolymer of propylene and undeconoic acid; (7) poly-butene-1 is graft polymerized and acrylic acid and the resultant polymer blended with polycaprolactam; (8) polyhexamethylene sebacamide is blended with the reaction product of isotactic poly-4-methyl-pentene-1 with a styrene-maleic acid copolymer; (9) a sulphonated copolymer ethylene and styrene is blended with polyhexamethylene adipamide; (10) a polyamide made from diethyl oxalate, 3-methoxy hexamethylene diamine and hexamethylene diamine is blended with an ethylenemethacrylic acid copolymer and (12) a phenyl isocyanate modified polyhexamethylene adipamide is blended with an ethylene-methacrylic acid copolymer. Specifications 461,236, 535,421, 548,263 and 619,707 are referred to.
GB5064063A 1962-12-31 1963-12-23 Thermoplastic compositions Expired GB998439A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US24822962A 1962-12-31 1962-12-31

Publications (1)

Publication Number Publication Date
GB998439A true GB998439A (en) 1965-07-14

Family

ID=22938222

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5064063A Expired GB998439A (en) 1962-12-31 1963-12-23 Thermoplastic compositions

Country Status (4)

Country Link
BE (1) BE641952A (en)
DE (1) DE1241606B (en)
GB (1) GB998439A (en)
NL (2) NL146193B (en)

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3755221A (en) * 1971-01-18 1973-08-28 Ici Ltd Fast cycling polyamide molding composition which contains a particulate nucleating agent, an alkylene diamide, and a metal salt of a monocarboxylic acid
DE2551014A1 (en) * 1974-11-13 1976-05-20 Du Pont THERMOPLASTIC GRAFT MIXED COPOLYMERISATES AND METHOD FOR THEIR PRODUCTION
DE2622973A1 (en) * 1975-05-23 1976-12-09 Du Pont CONSOLIDATED MULTI-PHASE THERMOPLASTIC COMPOSITION AND METHOD OF MANUFACTURING THE SAME
US4174358A (en) 1975-05-23 1979-11-13 E. I. Du Pont De Nemours And Company Tough thermoplastic nylon compositions
EP0030903A2 (en) * 1979-12-10 1981-06-24 Rhone-Poulenc Specialites Chimiques Polyphased polyamide compositions with particular shock resistant properties, and processes for their preparation
US4283502A (en) * 1979-04-30 1981-08-11 E. I. Du Pont De Nemours And Company Polyamide resins
EP0031287B1 (en) * 1979-12-10 1984-04-11 Rhone-Poulenc Specialites Chimiques Polyphased compositions of polyamides and polyester amides
JPS5989353A (en) * 1982-11-15 1984-05-23 Ube Ind Ltd Preparation of impact-resistant polyamide
JPS59164359A (en) * 1983-03-08 1984-09-17 Ube Ind Ltd Production of impact-resistant polyamide
GB2139234A (en) * 1983-05-06 1984-11-07 Dow Chemical Co Blown nylon film and process for the preparation thereof
JPS59197459A (en) * 1983-04-26 1984-11-09 Ube Ind Ltd Production of polyamide composition
JPS59215352A (en) * 1983-05-23 1984-12-05 Ube Ind Ltd Production of impact-resistant polyamide
JPS6069159A (en) * 1983-09-27 1985-04-19 Ube Ind Ltd Production of polyamide composition
JPS60112853A (en) * 1983-11-25 1985-06-19 Ube Ind Ltd Production of polyamide composition
JPS60137961A (en) * 1983-12-26 1985-07-22 Ube Ind Ltd Manufacture of polyamide composition
US4544702A (en) * 1984-06-11 1985-10-01 Uniroyal, Inc. Modified ionic elastomer and blend with nylon
US4628072A (en) * 1981-08-13 1986-12-09 Asahi Kasei Kogyo Kabushiki Kaisha Modified block copolymer composition
FR2592388A1 (en) * 1985-12-30 1987-07-03 Atochem POLYAMIDE, POLYETHERAMIDE AND THERMOPLASTIC ELASTOMER ALLOYS
EP0229439A1 (en) * 1985-07-29 1987-07-22 ARCO Chemical Technology, L.P. Impact resistant polyamide molding compositions
DE3728334A1 (en) * 1986-08-26 1988-03-03 Inventa Ag THERMOPLASTICALLY DEFORMABLE, IMPACT POLYAMIDE ALLOYS AND THEIR USE
US4739016A (en) * 1984-06-11 1988-04-19 Uniroyal Chemical Company, Inc. Modified ionic elastomer and blend with nylon
US4847330A (en) * 1986-12-30 1989-07-11 Basf Aktiengesellschaft Thermoplastic molding materials based on nylons and ethylene copolymers
US5112908A (en) * 1986-12-23 1992-05-12 E. I. Du Pont De Nemours And Company Tough polyamide compositions having high melt flow for complex moldings
US5122569A (en) * 1988-12-22 1992-06-16 Ferro Corporation Toughened compositions of polyamide and functionalized rubber block or graft copolymers
US5212238A (en) * 1988-12-22 1993-05-18 Ferro Corporation Toughened compositions of polyamide and functionalized rubber block or graft copolymers
US5332782A (en) * 1986-08-27 1994-07-26 Rohm And Haas Company Impact strength modifiers for thermoplastic polymers
US5342886A (en) * 1988-03-24 1994-08-30 Atochem α-monoolefinic graft copolymers
US5468259A (en) * 1992-12-07 1995-11-21 Sheth; Paresh J. Dyeable polyolefin compositions and dyeing polyolefin compositions
US6077906A (en) * 1998-03-11 2000-06-20 Thiruvengada; Seshan Nylon modifiers hauling enhanced flow properties
WO2007120707A2 (en) * 2006-04-10 2007-10-25 E. I. Du Pont De Nemours And Company Polyamide composition comprising a modifier

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3375219A (en) * 1964-11-23 1968-03-26 Gulf Oil Corp Pigmenting polycarbonamide by means of an ethylene copolymer carrier resin
JPS49116162A (en) * 1973-03-13 1974-11-06
JPS51125451A (en) * 1975-04-03 1976-11-01 Asahi Chem Ind Co Ltd Polyamide composition
DE2654168C2 (en) * 1976-11-30 1986-02-06 Bayer Ag, 5090 Leverkusen Polyamide alloys
DE2654346C2 (en) * 1976-12-01 1984-03-15 Bayer Ag, 5090 Leverkusen Polyamide molding compounds
DE3220380A1 (en) * 1982-05-29 1983-12-01 Basf Ag, 6700 Ludwigshafen IMPACT POLYAMIDE MOLDS
DE3576965D1 (en) * 1984-09-15 1990-05-10 Huels Chemische Werke Ag MOLDS BASED ON THERMOPLASTICS.
CH672495A5 (en) * 1987-07-17 1989-11-30 Inventa Ag
DE3806271A1 (en) * 1988-02-27 1989-09-07 Basf Ag THERMOPLASTIC MOLDING MATERIALS BASED ON POLYAMIDES AND ETHYLENE COPOLYMERS
DE4010958A1 (en) * 1990-04-05 1991-10-10 Wolff Walsrode Ag STRETCHED, SHRINKABLE TUBE FILM

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL219538A (en) * 1956-08-02

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3755221A (en) * 1971-01-18 1973-08-28 Ici Ltd Fast cycling polyamide molding composition which contains a particulate nucleating agent, an alkylene diamide, and a metal salt of a monocarboxylic acid
DE2551014A1 (en) * 1974-11-13 1976-05-20 Du Pont THERMOPLASTIC GRAFT MIXED COPOLYMERISATES AND METHOD FOR THEIR PRODUCTION
DE2622973A1 (en) * 1975-05-23 1976-12-09 Du Pont CONSOLIDATED MULTI-PHASE THERMOPLASTIC COMPOSITION AND METHOD OF MANUFACTURING THE SAME
US4174358A (en) 1975-05-23 1979-11-13 E. I. Du Pont De Nemours And Company Tough thermoplastic nylon compositions
US4283502A (en) * 1979-04-30 1981-08-11 E. I. Du Pont De Nemours And Company Polyamide resins
EP0030903A2 (en) * 1979-12-10 1981-06-24 Rhone-Poulenc Specialites Chimiques Polyphased polyamide compositions with particular shock resistant properties, and processes for their preparation
EP0030903A3 (en) * 1979-12-10 1981-07-29 Rhone-Poulenc Specialites Chimiques Polyphased polyamide compositions with particular shock resistant properties, and processes for their preparation
EP0031287B1 (en) * 1979-12-10 1984-04-11 Rhone-Poulenc Specialites Chimiques Polyphased compositions of polyamides and polyester amides
US4628072A (en) * 1981-08-13 1986-12-09 Asahi Kasei Kogyo Kabushiki Kaisha Modified block copolymer composition
US4657971A (en) * 1981-08-13 1987-04-14 Asahi Kasei Kogyo Kabushiki Kaisha Modified block copolymer composition
US4657970A (en) * 1981-08-13 1987-04-14 Asahi Kasei Kogyo Kabushiki Kaisha Modified block copolymer composition
JPS5989353A (en) * 1982-11-15 1984-05-23 Ube Ind Ltd Preparation of impact-resistant polyamide
JPS59164359A (en) * 1983-03-08 1984-09-17 Ube Ind Ltd Production of impact-resistant polyamide
JPS59197459A (en) * 1983-04-26 1984-11-09 Ube Ind Ltd Production of polyamide composition
GB2139234A (en) * 1983-05-06 1984-11-07 Dow Chemical Co Blown nylon film and process for the preparation thereof
JPS59215352A (en) * 1983-05-23 1984-12-05 Ube Ind Ltd Production of impact-resistant polyamide
JPS6069159A (en) * 1983-09-27 1985-04-19 Ube Ind Ltd Production of polyamide composition
JPS60112853A (en) * 1983-11-25 1985-06-19 Ube Ind Ltd Production of polyamide composition
JPS60137961A (en) * 1983-12-26 1985-07-22 Ube Ind Ltd Manufacture of polyamide composition
US4544702A (en) * 1984-06-11 1985-10-01 Uniroyal, Inc. Modified ionic elastomer and blend with nylon
US4739016A (en) * 1984-06-11 1988-04-19 Uniroyal Chemical Company, Inc. Modified ionic elastomer and blend with nylon
EP0229439A1 (en) * 1985-07-29 1987-07-22 ARCO Chemical Technology, L.P. Impact resistant polyamide molding compositions
FR2592388A1 (en) * 1985-12-30 1987-07-03 Atochem POLYAMIDE, POLYETHERAMIDE AND THERMOPLASTIC ELASTOMER ALLOYS
EP0233428A1 (en) * 1985-12-30 1987-08-26 Elf Atochem S.A. Alloys based on polyamide, polyether amide and thermoplastic elastomer
US5883195A (en) * 1985-12-30 1999-03-16 Atochem Thermoplastic polyamide/-polyetheramide/elastomer alloys having improved mechanical properties
DE3728334A1 (en) * 1986-08-26 1988-03-03 Inventa Ag THERMOPLASTICALLY DEFORMABLE, IMPACT POLYAMIDE ALLOYS AND THEIR USE
US5457156A (en) * 1986-08-27 1995-10-10 Rohm And Haas Company Impact-strength modifiers for thermoplastic polymers
US5332782A (en) * 1986-08-27 1994-07-26 Rohm And Haas Company Impact strength modifiers for thermoplastic polymers
US5112908A (en) * 1986-12-23 1992-05-12 E. I. Du Pont De Nemours And Company Tough polyamide compositions having high melt flow for complex moldings
US4847330A (en) * 1986-12-30 1989-07-11 Basf Aktiengesellschaft Thermoplastic molding materials based on nylons and ethylene copolymers
US5342886A (en) * 1988-03-24 1994-08-30 Atochem α-monoolefinic graft copolymers
US5122569A (en) * 1988-12-22 1992-06-16 Ferro Corporation Toughened compositions of polyamide and functionalized rubber block or graft copolymers
US5212238A (en) * 1988-12-22 1993-05-18 Ferro Corporation Toughened compositions of polyamide and functionalized rubber block or graft copolymers
US5468259A (en) * 1992-12-07 1995-11-21 Sheth; Paresh J. Dyeable polyolefin compositions and dyeing polyolefin compositions
US6077906A (en) * 1998-03-11 2000-06-20 Thiruvengada; Seshan Nylon modifiers hauling enhanced flow properties
US6235840B1 (en) 1998-03-11 2001-05-22 Uniroyal Chemical Company, Inc. Nylon modifiers having enhanced flow properties
WO2007120707A2 (en) * 2006-04-10 2007-10-25 E. I. Du Pont De Nemours And Company Polyamide composition comprising a modifier
WO2007120707A3 (en) * 2006-04-10 2008-02-07 Du Pont Polyamide composition comprising a modifier

Also Published As

Publication number Publication date
BE641952A (en) 1964-04-06
DE1241606B (en) 1967-06-01
NL146193B (en) 1975-06-16
NL302805A (en)

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