GB994497A - Process for treating wool with finishing agents - Google Patents

Process for treating wool with finishing agents

Info

Publication number
GB994497A
GB994497A GB7837/63A GB783763A GB994497A GB 994497 A GB994497 A GB 994497A GB 7837/63 A GB7837/63 A GB 7837/63A GB 783763 A GB783763 A GB 783763A GB 994497 A GB994497 A GB 994497A
Authority
GB
United Kingdom
Prior art keywords
treating
wool
sodium
chloride
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7837/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arthur D Little Inc
Original Assignee
Arthur D Little Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arthur D Little Inc filed Critical Arthur D Little Inc
Publication of GB994497A publication Critical patent/GB994497A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/006—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with wool-protecting agents; with anti-moth agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/18—Grafting textile fibers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/916—Natural fiber dyeing
    • Y10S8/917—Wool or silk

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Wool is shrink proofed and treated with antiseptics, insect repellents and insecticides by grafting on to it a condensation polymer by treating the wool serially with the reagents required to form the desired polymer and forming the polymer in situ on the wool, there also being applied to the wool together with one of the reactants an antiseptic, insect repellent or insecticide which becomes embedded in the treated wool when the polymer is formed. Polyamides may be grafted on to wool by treating it with a diamine and a diacid chloride, polyurethanes by treating with a diamine and a bischloroformate, polyureas by treating with a diamine and a diisocyanate, polyesters by treating with a diol and a diacid chloride, polycarbonates by treating with a diol and a bischloroformate, polysulphonamides by treating with a diamine and a disulphonyl chloride and polysulphonates by treating with a diol and a disulphonyl chloride, the components being applied in either order and being reacted by drying the impregnated wool. The components may be applied as solutions in mutually immiscible solvents, the polymer being formed at the inter face between the phases. Suitable pairs of immiscible solvents are water and toluene, carbontetrachloride, xylene or a volatile petroleum hydrocarbon distillate. Suitable antiseptics are b -naphthol, o-phenylphenol, 2,4,5 - trichloro phenol, 2 - bromo - 4 - phenyl phenol, tetrachloro phenol, pentachlorophenol, 4 - chloro - 2 - phenyl phenol, 6 - chloro - 2-phenyl phenol, sodium o-phenyl phenate, sodium 2,4,5 - trichloro phenate, sodium tetrachloro phenate, sodium pentachloro phenate, lauryl pyridinium chloride, 2,21 - dihydroxy - 5,51 - dichloro diphenylmethane, salicyl anilide, dodecyl dimethyl benzyl ammonium chloride, sodium dimethyl dithiocarbamate, the laurylamine salt of tetrachlorophenol and the dodecylamine salt of lactic or salicyclic acid, suitable insect repellents are N-ethyl toluamide, 2-ethyl-1,3-hexane diol, dimethyl phthalate, dimethyl carbate and butopyronoxyl, and suitable insecticides are p-dichloro benzene, sodium silicofluoride, pyrethrins, dieldrin, pentachloro-dihydro triphenyl methane sodium sulphonate, extract of derris root, pentachlorophenol, dinitronaphthol, dinitroortho cresol, benzene hexachloride, DDT, N,N - diethyl - N1 - acetyl thiocarbamo sulphenamide and N,N-diphenyl-N1-acetylthiocarbamo sulphenamide.ALSO:Wool is shrink proofed and otherwise finished by grafting on to it a condensation polymer by treating the wool serially with the reagents required to form the desired polymer and forming the polymer in situ on the wool, there also being applied to the wool together with one of the reactants a finishing agent which becomes embedded in the treated wool when the polymer is formed. Polyamides may be grafted on to wool by treating it with a diamine and a diacid chloride, polyurethanes by treating with a diamine and a bischloroformate, polyureas by treating with a diamine and a diisocyanate, polyesters by treating with a diol and a diacid chloride, polycarbonates by treating with a diol and a bischloroformate, polysulphonamides by treating with a diamine and a disulphonyl chloride and polysulphonates by treating with a diol and a disulphonyl chloride, the components being applied in either order and being reacted by drying the impregnated wool. The components may be applied as solutions in mutually immiscible solvents, the polymer being formed at the interface between the phases. Suitable pairs of immiscible solvents are water and toluene, carbontetrachloride, xylene or a volatile petroleum hydrocarbon distillate. Suitable finishing agents are agents for imparting fire-or-flame-resistance, e.g. sodium borophosphate, ammonium sulphamate, chlorinated diphenyl, chlorinated paraffin and the bromoform adduct of triallyl phosphate, soil, oil and water repellents, e.g. emulsions of waxes and aluminium or zirconium acetate, polydimethyl siloxanes, polymethyl hydrogen siloxanes, polyvinyl perfluorobutyrate, polyperfluorobutylacrylate, the chromium complexes of CF3(CF2)2-15 COOH, chlorinated paraffin waxes, aluminium soaps, cetyl palmitate and stearyl stearate, odorants, deodorants, sizes, e.g. starches, gums, methylcellulose, sodium carboxymethyl cellulose, sodium alginate, gelatin, polyvinyl alcohol, polyvinyl acetate, polyacrylic acid and sodium polyacrylate, acid, direct, sulphur and solvent type dyes, pigments e.g. bariumchromate, strontium chromate, zinc chromate, venetian red, turkey red, indian red, carbon black, ochres, siennas, umbers, cinnabar, powdered metals, titanium dioxide, zinc oxide, lithopone, basic lead carbonate and basic lead sulphate, fluorescent brightening agents, softeners, e.g. fatty acid esters of diethylene glycol, polyethylene glycol, sulphonated animal or vegetable fats, high molecular weight aliphatic alcohols, stearic or palmitic acid, sorbitan monolaurate, palmitate or stearate, condensation products of fatty acids and alkylolamines, or amino sulphonic acids, fatty acid esters of ethylene glycol monoalky ethers, stearamido methylpyridinium chloride and octadecyloxymethyl pyridinium chloride and anti-static agents, e.g. polymers of b -propiolactone and quaternary ammonium compounds. The finishing agent may be added to either treating solution or both.
GB7837/63A 1960-04-15 1963-02-27 Process for treating wool with finishing agents Expired GB994497A (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US2265160A 1960-04-15 1960-04-15
US8384861A 1961-01-19 1961-01-19
US54389161A 1961-01-27 1961-01-27
US8823261A 1961-02-09 1961-02-09
US8823361A 1961-02-09 1961-02-09
US9060461A 1961-02-20 1961-02-20
US98718A US3078138A (en) 1960-04-15 1961-03-27 Shrinkproofing wool with polyamides
US19865362A 1962-05-29 1962-05-29

Publications (1)

Publication Number Publication Date
GB994497A true GB994497A (en) 1965-06-10

Family

ID=27574077

Family Applications (2)

Application Number Title Priority Date Filing Date
GB13127/61A Expired GB913370A (en) 1960-04-15 1961-04-12 Shrink proofing of wool
GB7837/63A Expired GB994497A (en) 1960-04-15 1963-02-27 Process for treating wool with finishing agents

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB13127/61A Expired GB913370A (en) 1960-04-15 1961-04-12 Shrink proofing of wool

Country Status (5)

Country Link
US (2) US3078138A (en)
BE (2) BE602620A (en)
CH (1) CH403705A (en)
DE (1) DE1444087A1 (en)
GB (2) GB913370A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2491377C2 (en) * 2011-09-19 2013-08-27 Российская Федерация в лице Министерства промышленности и торговли Российской Федерации (Минпромторг России) Method of antimicrobial treatment of half-woollen cloth

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE629488A (en) * 1960-04-15
US3243253A (en) * 1963-11-20 1966-03-29 Lowell A Miller Continuous shrinkproofing of wool textiles
US3537808A (en) * 1961-02-17 1970-11-03 Rohm & Haas Method of depositing polymers on fibrous products
US3390949A (en) * 1963-10-18 1968-07-02 Universal Oil Prod Co Interfacial polymerization on wool using a polyacid polyhalide and a combination of polyamines
US3305391A (en) * 1963-12-12 1967-02-21 Universal Oil Prod Co Treatment of fibrous materials with certain amino compounds and certain polyacid polyhalides
US3466136A (en) * 1964-03-17 1969-09-09 Us Agriculture Shrinkproofing of wool
GB1109163A (en) * 1964-05-12 1968-04-10 Ici Ltd Surface-modifying treatment of shaped articles made from synthetic polyamides
FR1455905A (en) * 1964-05-28 1966-10-21 New methods for the treatment of fibrous materials as well as products obtained
US3372978A (en) * 1964-05-28 1968-03-12 Agriculture Usa Fibrous material carrying a deposit of a cross-linked polymer
DE1469332A1 (en) * 1965-10-09 1969-08-07 Deutsches Wollforschinst Process for anti-felting finishing of wool
US3537880A (en) * 1967-01-31 1970-11-03 Fmc Corp Heat-bondable fibers
US3958933A (en) * 1970-08-13 1976-06-01 Ciba-Geigy Corporation Process for the manufacture of fast dyeings on synthetic hydrophobic textile material
US3999942A (en) * 1974-08-01 1976-12-28 Cassella Farbwerke Mainkur Aktiengesellschaft N-Acyloyl-N-alkyl-alkylenediamines as dye levelers
US4365966A (en) * 1981-09-15 1982-12-28 The United States Of America As Represented By The Secretary Of Agriculture Process for modifying cellulosic fabrics for improved heat transfer printing
US5573553A (en) * 1992-04-24 1996-11-12 Milliken Research Corporation Method for improving the bleach resistance of dyed textile fiber and product made thereby
US7148269B2 (en) * 2002-03-11 2006-12-12 Trustees Of The University Of Pennsylvania Interfacial polymer incorporation of nanotubes
JP5214181B2 (en) * 2007-06-25 2013-06-19 亮 梅原 Method for preventing shrinkage of animal hair fibers by hydrophobization treatment
JP5629794B2 (en) * 2013-02-27 2014-11-26 亮 梅原 Animal hair fiber products
CN113853461B (en) * 2019-07-24 2024-05-28 东亚纺株式会社 Method for manufacturing shrink-proof animal hair fiber
CN115737506B (en) * 2022-12-16 2023-09-05 江苏亨瑞生物医药科技有限公司 A facial mask containing collagen and its preparation method
CN116535827B (en) * 2023-05-05 2024-02-02 波司登羽绒服装有限公司 Anti-counterfeiting composite luminescent material and preparation method and application thereof

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2522338A (en) * 1945-02-19 1950-09-12 Eavenson & Levering Company Process for shrink-proofing wool and woolen fabrics
US2526948A (en) * 1945-10-23 1950-10-24 Phillips Petroleum Co Process of treating textiles with half-acid amide derivatives
US2537064A (en) * 1946-08-30 1951-01-09 American Cyanamid Co Treatment of organic textile materials and products thereof
GB579340A (en) * 1946-10-02 1946-07-31 James Gordon Cook Use of polyester-amide compositions for coating, impregnating, adhesive or like purposes
US2565259A (en) * 1947-05-17 1951-08-21 American Cyanamid Co Treatment of protein-containing textile materials and products thereof
US2644773A (en) * 1949-03-17 1953-07-07 Montclair Res Corp Control of wool shrinkage by polyamides
US2696448A (en) * 1949-03-17 1954-12-07 Montclair Res Corp Shrinkproofed wool and method for producing same
US2684305A (en) * 1951-01-09 1954-07-20 Celastic Corp Process of effecting polymerization
US2929737A (en) * 1953-08-13 1960-03-22 Bayer Ag Coated textiles and method of producing the same
US2862836A (en) * 1955-03-14 1958-12-02 Texas Co In situ polyamide coating method
BE629488A (en) * 1960-04-15

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2491377C2 (en) * 2011-09-19 2013-08-27 Российская Федерация в лице Министерства промышленности и торговли Российской Федерации (Минпромторг России) Method of antimicrobial treatment of half-woollen cloth

Also Published As

Publication number Publication date
CH403705A (en) 1965-08-31
BE629488A (en)
US3429650A (en) 1969-02-25
US3078138A (en) 1963-02-19
DE1444087A1 (en) 1969-03-27
BE602620A (en)
GB913370A (en) 1962-12-19

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