GB990579A - Polyesters - Google Patents

Polyesters

Info

Publication number
GB990579A
GB990579A GB28637/61A GB2863761A GB990579A GB 990579 A GB990579 A GB 990579A GB 28637/61 A GB28637/61 A GB 28637/61A GB 2863761 A GB2863761 A GB 2863761A GB 990579 A GB990579 A GB 990579A
Authority
GB
United Kingdom
Prior art keywords
polyesters
tert
acid
butyldiethanolamine
ethyl hexanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28637/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB990579A publication Critical patent/GB990579A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6858—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/042—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds between the nitrogen-containing monomer and an aldehyde or ketone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/043—Mannich bases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

A polyester is formed by condensing a polycarboxylic acid or ester-forming derivative thereof with a polyhydric alcohol or ester-forming derivative thereof, which is or contains N-tert-butyldiethanolamine or N-tert-butyldiisopropanolamine. Lists of suitable polycaroxylic acids and polyhydric alcohols are given. Unsaturated polycarboxylic acids may be used to give unsaturated polyesters which may be mixed with copolymerizable monomers, several of which are mentioned, and with a stabilizer, e.g. quinone, hydroquinone, pyrocatechol, resorcinol or aniline. The mixtures may be copolymerized, e.g. with benzoyl peroxide in casting, moulding or laminating applications. The polyesters may have terminal OH or COOH groups, or, if monohydric alcohols are used in the reaction mixture may have no terminal functionality. Polyesters with terminal functional groups may be reacted, e.g. with organic polyisocyanates, if desired together with water to give cellular products. Polyesters of aromatic polycarboxylic acids may be used for fibres, films or sheets, which have good dyeability. The dyeing properties of the polyesters may be enhanced by quaternization of their tert-amine groups. Treated with acidic aqueous solutions the polyesters may be solubilsed for use in aqueous coating compositions. They may be used as plasticizers, and stabilizers, e.g. for vinyl halide polymers or copolymers, and also as additives to lubricants, hydraulic or heat transfer liquids. Examples describe polyesters from N-t-butyldiethanolamine and (1), (2) trimethylolethane and adipic acid with or without sebacic acid, (3) glycerol and adipic acid, (4) adipic acid, (5) 2-ethyl hexanol and sebacic acid (6) 2-ethyl hexanol, propylene glycol and sebacic acid (12) ethylene glycol and dimethyl terephthalate. Fibres were melt spun from the product, (13) hexane-1,6-diol and dimethyl terephthalate. Examples 7-9 uses tert-butyl-bis-(2-hydroxypropyl amine together with (7) maleic and phthalic anhydrides, (8) itaconic acid and phthalic anhydride, (9) fumaric acid and phthalic anhydride. In Example (10) the polyester of Example (7) is mixed with quinone and methyl methacrylate and cured with benzoyl peroxide, and in Example (11) copolymers are similarly prepared, using ethyl methacrylate, methyl acrylate, vinyl acetate or styrene as comonomers.ALSO:Polyesters containing residues of N-t.-butyldiethanolamine or N-tert.-butyl-diisopropanolamine may be added to hydraulic or heat transfer fluids, or mineral or synthetic lubricants and act as sludge dispersants and V.I. improvers. Examples 5, 6 describe oily polyesters from t.-butyldiethanolamine sebacic acid and either 2-ethyl hexanol or a mixture of 2-ethyl hexanol and propylene glycol, which show sludge-dispersant properties in hydrocarbon lubricants.
GB28637/61A 1960-08-26 1961-08-08 Polyesters Expired GB990579A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US5206560A 1960-08-26 1960-08-26

Publications (1)

Publication Number Publication Date
GB990579A true GB990579A (en) 1965-04-28

Family

ID=29709181

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28637/61A Expired GB990579A (en) 1960-08-26 1961-08-08 Polyesters

Country Status (4)

Country Link
BE (1) BE607526A (en)
FR (1) FR1298212A (en)
GB (1) GB990579A (en)
NL (1) NL268584A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2449099A1 (en) * 1973-10-15 1975-04-17 Rhone Poulenc Textile POLYESTERAMINE WITH GOOD AFFINITY TO ANIONIC COLORS AND THE PROCESS FOR THEIR PRODUCTION
WO1998021264A1 (en) * 1996-11-14 1998-05-22 Multicore Solders Limited Viscosity defined materials for use in the fabrication of electronic assemblies
EP1596875A2 (en) * 2003-02-14 2005-11-23 Inolex Investment Corporation Tertiary amine functional complex polyester polymers and methods of production and use

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2449099A1 (en) * 1973-10-15 1975-04-17 Rhone Poulenc Textile POLYESTERAMINE WITH GOOD AFFINITY TO ANIONIC COLORS AND THE PROCESS FOR THEIR PRODUCTION
WO1998021264A1 (en) * 1996-11-14 1998-05-22 Multicore Solders Limited Viscosity defined materials for use in the fabrication of electronic assemblies
EP1596875A2 (en) * 2003-02-14 2005-11-23 Inolex Investment Corporation Tertiary amine functional complex polyester polymers and methods of production and use
EP1596875A4 (en) * 2003-02-14 2006-04-05 Inolex Investment Corp Tertiary amine functional complex polyester polymers and methods of production and use

Also Published As

Publication number Publication date
FR1298212A (en) 1962-07-06
NL268584A (en)
BE607526A (en)

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