GB988171A - Improvements in or relating to thermosetting resin compositions - Google Patents
Improvements in or relating to thermosetting resin compositionsInfo
- Publication number
- GB988171A GB988171A GB1337760A GB1337760A GB988171A GB 988171 A GB988171 A GB 988171A GB 1337760 A GB1337760 A GB 1337760A GB 1337760 A GB1337760 A GB 1337760A GB 988171 A GB988171 A GB 988171A
- Authority
- GB
- United Kingdom
- Prior art keywords
- poly
- methacrylate
- copolymer
- films
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
Ethylene glycol bis-(b ,b -dimethyl glycidate) is prepared by condensing 2 mols. of acetone with 1 mol. of ethylene glycol di-(monochloro-acetate) in presence of sodium methoxide at a low temperature.ALSO:Thermoset resins are prepared by heating in absence of a cross-linking catalyst and in presence of molecular oxygen at above 100 DEG C., a mixture of a non-ionizable polyepoxide with a polymer or copolymer of an ester of a mono- or di-hydric ether alcohol with an a ,b -ethylenically-unsaturated mono- or poly-carboxylic acid. In a modification, the mixture is replaced by a copolymer of a glycidyl ester of an a , b -ethylenically-unsaturated mono- or poly-carboxylic acid with the unsaturated ester. a ,b -ethylenically unsaturated acids mentioned are acrylic, methacrylic, fumaric, maleic, itaconic, aconitic, and mesaconic. Polyepoxides mentioned are condensates of di-p-phenylol-2,2-propane and epichlorhydrin, e.g. "Epikote" or "Araldite" (Registered Trade Marks); and a polymer of a glycidyl ester of an a ,b -ethylenically-unsaturated mono- or poly-carboxylic acid. When a copolymer of the unsaturated ester is used, the co-monomer is preferably non-acidic, e.g. styrene, and at least 10% of the ester is used, based on the weight of copolymer. The compositions may be applied to wood, stone, concrete, plaster, paper, textile materials or metals, if desired from solution or emulsion, before thermosetting. In Examples, (1) a solution of poly-(b -ethoxy-ethyl methacrylate) in toluene was mixed with various quantities of "Epikote" and "Araldite" resins, films were deposited from the, mixtures and heated at temperatures of 120 DEG 150 DEG and 180 DEG C. (2) Copolymers were produced from mixtures of b -ethoxyethyl methacrylate and glycidyl methacrylate using benzoyl peroxide as catalyst, and dissolved in toluene. One mixture also included methyl methacrylate and ethyl acrylate, and this copolymer was dissolved in xylene and methyl ethyl ketone. Heated at 150 DEG C. the solution yielded films. (3) Films were cast from solutions of poly-(b -ethoxyethyl acrylate) in xylene-methyl ethyl ketone mixture, dried and baked at 150 DEG C. Poly-)methoxybutyl methacrylate) and poly-(diethylene glycol monobutyl ether methacrylate) are also referred to as suitable polyesters. (4) Films deposited from a toluene solution of a copolymer of b -ethoxyethylmethacrylate, glycidyl methacrylate, styrene and ethyl acrylate were baked at 150 DEG C. (5) Mixtures of varying proportions of b -ethoxyethyl methacrylate and glycidyl methacrylate were copolymerized in emulsion with potassium persulphate. The emulsifiers are specified. One of the mixtures also contained methyl methacylate. Films deposited from the copolymer emulsions were dried and insolubilized at 150 DEG C. (6) An emulsion of poly-(b -ethoxyethyl methacrylate) was mixed with an emulsion of a copolymer of glycidyl methacrylate and styrene, and used for making films which were stored at 150 DEG C. The emulsifiers used are specified. (7) A film of mixed ethylene glycol bis-(b -b -dimethyl glycidate) and poly-(b -ethoxyethyl methacrylate) was stored at 150 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1337760A GB988171A (en) | 1960-04-14 | 1960-04-14 | Improvements in or relating to thermosetting resin compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1337760A GB988171A (en) | 1960-04-14 | 1960-04-14 | Improvements in or relating to thermosetting resin compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB988171A true GB988171A (en) | 1965-04-07 |
Family
ID=10021864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1337760A Expired GB988171A (en) | 1960-04-14 | 1960-04-14 | Improvements in or relating to thermosetting resin compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB988171A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1984004099A1 (en) * | 1983-04-09 | 1984-10-25 | Basf Farben & Fasern | Thermosetting binder mixture |
GB2152947A (en) * | 1984-01-02 | 1985-08-14 | Jotun As | Marine coating and certain new terpolymers for use therein |
-
1960
- 1960-04-14 GB GB1337760A patent/GB988171A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1984004099A1 (en) * | 1983-04-09 | 1984-10-25 | Basf Farben & Fasern | Thermosetting binder mixture |
GB2152947A (en) * | 1984-01-02 | 1985-08-14 | Jotun As | Marine coating and certain new terpolymers for use therein |
AU570530B2 (en) * | 1984-01-02 | 1988-03-17 | Jotun A/S | Acrylic anti-fouling marine coatings |
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