GB988012A - Production of 1,4-cyclohexanedimethanol - Google Patents
Production of 1,4-cyclohexanedimethanolInfo
- Publication number
- GB988012A GB988012A GB24818/61A GB2481861A GB988012A GB 988012 A GB988012 A GB 988012A GB 24818/61 A GB24818/61 A GB 24818/61A GB 2481861 A GB2481861 A GB 2481861A GB 988012 A GB988012 A GB 988012A
- Authority
- GB
- United Kingdom
- Prior art keywords
- stage
- cyclohexanedimethanol
- hydrogenating
- production
- dialkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/27—Polyhydroxylic alcohols containing saturated rings
- C07C31/272—Monocyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,4-Cyclohexanedimethanol is prepared by hydrogenating a dialkyl terephthalate in presence of a palladium catalyst in a first stage (giving apparently the dialkyl 1,4-cyclohexanedicarboxylate) and hydrogenating in a second stage the effluent from the first stage in presence of copper chromite catalyst. Minor products present include methyl (or n-butyl) 4-hydroxymethylcyclohexanecarboxylate, 4 - methoxymethyl (or n-butoxymethyl) cyclohexanemethanol and 4-methylcyclohexanemethanol. Specifications 818,157 and 879,264 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4345460A | 1960-07-18 | 1960-07-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB988012A true GB988012A (en) | 1965-03-31 |
Family
ID=21927251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24818/61A Expired GB988012A (en) | 1960-07-18 | 1961-07-10 | Production of 1,4-cyclohexanedimethanol |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB988012A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4999090A (en) * | 1988-04-10 | 1991-03-12 | Towa Chemical Industry Co., Ltd. | Process for preparing trans-1,4-cyclohexanedimethanol and powder of the same |
-
1961
- 1961-07-10 GB GB24818/61A patent/GB988012A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4999090A (en) * | 1988-04-10 | 1991-03-12 | Towa Chemical Industry Co., Ltd. | Process for preparing trans-1,4-cyclohexanedimethanol and powder of the same |
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