GB984806A - Process for the production of substituted borazoles - Google Patents
Process for the production of substituted borazolesInfo
- Publication number
- GB984806A GB984806A GB1656862A GB1656862A GB984806A GB 984806 A GB984806 A GB 984806A GB 1656862 A GB1656862 A GB 1656862A GB 1656862 A GB1656862 A GB 1656862A GB 984806 A GB984806 A GB 984806A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrocarbon radical
- borazole
- trihydrogen
- chlorophenyl
- tri
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004215 Carbon black (E152) Substances 0.000 abstract 4
- BGECDVWSWDRFSP-UHFFFAOYSA-N borazine Chemical compound B1NBNBN1 BGECDVWSWDRFSP-UHFFFAOYSA-N 0.000 abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 4
- 229910000085 borane Inorganic materials 0.000 abstract 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 abstract 2
- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 abstract 1
- 101100037762 Caenorhabditis elegans rnh-2 gene Proteins 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- -1 boron halide Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/02—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant
- C06B47/10—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase the components comprising a binary propellant a component containing free boron, an organic borane or a binary compound of boron, except with oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
N-Substituted borazoles of the formula <FORM:0984806/C2/1> where R represents an aliphatic hydrocarbon radical, a cycloaliphatic hydrocarbon radical, an aromatic hydrocarbon radical, a substituted aromatic hydrocarbon radical or an aralkyl hydrocarbon radical, are made by reacting an amine-borane represented by the formula R13N:BH3 wherein R1 represents an aliphati hydrocarbon radical, a cycloaliphatic hydrocarbon radical, or an aromatic hydrocarbon radical with a primary amine RNH2 under anhydrous conditions, in an inert medium at a molar ratio of about 1:1 of the reactants and at a temperature at which 2 mols. of hydrogen are split off per mol. amine, preferably in a temperature range from 40 DEG -130 DEG C., and isolating a borazole from the resulting mass. The amineborane can be made in situ by reaction of a tertiary amine, borohydride and boron halide as described in Specification 877,863. Suitable starting materials are specified. Detailed examples describe the preparation of (1) N,N1,N11 - tricyclohexyl - B,B1,B11 - trihydrogen barazole; (2) N,N1,N11 - tridodecyl - B,B1,B11 - trihydrogen borazole; (3) N,N1,N11 - tri (2 - chlorophenyl), (4) N,N1,N11 - tri (3 - chlorophenyl) - and (5) N,N1,N11 - (tri - 4 - chlorophenyl) - B,B1,B11 - trihydrogen borazole; (6) N,N1,N11 - tribenzyl - B,B1,B11 - trihydrogen borazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1656862A GB984806A (en) | 1962-05-01 | 1962-05-01 | Process for the production of substituted borazoles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1656862A GB984806A (en) | 1962-05-01 | 1962-05-01 | Process for the production of substituted borazoles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB984806A true GB984806A (en) | 1965-03-03 |
Family
ID=10079658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1656862A Expired GB984806A (en) | 1962-05-01 | 1962-05-01 | Process for the production of substituted borazoles |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB984806A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014057885A1 (en) * | 2012-10-12 | 2014-04-17 | Ｊｘ日鉱日石エネルギー株式会社 | Lubricant additive and lubricating oil composition |
| JP2014080460A (en) * | 2012-10-12 | 2014-05-08 | Jx Nippon Oil & Energy Corp | Lubricating oil composition |
| JP2014080459A (en) * | 2012-10-12 | 2014-05-08 | Jx Nippon Oil & Energy Corp | Lubricant additive and lubricating oil composition |
| WO2015156393A1 (en) * | 2014-04-11 | 2015-10-15 | Ｊｘ日鉱日石エネルギー株式会社 | Lubricant composition |
| WO2015156392A1 (en) * | 2014-04-11 | 2015-10-15 | Ｊｘ日鉱日石エネルギー株式会社 | Lubricant composition for internal combustion engine |
-
1962
- 1962-05-01 GB GB1656862A patent/GB984806A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014057885A1 (en) * | 2012-10-12 | 2014-04-17 | Ｊｘ日鉱日石エネルギー株式会社 | Lubricant additive and lubricating oil composition |
| JP2014080460A (en) * | 2012-10-12 | 2014-05-08 | Jx Nippon Oil & Energy Corp | Lubricating oil composition |
| JP2014080459A (en) * | 2012-10-12 | 2014-05-08 | Jx Nippon Oil & Energy Corp | Lubricant additive and lubricating oil composition |
| WO2015156393A1 (en) * | 2014-04-11 | 2015-10-15 | Ｊｘ日鉱日石エネルギー株式会社 | Lubricant composition |
| WO2015156392A1 (en) * | 2014-04-11 | 2015-10-15 | Ｊｘ日鉱日石エネルギー株式会社 | Lubricant composition for internal combustion engine |
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