GB981822A - New pyridinium chloride compounds, process for their manufacture and their use - Google Patents
New pyridinium chloride compounds, process for their manufacture and their useInfo
- Publication number
- GB981822A GB981822A GB2559/63A GB255963A GB981822A GB 981822 A GB981822 A GB 981822A GB 2559/63 A GB2559/63 A GB 2559/63A GB 255963 A GB255963 A GB 255963A GB 981822 A GB981822 A GB 981822A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- methyl
- formula
- hydrogen
- furan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/62—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings
- C07D263/64—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings linked in positions 2 and 2' by chains containing six-membered aromatic rings or ring systems containing such rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/614—Optical bleaching or brightening in aqueous solvents
- D06L4/629—Optical bleaching or brightening in aqueous solvents with cationic brighteners
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Plural Heterocyclic Compounds (AREA)
- Detergent Compositions (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
The invention comprises compounds of the formula <FORM:0981822/C2/1> or <FORM:0981822/C2/2> n which X is hydrogen or methyl and m is 1 or 2. They may be prepared by reacting the corresponding chloromethyl compounds with a pyridine compound of formula <FORM:0981822/C2/3> in which X is hydrogen or methyl. The chlormethyl compounds used as starting materials may be prepared by introducing 1 or 2 chloromethyl groups into 2,5-di-[benzoxcyolyl-(21)]-furan compounds of formula <FORM:0981822/C2/4> in which Z stands for H or CH3, by reaction with hydrogen chloride and formaldehyde or with dichloromethyl ether in the presence of chlorosulphonic acid. The 2,5-di-[benzoxazoly-1-(21)]-furan compounds may themselves be formed by reacting furan-2,5-dicarboxylic acid or a functional derivative thereof at 160-260 DEG C., preferably in the presence of a condensation catalyst, with 1-amino-2-hydroxy-5-methyl-benzene in the molecular ratio of 1 : 2.ALSO:New compounds having the formula <FORM:0981822/D1-D2/1> or <FORM:0981822/D1-D2/2> in which X is hydrogen or methyl and m is 1 or 2 are used for the optical brightening of fibrous materials made of cotton, viscoses, acetate rayon, polyvinyl chloride, polyethylene, polypropylene and polyamides, and polyacrylonitrile and acrylonitrile copolymers. The fibrous materials may be treated with aqueous solutions of the optical brightening agents, preferably at 50-100 DEG C. The solutions used may be partial, weakly alkaline or acidic. The new compounds may be added to bleaching baths, for example, chlorite bleaching baths and may also be used in conjunction with a dispersant, a water-soluble inorganic salt or a dressing agent. In an example a polyacrylonitrile fabric is treated at 60-100 DEG C. with a bath containing one of the new optical brightening agents, formic acid, an adduct from ethylene oxide and octadecyl alcohol and sodium chlorite.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH285162A CH459210A (en) | 1962-03-09 | 1962-03-09 | Process for the preparation of halomethyloxazole derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB981822A true GB981822A (en) | 1965-01-27 |
Family
ID=4242994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2559/63A Expired GB981822A (en) | 1962-03-09 | 1963-01-21 | New pyridinium chloride compounds, process for their manufacture and their use |
Country Status (3)
| Country | Link |
|---|---|
| CH (1) | CH459210A (en) |
| DE (1) | DE1287038B (en) |
| GB (1) | GB981822A (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE535064A (en) * | 1954-01-22 |
-
1962
- 1962-03-09 CH CH285162A patent/CH459210A/en unknown
-
1963
- 1963-01-21 GB GB2559/63A patent/GB981822A/en not_active Expired
- 1963-03-08 DE DEC29336A patent/DE1287038B/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE1287038B (en) | 1969-01-16 |
| CH459210A (en) | 1968-07-15 |
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