GB976088A - Ethers of polyols - Google Patents
Ethers of polyolsInfo
- Publication number
- GB976088A GB976088A GB12977/61A GB1297761A GB976088A GB 976088 A GB976088 A GB 976088A GB 12977/61 A GB12977/61 A GB 12977/61A GB 1297761 A GB1297761 A GB 1297761A GB 976088 A GB976088 A GB 976088A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sucrose
- oxo
- carbon atoms
- tridecyl
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005862 polyol Polymers 0.000 title abstract 6
- 150000003077 polyols Chemical class 0.000 title abstract 4
- 150000002170 ethers Chemical class 0.000 title 1
- 239000005720 sucrose Substances 0.000 abstract 20
- 229930006000 Sucrose Natural products 0.000 abstract 19
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 abstract 11
- 125000004432 carbon atom Chemical group C* 0.000 abstract 6
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 abstract 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract 2
- 229930195725 Mannitol Natural products 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 abstract 2
- 239000003599 detergent Substances 0.000 abstract 2
- 229960001760 dimethyl sulfoxide Drugs 0.000 abstract 2
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 239000000594 mannitol Substances 0.000 abstract 2
- 235000010355 mannitol Nutrition 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- -1 polyol ethers Chemical class 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- 239000000600 sorbitol Substances 0.000 abstract 2
- 150000005846 sugar alcohols Chemical class 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- SNXYIOIMZXSIDC-UHFFFAOYSA-A hexadecasodium;phosphonato phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O SNXYIOIMZXSIDC-UHFFFAOYSA-A 0.000 abstract 1
- 239000011630 iodine Chemical group 0.000 abstract 1
- 229910052740 iodine Chemical group 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002840 non-reducing disaccharides Chemical class 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
- C07H15/02—Acyclic radicals, not substituted by cyclic structures
- C07H15/04—Acyclic radicals, not substituted by cyclic structures attached to an oxygen atom of the saccharide radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/13—Saturated ethers containing hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Saccharide Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyethers (AREA)
Abstract
The invention comprises polyol ethers of formula <FORM:0976088/C1/1> where R is an alkyl, alkenyl or alkoxy group of 8 to 24 carbon atoms or an alkaryl group of 14 to 24 carbon atoms in which alkaryl group from 8 to 18 of the carbon atoms form at least one alkyl group, and OZ is the residue of a non-reducing disacchloride or a sugar alcohol. The compounds are prepared by reacting a polyol of formula H-OZ with a halide of formula R-CH2X where X is chlorine, bromine or iodine; a metal derivative of the polyol may be reacted instead of the polyol. Z may be the residue of sucrose, trehalose, mannitol, sorbitol or dulcitol. In examples solutions of sucrose in dimethyl sulphoxide and solutions obtained by adding methanolic sodium methoxide to solutions of sucrose in dimethyl sulphoxide and then removing the methanol, are reacted with various halides to obtain O-dodecylbenzyl sucrose, O-dodecenyl sucrose, O-octadecylbenzyl sucrose, O-(n-tridecyl) sucrose, O-oxo-decyl sucrose, O-oxo-tridecyl sucrose, O-oxo-hexadecyl sucrose, O-(2-butyloctyl) sucrose, O-n-tetradecyl sucrose and O-(oxo-tridecyloxymethyl) sucrose.ALSO:Detergent compositions comprise polyol ethers of formula R-CH2-OZ where R is an alkyl, alkenyl or alkoxy group of 8 to 24 carbon atoms or an alkaryl group of 14 to 24 carbon atoms in which alkaryl group from 8 to 18 of the carbon atoms form at least one alkyl group, and OZ is the residue of a nonreducing disaccharide or a sugar alcohol. Z may be the residue of sucrose, trehalose, mannitol, sorbitol or dulcitol. In examples detergent compositions are prepared containing O-(n-tridecyl) sucrose, O-oxo-decyl-sucrose, O-oxo-tridecyl - sucrose, O-oxo-hexadecyl - sucrose and O-(2-butyloctyl) sucrose mixed with sodium tripolyphosphate, sodium tetrapyrophosphate, soda ash and sodium silicate, and a soap bar prepared from O-oxo-tridecyl sucrose, white chip soap, sodium sulphate, sodium dodecyl-benzenesulphonate, titanium dioxide, perfume oil and water.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21120A US3170915A (en) | 1960-04-11 | 1960-04-11 | Sucrose ethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB976088A true GB976088A (en) | 1964-11-25 |
Family
ID=21802446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12977/61A Expired GB976088A (en) | 1960-04-11 | 1961-04-11 | Ethers of polyols |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3170915A (en) |
| GB (1) | GB976088A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58104625A (en) * | 1981-07-13 | 1983-06-22 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Foamable surfactant composition |
| JPS58187500A (en) * | 1982-04-26 | 1983-11-01 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Foamable surfactant composition |
| EP0727485A1 (en) * | 1995-02-16 | 1996-08-21 | Stichting Nederlands Instituut Voor Koolhydraat Onderzoek Tno | Method for conversion of a starch material, and enzyme composition suitable therefor |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3300413A (en) * | 1963-08-14 | 1967-01-24 | Geoffrey R Ames | Surface active compositions containing mixtures of mono- and di-alkyloxymethyl ethers of sugar |
| GB1077317A (en) * | 1964-11-26 | 1967-07-26 | Fuji Photo Film Co Ltd | Improvements in and relating to photographic gelatin-containing coating compositions |
| US4076930A (en) * | 1968-12-13 | 1978-02-28 | James Ellingboe | Polysaccharide polyols |
| US5236909A (en) * | 1990-07-25 | 1993-08-17 | Henkel Research Corporation | Octyl ethers and octadienyl ethers |
| US5126438A (en) * | 1990-12-07 | 1992-06-30 | Hawaiian Sugar Planters' Association | 6,6'-dihalo-6,6'-dideoxy-1',2,3,3',4,4'-hexa-o-methylsucrose compounds |
| US6075139A (en) * | 1996-07-24 | 2000-06-13 | Iowa State University Research Foundation, Inc. | Linear and cyclic sucrose reaction products, their preparation and their use |
| US5900478A (en) * | 1997-06-20 | 1999-05-04 | Iowa State University Research Foundation, Inc. | Activated mono-, di-, and polysaccharides reaction products thereof, their preparation and uses |
| DE102005016152A1 (en) * | 2005-04-07 | 2006-10-12 | Basf Ag | Preparation of (co) surfactants by reaction of polyols with olefins |
| EP4244214A1 (en) * | 2020-11-16 | 2023-09-20 | Kirk J. Abbey | Method for producing alpha-methylene lactones |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE23443E (en) * | 1951-12-18 | Esters of carbohydrates | ||
| US1504178A (en) * | 1922-08-28 | 1924-08-05 | Augustus Dacre Lacy | Process for the production of ethers of carbohydrates |
| US1936093A (en) * | 1930-10-17 | 1933-11-21 | Du Pont | Sorbitol ethers |
| US2258171A (en) * | 1940-08-14 | 1941-10-07 | Dow Chemical Co | Monosaccharose ethers from polysaccharide ethers |
| US2543744A (en) * | 1946-04-04 | 1951-03-06 | Gen Aniline & Film Corp | Nonfoaming soap composition |
| US2585035A (en) * | 1946-10-24 | 1952-02-12 | Gen Mills Inc | Unsaturated ethers of polyhydric alcohols and polymers thereof |
| US2719970A (en) * | 1952-10-14 | 1955-10-04 | Jr Edward L Griffin | Process for preparation of allylsucrose |
| US2875153A (en) * | 1955-04-27 | 1959-02-24 | Colgate Palmolive Co | Detergent compositions |
| US2974134A (en) * | 1957-12-02 | 1961-03-07 | Universal Oil Prod Co | Surface active glucose ethers |
| US2938898A (en) * | 1958-03-04 | 1960-05-31 | Gen Aniline & Film Corp | Process of reacting mono- and di-saccharides with various reagents in the presence of gamma-butyrolactone |
-
1960
- 1960-04-11 US US21120A patent/US3170915A/en not_active Expired - Lifetime
-
1961
- 1961-04-11 GB GB12977/61A patent/GB976088A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58104625A (en) * | 1981-07-13 | 1983-06-22 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Foamable surfactant composition |
| JPH037718B2 (en) * | 1981-07-13 | 1991-02-04 | Procter & Gamble | |
| JPS58187500A (en) * | 1982-04-26 | 1983-11-01 | ザ・プロクタ−・エンド・ギヤンブル・カンパニ− | Foamable surfactant composition |
| JPH037719B2 (en) * | 1982-04-26 | 1991-02-04 | Procter & Gamble | |
| EP0727485A1 (en) * | 1995-02-16 | 1996-08-21 | Stichting Nederlands Instituut Voor Koolhydraat Onderzoek Tno | Method for conversion of a starch material, and enzyme composition suitable therefor |
| NL9500292A (en) * | 1995-02-16 | 1996-10-01 | Stichting Nl Instituut Voor Ko | Process for conversion of a starch material, and enzyme preparation useful therefor. |
Also Published As
| Publication number | Publication date |
|---|---|
| US3170915A (en) | 1965-02-23 |
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