GB974834A - Sulphonation of cross-linked vinylbenzene polymers - Google Patents
Sulphonation of cross-linked vinylbenzene polymersInfo
- Publication number
- GB974834A GB974834A GB1205/61A GB120561A GB974834A GB 974834 A GB974834 A GB 974834A GB 1205/61 A GB1205/61 A GB 1205/61A GB 120561 A GB120561 A GB 120561A GB 974834 A GB974834 A GB 974834A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphonated
- benzene
- polymer
- sulphonic acid
- cross
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
- C08F8/36—Sulfonation; Sulfation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Sulphonated cross-linked vinyl-benzene polymers are treated with oleum between 50-120 DEG C. to increase the sulphonic acid content. Suitable monomers e.g. styrene, vinyl ethyl benzenes or vinyl xylenes, are co-polymerized with 1-20% by weight of divinyl-benzene or -toluene or trivinyl benzene. The resulting polymer is sulphonated with either chlorosulphonic acid or sulphuric acid to give a sulphonated polymer with 0.7-1 sulphonic acid groups per nucleus. This polymer is further sulphonated with 4-20 times its weight of oleum (containing 10-70% of free sulphur trioxide) giving a polymer with 1.2-2 sulphonic acid groups per nucleus and may be used as a cation-exchange resin. Sulphonated cross-linked vinylbenzene polymers containing 1.2-2 sulphonic acid groups per benzene nucleus measured on the basis of the ion-exchange capacity of the resin are also claimed per se. Specifications 577,707 and 894,391 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF30357A DE1168081B (en) | 1960-01-21 | 1960-01-21 | Process for increasing the capacity of cation exchangers containing a maximum of one sulfonic acid group per aryl nucleus |
Publications (1)
Publication Number | Publication Date |
---|---|
GB974834A true GB974834A (en) | 1964-11-11 |
Family
ID=7093736
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1205/61A Expired GB974834A (en) | 1960-01-21 | 1961-01-11 | Sulphonation of cross-linked vinylbenzene polymers |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1168081B (en) |
GB (1) | GB974834A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2012552A1 (en) * | 1968-07-09 | 1970-03-20 | Shell Int Research | Tertiary olefins prodn and purification - using an ion-exchange catalyst |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2678306A (en) * | 1954-05-11 | Carboxtsulfonic cation-exchange | ||
US2366007A (en) * | 1942-08-11 | 1944-12-26 | Gen Electric | Production of synthetic polymeric compositions comprising sulphonated polymerizates of poly-vinyl aryl compounds and treatment of liquid media therewith |
FR960585A (en) * | 1942-08-11 | 1950-04-20 | ||
US2645621A (en) * | 1949-09-24 | 1953-07-14 | Koppers Co Inc | Sulfonated aromatic hydrocarbonaliphatic polyene hydrocarbon ion-exchange resins |
DE963020C (en) * | 1951-05-12 | 1957-05-02 | Rohm & Haas | Process for the preparation of cation exchange polymers |
US2868737A (en) * | 1954-04-13 | 1959-01-13 | Bayer Ag | Cation exchangers containing selenic acid groups |
-
1960
- 1960-01-21 DE DEF30357A patent/DE1168081B/en active Pending
-
1961
- 1961-01-11 GB GB1205/61A patent/GB974834A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1168081B (en) | 1964-04-16 |
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