GB960249A - Improvements in linear polyesteramides - Google Patents

Improvements in linear polyesteramides

Info

Publication number
GB960249A
GB960249A GB22435/60A GB2243560A GB960249A GB 960249 A GB960249 A GB 960249A GB 22435/60 A GB22435/60 A GB 22435/60A GB 2243560 A GB2243560 A GB 2243560A GB 960249 A GB960249 A GB 960249A
Authority
GB
United Kingdom
Prior art keywords
acid
dicarboxylic
ester
benzoic
specified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22435/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kodak Ltd
Original Assignee
Kodak Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US554639A external-priority patent/US2901466A/en
Priority claimed from US823296A external-priority patent/US3033827A/en
Priority claimed from US823295A external-priority patent/US3033826A/en
Application filed by Kodak Ltd filed Critical Kodak Ltd
Publication of GB960249A publication Critical patent/GB960249A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02Aliphatic polycarbonates
    • C08G64/0208Aliphatic polycarbonates saturated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199Acids or hydroxy compounds containing cycloaliphatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6888Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/80Solid-state polycondensation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44Polyester-amides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyamides (AREA)

Abstract

Polyesteramides melting at 100 DEG -330 DEG C. and having an intrinsic viscosity of at least 0.4 are made by reacting (a) a dicarboxylic acid (or ester-forming derivative thereof) or an ester-forming derivative of carbonic acid (b) a dihydroxy compound at least 50 mol. per cent of which is 1:4-cyclohexanedimethanol and (c) an aminocarboxylic acid (or lactam thereof) in an amount of at between 10 and 60 mol. per cent of component (a). Specified dicarboxylic acids are oxalic, adipic, suberic, azelaic, succinic, sebacic, glutaric, dimethylmalonic, a -ethylsuberic, a , a -diethyladipic, dimerized fatty, norcamphanedicarboxylic, o-and tere-phthalic, naphthalene dicarboxylic, p-carboxycarbonilic, hexahydro-o-phthalic, trans-1:4-cyclohexanedicarboxylic, sulphonyldipropionic, p:p-sulphonyldibenzoic, 4:41-benzophenone dicarboxylic and 4:41-diphenic acid; also b :b -dicarboxy diethyl ether and 1:2-di(p-carboxyphenyl) alkanes. Specified dihydroxy compounds in addition to the 1:4-cyclohexanedimethanol are ethylene glycol, neopentyl glycol, di-, tri- and poly-ethylene glycols, 2-methyl-1:5-pentanediol, 2:2-dimethyl-3-isopropyl-1:3-propanediol, 1:4-bis (hydroxymethyl) benzene, norcamphanedimethanol, dihydroxylates polystyrene and glycols containing internal ether, thioether, sulphone, ester and urethane groups; also hydroquinone, dihydroxynaphthalene and resorcinol. Specified amino acids and lactams are 6-aminocaproic, o -aminoundecanoic, 3-amino-2:2-dimethyporpionic, 4-amino benzoic, 4-(b -aminoethyl) benzoic, 2-(b -aminopropoxyl) benzoic, 4-aminomethyl-cyclohexanecarboxylic and 2-(b -aminopoupoxy)-cyclohexane carboxylic acid and caprolactam. The polyesteramides may be prepared by the melt phase or solid phase technique and the ingredients may be reacted simultaneously or stepwise. Uses: fibres, films, moulded articles and coating materials.
GB22435/60A 1955-12-22 1960-06-27 Improvements in linear polyesteramides Expired GB960249A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US818157XA 1955-12-22 1955-12-22
US554639A US2901466A (en) 1955-12-22 1955-12-22 Linear polyesters and polyester-amides from 1,4-cyclohexanedimethanol
US823296A US3033827A (en) 1959-06-29 1959-06-29 Linear polyesters of 1, 4-cyclohexane-dimethanol and aminoalcohols
US823295A US3033826A (en) 1959-06-29 1959-06-29 Linear polyesters of 1, 4-cyclohexanedimethanol and amino-carboxylic acids

Publications (1)

Publication Number Publication Date
GB960249A true GB960249A (en) 1964-06-10

Family

ID=30119269

Family Applications (2)

Application Number Title Priority Date Filing Date
GB22435/60A Expired GB960249A (en) 1955-12-22 1960-06-27 Improvements in linear polyesteramides
GB22436/60A Expired GB959671A (en) 1955-12-22 1960-06-27 Improvements in linear polyesteramides

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB22436/60A Expired GB959671A (en) 1955-12-22 1960-06-27 Improvements in linear polyesteramides

Country Status (1)

Country Link
GB (2) GB960249A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2542467A1 (en) * 1975-09-24 1977-03-31 Huels Chemische Werke Ag METHOD FOR MANUFACTURING POLYESTERAMIDES

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004039102A1 (en) * 2004-08-11 2006-02-23 Basf Ag Process for the preparation of highly branched polyesteramides
TWI766628B (en) * 2021-03-25 2022-06-01 遠東新世紀股份有限公司 Polyether-ester material containing amide group and preparation method thereof, molded article and forming method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2542467A1 (en) * 1975-09-24 1977-03-31 Huels Chemische Werke Ag METHOD FOR MANUFACTURING POLYESTERAMIDES

Also Published As

Publication number Publication date
GB959671A (en) 1964-06-03

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