GB950336A - Improvements in or relating to the cements for use in the bonding of surfaces - Google Patents

Improvements in or relating to the cements for use in the bonding of surfaces

Info

Publication number
GB950336A
GB950336A GB2077761A GB2077761A GB950336A GB 950336 A GB950336 A GB 950336A GB 2077761 A GB2077761 A GB 2077761A GB 2077761 A GB2077761 A GB 2077761A GB 950336 A GB950336 A GB 950336A
Authority
GB
United Kingdom
Prior art keywords
glass
cement
methyl methacrylate
esters
glycol dimethacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2077761A
Inventor
Tom Anthony Downing
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL257105D priority Critical patent/NL257105A/xx
Priority to NL279493D priority patent/NL279493A/xx
Priority to BE618597D priority patent/BE618597A/xx
Priority to NL257157D priority patent/NL257157A/xx
Priority to BE596839D priority patent/BE596839A/xx
Priority to DE1960J0018925 priority patent/DE1115389B/en
Priority to FR843488A priority patent/FR1273223A/en
Priority to FR843487A priority patent/FR1273222A/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2077761A priority patent/GB950336A/en
Priority to FR900294A priority patent/FR82315E/en
Publication of GB950336A publication Critical patent/GB950336A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00—Producing optical elements, e.g. lenses or prisms
    • B29D11/0073—Optical laminates
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06—Joining glass to glass by processes other than fusing
    • C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/10—Presence of inorganic materials
    • C09J2400/14—Glass
    • C09J2400/146—Glass in the pretreated surface to be joined
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00—Presence of polysiloxane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Ophthalmology & Optometry (AREA)
  • Mechanical Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

A glass surface is bonded to another glass surface or to the surface of a transparent rigid sheet by first treating the glass surface or surfaces with vinyl trichlorosilane, then interposing between the surfaces to be cemented a cement which is a polymerizable material that is liquid at the cementing temperature and which comprises methyl methacrylate, a plasticiser therefor and a cross-linking agent which is a polymerizable compound containing at least two >C=C< groups per molecule, said methyl methacrylate being in monomeric or partially polymerized form or in monomeric form containing in solution a solid polymer of methyl methacrylate, there being to each 100 parts by weight of methylmethacrylate in whatever form, from 30 to 80 parts by weight of said plasticizer and from 0.8 to 15 parts by weight of said cross-linking agent, and then subjecting the cementing layer to polymerizing conditions to convert said layer into a plasticized polymeric composition. The term "glass surface" includes ceramic surfaces. Before use the cement is preferably degassed by subjecting it to reduced pressure, so that there is less than 4 mls of dissolved gas per 100 gms. of cement at 20 DEG C. and atmospheric pressure. Lists of suitable plasticizers are given including phosphates, phthalates, esters of other dibasic acids, esters of monobasic acids, substituted toluene sulphonamides, substituted amides, hydrocarbons, halogenated hydrocarbons and ether compounds and the cross-linking agents mentioned are esters of polyhydric alcohols with monobasic unsaturated carboxylic acids e.g. triethylene glycol dimethacrylate and ethylene glycol dimethacrylate, esters of unsaturated alcohols with dibasic carboxylic acids e.g. diallyl phthalate, adipate and carbonate, and divinyl benzene. Small amounts of other polymerized and/or polymerizable monoethylenically unsaturated compounds may be present in the cement e.g. styrene. Catalysts which are activated by heat or light may be used for polymerizing the cement. Catalysts activated by heat include benzoyl peroxide, lauroyl peroxide, certain organic azo compounds such as a a 1azodiisobutyronitrile, and organic peroxides used with tertiary amines, e.g. benzoyl peroxide with dimethyl para toluidine or dimethyl aniline. Catalysts activated by light include benzoin, acetoin, butyroin and diacetyl. In the examples the cements consist of methyl methacrylate monomer, methyl methacrylate polymer, dibutyl phthalate and triethylene glycol dimethacrylate or ethylene glycol dimethacrylate as cross-linking agent and the surfaces bonded are glass to glass and glass to polymethylmethacrylate. Also a glass guard is bonded to the viewing surface of a television tube.
GB2077761A 1960-11-09 1961-06-08 Improvements in or relating to the cements for use in the bonding of surfaces Expired GB950336A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
NL279493D NL279493A (en) 1961-06-08
BE618597D BE618597A (en) 1961-06-08
NL257157D NL257157A (en) 1961-06-08
BE596839D BE596839A (en) 1961-06-08
NL257105D NL257105A (en) 1961-06-08
DE1960J0018925 DE1115389B (en) 1961-06-08 1960-10-27 Method for gluing or cementing two surfaces to one another, at least one of which is a glass surface
FR843488A FR1273223A (en) 1960-11-09 1960-11-09 Bonding of surfaces using methacrylate and acrylate
FR843487A FR1273222A (en) 1960-11-09 1960-11-09 Binding of surfaces using methyl methacrylate
GB2077761A GB950336A (en) 1961-06-08 1961-06-08 Improvements in or relating to the cements for use in the bonding of surfaces
FR900294A FR82315E (en) 1961-06-08 1962-06-08 Binding of surfaces using methyl methacrylate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2077761A GB950336A (en) 1961-06-08 1961-06-08 Improvements in or relating to the cements for use in the bonding of surfaces

Publications (1)

Publication Number Publication Date
GB950336A true GB950336A (en) 1964-02-26

Family

ID=10151516

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2077761A Expired GB950336A (en) 1960-11-09 1961-06-08 Improvements in or relating to the cements for use in the bonding of surfaces

Country Status (4)

Country Link
BE (2) BE596839A (en)
DE (1) DE1115389B (en)
GB (1) GB950336A (en)
NL (3) NL279493A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2313207A1 (en) * 1975-06-04 1976-12-31 Roehm Gmbh Transparent safely panels eg for windscreens - compresing contiguous (polycarbonate) panels bonded with hydroxyalkyl acrylate (co) polymer
GB2134533A (en) * 1983-01-27 1984-08-15 Screen Printing Systems Inc Screen printing ink and printing press therefor
WO2005030666A2 (en) * 2003-09-26 2005-04-07 Alfredo Fornieles Improvements relating to glass
EP1568747A1 (en) * 2004-02-26 2005-08-31 Uvix SLL Adhesion of reinforcing meshes or rigid sheets to the back of ceramic tiles, natural stone and mosaic composition of any nature used in building by an adhesive cured with ultraviolet lamps.
ES2366533A1 (en) * 2010-04-15 2011-10-21 Juan Lloveras Calvo Stratified with a metacrylate sheet and manufacturing procedure (Machine-translation by Google Translate, not legally binding)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1254303B (en) * 1964-01-22 1967-11-16 Beiersdorf & Co Ag P Process for the production of organic adhesive layers on glass surfaces and thus obtainable composite bodies with elastic, firmly adhering and water-resistant intermediate layers

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2313207A1 (en) * 1975-06-04 1976-12-31 Roehm Gmbh Transparent safely panels eg for windscreens - compresing contiguous (polycarbonate) panels bonded with hydroxyalkyl acrylate (co) polymer
GB2134533A (en) * 1983-01-27 1984-08-15 Screen Printing Systems Inc Screen printing ink and printing press therefor
WO2005030666A2 (en) * 2003-09-26 2005-04-07 Alfredo Fornieles Improvements relating to glass
WO2005030666A3 (en) * 2003-09-26 2005-11-03 Alfredo Fornieles Improvements relating to glass
EP1568747A1 (en) * 2004-02-26 2005-08-31 Uvix SLL Adhesion of reinforcing meshes or rigid sheets to the back of ceramic tiles, natural stone and mosaic composition of any nature used in building by an adhesive cured with ultraviolet lamps.
ES2366533A1 (en) * 2010-04-15 2011-10-21 Juan Lloveras Calvo Stratified with a metacrylate sheet and manufacturing procedure (Machine-translation by Google Translate, not legally binding)

Also Published As

Publication number Publication date
BE596839A (en)
NL257105A (en)
DE1115389B (en) 1961-10-19
BE618597A (en)
NL257157A (en)
NL279493A (en)

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