GB948137A - Preparation of condensed isopropyl silicate materials - Google Patents
Preparation of condensed isopropyl silicate materialsInfo
- Publication number
- GB948137A GB948137A GB41209/62A GB4120962A GB948137A GB 948137 A GB948137 A GB 948137A GB 41209/62 A GB41209/62 A GB 41209/62A GB 4120962 A GB4120962 A GB 4120962A GB 948137 A GB948137 A GB 948137A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- sicl4
- alcohol
- water
- isopropyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000002360 preparation method Methods 0.000 title abstract 2
- ZUEKXCXHTXJYAR-UHFFFAOYSA-N tetrapropan-2-yl silicate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)OC(C)C ZUEKXCXHTXJYAR-UHFFFAOYSA-N 0.000 title abstract 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- 229910003910 SiCl4 Inorganic materials 0.000 abstract 4
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- 229910052681 coesite Inorganic materials 0.000 abstract 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract 3
- 238000004821 distillation Methods 0.000 abstract 3
- 239000000377 silicon dioxide Substances 0.000 abstract 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract 3
- 229910052682 stishovite Inorganic materials 0.000 abstract 3
- 229910052905 tridymite Inorganic materials 0.000 abstract 3
- 238000010992 reflux Methods 0.000 abstract 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- 239000012043 crude product Substances 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 238000005058 metal casting Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/04—Esters of silicic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/205—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of organic silicon or metal compounds, other organometallic compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1315—Non-ceramic binders
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/02—Polysilicates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Ceramic Products (AREA)
- Mold Materials And Core Materials (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
A condensed isopropyl silicate is made by adding gradually to SiCl4 a mixture of water and isopropyl alcohol, the amount of water added being from 0.75 to 1 mol per mol of SiCl4 and the amount of alcohol added being in excess of that stoichiometrically required to replace those chlorine atoms of the SiCl4 with which the water is insufficient to react, refluxing the mixture and removing excess alcohol by distillation. In examples (1) a mixture of anhydrous isopropyl alcohol and water was gradually added to SiCl4 and the resulting mixture was refluxed for 1 hour and left overnight, unreacted alcohol was then removed by distillation up to 100 DEG C., leaving a crude product having a SiO2 content of 38.05%; further distillation up to 200 DEG C. removed the orthosilicate content, leaving a mixture of isopropyl polysilicates having a SiO2 content of 38.5%; (2) the process was similar to (1) except that the reflux time was increased to 4 hours, resulting in products having SiO2 contents of 39.5% and 40.7% respectively. Uses: for binding refractory powders in the preparation of moulds for the casting of metals, as described in Specification 948,132.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9375/59A GB948132A (en) | 1959-03-18 | 1959-03-18 | Improvements relating to processes for binding particulate solid materials |
Publications (1)
Publication Number | Publication Date |
---|---|
GB948137A true GB948137A (en) | 1964-01-29 |
Family
ID=9870760
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB41208/62A Expired GB948136A (en) | 1959-03-18 | 1959-03-18 | Preparation of condensed isopropyl silicate materials |
GB9375/59A Expired GB948132A (en) | 1959-03-18 | 1959-03-18 | Improvements relating to processes for binding particulate solid materials |
GB41209/62A Expired GB948137A (en) | 1959-03-18 | 1959-03-18 | Preparation of condensed isopropyl silicate materials |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB41208/62A Expired GB948136A (en) | 1959-03-18 | 1959-03-18 | Preparation of condensed isopropyl silicate materials |
GB9375/59A Expired GB948132A (en) | 1959-03-18 | 1959-03-18 | Improvements relating to processes for binding particulate solid materials |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE588775A (en) |
CH (1) | CH415969A (en) |
DE (1) | DE1209252B (en) |
GB (3) | GB948136A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4810441A (en) * | 1985-04-02 | 1989-03-07 | Clinotherm Limited | Process for the preparation of a ceramic fiber |
US4897232A (en) * | 1986-11-28 | 1990-01-30 | Clinotherm Limited | Preparation of fibres from a liquid precursor |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1300289B (en) * | 1962-06-30 | 1969-07-31 | Ruhrchemie Ag | Process for the production of solid polysilicic acid esters |
DE2809871A1 (en) * | 1978-03-08 | 1979-09-13 | Dynamit Nobel Ag | PROCESS FOR THE PREPARATION OF PARTIAL HYDROLYZATES FROM TETRA- (2-ALCOXY ETHYL) - SILICATES |
EP0004730B1 (en) * | 1978-03-23 | 1982-11-10 | Zirconal Processes Limited | Improvements in the manufacture of alkylsilicates and their conversion to alkylpolysilicates |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB290717A (en) * | 1927-02-16 | 1928-05-16 | King George | Improvements in materials for use in the art of painting or varnishing |
CH275202A (en) * | 1943-07-26 | 1951-05-15 | Union Chimique Belge Sa | Process for making molds and cores for casting metals. |
-
1959
- 1959-03-18 GB GB41208/62A patent/GB948136A/en not_active Expired
- 1959-03-18 GB GB9375/59A patent/GB948132A/en not_active Expired
- 1959-03-18 GB GB41209/62A patent/GB948137A/en not_active Expired
-
1960
- 1960-03-17 BE BE588775A patent/BE588775A/en unknown
- 1960-03-17 DE DEU6988A patent/DE1209252B/en active Pending
- 1960-03-18 CH CH308960A patent/CH415969A/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4810441A (en) * | 1985-04-02 | 1989-03-07 | Clinotherm Limited | Process for the preparation of a ceramic fiber |
US4897232A (en) * | 1986-11-28 | 1990-01-30 | Clinotherm Limited | Preparation of fibres from a liquid precursor |
Also Published As
Publication number | Publication date |
---|---|
DE1209252B (en) | 1966-01-20 |
GB948136A (en) | 1964-01-29 |
GB948132A (en) | 1964-01-29 |
CH415969A (en) | 1966-06-30 |
BE588775A (en) | 1960-09-19 |
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