GB939225A - Improvements in or relating to a process for the production of thermoplastic products derived from di-epoxy compounds - Google Patents
Improvements in or relating to a process for the production of thermoplastic products derived from di-epoxy compoundsInfo
- Publication number
- GB939225A GB939225A GB521/61A GB52161A GB939225A GB 939225 A GB939225 A GB 939225A GB 521/61 A GB521/61 A GB 521/61A GB 52161 A GB52161 A GB 52161A GB 939225 A GB939225 A GB 939225A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- compound
- preferred
- reacting
- diepoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
- C08G59/302—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
- C08G59/621—Phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
Thermoplastic products are prepared by reacting (a) a di-hydric phenol of which at least one aromatic nucleus has at least one alkyl substituent with (b) a substantially equimolar amount of a diepoxy compound, in which process either the dihydric phenol or the diepoxy compound, or both, contain an SO2 group joining two aromatic nuclei, in the presence of an alkaline compound as catalyst, and in a solvent in which the dihydric phenol, the diepoxy compound and the product are at least partly soluble and p which is substantially non-reactive with the dihydric phenol or the di-epoxy compound, the reaction mixture being substantially free from water and the nature and the quantity of the solvent and the temperature being such that the reaction product remains dissolved in the reaction mixture until the product has an intrinsic viscosity (measured in dimethyl formamide) of at least 0,4. A list of suitable phenols (a) is given, of which the preferred compound is 3,31,5,51-tetramethyl-4,41-dihydroxy diphenyl sulphone, and the preferred alkyl substituents in general are methyl and ethyl. The preferred diepoxy compounds are the diglycidyl ethers of the above phenol and of bisphenol A. The preferred alkaline catalyst is the mono sodium salt of the above phenol, the salt being counted as phenol from the point of view of molar calculations. Long lists of suitable solvents are given including ketones, nitriles, nitro compounds, sulphoxides and sulphones, a mixture of acetophenone and sulpholane being used in the example. The products may be used as threads of fibres.ALSO:3,315,51-Tetramethyl-4,41-dihydroxy diphenyl sulphone is prepared:-(1) from 2,6-dimethyl phenol and sulphuric acid: (a) one-stage, by reacting them in the presence of an organic solvent, e.g. tetrachloroethane; (b) two-stage, reacting them in equimolar quantities to prepare the para-sulphuric acid, and continuing the reaction with the same quantity of the phenol; (2) from 2,6-dimethyl phenol and ether a sulphur dihalide or a thionyl halide, e.g. the chlorides, the resultant sulphide or sulphonide being then oxidized to the sulphone in the oxidizing agent, e.g. H2O2, or a peracid, e.g. peracetic acid.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL240241 | 1959-06-15 | ||
NL247120A NL112987C (en) | 1959-06-15 | 1960-01-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB939225A true GB939225A (en) | 1963-10-09 |
Family
ID=26641693
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB521/61A Expired GB939225A (en) | 1959-06-15 | 1961-01-05 | Improvements in or relating to a process for the production of thermoplastic products derived from di-epoxy compounds |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE598852A (en) |
CH (1) | CH459582A (en) |
FR (1) | FR79616E (en) |
GB (1) | GB939225A (en) |
NL (2) | NL112987C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0987567A1 (en) * | 1998-09-08 | 2000-03-22 | Mitsui Chemicals, Inc. | A sulfur-containing (thio)ether (co)polymer and a use thereof |
WO2011087153A1 (en) * | 2010-01-18 | 2011-07-21 | 新日鐵化学株式会社 | Sulfo-group-containing polyhydroxy polyether resin, resin composition containing said resin, curable resin composition containing said resin, and film obtainable therefrom |
-
0
- BE BE598852D patent/BE598852A/xx unknown
- NL NL247120D patent/NL247120A/xx unknown
-
1960
- 1960-01-07 NL NL247120A patent/NL112987C/nl active
-
1961
- 1961-01-05 FR FR848873A patent/FR79616E/en not_active Expired
- 1961-01-05 GB GB521/61A patent/GB939225A/en not_active Expired
- 1961-01-05 CH CH10461A patent/CH459582A/en unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0987567A1 (en) * | 1998-09-08 | 2000-03-22 | Mitsui Chemicals, Inc. | A sulfur-containing (thio)ether (co)polymer and a use thereof |
US6320020B1 (en) | 1998-09-08 | 2001-11-20 | Mitsui Chemicals, Inc. | Sulfur-containing (thio)ether (co)polymer and a use thereof |
WO2011087153A1 (en) * | 2010-01-18 | 2011-07-21 | 新日鐵化学株式会社 | Sulfo-group-containing polyhydroxy polyether resin, resin composition containing said resin, curable resin composition containing said resin, and film obtainable therefrom |
Also Published As
Publication number | Publication date |
---|---|
CH459582A (en) | 1968-07-15 |
BE598852A (en) | 1900-01-01 |
FR79616E (en) | 1962-12-28 |
NL247120A (en) | 1900-01-01 |
NL112987C (en) | 1966-07-15 |
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