GB936911A - New pigment compositions - Google Patents
New pigment compositionsInfo
- Publication number
- GB936911A GB936911A GB19960A GB19960A GB936911A GB 936911 A GB936911 A GB 936911A GB 19960 A GB19960 A GB 19960A GB 19960 A GB19960 A GB 19960A GB 936911 A GB936911 A GB 936911A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pigments
- mixture
- latex
- copper
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/006—Preparation of organic pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
Abstract
A solid pigment composition for the pigmentation of non aqueous media, is prepared by flocculating a mixture of an aqueous pigment dispersion and an aqueous latex of solid synthetic polymer (i.e. does not include elastomers or waxes) which is soluble in said non aqueous medium to the extent of at least 2% by weight and preferably at least 5% by weight, said latex being obtained by emulsion polymerization of a monomer or a mixture of monomers and the diameter of the polymer particles in latex being between 0,01 and 0,5 micron, separating the flocculated mixture from the aqueous phase and drying it. Pigments may be of the inorganic type, e.g. titanium dioxide, zinc oxide, cadmium sulphide, carbon black, iron oxides, ultramarine, cobalt blue, Prussian blue, lead chromate and chromium oxide or of the organic type, e.g. azo, vat dye, triphendioxazine, phthalocyanine, e.g. copper phthalocyanine, its nuclear chlorinated derivatives and copper tetra- and octaphenyl phthalocyanine, quinacridone, e.g. linear quinacridone and various other pigments. Preferred latices are prepared from vinyl alkylbenzenes, alkyl methacrylates and dialkyl fumarates, preferably in the presence of a chain transfer agent, e.g. alkyl mercaptan (t-dodecyl- and t-amylmercaptans). The flocculating step is carried out in the presence of an electrolyte such as a water soluble acid or salt other than an alkali metal salt, e.g. HCl and H2SO4. The flocculated mixture may be heated and cooled before being separated. In the examples an aqueous suspension of the pigment is ball-milled to give a dispersion to which is added a latex of a synthetic polymer and then this mixture is mixed with a flocculating agent. The flocculated product is filtered, washed free from acid and dried. The pigments specified are copper phthalocyanine, scarlet pigment, molybdated lead chromate, lead chromate, Brunswick green, Prussian blue, carbon black, yellow and red azo pigments, rubine and pink toner lakes, iron complex of a -nitroso-b -naphthol, copper hexadecachlorophthalocyanine, copper tetrabromododecachlorophthalocyanine, 6:61-dichloro-4:41-dimethylthiondigo, flavanthrone, dibromoanthrone, indanthrone and linear quinacridone. The synthetic polymers mixed with these pigments are prepared from commercial vinyltoluene and n-butyl methacrylate; vinyltoluene and n- or iso-butyl methacrylate; isobutyl methacrylate; vinyltoluene; or commercial vinyltoluene and di-n-butylfumarate. The pigment compositions are readily dispersible in alkyd resins, e.g. linseed oil modified alkyd resin and 69% oil length linseed pentaerythritol phthalate alkyd resin, cellulose acetate (which may be molten), cellulose nitrate, polythene, polypropylene, plasticised polyvinyl chloride, lithographic varnish, waxes, oils, e.g. linseed oil, and organic solvents.ALSO:A solid pigment composition for the pigmentation of non aqueous media, is prepared by flocculating a mixture of an aqueous pigment dispersion and an aqueous latex of solid synthetic polymer (i.e. does not include elastomers or waxes) which is soluble in said non aqueous medium to the extent of at least 2% by weight and preferably at least 5% by weight, said latex being p obtained by emulsion polymerization of a monomer or a mixture of monomers and the diameter of the polymer particles in latex being between 0,01 and 0,5 micron, separating the flocculated mixture from the aqueous phase and drying it. Pigments may be of the inorganic type, e.g. titanium dioxide, zinc oxide, cadmium sulphide, carbon black, iron oxides, ultramarine, cobalt blue, Prussian blue, lead chromate and chromium oxide or of the organic type, e.g. azo, vat dye, triphendioxazine, phthalocyanine, e.g. copper phthalocyanine, its nuclear chlorinated derivatives and copper tetra- and octa-phenyl phthalocyanine, quinacridone, e.g. linear quinacridone and various other pigments. Preferred latices are prepared from vinyl alkyl benzenes, alkyl methacrylates and dialkyl fumarates, preferably in the presence of a chain transfer agent, e.g. alkyl mercaptan (t-dodecyl and t-amyl-mercaptans). The flocculating step is carried out in the presence of an electrolyte such as a water-soluble acid or salt other than an alkali metal salt, e.g. HCl and H2SO4. The flocculated mixture may be heated and cooled before being separated. In the examples an aqueous suspension of the pigment is ball-milled to give a dispersion to which is added a latex of a synthetic polymer and then this mixture is mixed with a flocculating agent. The flocculated product is filtered, washed free from acid and dried. The pigments specified are copper phthalocyanine, scarlet pigment, molybdated lead chromate, lead chromate, Brunswick green, Prussian blue, carbon black, yellow and red azo pigments, rubine and pink toner lakes, iron complex of a -nitroso-b -naphthol, copper hexadecachlorophthalocyanine, copper tetrabromo dodecachlorophthalocyanine, 6:61-dichloro-4:41-dimethyl thioindigo, flavanthrone, dibromoanthrone, indanthrone and linear quinacridone. The synthetic polymers mixed with these pigments are prepared from commercial vinyltoluene and n-butyl methacrylate; vinyltoluene and n- or iso-butyl methacrylate; isobutyl methacrylate; vinyltoluene; or commercial vinyltoluene and di-n-butylfumarate. The pigment compositions are readily dispersible in alkyd resins, e.g. linseed oil modified alkyd resin and 69% oil length linseed pentaerythritol phthalate alkyd resin, cellulose acetate (which may be molten), cellulose nitrate, polythene, polypropylene, plasticized polyvinyl chloride, lithographic varnish, waxes, oils, e.g. linseed oil, and organic solvents.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78321A US3220965A (en) | 1960-01-04 | 1960-12-27 | Manufacture of new pigment compositions |
CH161A CH435518A (en) | 1960-01-04 | 1961-01-03 | Process for the production of new pigment compositions and new pigment compositions obtained by this process |
FR848788A FR1277177A (en) | 1960-01-04 | 1961-01-04 | Pigment compositions easily dispersible in non-aqueous media |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1867962A GB979666A (en) | 1962-05-15 | 1962-05-15 | Pigmentation of plastics |
Publications (1)
Publication Number | Publication Date |
---|---|
GB936911A true GB936911A (en) | 1963-09-18 |
Family
ID=10116571
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19960A Expired GB936911A (en) | 1960-01-04 | 1960-01-04 | New pigment compositions |
GB1867962A Expired GB979666A (en) | 1960-01-04 | 1962-05-15 | Pigmentation of plastics |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1867962A Expired GB979666A (en) | 1960-01-04 | 1962-05-15 | Pigmentation of plastics |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE632389A (en) |
CH (1) | CH465205A (en) |
DE (1) | DE1278654B (en) |
DK (1) | DK108269C (en) |
GB (2) | GB936911A (en) |
NL (2) | NL292703A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2185225A5 (en) * | 1972-05-17 | 1973-12-28 | Color Service | |
US4105464A (en) * | 1974-07-12 | 1978-08-08 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process for the production of pigment-synthetic resin concentrates |
US5049594A (en) * | 1985-08-30 | 1991-09-17 | Ecc International Limited | Polymer compositions containing inorganic fillers coated with latex and process for preparing coated fillers |
US5458973A (en) * | 1989-07-24 | 1995-10-17 | Ecc International Ltd. | Granular filler |
EP1953197A1 (en) * | 2007-01-31 | 2008-08-06 | Air Products and Chemicals, Inc. | Hydrophobic Metal and Metal Oxide Particles with Unique Optical Properties |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1931998C3 (en) * | 1968-06-25 | 1982-04-08 | Harlow Chemical Co. Ltd., London | Process for the production of multicolored paints |
DE2522987A1 (en) * | 1975-05-23 | 1977-01-20 | Bayer Ag | PROCESS FOR THE PRODUCTION OF CHALK-RESISTANT TITANIUM DIOXIDE PIGMENTS |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1984182A (en) * | 1929-07-30 | 1934-12-11 | Zinsser & Company Inc | Pigment |
US2114713A (en) * | 1935-02-28 | 1938-04-19 | Du Pont | Process of dispersing pigments and products thereof |
CH284079A (en) * | 1950-06-26 | 1952-07-15 | Ciba Geigy | Process for the production of pigment preparations. |
DE1044027B (en) * | 1956-08-01 | 1958-11-20 | Siegle & Co G M B H Farbenfabr | Process for the production of an easily distributable phthalocyanine pigment preparation in powder form |
-
0
- NL NL259690D patent/NL259690A/xx unknown
- NL NL292703D patent/NL292703A/xx unknown
-
1960
- 1960-01-04 GB GB19960A patent/GB936911A/en not_active Expired
- 1960-12-30 DE DE1960J0019243 patent/DE1278654B/en active Pending
-
1962
- 1962-05-15 GB GB1867962A patent/GB979666A/en not_active Expired
-
1963
- 1963-05-15 CH CH606863A patent/CH465205A/en unknown
- 1963-05-15 BE BE632389D patent/BE632389A/da unknown
- 1963-05-15 DK DK230963A patent/DK108269C/en active
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2185225A5 (en) * | 1972-05-17 | 1973-12-28 | Color Service | |
US4105464A (en) * | 1974-07-12 | 1978-08-08 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process for the production of pigment-synthetic resin concentrates |
US5049594A (en) * | 1985-08-30 | 1991-09-17 | Ecc International Limited | Polymer compositions containing inorganic fillers coated with latex and process for preparing coated fillers |
US5458973A (en) * | 1989-07-24 | 1995-10-17 | Ecc International Ltd. | Granular filler |
EP1953197A1 (en) * | 2007-01-31 | 2008-08-06 | Air Products and Chemicals, Inc. | Hydrophobic Metal and Metal Oxide Particles with Unique Optical Properties |
Also Published As
Publication number | Publication date |
---|---|
CH465205A (en) | 1968-11-15 |
NL259690A (en) | |
DE1278654B (en) | 1968-09-26 |
NL292703A (en) | |
DK108269C (en) | 1967-10-30 |
BE632389A (en) | 1963-11-18 |
GB979666A (en) | 1965-01-06 |
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