GB924423A - Acrolein resin compositions - Google Patents
Acrolein resin compositionsInfo
- Publication number
- GB924423A GB924423A GB41333/59A GB4133359A GB924423A GB 924423 A GB924423 A GB 924423A GB 41333/59 A GB41333/59 A GB 41333/59A GB 4133359 A GB4133359 A GB 4133359A GB 924423 A GB924423 A GB 924423A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrolein
- resin
- acid
- ethylene
- epichlorhydrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/12—Homopolymers or copolymers of unsaturated ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Epoxy Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
Film-forming compositions which have good adhesion to wood panels, glass and metal comprise an acrolein resin and one or more hardening agents containing free NH2 and/or NH groups bound to non-carboxylic carbon atoms chosen from the group of aliphatic, cycloaliphatic and aromatic amines, including polyamines, polyamide resins and 2-thionotetrahydrotriazines. By "acrolein resin" is meant a resinous reaction product of acrolein with one or more other substances such as alcohols, phenols, hydroxy-containing polyesters and epoxy compounds optionally in the presence of a vinyl compound (see Group IV(a)). Suitable solvents are ethanol, ethylene glycol monoethyl ether, styrene and toluene. A pigment, e.g. titanium dioxide, may be present. Specification 849,401 is referred to.ALSO:A film-forming composition comprises an acrolein resin and one or more hardening agents containing free NH2 and/or NH groups bound to non-carboxylic carbon atoms chosen from the group of aliphatic, cycloaliphatic and aromatic amines, including polyamines, polyamide resins and 2-thiono-tetra-hydrotriazines. By "acrolein resin" is meant a resinous reaction product of acrolein with one or more other substances, e.g. alcohols, phenols, hydroxycontaining polyesters or epoxy compounds, particularly glycols, diphenylol and trimethylol propane and ethers thereof, polypropylene oxide, esters of adipic acid with glycerol, trimethylol propane or diphenylol propane, maleic acid-di(trimethylol propane) ester, resorcinol, glycidyl ethers and esters, epoxidized fat acid esters, epichlorhydrin, ethylene oxide, 3,4-epoxycyclohexyl-ethylene oxide, the ester of 1-methylol3,4-epoxy-6-methylcyclohexane and 3,4-epoxy6-methylcyclohexane carboxylic acid, ethylene bis-(2,3-epoxypropyl carbonate), butadiene dioxide, dibenzyl urea diglycidyl ether, glycidyl aldehyde, epoxy resins derived from epichlorhydrin and diphenylol propane and other polyglycidyl ethers derived, for example, from diols and epichlorhydrin. In addition, vinyl compounds such as acrylonitrile and styrene may be present during the reaction. Specified hardening agents are cyclohexylamine, dicyclohexylamine, 2-ethylhexyl- and di-(2-ethylhexyl)-amine, 3-methoxy- and cyclohexyl propylamine, laurylamine, stearylamine, ethylene diamine, diethylene triamine, trimethylene diamine, dipropylene triamine, cyclohexylpropylene diamine, 4,41-diphenylamine, 3,31-bis-(methyl-imino)-dipropylamine, polyamide resins obtained from di- or trimerized fat acids and polyamines, e.g. dimerized linoleic acid and diethylene triamine, and 2-thiono-tetra-hydrotriazines substituted in the 5 and/or 4,6- positions by alkyl or aminoalkyl groups. The hardener is preferably added to a solution of the resin, suitable solvents being ethyl alcohol, ethylene glycol monoethyl ether, styrene and toluene. The hardener may also be in solution, in for example an alcohol, a mixture of ethanol, water and acetone, or ethylene glycol monoethyl ether. Pigments and fillers, e.g. titanium dioxide, may be added. Hardening of the composition may occur at room temperature or may be effected at elevated temperatures, e.g. 70 DEG -120 DEG C. The films have good adhesion to wood, glass and metal and have improved resistance to chemicals, e.g. caustic soda and acetic acid. Examples are given with details of the composition of the acrolein resin. Specification 849,401 is referred to.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC18068A DE1117800B (en) | 1958-12-16 | 1958-12-16 | Varnishes and paints that provide fast curing, especially cold curing, chemical-resistant films |
DEC18813A DE1141399B (en) | 1958-12-16 | 1959-04-16 | Fast curing, especially cold curing, chemical-resistant films delivering lacquers and paints |
Publications (1)
Publication Number | Publication Date |
---|---|
GB924423A true GB924423A (en) | 1963-04-24 |
Family
ID=25969225
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB41333/59A Expired GB924423A (en) | 1958-12-16 | 1959-12-04 | Acrolein resin compositions |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE1141399B (en) |
FR (1) | FR1245807A (en) |
GB (1) | GB924423A (en) |
NL (2) | NL120719C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3475359A (en) * | 1966-10-13 | 1969-10-28 | Pacific Vegetable Oil Corp | Polyaldehyde-polyamine coating composition |
-
0
- NL NL243680D patent/NL243680A/xx unknown
- NL NL120719D patent/NL120719C/xx active
-
1959
- 1959-04-16 DE DEC18813A patent/DE1141399B/en active Pending
- 1959-11-20 FR FR810731A patent/FR1245807A/en not_active Expired
- 1959-12-04 GB GB41333/59A patent/GB924423A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3475359A (en) * | 1966-10-13 | 1969-10-28 | Pacific Vegetable Oil Corp | Polyaldehyde-polyamine coating composition |
Also Published As
Publication number | Publication date |
---|---|
NL120719C (en) | |
FR1245807A (en) | 1960-11-10 |
DE1141399B (en) | 1962-12-20 |
NL243680A (en) |
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