GB923086A - Perfluoroacidoguanamines - Google Patents
PerfluoroacidoguanaminesInfo
- Publication number
- GB923086A GB923086A GB43299/59A GB4329959A GB923086A GB 923086 A GB923086 A GB 923086A GB 43299/59 A GB43299/59 A GB 43299/59A GB 4329959 A GB4329959 A GB 4329959A GB 923086 A GB923086 A GB 923086A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formaldehyde resins
- alkyl
- hydrogen
- compounds
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Textile treating agents comprise a compound of formula <FORM:0923086/IV(a)/1> <FORM:0923086/IV(a)/2> where n is 0-13, m is 1-8, and R1-R8 are hydrogen, alkyl, cycloalkyl, allyl, phenyl, substituted phenyl, or -CH2OR9, where R9 is hydrogen or C1-4 alkyl, together with conventional textile resins, such as urea p formaldehyde resins and cyclic urea formaldehyde resins, e.g. from 1,2-propylene-, 1,3-propylene- and ethylene urea, and their alkylated derivatives; phenol formaldehyde resins; ketone formaldehyde resins; epoxy resins, e.g. polyglycidy ethers of polyhydric alcohols; and polymethylol melamines.ALSO:The invention comprises compounds of the formula <FORM:0923086/IV(a)/1> <FORM:0923086/IV(a)/2> wherein n is 0-13, m is 1-8, and R1-R8 are hydrogen, alkyl, cycloalkyl, allyl, phenyl, substituted phenyl (e.g. p-chlorophenyl), or -CH2OR9, where R9 is hydrogen or C1-4 alkyl; their production (other than -CH2OR9 compounds) by reacting an ester of a perfluoroalkane carboxylic acid with a biguanide at 15-100 DEG C.; the production of N-CH2OH compounds by reacting an N-H compound with formaldehyde or a formaldehyde-producing substance at an alkaline pH at 30-100 DEG C.; and the alkylation of the N-methylol compounds by means of a C1-4 alkanol at an acid pH. The compounds of the invention are used for treating textiles (see Group IV(c)).ALSO:Textile and other materials are treated with a compound <FORM:0923086/IV(a)/1> <FORM:0923086/IV(a)/2> where n is 0-13, m is 1-8, and R1-R: are hydrogen, alkyl, cycloalkyl, allyl, phenyl, substituted phenyl, or -CH2OR9, where R9 is hydrogen or C1-4 alkyl (see Group IV(b)) to impart properties such as insect repellency, grease and oil repellancy, germicidal activity, and, with cellulosic materials, crease resistance and shrinkage control. The compounds may be applied from aqueous, aqueous alcohol, or solvent solutions or from aqueous dispersion by spraying, immersion, dipping or padding. Suitable materials are proteinaceous or cellulosic fibres and fabrics, including felted, wood, paper and cellulosic films, wool, furs, feathers, hair and hides; proteinaceous materials blended with other materials, such as cellulosics, nylons and acrylics; cotton, regenerated cellulose, viscose, rayon, linen, hemp and jute, alone or blended with, for example, nylon, acrylic, polyester or wool fibres or silk. Specified solvents are dimethylformamide, methanol, water and dimethylformamide or an alcohol, e.g. methanol and ethanol, or mixtures thereof. Curing catalysts may be present in the compositions, e.g. ammonium salts such as the floride and sulphate, amine salts such as triethylamine and isopropylamine hydrochloride, alkanolamine salts such as triethanolamine hydrochloride, metal salts such as Mg Cl2, Zn(NO3)2 and Al Cl3, and free acids such as oxalic and tartaric acid. Drying and curing may be carried out together or in separate steps. Other textile-treating agents may also be present, e.g. polymethylolated melamines; urea formaldehyde resins and cyclic urea formaldehyde resins and their alkylated derivatives; phenol formaldehyde resins; ketone formaldehyde resins; epoxy resins; acrylate and methacrylate polymers and copolymers with styrenes, acrylonitrile, polyvinyl chloride and polyvinyl acetate; and dicyandiamide.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78264058A | 1958-12-24 | 1958-12-24 | |
US192090A US3162633A (en) | 1958-12-24 | 1962-05-03 | Perfluoroguanamines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB923086A true GB923086A (en) | 1963-04-10 |
Family
ID=26887714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB43299/59A Expired GB923086A (en) | 1958-12-24 | 1959-12-21 | Perfluoroacidoguanamines |
Country Status (2)
Country | Link |
---|---|
US (1) | US3162633A (en) |
GB (1) | GB923086A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3536710A (en) * | 1968-06-05 | 1970-10-27 | Du Pont | Substituted guanamines and their derivatives |
US3687900A (en) * | 1968-06-05 | 1972-08-29 | Du Pont | Homopolymers of substituted guanamines |
US4055720A (en) * | 1976-05-25 | 1977-10-25 | The United States Of America, As Represented By The Secretary Of Agriculture | Diaminotrihalopropyl triazines: and their methylol derivatives |
US4932998A (en) * | 1986-09-30 | 1990-06-12 | Idemitsu Kosan Company Limited | Triazine derivatives, and herbicides comprising the same as the effective ingredient |
WO2023013697A1 (en) * | 2021-08-03 | 2023-02-09 | 東ソー株式会社 | Material for metal patterning, fluoro compound, thin film for metal patterning, organic electroluminescence device, electronic device, and method for forming metal pattern |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2845421A (en) * | 1958-07-29 | Fluorination of chloro triazines with | ||
US2427315A (en) * | 1947-09-09 | Carboxy polymethylene guanamines | ||
US2423353A (en) * | 1947-07-01 | Polymethylene diguanamines | ||
US2394526A (en) * | 1946-02-05 | Aliphatic substituted guanamines | ||
US2451432A (en) * | 1948-10-12 | High molecular guanamines and a | ||
US2385766A (en) * | 1941-08-30 | 1945-09-25 | American Cyanamid Co | Guanamines in textile finishing |
US2535968A (en) * | 1945-04-13 | 1950-12-26 | American Cyanamid Co | Heterocyclic guanamines |
US2526948A (en) * | 1945-10-23 | 1950-10-24 | Phillips Petroleum Co | Process of treating textiles with half-acid amide derivatives |
US2480084A (en) * | 1948-03-20 | 1949-08-23 | Dow Chemical Co | Protection of cellulosic textile materials |
US2734004A (en) * | 1952-08-25 | 1956-02-07 | Water soluble n-methylol polypyrroli- | |
US2871145A (en) * | 1954-05-21 | 1959-01-27 | Hajdu Joseph | Process of impregnating textile material to increase its wear resistance |
NL105210C (en) * | 1954-07-22 | |||
US2892810A (en) * | 1954-08-24 | 1959-06-30 | Ciba Ltd | New derivatives of aldehyde condensation products of the aminotriazine or urea group and their manufacture and use |
-
1959
- 1959-12-21 GB GB43299/59A patent/GB923086A/en not_active Expired
-
1962
- 1962-05-03 US US192090A patent/US3162633A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US3162633A (en) | 1964-12-22 |
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