GB922457A - Graft copolymers and process for preparing them - Google Patents

Graft copolymers and process for preparing them

Info

Publication number
GB922457A
GB922457A GB12886/59A GB1288659A GB922457A GB 922457 A GB922457 A GB 922457A GB 12886/59 A GB12886/59 A GB 12886/59A GB 1288659 A GB1288659 A GB 1288659A GB 922457 A GB922457 A GB 922457A
Authority
GB
United Kingdom
Prior art keywords
oxide
polyalkylene
glycols
specified
polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB12886/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEF25494A external-priority patent/DE1077430B/en
Priority claimed from DEF26081A external-priority patent/DE1081230B/en
Priority claimed from DEF27283A external-priority patent/DE1084917B/en
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB922457A publication Critical patent/GB922457A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

Graft copolymers are made by dissolving a polyalkylene oxide or glycol in at least one monomer, which is then polymerized by the action of a free-radical catalyst and/or actinic light. Monomers specified are vinyl acetate, propionate, butyrate and benzoate, methyl, ethyl, propyl and isopropyl acrylates and methacrylates, and mixtures of such monomers with one another or with other polymerizable compounds, e.g. acrylic, methacrylic and crotonic acids, dimethyl maleate and dibutyl fumarate and itaconate. Polyalkylene oxides and glycols specified are polyethylene and polypropylene glycols, copolymers of ethylene oxide with propylene oxide, 1:2-epoxybutane, isobutylene oxide and/or styrene oxide, polyalkylene glycols esterified or etherified at one or both ends with acetic, propionic or butyric acid or methanol or butanol, the condensation product of ethylene oxide with nonyl phenol and the condensation product of propylene oxide with tributyl phenol, polyalkylene glycols substituted at one or both ends by mono or polyamines, e.g. ethylene diamine, polyalkylene glycols substituted at one or both ends of the chain by carboxylic or sulphonic amide groups, and the reaction product of polyethylene glycol and p-phenylene diisocyanate. Polymerization catalysts specified are acetyl, benzoyl and lauroyl peroxides, a benzoyl peroxide/benzoin mixture and azodiisobutyronitrile. The polymerization may be carried out in bulk or in solution in a solvent such as methanol or methyl acetate. In an example (7) a graft copolymer of vinyl acetate crotonic acid and polyethylene oxide is dissolved in aqueous ammonia. Specification 874,130 is referred to.
GB12886/59A 1958-04-15 1959-04-15 Graft copolymers and process for preparing them Expired GB922457A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE1222944X 1958-04-15
DEF25494A DE1077430B (en) 1958-04-15 1958-04-15 Process for the production of graft polymers of polyvinyl esters
DEF26081A DE1081230B (en) 1958-07-03 1958-07-03 Process for the production of graft polymers of polyvinyl esters
DEF27283A DE1084917B (en) 1958-12-17 1958-12-17 Process for the production of graft polymers

Publications (1)

Publication Number Publication Date
GB922457A true GB922457A (en) 1963-04-03

Family

ID=27436851

Family Applications (1)

Application Number Title Priority Date Filing Date
GB12886/59A Expired GB922457A (en) 1958-04-15 1959-04-15 Graft copolymers and process for preparing them

Country Status (2)

Country Link
FR (1) FR1222944A (en)
GB (1) GB922457A (en)

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EP0285038A2 (en) * 1987-04-03 1988-10-05 BASF Aktiengesellschaft Use of graft polymers of polyalkylene oxides as anti-redeposition agents in the washing and after-treatment of textiles containing synthetic fibres
US4846994A (en) * 1987-04-03 1989-07-11 Basf Aktiengesellschaft Use of graft polymers based on polyalkylene oxides as grayness inhibitors in the wash and aftertreatment of textile material containing synthetic fibers
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US5049302A (en) * 1988-10-06 1991-09-17 Basf Corporation Stable liquid detergent compositions with enchanced clay soil detergency and anti-redeposition properties
US5217798A (en) * 1991-05-07 1993-06-08 National Starch And Chemical Investment Holding Corporation Water sensitive hot melt adhesives for nonwoven applications
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US6579953B1 (en) 1998-09-30 2003-06-17 Basf Aktiengesellschaft Application of water-soluble or water-dispersible polymerizates which contain poly-ether and which are used as a coating agent, a binding agent and/or as a film-forming auxiliary agent in pharmaceutical forms of administration
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US7824664B2 (en) 2005-04-29 2010-11-02 L'oreal S.A. Semipermanent hair shaping method
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US7976831B2 (en) 2004-04-02 2011-07-12 L'oreal S.A. Method for treating hair fibers
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US8246940B2 (en) 2003-11-18 2012-08-21 L'oreal S.A. Cosmetic composition comprising gellan gum or a derivative thereof, a fixing polymer, a monovalent salt and an alcohol, process of using the same
US8399001B2 (en) 2003-11-18 2013-03-19 L'oreal Cosmetic composition comprising at least one gellan gum or derivative thereof, at least one monovalent salt, and at least one suspension compound, processes using this composition, and uses thereof
US8414905B2 (en) 2009-12-16 2013-04-09 Basf Se Film coating compositions based on polyvinyl alcohol-polyether graft copolymer/polyvinyl alcohol combinations with an improved moisture barrier effect
WO2013132042A1 (en) 2012-03-09 2013-09-12 Basf Se Continuous process for the synthesis of graft polymers based on polyethers
US8545817B2 (en) 2006-08-04 2013-10-01 L'oreal Cosmetic composition comprising at least one polysaccharide of λ-carrageenan type in aerosol form, method for the cosmetic treatment of keratinous fibers, and product comprising the composition
US8623463B2 (en) 2010-07-22 2014-01-07 Basf Se Sound deadener composition with emulsion polymer stabilized by protective colloids
US8715729B2 (en) 2010-12-22 2014-05-06 Basf Se Rapidly disintegrating, solid coated dosage form
US8859484B2 (en) 2012-03-09 2014-10-14 The Procter & Gamble Company Detergent compositions comprising graft polymers having broad polarity distributions
US8968707B2 (en) 2004-05-07 2015-03-03 L'oreal Composition packaged in an aerosol device, comprising at least one anionic fixing polymer, at least one silicone oxyalkylenated in the alpha and omega positions of the silicone chain, and at least one propellant
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