GB916552A - Purification of polyethers - Google Patents
Purification of polyethersInfo
- Publication number
- GB916552A GB916552A GB1152560A GB1152560A GB916552A GB 916552 A GB916552 A GB 916552A GB 1152560 A GB1152560 A GB 1152560A GB 1152560 A GB1152560 A GB 1152560A GB 916552 A GB916552 A GB 916552A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyethers
- polyether
- acids
- kieselguhr
- optionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Polyethers are rendered free from basic inorganic materials used as catalysts by treating with an aliphatic dicarboxylic acid containing 2 to 10 carbon atoms in the molecule. Examples of such acids are oxalic, malonic, succinic, glutaric, adipic, alkyladipic, pimelic, suberic, azelaic and sebacic acids. Mixtures of acids may be used. The polyethers are particularly those obtained by polymerizing an a ,b -alkylene oxide, e.g. ethylene, propylene-1,2 and butylene-1,2 and -2,3 oxides, in the presence of an alkaline catalyst and optionally in the presence of a compound containing one or more reactive hydrogen atoms. The inorganic materials are generally compounds of alkali and alkaline earth metals, particularly potassium and sodium hydroxides. Treatment may be effected at 25 DEG to 150 DEG C., preferably 90 DEG to 110 DEG C., when the polyether is liquid. Water is preferably added before or after the addition of the acid and before the removal of volatile and insoluble materials. A basic material insoluble in the polyether is also preferably added before these removals, optionally in conjunction with a filter aid such as kieselguhr. And the polyether may be treated with an absorbent material, e.g. finely divided carbon, before the final filtration. The examples describe the preparation and purification of polyethers prepared by reacting propylene oxide with diethylene glycol, 1,1,1-trimethylolpropane and glycerol respectively. In Example 6, after treatment with adipic acid and kieselguhr, there are added finely divided carbon and 2-(a -methylcyclohexyl)-4,6-dimethyl phenol before removal of volatiles &c. Specification 864,097 is disclaimed.ALSO:Polyethers are rendered free from basic inorganic materials used as catalysts by treating with an aliphatic dicarboxylic acid containing 2 to 10 carbon atoms in the molecule. Examples of such acids are oxalic, malonic, succinic, glutaric, adipic, p alkyladipic, pimelic, suberic, azelaic and sebacic acids. Mixtures of acids may be used. The polyethers are particularly those obtained by polymerizing an a ,b -alkylene oxide, e.g. ethylene, propylene-1,2 and butylene-1,2 and -2,3 oxides, in the presence of an alkaline catalyst and optionally in the presence of a compound containing one or more reactive hydrogen atoms. The inorganic materials are generally compounds of alkali and alkaline earth metals, particularly potassium and sodium hydroxides. Treatment may be effected at 25 to 150 DEG C., preferably 90 DEG to 110 DEG C., when the polyether is liquid. Water is preferably added before or after the addition of the acid and before the removal of volatile and insoluble materials. A basic material insoluble in the polyether is also preferably added before these removals, optionally in conjunction with a filter aid such as kieselguhr. And the polyether may be treated with an absorbent material, e.g. finely divided carbon, before the final filtration. The examples describe the preparation and purification of polyethers prepared by reacting propylene oxide with diethylene glycol, 1,1,1-trimethylol propane and glycerol respectively. In Example 6, after treatment with adipic acid and kieselguhr, there are added finely divided carbon and 2-(a -methylcyclohexyl)-4,6-dimethyl phenol before removal of volatiles &c. Specification 864,097 is disclaimed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1152560A GB916552A (en) | 1960-04-01 | 1960-04-01 | Purification of polyethers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1152560A GB916552A (en) | 1960-04-01 | 1960-04-01 | Purification of polyethers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB916552A true GB916552A (en) | 1963-01-23 |
Family
ID=9987847
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1152560A Expired GB916552A (en) | 1960-04-01 | 1960-04-01 | Purification of polyethers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB916552A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2173108A1 (en) * | 1972-02-24 | 1973-10-05 | Basf Ag | |
GB2135322A (en) * | 1983-01-21 | 1984-08-30 | Vyzk Ustav Petrochem | A process for purifying at least partially water-soluble polyethers and/or copolymers |
WO1992012951A1 (en) * | 1991-01-22 | 1992-08-06 | Henkel Kommanditgesellschaft Auf Aktien | Method of preparing fatty-alcohol polyalkylene-glycol ethers |
WO2001088015A1 (en) * | 2000-05-15 | 2001-11-22 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of polyether polyols |
WO2002010252A1 (en) * | 2000-07-27 | 2002-02-07 | Huntsman International Llc | Polyol processing |
-
1960
- 1960-04-01 GB GB1152560A patent/GB916552A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2173108A1 (en) * | 1972-02-24 | 1973-10-05 | Basf Ag | |
GB2135322A (en) * | 1983-01-21 | 1984-08-30 | Vyzk Ustav Petrochem | A process for purifying at least partially water-soluble polyethers and/or copolymers |
WO1992012951A1 (en) * | 1991-01-22 | 1992-08-06 | Henkel Kommanditgesellschaft Auf Aktien | Method of preparing fatty-alcohol polyalkylene-glycol ethers |
WO2001088015A1 (en) * | 2000-05-15 | 2001-11-22 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of polyether polyols |
US8017814B2 (en) | 2000-05-15 | 2011-09-13 | Shell Oil Company | Process for the preparation of polyether polyols |
WO2002010252A1 (en) * | 2000-07-27 | 2002-02-07 | Huntsman International Llc | Polyol processing |
US6762279B2 (en) | 2000-07-27 | 2004-07-13 | Huntsman International Llc | Polyol processing |
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