GB904227A - New phthalocyanine dyestuffs containing aminotriazine radicals - Google Patents

New phthalocyanine dyestuffs containing aminotriazine radicals

Info

Publication number
GB904227A
GB904227A GB1803959A GB1803959A GB904227A GB 904227 A GB904227 A GB 904227A GB 1803959 A GB1803959 A GB 1803959A GB 1803959 A GB1803959 A GB 1803959A GB 904227 A GB904227 A GB 904227A
Authority
GB
United Kingdom
Prior art keywords
hydrogen
carbon atoms
radical containing
dyes
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1803959A
Inventor
Peter Frederick Clark
Harold Thompson Howard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1803959A priority Critical patent/GB904227A/en
Priority to CH602760A priority patent/CH415911A/en
Priority to CH706665A priority patent/CH439542A/en
Publication of GB904227A publication Critical patent/GB904227A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/002—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the linkage of the reactive group being alternatively specified
    • C09B62/016—Porphines; Azaporphines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/78—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with other reactive groups
    • C09B62/84—Porphines; Azaporphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention comprises metal-containing phthalocyanine dyestuffs which contain, attached to the 41-position of the benz rings of the phthalocyanine nucleus, at least one sulphonic acid group and at least one group of the formula:- <FORM:0904227/IV (b)/1> wherein Y is hydrogen, halogen, methyl or alkoxy, X is hydrogen or a sulphonic acid group, R1 is hydrogen or an alkyl or hydroxyalkyl radical containing 1 to 5 carbon atoms, R2 is hydrogen or an alkyl or hydroxyalkyl radical containing 1 to 5 carbon atoms or an alkenyl radical containing 3 or 4 carbon atoms and R3 is hydrogen, a hydroxyalkyl radical containing 1 to 5 carbon atoms or an alkenyl radical containing 3 or 4 carbon atoms. The dyes which do not contain hydroxymethyl groups are made by heating together an appropriate amine and a phthalocyanine containing at least one group of the formula:- <FORM:0904227/IV (b)/2> where Z is chlorine or bromine and R6 has the meaning of R1 above except hydroxymethyl. When at least one of R1, R2 and R3 is hydroxymethyl, the dyes are made by treating the dyes where at least one of R1, R2 and R3 is hydrogen with formaldehyde. The dyes dye, pad or print cellulose textiles such as cotton viscose rayon, regenerated cellulose and linen greenish-blue shades, preferably in the presence of a substance which yields a resin on heating and a substance which is acid or yields an acid on heating and then heating the material. Resin-forming substances are methylomelamine, methylolurea, acetals, epoxides and isocyanates and acid-liberating substances are ammonium dihydrogen phosphate, ammonium thiocyanate, zinc chloride, magnesium chloride, zinc nitrate and amine hydrochlorides. In an Example (6) cotton cloth is passed through an aqueous solution containing a dye of the above type, a melamine-formaldehyde precondensate or 1 : 3-dimethylol-2-imidazolidone and ammonium thiocyanate, squeezed, dried and cured at 140 DEG C., and then heated in sodium carbonate and detergent solution, rinsed and dried. Specification 805,562 is referred to.
GB1803959A 1959-05-27 1959-05-27 New phthalocyanine dyestuffs containing aminotriazine radicals Expired GB904227A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB1803959A GB904227A (en) 1959-05-27 1959-05-27 New phthalocyanine dyestuffs containing aminotriazine radicals
CH602760A CH415911A (en) 1959-05-27 1960-05-25 Process for the preparation of phthalocyanine dyes
CH706665A CH439542A (en) 1959-05-27 1960-05-25 Process for the preparation of metal-containing phthalocyanine dyes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1803959A GB904227A (en) 1959-05-27 1959-05-27 New phthalocyanine dyestuffs containing aminotriazine radicals

Publications (1)

Publication Number Publication Date
GB904227A true GB904227A (en) 1962-08-22

Family

ID=10105583

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1803959A Expired GB904227A (en) 1959-05-27 1959-05-27 New phthalocyanine dyestuffs containing aminotriazine radicals

Country Status (2)

Country Link
CH (2) CH439542A (en)
GB (1) GB904227A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3983588A (en) * 1970-12-23 1976-10-05 Ciba-Geigy Ag Process for the dyeing or printing and simultaneous finishing of cellulose materials

Also Published As

Publication number Publication date
CH439542A (en) 1967-07-15
CH415911A (en) 1966-06-30

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