GB903933A - Curing epoxidised resins and curing compositions therefor - Google Patents
Curing epoxidised resins and curing compositions thereforInfo
- Publication number
- GB903933A GB903933A GB531462A GB531462A GB903933A GB 903933 A GB903933 A GB 903933A GB 531462 A GB531462 A GB 531462A GB 531462 A GB531462 A GB 531462A GB 903933 A GB903933 A GB 903933A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- curing
- organic
- anhydride
- curing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4071—Curing agents not provided for by the groups C08G59/42 - C08G59/66 phosphorus containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/681—Metal alcoholates, phenolates or carboxylates
- C08G59/685—Carboxylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/688—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Polyepoxides are cured by a mixture of a curing agent and a curing assistant which comprises a polyvalent metal salt of an organic acidic compound containing up to 24 carbon atoms in the molecule. The curing assistants are salts of, for example, zinc, aluminium, iron, manganese, cobalt, lead, cadmium, barium, chromium and copper with, for example, stearic acid, linoleic acid, benzoic acid, naphthenic acid, phenol, resorcinol, organic sulphonic, sulphinic, sulphuric, phosphonic, phosphinic and phosphoric acids. The curing agent may be any conventional curing agent for polyepoxides, other than a curing assistant as defined above or a phenol-aldehyde reaction product. The curing agent may be an organic amine, e.g. dimethylamine, hexamethylenediamine, diethylenetriamine, phenylenediamine and dimethylaminomethylphenol; a carboxylic acid anhydride, e.g. maleic anhydride, succinic anhydride, chlorosuccinic anhydride and tetrahydrophthalic anhydride; carboxylic acids, e.g. adipic acid and dimerized linoleic acid; organic acid phosphates; sulphonic acids, e.g. methanesulphonic acid and benzenesulphonic acid; sulphonyl halides, e.g. ethanesulphonyl chloride and benzenesulphonyl bromide; liquid organic polysulphides, e.g. the reaction product of dichlorodiethyl formal and an alkali polysulphide, liquid polyamides; organic phosphites, e.g. triphenyl phosphite, and phenols, e.g. phenol, resorcinol and bisphenol A. Polyepoxides mentioned or exemplified include, e.g. 1,8-bis(2,3-epoxypropoxy)octane, glycidyl polyethers of bisphenol A, 1,3-bis(4,5-epoxypentoxy)-5-chlorobenzene and epoxidized glycerol trioleate. Examples are given. Specifications 729,253 and 770,488 also are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US79783759A | 1959-03-09 | 1959-03-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB903933A true GB903933A (en) | 1962-08-22 |
Family
ID=25171924
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB761060A Expired GB903932A (en) | 1959-03-09 | 1960-03-03 | Curing epoxidized resins and curing compositions therefor |
GB531462A Expired GB903933A (en) | 1959-03-09 | 1960-03-03 | Curing epoxidised resins and curing compositions therefor |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB761060A Expired GB903932A (en) | 1959-03-09 | 1960-03-03 | Curing epoxidized resins and curing compositions therefor |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE588383A (en) |
CH (1) | CH430201A (en) |
DE (1) | DE1150202B (en) |
GB (2) | GB903932A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3336251A (en) * | 1964-05-14 | 1967-08-15 | Shell Oil Co | Rapid curing fluidized bed coating composition |
US3344096A (en) * | 1963-12-23 | 1967-09-26 | Shell Oil Co | Fast curing fluidized bed coating composition |
US3468824A (en) * | 1965-12-13 | 1969-09-23 | Morton Int Inc | Epoxy composition |
US3484398A (en) * | 1965-03-18 | 1969-12-16 | Dexter Corp | Powdered epoxy resin compositions |
US3506598A (en) * | 1965-08-09 | 1970-04-14 | Minnesota Mining & Mfg | Thermo-curing coating powder composition |
US3510439A (en) * | 1967-12-01 | 1970-05-05 | Gen Motors Corp | Structural adhesives |
US3528935A (en) * | 1967-11-30 | 1970-09-15 | Sinclair Research Inc | Package stable,low viscosity,high solids,thermosetting coating compositions with latent curing catalyst |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3314912A (en) * | 1963-01-23 | 1967-04-18 | Hooker Chemical Corp | Epoxy resin compositions containing triorgano phosphate diluents |
US3432440A (en) * | 1965-02-11 | 1969-03-11 | Celanese Coatings Co | Epoxy curing agents comprising a fluoborate salt and a hydrolyzable ester |
DE3151540A1 (en) * | 1980-12-29 | 1982-08-19 | Ciba-Geigy GmbH, 7867 Wehr | Use of transparent anhydride-curable casting epoxy resins |
DE3135636A1 (en) * | 1981-09-09 | 1983-03-17 | Basf Ag, 6700 Ludwigshafen | CURABLE EPOXY RESINS |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE931729C (en) * | 1952-03-27 | 1955-08-16 | Albert Ag Chem Werke | Process for curing oil-free ethoxylin resins |
US2819233A (en) * | 1953-06-11 | 1958-01-07 | Phelps Dodge Copper Prod | Curing of epoxide resins with a chelate |
NL192833A (en) * | 1954-04-17 | |||
NL94293C (en) * | 1956-08-30 |
-
0
- BE BE588383D patent/BE588383A/xx unknown
-
1960
- 1960-03-03 GB GB761060A patent/GB903932A/en not_active Expired
- 1960-03-03 GB GB531462A patent/GB903933A/en not_active Expired
- 1960-03-09 CH CH266560A patent/CH430201A/en unknown
- 1960-03-09 DE DEA34172A patent/DE1150202B/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3344096A (en) * | 1963-12-23 | 1967-09-26 | Shell Oil Co | Fast curing fluidized bed coating composition |
US3336251A (en) * | 1964-05-14 | 1967-08-15 | Shell Oil Co | Rapid curing fluidized bed coating composition |
US3484398A (en) * | 1965-03-18 | 1969-12-16 | Dexter Corp | Powdered epoxy resin compositions |
US3506598A (en) * | 1965-08-09 | 1970-04-14 | Minnesota Mining & Mfg | Thermo-curing coating powder composition |
US3468824A (en) * | 1965-12-13 | 1969-09-23 | Morton Int Inc | Epoxy composition |
US3528935A (en) * | 1967-11-30 | 1970-09-15 | Sinclair Research Inc | Package stable,low viscosity,high solids,thermosetting coating compositions with latent curing catalyst |
US3510439A (en) * | 1967-12-01 | 1970-05-05 | Gen Motors Corp | Structural adhesives |
Also Published As
Publication number | Publication date |
---|---|
DE1150202B (en) | 1963-06-12 |
CH430201A (en) | 1967-02-15 |
BE588383A (en) | |
GB903932A (en) | 1962-08-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB903933A (en) | Curing epoxidised resins and curing compositions therefor | |
EP0117562B1 (en) | A process for preparing advanced epoxy resins employing tetrahydrocarbyl phosphonium salts as catalysts and advanced epoxy resins prepared by the process | |
EP2698393B1 (en) | Resin composition | |
US3553298A (en) | Hydrolytic stabilized phosphite esters | |
US3492269A (en) | Epoxy resin hardening process using inorganic metal salt accelerators | |
JP5260639B2 (en) | Catalyst for epoxide curing | |
KR102091389B1 (en) | Resin curing agent and one-pack type epoxy resin composition | |
BR112013022114B1 (en) | COMPOSITION FOR COATING; AND METHOD FOR LOADING A LOAD TANK | |
KR870001245A (en) | Resin composition and method for producing laminate therefrom | |
JPS5867718A (en) | Curing of polyepoxide compound using polymercaptanes and catalytic cocuring agent together | |
CA1136798A (en) | Process for the preparation of crosslinked high polymers | |
KR100571136B1 (en) | Novolac, an epoxy resin curing accelerator that is not affected by water | |
US3006891A (en) | Epoxide resin process and composition | |
US3703496A (en) | Hydrolytic stabilizer of phosphite esters and use as epoxy resin stabilizer | |
US4946817A (en) | Latent catalysts for epoxy-containing compounds | |
NO145541B (en) | HARDENABLE MIXING INCLUDING AROMATIC AMINE, METAL NITRATE AND EPOSY RESIN. | |
ES394078A1 (en) | Curable epoxide resin compositions containing boron-trichloride-tertiary amine complexes | |
US3240751A (en) | Stabilization of phosphites and epoxy resins containing phosphites by alkaline earthmetal oxides | |
US5442035A (en) | Calcium sulfonate or calcium hydrocarbyl sulfate accelerator for amine cure of epoxy resins | |
GB939210A (en) | Epoxy resin hardener compositions | |
US4689376A (en) | Heat-hardenable epoxide resin mixtures | |
SU509243A3 (en) | The method of obtaining epoxy polymers | |
JPS6056733B2 (en) | Fast curing epoxy resin compound and its usage | |
CA1185253A (en) | Cycloaliphatic diepoxide, its preparation and its use | |
KR20160046795A (en) | Phosphorus-containing compound, and curable epoxy resin composition containing same |