GB899780A - Improvements in or relating to oil additives - Google Patents

Improvements in or relating to oil additives

Info

Publication number
GB899780A
GB899780A GB27111/60A GB2711160A GB899780A GB 899780 A GB899780 A GB 899780A GB 27111/60 A GB27111/60 A GB 27111/60A GB 2711160 A GB2711160 A GB 2711160A GB 899780 A GB899780 A GB 899780A
Authority
GB
United Kingdom
Prior art keywords
phosphorus
methacrylate
esters
fatty alcohols
mixed fatty
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27111/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm and Haas GmbH
Original Assignee
Roehm and Haas GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm and Haas GmbH filed Critical Roehm and Haas GmbH
Publication of GB899780A publication Critical patent/GB899780A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/123Reaction products obtained by phosphorus or phosphorus-containing compounds, e.g. P x S x with organic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Lubricants (AREA)

Abstract

The viscosity index and pour-point of lubricating oil are improved by adding thereto the product obtained by reacting oil-soluble polymers of aliphatic acrylic and/or methacrylic esters first with a phosphorus sulphide and then with ammonia or an organic base. Preferred polymers are those derived by the copolymerization of C12-C18 mixed fatty alcohols methacrylate with one or more nitrogen-containing monomers, e.g. acrylonitrile, acrylamide or methacrylamide; with methyl methacrylate as an optional further comonomer. The phosphorus sulphide may be replaced in part by other readily decomposed phosphorus compounds, e.g. phosphorus chlorides, phosphorus oxychloride, phosphorus thiochloride, thiophosphoric esters and chlorothiophosphoric esters, or mixtures of such compounds. The preparation is described of lubricating oil compositions containing the above-described modified polymers together with zinc alkyldithiophosphate.ALSO:Oil-soluble homopolymers or copolymers of C8-C20 esters of acrylic and/or methacrylic acids are reacted first with a phosphorus sulphide and then with ammonia or an organic base. Copolymers specified are: (1) methacrylamide-methyl methacrylate-C12-C18 mixed fatty alcohols methacrylate, (2) acrylonitrileacrylamide-C12-C18 mixed fatty alcohols methacrylate, (3) acrylonitrile-methyl methacrylate-C12-C18 mixed fatty alcohols methacrylate and (4) methacrylamide-acrylonitrile-methyl methacrylate-C12-C18 mixed fatty alcohols methacrylate. The phosphorus sulphide may be formed in situ by the use of elemental sulphur and phosphorus, and may be replaced in part by other readily decomposed phosphorus compounds, e.g. phosphorus chlorides, phosphorus oxychloride, phosphorus thiochloride, thiophosphoric esters and chlorthiophosphoric esters, or mixtures of such compounds. Organic bases specified are ethanolamines, tert. octylamine or 3-lauryloxypropylamine.
GB27111/60A 1960-08-03 1960-08-04 Improvements in or relating to oil additives Expired GB899780A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR834862A FR1264329A (en) 1960-08-03 1960-08-03 Process for preparing adjuvants for lubricating oils

Publications (1)

Publication Number Publication Date
GB899780A true GB899780A (en) 1962-06-27

Family

ID=8736809

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27111/60A Expired GB899780A (en) 1960-08-03 1960-08-04 Improvements in or relating to oil additives

Country Status (2)

Country Link
FR (1) FR1264329A (en)
GB (1) GB899780A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110305724A (en) * 2019-07-17 2019-10-08 泉州市欧美润滑油制品有限公司 A kind of multi-vehicle-type universal stepless gear box oil and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110305724A (en) * 2019-07-17 2019-10-08 泉州市欧美润滑油制品有限公司 A kind of multi-vehicle-type universal stepless gear box oil and preparation method thereof
CN110305724B (en) * 2019-07-17 2022-04-05 泉州市欧美润滑油制品有限公司 Multi-vehicle type universal stepless transmission oil and preparation method thereof

Also Published As

Publication number Publication date
FR1264329A (en) 1961-06-19

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