GB895033A - Synthetic latexes comprising ar-monovinyl aromatic sulphonic acid salt copolymers - Google Patents

Synthetic latexes comprising ar-monovinyl aromatic sulphonic acid salt copolymers

Info

Publication number
GB895033A
GB895033A GB31375/60A GB3137560A GB895033A GB 895033 A GB895033 A GB 895033A GB 31375/60 A GB31375/60 A GB 31375/60A GB 3137560 A GB3137560 A GB 3137560A GB 895033 A GB895033 A GB 895033A
Authority
GB
United Kingdom
Prior art keywords
styrene
vinyl
sodium
sulphonate
butadiene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31375/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB895033A publication Critical patent/GB895033A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/14—Monomers containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/30—Nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile
    • C08F220/46—Acrylonitrile with carboxylic acids, sulfonic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F246/00—Copolymers in which the nature of only the monomers in minority is defined
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)

Abstract

Synthetic aqueous latices comprise colloidally dispersed solid addition polymers of predominantly non-ionic ethylenically unsaturated monomers containing 0 to 70% by weight of acrylonitrile, at least 10 mole per cent of the monomers being polymerizable monomers having a vinyl or a -substituted vinyl group attached to a carbon atom that is multiply bonded to an atom of atomic number 6 to 8, said addition polymer containing as comonomer in the polymer chain from 0,5 to 3 weight per cent of a water-soluble salt of the radicals of an ar-monovinyl aromatic sulphonic acid of formula: <FORM:0895033/IV (a)/1> wherein A is an aromatic hydrocarbon nucleus, X is an alkyl, cycloalkyl or halogen substituent, n is 0 to 4, m is 0 or 1 and M is a salt-forming cation, the weight per cent being calculated as sodium salt based on the weight of solid polymer. Specified salts include the sodium, potassium, calcium, ammonium and amine salts of styrene sulphonic acid, vinyltoluene sulphonic acid, vinyl xylene sulphonic acid, vinyl chlorobenzene sulphonic acid, vinyl naphthalene sulphonic acid, vinylbenzyl sulphonic acid and vinyl-a -xylene sulphonic acid. Specified conjugated non-ionic monomers include styrene and alkyl, akoxy, cyano, acetyl and halo styrenes; divinyl benzenes and naphthalenes; esters and nitriles of acrylic and methacrylic acids; ethyl a -chloracrylate; acrylanilide; methyl vinyl and methyl isopropenyl ketones and conjugated dienes. Other non-ionic monomers which may be employed include dialkyl maleates; vinyl esters of organic acids; vinyl and vinylidene halides; and vinyl ethers. Small amounts of other ionic monomers, e.g. acrylic acid, methacrylic acid and itaconic acid, may also be used. The monomers may be polymerized in aqueous media in the presence of catalysts, e.g. hydrogen peroxide, potassium persulphate, sodium persulphate, ammonium persulphate, dibenzoyl peroxide, dilauroyl peroxide, cumene hydroperoxide or tertiary butyl hydroperoxide, optionally activated by sodium bisulphite, sodium thiosulphate, sodium formaldehyde sulphoxylate, polyalkylenepolyamines, or ferrous or ferric ions, or azodi-isobutyronitrile; and anionic or nonionic emulsifiers, e.g. sodium, potassium or amine stearates, oleates, palmitates and myristates; sodium or potassium lauryl sulphates or myristyl sulphates; sodium dodecylbenzene sulphonate; sodium alkylnaphthalene sulphonates and sodium dioctylsulphosuccinate. Polymerization may be terminated prior to completion by the addition of a catalyst inactivator, and the latex freed from residual monomer by steam distillation. Non-colloidal solid matter in the latex may be removed by filtration or centrifugation. Examples describe the formation of latices by the copolymerization of sodium styrene sulphonate with (2, 35, 36, 38-40, 44 and 46) styrene and butadiene; (4) methyl methacrylate and 2-ethylhexyl acrylate; (5) methyl methacrylate, 2-ethylhexyl acrylate and vinyl acetate; (6-28, 33 and 34) styrene and butadiene; (29-32 and 45) butadiene and acrylonitrile; (37) vinyl toluene and butadiene; (41 and 42) styrene, butadiene and acrylonitrile; (43) styrene; (55) vinyl toluene and butadiene; (56) vinyl xylene and butadiene; (57) chlorostyrene; (58) dichlorostyrene; (59) vinyl naphthalene; (60) styrene and isoprene; (61) styrene, butadiene, acrylonitrile, methacrylic acid and divinyl benzene; (62) vinyl toluene, butadiene and methyl isopropenyl ketone; and (63) vinyl acetate and vinyl chloride: of sodium paravinyl benzyl sulphonate with (1) styrene and butadiene: of styrene and butadiene with (47) potassium para-vinylbenzyl sulphonate; (48) calcium paravinyl benzyl sulphonate; (49) ammonium paravinyl benzyl sulphonate; (50) triethyl-ammonium paravinyl benzyl sulphonate; (51) potassium styrene sulphonate; (52) calcium styrene sulphonate; (53) ammonium styrene sulphonate; (54) triethylammonium styrene sulphonate; (64) sodium ar-methyl styrene sulphonate; and (65) sodium ar-chloro styrene sulphonate. The latices may be used in the formation of films and coatings, and for impregnating fabrics, e.g. for making box toes and counters for shoes.
GB31375/60A 1959-09-23 1960-09-12 Synthetic latexes comprising ar-monovinyl aromatic sulphonic acid salt copolymers Expired GB895033A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US84170259A 1959-09-23 1959-09-23

Publications (1)

Publication Number Publication Date
GB895033A true GB895033A (en) 1962-04-26

Family

ID=25285506

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31375/60A Expired GB895033A (en) 1959-09-23 1960-09-12 Synthetic latexes comprising ar-monovinyl aromatic sulphonic acid salt copolymers

Country Status (3)

Country Link
DE (1) DE1445333B2 (en)
GB (1) GB895033A (en)
NL (2) NL256198A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034020A1 (en) * 1980-01-31 1981-08-19 Exxon Research And Engineering Company Sulphonated co- and terpolymer
US4525522A (en) * 1982-09-13 1985-06-25 Exxon Research And Engineering Co. Drilling fluids based on sulfonated thermoplastic polymers having improved low temperature rheological properties
EP0295402A2 (en) * 1987-04-30 1988-12-21 Nitto Denko Corporation Latex for immobilization of physiologically active substance and latex reagent using the latex
US5166077A (en) * 1987-04-30 1992-11-24 Nitto Denko Corporation Latex for immobilization of physiologically active substances for immuno nephelometry
CN111234084A (en) * 2020-01-10 2020-06-05 江苏利思德新材料有限公司 Vinyl chloride copolymer emulsion for water-based anticorrosive paint and preparation method and application thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114797800B (en) * 2022-04-19 2023-02-07 江苏贝美医疗科技有限公司 Adsorbent for removing toxin in body of uremia patient and preparation method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034020A1 (en) * 1980-01-31 1981-08-19 Exxon Research And Engineering Company Sulphonated co- and terpolymer
EP0096771A1 (en) * 1980-01-31 1983-12-28 Exxon Research And Engineering Company A sulphonated terpolymer
US4525522A (en) * 1982-09-13 1985-06-25 Exxon Research And Engineering Co. Drilling fluids based on sulfonated thermoplastic polymers having improved low temperature rheological properties
EP0295402A2 (en) * 1987-04-30 1988-12-21 Nitto Denko Corporation Latex for immobilization of physiologically active substance and latex reagent using the latex
EP0295402A3 (en) * 1987-04-30 1989-02-15 Nitto Denko Corporation Latex for immobilization of physiologically active substance and latex reagent using the latex
US5166077A (en) * 1987-04-30 1992-11-24 Nitto Denko Corporation Latex for immobilization of physiologically active substances for immuno nephelometry
CN111234084A (en) * 2020-01-10 2020-06-05 江苏利思德新材料有限公司 Vinyl chloride copolymer emulsion for water-based anticorrosive paint and preparation method and application thereof

Also Published As

Publication number Publication date
DE1445333A1 (en) 1968-11-21
NL121289C (en)
NL256198A (en)
DE1445333B2 (en) 1973-02-22

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