GB889297A - Improvements in and relating to the separation of a gaseous mixture of hydrocarbons into components - Google Patents
Improvements in and relating to the separation of a gaseous mixture of hydrocarbons into componentsInfo
- Publication number
- GB889297A GB889297A GB6118/58A GB611858A GB889297A GB 889297 A GB889297 A GB 889297A GB 6118/58 A GB6118/58 A GB 6118/58A GB 611858 A GB611858 A GB 611858A GB 889297 A GB889297 A GB 889297A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrocarbons
- ethylene
- stage
- washing
- conditions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/09—Purification; Separation; Use of additives by fractional condensation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/005—Processes comprising at least two steps in series
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Ethylene is separated from a mixture thereof with higher hydrocarbons, e.g. as obtained by the pyrolysis of hydrocarbons and containing, for example, 10-20% of ethylene by compressing to liquefy the normally liquid hydrocarbons, contacting the remaining gas with a hydrocarbon oil washing liquid boiling below 200 DEG C. to dissolve out hydrocarbons of 3 or more carbon atoms and dissolving ethylene from the residual gas with a solution containing a salt of monovalent copper. The condensation by compression may be regulated to condense C4 hydrocarbons also, conditions at this stage preferably being 10-50 atmospheres gauge and 15 DEG -50 DEG C. The washing oil used in the second stage preferably boils in the range 75 DEG -200 DEG C. and may be a fraction of liquid hydrocarbons obtained in the pyrolysis, e.g. the product from the first stage of the separation; hexane, heptane, octane, decane, undecane (each being normal or branched chain); benzene, toluene, xylene, ethylbenzene, cymene, cumene, diisopropyl benzene, pseudocumene, or mesitylene. The dissolved hydrocarbons may be recovered by reducing the pressure and this is preferably done in stages, the product from the first pressure reduction containing some ethylene being recycled to join the feed to the separation process first (compression) stage. The cuprous salt solution used in the final stage may be acid, neutral or basic and may contain hydrochloric acid, ammonia or organic nitrogen bases such as piperidine, pyridine, ethylene diamine or monoethanolamine. Conditions of 0 DEG -30 DEG C. and 10-25 atmospheres gauge may be used. The ethylene is recovered by lowering the pressure and/or raising the temperature, e.g. under conditions of 0,1-2 atmospheres (absolute) and 30 DEG -70 DEG C. Sulphur compounds should preferably be removed before the third stage, e.g. by washing with ethanolamine or caustic soda and acetylenes are preferably removed by selective hydrogenation. Specification 855,133 is referred to.ALSO:Ethylene is separated from a mixture thereof with higher hydrocarbons, e.g. as obtained by the pyrolysis of hydrocarbons and containing, for example, 10%-20% of ethylene, by compressing to liquefy the normally liquid hydrocarbons, contacting the remaining gas with a hydrocarbon oil washing liquid boiling below 200 DEG C. to dissolve out hydrocarbons of 3 or more carbon atoms and dissolving ethylene from the residual gas with a solution containing a salt of monovalent copper. The condensation by compression may be regulated to condense C4 hydrocarbons also, conditions at this stage preferably being 10-50 atmospheres gauge and 15 DEG C.-50 DEG C. The washing oil used in the second stage preferably boils in the range 75 DEG C.-200 DEG C. and may be a fraction of the liquid hydrocarbons obtained in the pyrolysis, e.g. the p product from the first stage of the separation; hexane, heptane, octane, decane, undecane (each being normal or branched chain); benzene, toluene, xylene, ethylbenzene, cymene, cumene, di-isopropyl benzene, pseudo-cumene, or mesitylene. The dissolved hydrocarbons may be recovered by reducing the pressure and this is preferably done in stages, the product from the first pressure reduction containing some ethylene being recycled to join the feed to the separation process first (compression) stage. The cuprous salt solution used in the final stage may be acid, neutral or basic and may contain hydrochloric acid ammonia or organic nitrogen bases such as piperidine pyridine, ethylene diamine or monoethanolamine. Conditions of 0 DEG C-30 DEG C. and 10-25 atmospheres gauge may be used. The ethylene is recovered by lowering the pressure and/or raising the temperature, e.g. under conditions of 0.1-2 atmospheres (absolute) and 30 DEG C.-70 DEG C. Sulphur compounds should preferably be removed before the third stage e.g. by washing with ethanolamine or caustic soda and acetylenes are preferably removed by selective hydrogenation. Specification 855,133 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE889297X | 1957-02-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB889297A true GB889297A (en) | 1962-02-14 |
Family
ID=6834477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB6118/58A Expired GB889297A (en) | 1957-02-26 | 1958-02-25 | Improvements in and relating to the separation of a gaseous mixture of hydrocarbons into components |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB889297A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4169506A (en) * | 1977-07-15 | 1979-10-02 | Standard Oil Company (Indiana) | In situ retorting of oil shale and energy recovery |
EP3026101A1 (en) * | 2014-11-26 | 2016-06-01 | Borealis AG | Wash oil for use as an antifouling agent in gas compressors |
-
1958
- 1958-02-25 GB GB6118/58A patent/GB889297A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4169506A (en) * | 1977-07-15 | 1979-10-02 | Standard Oil Company (Indiana) | In situ retorting of oil shale and energy recovery |
EP3026101A1 (en) * | 2014-11-26 | 2016-06-01 | Borealis AG | Wash oil for use as an antifouling agent in gas compressors |
WO2016083290A1 (en) * | 2014-11-26 | 2016-06-02 | Borealis Ag | Wash oil for use as an antifouling agent in gas compressors |
CN107109308A (en) * | 2014-11-26 | 2017-08-29 | 博里利斯股份有限公司 | It is used as the washing oil of anti-fouling agent in gas compressor |
JP2017538863A (en) * | 2014-11-26 | 2017-12-28 | ボレアリス アーゲーBorealis Ag | Cleaning oil for use as an anti-fouling agent in a gas compressor |
RU2673662C1 (en) * | 2014-11-26 | 2018-11-29 | Бореалис Аг | Washing oil, which is intended for use as a means against the formation of sediments in gas compressors |
EP3224339B1 (en) | 2014-11-26 | 2019-01-02 | Borealis AG | Wash oil for use as an antifouling agent in gas compressors |
CN107109308B (en) * | 2014-11-26 | 2020-03-27 | 博里利斯股份有限公司 | Wash oil as anti-fouling agent in gas compressors |
US10731093B2 (en) | 2014-11-26 | 2020-08-04 | Borealis Ag | Wash oil for use as an antifouling agent in gas compressors |
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