GB861971A - Improvements in or relating to polyepoxide-thermoplastic polymer compositions - Google Patents
Improvements in or relating to polyepoxide-thermoplastic polymer compositionsInfo
- Publication number
- GB861971A GB861971A GB27294/57A GB2729457A GB861971A GB 861971 A GB861971 A GB 861971A GB 27294/57 A GB27294/57 A GB 27294/57A GB 2729457 A GB2729457 A GB 2729457A GB 861971 A GB861971 A GB 861971A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxidized
- oil
- radiation
- sheets
- polyepoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4064—Curing agents not provided for by the groups C08G59/42 - C08G59/66 sulfur containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4071—Curing agents not provided for by the groups C08G59/42 - C08G59/66 phosphorus containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
- C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Fertilizers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Polyethers (AREA)
Abstract
Substantially insoluble, infusible resin compositions are produced by subjecting to high-energy ionizing radiation a mixture of a polyepoxide and a thermoplastic polymer of the type which is normally degraded by ionizing radiation. Suitable polyepoxides are epoxidized oils, e.g. epoxidized safflower seed, soyabean, or linseed oil. Bisphenol epihalohydrin type condensates may also be used. Thermoplastic polymers mentioned are polyvinyl chloride, polyvinylidene chloride and cellulose nitrate. Types of radiation which may be employed are high-energy electrons, X-rays, or g -rays. In the example, compositions of polyvinyl chloride, stabilizer, lubricant and epoxidized soyabean oil were formed into sheets and irradiated with electrons. Compared with similar sheets having dioctyl phthalate or epoxidized acetylated monoglyceride of lard oil in place of the epoxidized soya bean oil, the sheets showed higher melting-point and increased stiffness indicative of cross-linking. If desired, some flexibility may be maintained in spite of the cross-linking by adding plasticizers, e.g. for vinyl resins, dioctyl phthalate, tricresyl phosphate, or di-isooctyl adipate. Fillers, pigments and other inert materials may also be added. Different faces of an object may be successively irradiated to aid penetration of the radiation.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US607256A US2964454A (en) | 1956-08-31 | 1956-08-31 | Improvements in irradiation polymerization |
US625250A US2964484A (en) | 1956-11-30 | 1956-11-30 | Cross-linked reaction product of an epoxidized fatty acid ester and polyvinyl halide or cellulose nitrate |
US651161A US3042692A (en) | 1956-11-30 | 1957-04-08 | Epoxy ether polyamides |
US877134XA | 1957-04-10 | 1957-04-10 | |
US651822A US3035069A (en) | 1956-11-30 | 1957-04-10 | Treatment of epoxy fatty compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB861971A true GB861971A (en) | 1961-03-01 |
Family
ID=62527879
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB43001/59A Expired GB877134A (en) | 1956-08-31 | 1957-08-29 | Improvements in or relating to polyethers |
GB27294/57A Expired GB861971A (en) | 1956-08-31 | 1957-08-29 | Improvements in or relating to polyepoxide-thermoplastic polymer compositions |
GB43003/59A Expired GB877136A (en) | 1956-08-31 | 1957-08-29 | Improvements in or relating to polyesters |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB43001/59A Expired GB877134A (en) | 1956-08-31 | 1957-08-29 | Improvements in or relating to polyethers |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB43003/59A Expired GB877136A (en) | 1956-08-31 | 1957-08-29 | Improvements in or relating to polyesters |
Country Status (1)
Country | Link |
---|---|
GB (3) | GB877134A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003022904A1 (en) * | 2001-09-12 | 2003-03-20 | Dow Global Technologies Inc. | Network polymers comprising epoxy-terminated esters |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB969041A (en) * | 1961-10-11 | 1964-09-09 | Ciba Ltd | Esters containing both epoxide and oxetane groups, their production and their uses |
CA2130113A1 (en) * | 1992-04-02 | 1993-10-14 | Shanti Swarup | Epoxide-phosphorous-containing acids-cyclic anhydride reaction products and their use in coating compositions |
EP1797057B1 (en) | 2004-06-25 | 2018-08-29 | Pittsburg State University | Modified vegetable oil-based polyols |
DE102004031787A1 (en) | 2004-07-01 | 2006-01-26 | Cognis Deutschland Gmbh & Co. Kg | Viscosity reducer for high-viscosity polyols |
CN104497295B (en) * | 2014-12-16 | 2017-01-11 | 中国林业科学研究院林产化学工业研究所 | Vegetable-fat anionic polymer surfactant and preparation method thereof |
-
1957
- 1957-08-29 GB GB43001/59A patent/GB877134A/en not_active Expired
- 1957-08-29 GB GB27294/57A patent/GB861971A/en not_active Expired
- 1957-08-29 GB GB43003/59A patent/GB877136A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003022904A1 (en) * | 2001-09-12 | 2003-03-20 | Dow Global Technologies Inc. | Network polymers comprising epoxy-terminated esters |
CN1326905C (en) * | 2001-09-12 | 2007-07-18 | 陶氏环球技术公司 | Network polymers comprising epoxy-terminated esters |
US7247684B2 (en) | 2001-09-12 | 2007-07-24 | Dow Global Technologies Inc. | Network polymers comprising epoxy-terminated esters |
KR100854544B1 (en) | 2001-09-12 | 2008-08-26 | 다우 글로벌 테크놀로지스 인크. | Network Polymers Comprising Epoxy-Terminated Esters |
Also Published As
Publication number | Publication date |
---|---|
GB877134A (en) | 1961-09-13 |
GB877136A (en) | 1961-09-13 |
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