GB859696A - Improvements in or relating to composite metal-polymer compositions - Google Patents

Improvements in or relating to composite metal-polymer compositions

Info

Publication number
GB859696A
GB859696A GB22089/59A GB2208959A GB859696A GB 859696 A GB859696 A GB 859696A GB 22089/59 A GB22089/59 A GB 22089/59A GB 2208959 A GB2208959 A GB 2208959A GB 859696 A GB859696 A GB 859696A
Authority
GB
United Kingdom
Prior art keywords
vanadium
metal
alkyl
trichloride
titanium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22089/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NAT LEAD CO
NL Industries Inc
Original Assignee
NAT LEAD CO
NL Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NAT LEAD CO, NL Industries Inc filed Critical NAT LEAD CO
Priority claimed from US58169A external-priority patent/US3300329A/en
Publication of GB859696A publication Critical patent/GB859696A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/20—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
    • H01F1/22—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
    • H01F1/24—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated
    • H01F1/26—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated by macromolecular organic substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/14—Polymerisation; cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/16—Metallic particles coated with a non-metal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62—Metallic pigments or fillers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F1/00—Shielding characterised by the composition of the materials
    • G21F1/02—Selection of uniform shielding materials
    • G21F1/10—Organic substances; Dispersions in organic carriers
    • G21F1/103—Dispersions in organic carriers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/20—Powder free flowing behaviour
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Power Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

The invention comprises a composition consisting of a metal, including boron, partly or wholly encapsulated by a polymer formed by polymerization of an olefinically unsaturated polymerizable hydrocarbon in situ on the surface of the metal. The composition may be made by treating a metal of Group Ib, II, III, IV, Va, VIa, VII or VIII with a catalyst representable (i) by the formula Rn\TiXm or (ii) the reaction product of catalytic mixtures of compounds representable by the formulae MX1p + R1 (z-x) M1Yx, wherein R is an alkyl or aryl radical which is linked to titanium by a C-Ti bond, X is an alkoxide or halide radical, n is 1 or 2 an m is 1, 2 or 3, the sum of m + n being 2, 3 or 4, M is a metal of Group IVa, Va, VIa, VIIa or VIII, X1 is a halide or alkoxide radical, p is the valency of M, R1 is an alkyl or aryl radical, Y is a halide radical, M1 is a metal or Group Ia, IIa, IIb or IIIb, x is 0, 1 or 2 and z is the valency of M1, and further treating the thustreated metal with an olefinically unsaturated polymerizable hydrocarbon comprising styrene, an alkyl-substituted styrene, ethylene, propylene, butadiene or isoprene. Exemplary of such metals which may be encapsulated are copper, magnesium, barium, mercury, boron, aluminium, yttrium, titanium, germanium, lead, tin, vanadium, chromium, molybdenum, manganese, iron, cobalt and nickel. The polymerization may be carried out in an inert diluent such as toluene. Catalysts of type (i) include dimethyltitanium dichloride, methyltitanium trichloride, dimethyltitanium monochloride, isopropyltitanium dichloride, phenyltitanium triisopropoxide, alphanaphthyl-titanium tributoxide, p-tolyltitanium tributoxide, p-anisyltitanium tributoxide, diphenyltitanium dibutoxide, isopropyltitanium tributoxide, dimethyltitanium diisopropoxide, methyltitanium monochloride, phenyltitanium monochloride and methyltitanium dibutoxide. Catalysts of type (ii) may comprise a compound such as zirconium tetrachloride, titanium tetrachloride, titanium trichloride, van adium dichloride, vanadium oxychloride, vanadium trifluoride, vanadium trichloride, vanadium oxydichloride, tantalum pentachloride, molybdenum trichloride, molybdenum pentachlordie, chromium trichloride, chromium difluoride, ferric chloride, manganese dichloride, vanadium oxyacetylacetonate, iron acetylacetonate, cobalt acetylacetonate, chromium acetylacetonate, manganese acetylacetonate, an alkyl vandate or an alkyl titanate together with an organometallic compound such as triethyl aluminium, butyl-lithium, amylsodium and phenylsodium, dimethylmagnesium, diethylmagnesium, diethylzinc, methylmagnesium bromide, butylmagnesium bromide, phenylmagnesium chloride, trimethylaluminium, triisobutylaluminium, tetraphenyltin and tetraphenyl-lead, trioctylaluminium tridodecylaluminium, dimethylaluminium bromide, diethylaluminium chloride, ethylaluminium dibromide, isobutylaluminium sesquichloride, dipropyl-aluminium iodide, diisobutylaluminium fluoride, diisobutylaluminium bromide, diethylaluminium hydride, diisobutylaluminium hydride, and complexes of such organometallic compounds, as for example, sodium aluminium tetrabutyl, lithium aluminium tetraoctyl and sodium aluminium triethylchloride.ALSO:A process for producing a metal-polymer composition comprises treating a metal of Group Ib, II, III, IV, Va, VIa, VII or VIII with a catalyst representable by the formula RnTiXm or with the reaction product of catalytic mixtures of compounds representable by the formulae MX1p + R1(z-x)M1Yx, wherein R is an alkyl or aryl radical which is linked to titanium by a C-Ti bond, X is an alkoxide or halide radical, n is 1 or 2 and m is 1, 2 or 3, the sum of m + n being 2, 3 or 4, M is a metal of Group IVa, Va, VIa, VIIa or VIII, X1 is a halide or alkoxide radical, p is the valency of M, R1 is an alkyl or aryl radical, Y is a halide radical, M1 is a metal of Group Ia, IIa, IIb or IIIb, x is 0, 1 or 2 and z is the valency of M1, and further treating the thus-treated metal with an olefinically unsaturated polymerizable hydrocarbon comprising styrene, an alkyl-substituted styrene, ethylene, propylene, butadiene or isoprene. Exemplary of such metals which may be encapsulated by the polymer, are copper, magnesium, barium, mercury, boron, aluminium, yttrium, titanium, germanium, lead, tin, vanadium, chromium, molybdenum, manganese, iron, cobalt and nickel. The polymerization may be carried out in an inert diluent such as toluene. The catalyst components which are specified and which are added to the metal include dimethyltitanium dichloride, methyltitanium trichloride, dimethyltitanium monochloride, isopropyltitanium dichloride, phenyltitanium triisopropoxide, alphanaphthyltitanium tributoxide, p-tolyltitanium tributoxide, p-anisyltitanium tributoxide, diphenyltitanium dibutoxide, isopropyltitanium tributoxide, dimethyltitanium diisopropoxide, methyltitanium monochloride, phenyltitanium monochloride, methyltitanium dibutoxide, zirconium tetrachloride, titanium tetrachloride, titanium trichloride, vanadium dichloride, vanadium oxychloride, vanadium trifluoride, vanadium trichloride, vanadium oxydichloride, tantalum pentachloride, molybdenum trichloride, molybdenum pentachloride, chromium trichloride, chromium difluoride, ferric chloride, manganese dichloride, vanadium oxyacetylacetonate, iron acetylacetonate, cobalt acetylacetonate, chromium acetylacetonate, manganese acetylacetonate, alkyl vanadates and alkyl titanates, the alkali metal alkyls or aryls such as butyllithium, amylsodium and phenylsodium, dimethylmagnesium, diethylmagnesium, diethylzinc, methylmagnesium bromide, butylmagnesium bromide, phenylmagnesium chloride, trimethylaluminium, triisobutylaluminium, tetraphenyltin and tetraphenyllead, trioctylaluminium, tridodecylaluminium, dimethylaluminium bromide, diethylaluminium chloride, triethylaluminium, ethylaluminium dibromide, isobutylaluminium sesquichloride, dipropylaluminium iodide, diisobutylaluminium fluoride, diisobutylaluminium bromide, diethylaluminium hydride, diisobutylaluminium hydride, and complexes of such organometallic compounds, as for example, sodium aluminium tetrabutyl, lithium aluminium tetraoctyl and sodium aluminium triethylchloride.
GB22089/59A 1958-07-09 1959-06-26 Improvements in or relating to composite metal-polymer compositions Expired GB859696A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74737158A 1958-07-09 1958-07-09
US58169A US3300329A (en) 1960-09-26 1960-09-26 Metal-polyolefin compositions and process for making same

Publications (1)

Publication Number Publication Date
GB859696A true GB859696A (en) 1961-01-25

Family

ID=26737318

Family Applications (3)

Application Number Title Priority Date Filing Date
GB929102D Active GB929102A (en) 1958-07-09
GB22089/59A Expired GB859696A (en) 1958-07-09 1959-06-26 Improvements in or relating to composite metal-polymer compositions
GB2842/61A Expired GB929101A (en) 1958-07-09 1961-01-24 Improvements in or relating to metal-polymer compositions

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB929102D Active GB929102A (en) 1958-07-09

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB2842/61A Expired GB929101A (en) 1958-07-09 1961-01-24 Improvements in or relating to metal-polymer compositions

Country Status (5)

Country Link
BE (2) BE580554A (en)
FR (1) FR1229343A (en)
GB (3) GB859696A (en)
LU (2) LU39846A1 (en)
NL (1) NL6514881A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3472812A (en) * 1968-01-17 1969-10-14 Monsanto Res Corp Ablation methods and materials
US4473672A (en) * 1981-04-09 1984-09-25 Imperial Chemical Industries Plc Polymer composition, production and use
EP0182280A2 (en) * 1984-11-16 1986-05-28 Siemens Aktiengesellschaft Filler based on metal powder cross-linked by means of plastics for the preparation of plastic compositions
FR2830367A1 (en) * 2001-10-01 2003-04-04 Transnucleaire NEUTRONIC SHIELDING AND SUB-CRITICALITY MAINTENANCE MATERIAL BASED ON INSATURE POLYESTER
US7399431B2 (en) 2002-10-25 2008-07-15 Cogema Logistics Material for neutron shielding and for maintaining sub-critically, process for its preparation and its applications

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3628986A (en) * 1969-08-22 1971-12-21 Exxon Research Engineering Co Water-repellent reduced iron ore
FR2441596A1 (en) * 1978-11-14 1980-06-13 Inst Khim Fiz An Sssr Porous material filled with polyolefin - prepd. by depositing catalyst in pores and then polymerising olefin monomer, used in concrete

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3472812A (en) * 1968-01-17 1969-10-14 Monsanto Res Corp Ablation methods and materials
US4473672A (en) * 1981-04-09 1984-09-25 Imperial Chemical Industries Plc Polymer composition, production and use
EP0182280A2 (en) * 1984-11-16 1986-05-28 Siemens Aktiengesellschaft Filler based on metal powder cross-linked by means of plastics for the preparation of plastic compositions
EP0182280A3 (en) * 1984-11-16 1988-01-20 Siemens Aktiengesellschaft Filler based on metal powder cross-linked by means of plastics for the preparation of plastic compositions
FR2830367A1 (en) * 2001-10-01 2003-04-04 Transnucleaire NEUTRONIC SHIELDING AND SUB-CRITICALITY MAINTENANCE MATERIAL BASED ON INSATURE POLYESTER
WO2003030183A2 (en) * 2001-10-01 2003-04-10 Cogema Logistics Neutron shielding material for maintaining sub-criticality based on unsaturated polymer
WO2003030183A3 (en) * 2001-10-01 2003-12-04 Cogema Logistics Neutron shielding material for maintaining sub-criticality based on unsaturated polymer
US7524438B2 (en) 2001-10-01 2009-04-28 Cogema Logistics Unsaturated polyester-based material for neutron-shielding and for maintaining sub-criticality
KR100901151B1 (en) * 2001-10-01 2009-06-04 꼬제마 로지스틱스 에스.아. Neutron shielding material for maintaining sub-criticality based on unsaturated polymer
US7399431B2 (en) 2002-10-25 2008-07-15 Cogema Logistics Material for neutron shielding and for maintaining sub-critically, process for its preparation and its applications

Also Published As

Publication number Publication date
LU37396A1 (en)
GB929101A (en) 1963-06-19
NL6514881A (en) 1966-01-25
FR1229343A (en) 1960-09-06
GB929102A (en)
BE580554A (en)
BE601325A (en)
LU39846A1 (en) 1961-05-02

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